U.S. patent number 3,693,750 [Application Number 05/073,890] was granted by the patent office on 1972-09-26 for composite metal structure useful in sound absorption.
This patent grant is currently assigned to Minnesota Mining and Manufacturing Company. Invention is credited to Philip D. Takkunen.
United States Patent |
3,693,750 |
Takkunen |
September 26, 1972 |
**Please see images for:
( Certificate of Correction ) ** |
COMPOSITE METAL STRUCTURE USEFUL IN SOUND ABSORPTION
Abstract
A composite metal structure, useful in sound absorption
applications, comprising a metal part having perforations or
recesses containing sintered porous powdered metal is made by
pressing said metal part with a mixture of powdered metal and
heat-fugitive binder to force said mixture into said perforations
or recesses, and then heating the assembly to volatilize the
burn-off said binder and sinter said powdered metal, the powdered
metal in the resulting structure being held in said perforations or
recesses by a metallurgically integral bond as well as mechanical
bond.
Inventors: |
Takkunen; Philip D. (Woodbury
Township, County of Washington, MN) |
Assignee: |
Minnesota Mining and Manufacturing
Company (St. Paul, MN)
|
Family
ID: |
22116410 |
Appl.
No.: |
05/073,890 |
Filed: |
September 21, 1970 |
Current U.S.
Class: |
428/558; 181/292;
210/496; 428/116; 428/555; 181/286; 210/510.1; 428/548 |
Current CPC
Class: |
B32B
15/043 (20130101); E04C 2/365 (20130101); B32B
3/12 (20130101); E04B 1/86 (20130101); B32B
2305/02 (20130101); B32B 2305/024 (20130101); Y10T
428/12097 (20150115); Y10T 428/24149 (20150115); Y10T
428/12028 (20150115); B32B 2307/102 (20130101); Y10T
428/12076 (20150115); E04B 2001/748 (20130101) |
Current International
Class: |
E04B
1/84 (20060101); E04C 2/34 (20060101); E04C
2/36 (20060101); E04B 1/86 (20060101); E04B
1/74 (20060101); E04b 001/86 (); B22f 007/04 () |
Field of
Search: |
;181/33G,33GA,42,50,36A,71,33HB
;29/182,182.1,182.2,182.3,182.5,182.7,182.8 ;210/496,510 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
|
|
|
|
|
|
|
935,119 |
|
Aug 1963 |
|
GB |
|
829,012 |
|
Feb 1960 |
|
GB |
|
Other References
"Acoustical-Impedance Characteristics of Sintered Stainless Steel,"
The Journal of the Acoustical Society of America, Volume 36, No. 5,
May 1964, pp. 811-815.
|
Primary Examiner: Ward, Jr.; Robert S.
Claims
What is claimed is:
1. A metal acoustical panel comprising a metal part having a
plurality of spaced apart perforations filled with porous bodies of
sintered powdered metal in the range of -20 to +325 mesh
metallurgically integral with the walls defining said
perforations.
2. The panel of claim 1, wherein said part is a sheet of wrought,
cast, or sintered powdered metal.
3. The panel of claim 2 wherein said bodies of sintered powdered
metal are integral with a sheet of porous sintered powdered metal
metallurgically integral by a sinter bond between the two
sheets.
4. The panel of claim 2 wherein said metal part is a wrought sheet
of stainless steel.
5. The panel of claim 2 wherein said powdered metal is powdered
stainless steel.
6. A metal acoustical panel comprising a solid metal base sheet, a
perforated metal sheet, a metal honeycomb structure interposed
between and bonded to said sheets, a face sheet of sintered
powdered metal sinter bonded to the top of said perforated metal
sheet, and porous bodies of sintered powder metal in the range of
-20 to +325 mesh integral with said face sheet and depending within
said perforations of said perforated sheet, said bodies being
metallurgically integral with the walls defining said
perforations.
7. The article of claim 1 wherein said sheet and bodies are made of
stainless steel.
