U.S. patent number 3,691,271 [Application Number 05/008,721] was granted by the patent office on 1972-09-12 for sanitary napkin having homogeneously distributed microcapsules filled with delay releasable bactericidal and fungicidal deodorant.
Invention is credited to Charles Zviak, 1, Rue Soldini, FR, Gregoire Kalopissis, 65, Rue Vauvenargues, Roger Charle, 61, Avenue Gavignot.
United States Patent |
3,691,271 |
|
September 12, 1972 |
SANITARY NAPKIN HAVING HOMOGENEOUSLY DISTRIBUTED MICROCAPSULES
FILLED WITH DELAY RELEASABLE BACTERICIDAL AND FUNGICIDAL
DEODORANT
Abstract
A sanitary napkin made of cellulose batting or layers of paper
or cotton absorbent fabric and a multiplicity of individual
microcapsules enveloping a deodorant agent. The microcapsules are
homogeneously distributed in the cellulose batting or in
alternating layers on the fabric to effect a delayed release of the
deodorant therefrom, the walls of said microcapsules being
permeable or soluble on contact with the fluid associated with
menstrual discharge. 4 Claims, No Drawings
Inventors: |
Roger Charle, 61, Avenue
Gavignot (Soisy-sous-Montmorency), FR (N/A), Charles
Zviak, 1, Rue Soldini (Franconville, FR), Gregoire
Kalopissis, 65, Rue Vauvenargues (Paris, FR) |
Family
ID: |
19725912 |
Appl.
No.: |
05/008,721 |
Filed: |
February 4, 1970 |
Foreign Application Priority Data
Current U.S.
Class: |
424/431; 162/161;
424/47; 424/65; 424/68; 424/69; 428/402.2; 428/402.22; 604/380;
604/359 |
Current CPC
Class: |
A61K
8/0208 (20130101); A61L 15/46 (20130101); A61K
8/11 (20130101); A61Q 15/00 (20130101); A61L
2300/404 (20130101); A61L 2300/622 (20130101); Y10T
428/2987 (20150115); A61K 2800/412 (20130101); Y10T
428/2984 (20150115); A61L 2300/408 (20130101) |
Current International
Class: |
A61L
15/16 (20060101); A61L 15/46 (20060101); A61k
007/00 () |
Field of
Search: |
;424/14,16,28,65-69,47
;252/316 ;15/104.93 ;401/132 ;128/270,284,285 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
J M. Miles et al., J. Soc. Cosmet. Chem. 22:655-666 (Sept. 17,
1971) .
"Encapsulated Perfumes in Aerosol Products.".
|
Primary Examiner: Shep K. Rose
Claims
1. A sanitary napkin consisting essentially of a body of an
absorbent material of cellulose batting or layered paper or cotton
fabric and a multiplicity of individual microcapsules enveloping
effective amounts of a bactericidal and fungicidal deodorant agent,
said microcapsules being homogeneously distributed in said
cellulose batting or in alternating layers on said paper or cotton
fabric, the size of each of said microcapsules ranging from 30-500
microns, the walls of said microcapsules being permeable or soluble
on contact with the fluid associated with menstrual discharge
whereby the release of said deodorant agent from said microcapsules
in said sanitary napkin is delayed until contact with sufficient
amounts of said fluid to permeate or solubilize the walls of said
homogeneously distributed microcapsules, said walls of said
microcapsules being made from a material selected from the group
consisting of gelatin, ethyl cellulose, cellulose acetophthalate,
polyvinyl alcohol and polyvinyl acetate and the density of said
microcapsules being essentially equal to the density of said body
of
2. The sanitary napkin of claim 1, wherein the walls of the
microcapsules
3. The sanitary napkin of claim 1, wherein the deodorant agent
includes
4. The sanitary napkin of claim 1, wherein the microcapsules have a
size ranging from 30 - 50 microns.
Description
The present invention relates to a treating cosmetic composition,
preferably a deodorant composition, in which the deodorant effect
is delayed with reference to the moment of application of the
composition, the effect appearing only after perspiration.
Deodorant compositions used for the care of the body, whose
deodorant effect is immediate after application are already known,
but it is obvious that such compositions cannot give entire
satisfaction. In the case in which the composition is used
preventatively, the deodorant effect is exerted as soon as it is
applied with gradually diminishing effectiveness. Moreover, and on
the other hand, application of such a composition at the desired
moment also presents obvious difficulties. It must be added that
there is the necessity of using the active product in excess at the
time of application of the composition, or else there must be
numerous applications with all the bother that this entails.