Description
This invention relates to powder metallurgy. In another aspect, it
relates to the metalworking field in which metal parts are joined
together. In another aspect, it relates to a composite metal
structure useful as an acoustic or sound suppression structure. In
a further aspect it relates to a metal sound absorption structure
having a laminated configuration. And in a further aspect it
relates to a reinforced fluid permeable structure useful as a
filter, air bearing, air diffuser, and the like.
For a number of years now, increasing attention has been focused on
the abatement or suppression of sound or noise, such as that
emanating from aircraft engines. A variety of assemblies have been
proposed, evaluated, or used for that purpose. One such assembly is
a damped-resonator acoustical panel (see U.S. Pat. No. 3,166,149)
comprising a honeycomb or cellular core sandwiched or interposed
between a solid sound reflecting sheet and a perforated, sound
admitting layer or acoustic face sheet. Similar assemblies are
known where the acoustic face sheet is a perforated metal sheet, a
sintered woven metal screen, or is made of sintered metal fibers.
Though these prior art assemblies have a number of useful
applications, they do have some limitations, particularly a balance
of sound suppression and structural integrity when subjected to
severe stress and corrosive environments.
In the accompanying drawing, FIGS. 1, 2, and 3 are cross-sectional
views illustrating various embodiments of the composite metal
structures of this invention; FIG. 4 is a view in perspective and
partial section of a honeycomb sandwich panel made in accordance
with this invention; FIG. 5 is a cross-section of a portion of FIG.
4 showing details thereof; and FIG. 6 is a view like FIG. 5
illustrating a modification thereof.
Briefly, according to one aspect of this invention, a composite
metal structure useful for sound suppression applications is
provided, said structure comprising a metal part, such as a
stainless steel, having perforations or recesses containing a
porous body of sintered powdered metal. Such a structure can be
made by pressing the metal part with a mixture, preferably in the
form of a plastic mass, comprising powdered metal and heat-fugitive
binder, to force the mixture into said perforations or recesses,
and then heating the assembly to volatilize, burn-off, or otherwise
remove said binder and sinter said powdered metal. Such a structure
can be used as an acoustic face sheet to suppress or attenuate the
sound or noise emanating from the operation of the aircraft engines
or other noise generators. Such a structure has improved structural
integrity, particularly at the severe stress and corrosive
conditions encountered in or by aircraft.
The body of sintered powdered metal is held within said
perforations or recesses by a combination of metallurgically
integral bond and a mechanical bond, the assembly of the metal
sheet and sintered powdered metal within the perforations or
recesses being in effect a single or integral piece of metal. Such
a bond and structure is distinguishable over that disclosed in U.S.
Pat. No. 3,264,720 which discloses a porous powdered metal layer
bonded to a permeable metal sheet or screen.
The term "metallurgically integral" in this context means that
there is a solid state or interatomic diffusion between the
contiguous sintered powdered metal particles and between the
surface of the metal parts and powdered metal particles contiguous
therewith. At the juncture between the sintered powdered metal and
the metal part contiguous therewith, there will be a solid state
diffusion zone of the powdered metal and said metal part with the
balance of the sintered powdered metal between the adjoined metal
parts having a density less than that of the theoretical density of
the powdered metal, a uniform microporisity, and a grain structure
free of dendritic grains. The portion of the metal parts between
the perforations or recesses are free of dissimilar heat-affected
zones. The walls of the perforations or recesses, apart from their
metallurgical or sintered bonding to the body of sintered powdered
metal, constrain the latter body, such constraint being enhanced by
irregularities in the surfaces of said walls which generally are
inherent in the fabrication of the metal part. Such constraint, in
effect, is a mechanical bond. When the above described structure is
subjected to sound, the intensity of the sound is attenuated by
absorption in the structure.
The perforated or recessed metal part can be made of a variety of
metals commonly used in construction, such metals including iron,
nickel, cobalt, copper, chromium, and alloys thereof such as steels
(e.g., stainless steel), inconel, nichrome, and monel. Any metal or
alloy which can be sinter-bonded to powdered metal can be used to
fabricate the perforated or recessed metal part. Of course, the
metal part cannot have a melting point lower than the sintering
temperatures necessary to effect the sinter bond relied on in this
invention. Further, said metal part can be made wrought, cast, or
sintered powdered metal. The perforations or recesses in the metal
part can be obtained by punching or drilling operation or the like.
The walls of the perforations or recesses can be relatively smooth
or irregular.
The stainless steels used for the metal part can be AISI stainless
steels, such as those of the 300 series, e.g., types 301, 302, 304,
305, 316, and 347, and precipitation hardening stainless steel,
e.g., PH 15-7 Mo, and nickel based alloy, e.g., Inconel-625.
The powdered metals used in the practice of this invention, in
addition to the stainless steels mentioned above, representatively
include known sinterable metals used in conventional powder
metallurgy such as iron, copper, nickel, berylium, chromium,
cobalt, molybdenum, tantalum, titanium, tungsten, and alloys
thereof. The stainless steel metal powders disclosed in copending
application, Ser. No. 743,588, now U.S. Pat. 3,620,690 will be
particularly useful because of the enhanced bond strength and
corrosion resistance which can be obtained. Precipitation hardening
stainless steel, e.g., PH-15-7 Mo, and nickel based alloys, e.g.,
Inconel- 625 can also be used. The non-refractory metals and alloys
are preferred as powdered metals because of the lower sintering
temperatures which can used. The powdered metal to be used will
depend upon the particular composition of the perforated or
recessed metal part, the desired sintering temperature, and the
degree of porosity desired for the sintered body of powdered metal.
Although the compositions of the metal part and powdered metal may
differ, it will be desirable if they are the same where
differential thermal expansion or galvanic corrosion is to be
avoided.
The mesh size of the powdered metal used in the practice of this
invention can vary and generally the particular powdered metal used
will have a range of particle size. Generally, the smaller the mesh
size, the greater the density of the sintered body of powdered
metal in the perforations or recesses, and hence the greater the
acoustical resistance. It may be desirable to use blends of two or
more powdered metal products to obtain a desirable balance of
acoustical and strength characteristics. For example, powdered
metal with mesh sizes in the range of -20+325 can be used, such as
-200+325, -100+200, -50+100, -20+50 or blends thereof (The term
"mesh" referred to herein means mesh size according to the U.S.
Standard Sieve system).
In preparing the green mixture of powdered metal and binder, the
powdered metal of desired mesh is blended with an organic
heat-fugitive binder, such as those disclosed in U.S. Pat. Nos.
2,593,943, 2,709,651, 2,851,354, and 3,158,532; the preferred
binder is methyl cellulose (e.g. Methocel 60-HG, 4,000 cps).
Various volatilizable vehicles can be used in conjunction with
these binders, such as water, as well as various plasticizers, such
as glycerin. The blending can be carried out in a conventional
manner in various types of commercially available mixers, blenders,
tumblers, and the like, care being taken to ensure that the blend
is homogeneous and the components well dispersed. The resulting
blend will be in the nature of a plastic mass or dough and will be
similar in consistency to that of modeling clay. The plastic mass
can be shaped in a rubber mill, calendered, or knife-coated to the
desired thickness to form a green sheet having a rubbery, pliable
nature. The green sheet can be pressed into the perforated or
recessed metal part so that the green material is in effect
extruded into the perforations or recesses to a desired degree.
This can be accomplished by roll pressing, ram pressing, isostatic
pressing or the like, depending on the shape of the metal part.
Alternatively, where the metal part is in the form of a sheet, the
plastic mass can be directly rolled into the perforations or
recesses, for example, by simultaneously feeding the plastic means
and metal part sheet into the nip of oppositely rotating rolls.
Another method is to spread powdered metal particles coated with
binder (as disclosed in U.S. Pat. Nos. 2,851,354 and 2,845,346)
over the perforated or recessed metal part, and then pass the
coated metal part through rollers to cause the perforations or
recesses to become filled with the green mixture. All of these
various modes of filling the perforations or recesses can be
carried out under heat, e.g., to facilitate release of the
resulting pressed article from the equipment used to carry out the
operation.