The present invention is intended to obviate the above mentioned
difficulties, and especially to avoid occurrence of the deodorant
effect from the moment of application of the deodorant cosmetic
composition.
The present invention thus relates to a new deodorant composition
containing the active elements of an ordinary deodorant
composition, the said elements only acting at the time of
perspiration or after a certain lapse of time after sufficient
perspiration.
The present invention also relates to the process of deferred
release effected in situ after perspiration, at the location of
application of the cosmetic composition.
The present invention also relates to the process of preparation of
the above mentioned cosmetic deodorant compositions.
According to the invention, it has been discovered that deferred
activity of the present cosmetic composition as well as an
improvement on its effectiveness can be attained if the active
deodorant component is physically separated from the vehicle
constituted by the rest of the cosmetic composition, until the
occurrence of perspiration. This is accomplished by the known
technique of microencapsulation wherein the active component,
divided into small particles, is surrounded by a suitable
envelope.
The process for preparing the microcapsules which are separately
obtained does not constitute part of the invention.
According to the present invention, the "support" phase of the
deodorant composition is constituted by the usual vehicle of these
compositions, the said "support" phase being cellulose batting or
any absorbent fabric on which the "treating" phase is deposited.
The "treating" phase which is constituted by microencapsulated
compounds or agents contained in the above mentioned vehicle causes
the perspiration odors or other odors to disappear at the end of a
certain period after occurrence of the said odors.
It has been discovered surprisingly that the setting off of the
deodorant activity can be ensured in that a deodorant product is
used which is contained in microcapsules C whose envelopes E are
soluble in water or permeable to water deriving from sweat, or
soluble in mixtures of water and other solvents, or destroyed by
microorganisms that develop after perspiration. Destruction of
envelopes occurs moreover in proportion to the degree of
sweating.
The use of the solubility or permeability of envelopes E in water
as well as the destruction of these envelopes by microorganisms
involves simple forms and preferably use of the mechanism of
release of the present invention.
A modification of the release process consists in attaining or
accelerating the destruction of envelope E by a mixture of water
and another suitable agent. In this case, capsules C contain in
addition to the deodorant composition, e.g., a lower alcohol such
as ethanol or a polysaccharide, envelope E being sufficiently
permeable to the water of perspiration. When there is used as
compound constituting membrane E a copolymer of styrene and
completely hydrolyzed maleic acid, for example, the water of
perspiration penetrates through envelope E of the capsule in which
it constitutes a mixture, e.g., water-ethanol which for a content
of about 50:50 readily dissolves the said envelope E. As a result,
after a certain interval and depending upon the abundance of
perspiration, a larger or smaller number of capsules release the
deodorant product, in a way that is accelerated by the fact that
more and more rapidly the optimal proportions for the solvent
mixture are reached.
Envelope E of microcapsules C which contain the deodorant
compositions are constituted by multifarious compounds, on
condition that they be sufficiently dissolved or permeable in
contact with the perspiration water, taking into account the pH
thereof, or on condition that they be destroyed by microorganisms
also developing in the course of perspiration.
The compounds forming envelopes E are selected especially from the
following: gelatin, ethyl cellulose, cellulose acetophthalates,
treated or untreated polyvinyl alcohols.
In general microcapsules are used whose sizes range from 30 to 500
microns, preferably from 100 to 250 microns, and the weight of
envelopes E with reference to the total weight of capsules C ranges
from 1 to 10 percent, preferably 3 to 6 percent by weight.
In accordance with the present invention, a powder, a stick or a
lotion can be used as vehicle for capsules C, the lotion
advantageously being used as an aerosol. Capsules C contain for
example deodorant agents such as compositions known as "G4" i.e.,
2,2'-dihydroxy-5,5'dichloro-diphenyl methane "G11," i.e.,
2,2'-methylenebis (3,4,6-trichlorophenal), quaternary ammonium
compositions, alums, anilide derivatives such as salicylanilides
and chlorophenyl hexanes, or ordinary deodorant cosmetic
compositions.
It is possible also to use in addition to these compositions or
compounds, or in their stead, microorganisms capable of destroying
the microorganisms which occur in perspiration and which to a great
extent are responsible for the odors that are to be suppressed.
Of course, the proportions of the release agents mentioned above
are calculated with respect to the nature and thickness of envelope
E so that release of the deodorant products occurs according to the
intensity of the sweating, and destruction of envelopes E is
effected necessarily after a sufficient interval. For this purpose
microcapsules C are used in an appropriate range insofar as size
and envelope thickness are concerned.