The assembly of the perforated or recessed metal part and green
material is heated to remove binder and volatilizable component,
such as water and plasticizer. The structure is then sintered under
vacuum or a suitable atmosphere, such as a reducing atmosphere like
hydrogen or dissociated ammonia. Sintering atmosphere, temperature,
and duration of sintering will depend upon the particular powdered
metals used, the selection of these conditions being within the
skill the art. In the case of where stainless steel is used as the
powdered metal, a hydrogen or dissociated ammonia atmosphere with a
dew point of -40.degree. F. or lower and sintering temperatures in
the range of 1,200.degree. to 1,400.degree. C., preferably
1,250.degree. to 1,350.degree. C. will be suitable, and the
duration of sintering will usually be from 10 minutes to 2 or 3
hours.
Referring now to the drawing and initially to FIG. 1, a metal part
1 is shown having a perforation defined by walls 2 (the part will
have a plurality of such perforations but only one is shown in the
drawing for purposes of brevity). Said metal part can be made of
wrought metal, cast metal or relatively dense sintered powdered
metal. Disposed within perforation 2 is a porous body 3 of sintered
powdered metal, the individual contiguous particles being sintered
together and the surface of the particles contiguous with the walls
2 of the perforation also sintered thereto. The density of the
sintered particles within perforation 2 and the extent to which the
body of sintered particles fills the perforations can vary,
depending upon the degree of acoustical resistance desired. FIG. 2
shows a modification where the upper surface 5 of the metal part 1
is sinter bonded to a porous layer 6 of sintered powdered metal,
this layer of course being integral with the body 3 of sintered
powdered metal within perforation 2. FIG. 3 shows another
modification where the body 3 of sintered powdered metal is
disposed within recess or cavity 7 and is integral with a layer 8
of porous sintered powdered metal which is sinter-bonded to the top
surface 9 of metal part 10. Other embodiments, not shown in the
interest of brevity include a structure, like FIG. 2, except that a
porous layer of sintered powder metal is also sinter-bonded to the
lower surface of the metal part, the body of sintered powdered
metal within the perforations being integral with the top and
bottom layers of sintered powdered metal. As mentioned
hereinbefore, the porous body of sintered powdered metal within the
perforations or recesses, is sinter-bonded to the walls defined by
said perforations or recesses and are further held therein by
reason of an inherent mechanical bond.
Referring now to FIGS. 4 and 5, the acoustical panel illustrated
there comprises a hard surfaced, substantially air impervious sound
reflecting layer 21, made for example of stainless steel, and a
honeycomb or cellular core 22, which are like that disclosed in
said U.S. Pat. No. 3,166,149. Bonded to the top of said honeycomb
is a sheet 23, made of stainless steel for example, having a
plurality of perforations defined by walls 24. Each honeycomb cell
will have generally a plurality of perforations 24 adjacent its
upper end, though only one such perforation is shown for purposes
of brevity. Surmounting perforated sheet 23 is a porous sintered
powdered metal sheet 25, made of stainless steel powder for
example, which is sintered to or metallurgically integral with
sheet 23, the underside of the powdered metal sheet having a
plurality of integral depending projections 26 which depend within
the perforations and are bonded to the walls 24 thereof by
metallurgically integral sinter bond. These projections are like
the porous body 3 of sintered powdered metal shown in FIG. 2. The
bonding of the sound reflecting sheet 21 and the perforated sheet
23 to the bottom and top of the honeycomb as indicated by reference
Nos. 27 and 28 can be conventional or can be accomplished as
disclosed in copending application FN 27,109, filed on even data
herewith, such a bond being made of sintered powdered metal.
FIG. 6 illustrates a modification of the honeycomb embodiment shown
in FIGS. 4 and 5, these embodiments being essentially the same
except that in FIG. 6 the honeycomb structure lacks a surface layer
of powdered metal, and though the porous bodies 29 of sintered
powdered metal in FIG. 6 are shown as substantially fitting the
perforations, they can fill only a portion thereof, e.g., as low as
10 percent.
As an example of this invention, a mixture of 95 parts by weight of
AISI type 347L stainless steel powder (-50+100 mesh), 5 parts by
weight of powdered molybdenum (3-4 microns), and 5 parts by weight
of methyl cellulose (Methocel 60 HG) is mixed with a sufficient
amount of a 15 weight percent aqueous solution of glycerin to
provide 180 cc of said solution per kilogram of the powdered
metals. The resulting green mixture is of a plastic consistency and
it is rolled on a heated rubber mill, one roll running at 40
surface ft./min. at 140.degree. F. and the other roll running at 30
surface ft./min. at 150.degree. F., to produce a green sheet of
0.015 inch thickness.
A perforated stainless steel sheet (AISI 347L, 0.018 inch thick,
having 0.050 inch holes on 0.093 inch centers) is degreased and
grit-blasted. If desired, the sheet can be coated with powdered
metal, e.g., stainless steel or molybdenum with a particle size of
3 to 10 microns, for example by spraying the sheet with an aerosol
spray adhesive and then spreading the powdered metal over the
sprayed surface. Alternatively, the stainless steel sheet can be
vapor coated with tin. The layer of powdered metal or vapor coated
metal will enhance the subsequently formed sinter bond, due to
increased surface area and/or chemical activity.
The green sheet and the perforated stainless steel sheet are
pressed together, for example with a hydraulic ram at 15 TSI with a
platen temperature of 200.degree. F. or by means of simultaneously
rolling the two sheets with heated rollers, as discussed above,
such that the perforations are filled with the green material. The
extent of filling the perforation can vary, e.g., 10 to 100 volume
percent, depending upon the consistency of the green material,
pressing conditions, and the degree of acoustical resistance
desired. The overall thickness of the perforated sheet-green sheet
can vary, and may be, for example, 0.025 inch to 0.030 inch.
The assembly is then heated in air to volatilize the water
component in the green material and then heated to burn-off the
binder (e.g., at 600.degree. F. for 1 hours). The assembly is then
heated in hydrogen at 1,350.degree. C. (dew point -60.degree. F.)
for 1 hour.
For acoustic face sheets made as described above, as well as those
made from perforated stainless steel with 0.077 inch holes and 45
percent open area, are shown below:
45% open area 26% open area acoustic sheet acoustic sheet with
0.077" 0.050" perforations perforations
__________________________________________________________________________
Acoustic properties: Rayl no. (at 20 cm/sec) 30-70 30-70 NLF*
2.5-2.9 3.2-3.9 Mechanical properties: Tensile strength (KSPI)**
18-21 30-32 Young's modulus (10.sup.6 PSI)** 4.8-8.0 9.8-12.0
Elongation (%) 18-21 15-23 Density (lb/ft.sup.2)*** 0.84 0.81
__________________________________________________________________________
The strength of the sinter bond between the bodies of sintered
powder metal within the perforation will vary and depend on the
size of the perforations, the extent of penetration of the green
material into the perforations, the extent of diffusion (which, in
turn, depends on particle size, sintering conditions, and metal
compositions used). A suitable test for strength is to insert a rod
into the perforations and determine the amount of force necessary
to dislodge the sintered bodies from the perforations. For the
particular examples given in the above table, a force in excess of
2,000 psi, and in some cases in excess of 6,000 psi, was necessary
to dislodge the bodies.
As a modification of the acoustic panel described above and
illustrated in FIGS. 4 and 5, the top of the webs of honeycomb can
be bonded to a sheet of sintered powdered metal which in turn is
sinter-bonded at its upper surface to a sheet of perforated metal,
the perforations of which contain the porous bodies of sintered
powdered metal integral to the sheet of sintered powdered metal
bonded to the honeycomb.
Various modifications and alterations of this invention will become
apparent to those skilled in the art without departing from the
scope and spirit of this invention.
* * * * *