In any case, when the above deodorant compositions are prepared,
particular care is taken to adjust the density of the vehicle of
the cosmetic composition to the density of microcapsules C or to
use or prepare microcapsules C with a density sufficiently close to
that of the above mentioned vehicle in which the said capsules are
introduced. This result is attained by modification of the density
of the vehicle, preferably, but it is also to proceed in the
opposite way.
In the first case the density of the mixture can be adjusted to
that of the microcapsules by addition of an excess of one of the
ingredients or by introduction of a suitable inert substance (inert
with reference to the other components).
Also, capsules C are introduced either directly at any moment of
the preparation, or in pre-mixtures obtained from components of the
vehicle of the cosmetic composition. It is likewise very useful to
add a moistener to the capsules before introducing them into the
deodorant composition or into a pre-mixture. In general, the
deodorant compound of the invention is presented as a powder, a
stick, a lotion or a sanitary napkin.
In the case of a powder, the cosmetic composition has in addition
to capsules C, ingredients in the form of solid particles such as
talcum powder and similar powders. In case it is in the form of a
stick, it is necessary to take particular care that the
microcapsules C not be destroyed by mechanical pressure during
manufacture and for this purpose pre-mixtures are advantageously
used, the envelopes being thicker and capsules C being smaller.
When the deodorant compositions are in aerosol form, envelope E of
the microcapsules is a compound that is sufficiently elastic so
that the capsules C are not destroyed in spraying by rapid increase
in volume due to sudden decompression.
The present invention relates especially to deodorant cosmetic
compositions, but it is obvious that it also applies very generally
to all compositions for treatment that are used for body care in
which perspiration plays a significant role either directly or
indirectly.
According to a modification, a mixture containing, in addition to
treating products and/or deodorants used in an anhydrous medium,
acid anhydrides such as phosphoric anhydride or lactic anhydride
which then yield the corresponding acids.
According to another embodiment, it is possible to utilize
microcapsules C whose envelope E is coated on the outside at least
by a thin envelope here designated E', said thin envelope being
inert with reference to the vehicle of the cosmetic composition and
having a degree of elasticity which is greater than that of
envelopes E, the said envelopes being water-permeable and subject
to destruction by an acid or by a water-ethanol mixture.
The use of envelopes E' allows use of envelopes E which have the
above mentioned properties but for which it is not necessary that
the compounds comprising them be inert to the vehicle of the
cosmetic composition. The association of envelopes E and E' allows
therefore the attaining more readily of microcapsules of the
invention especially in the case in which the cosmetic composition
is stored as aerosol since the microcapsules must not be destroyed
at the moment of projection. The envelopes E' may be prepared with
the polymers and colloids already mentioned.
The following non-limiting examples in which parts and percentages
refer to weight are given for purposes of illustration and to
facilitate a fuller understanding of the subject of the present
invention:
EXAMPLE 1 Deodorant powder. A vehicle (perfumed powder) is prepared
with the following mixture: talc 98 perfume 2 There is also
prepared, by grinding, a mixture of: basic aluminum hydrochlorate
98 hexachlorophene 2
The latter powder is microencapsulated using cellulose
acetophthalate, the average size of the capsule being about 100 to
250 microns.
There are then mixed: 72 parts by weight perfumed talc with 28
parts by weight microcapsules.
A delayed-action deodorant powder is thus obtained. This powder
clings to the skin at the selected places and at the moment of its
formation, sweat dissolves the envelope of the microcapsules,
releasing the active products and thus suppressing any unpleasant
odor.
EXAMPLE 2
Deodorant lotion used with a hand sprayer. A perfumed alcohol
solution is prepared using: 96.degree. alcohol 98 perfume 2 There
is also prepared a powder mixture containing: selected quaternary
ammonium 1.5 basic aluminum hydrochlorate 98.5 which is
microencapsulated in polyvinyl alcohol, the size of the
microcapsules being from 30 to 50 microns. To obtain the deodorant
lotion, there is then prepared the following mixture: perfumed
alcohol; 60 parts by weight microcapsules: 40 parts by weight
This lotion is used with a sprayer which must be agitated just
before use. The microcapsules are deposited on the skin at the
selected places, and the perspiration dissolves their jacket when
it forms, releasing the active products and thus suppressing any
troublesome odor.
EXAMPLE 3 Aerosol deodorant lotion
Hexachlorophene is microencapsulated, using polyvinyl acetate or
ethyl cellulose, the size of the microcapsules being 30 microns on
the average. A perfumed alcohol is then prepared with: 96.degree.
alcohol 98 perfume 2
To this perfumed alcohol, there is added 0.5 percent be weight
microcapsules. There is thus obtained an alcohol lotion with
delayed deodorant effect, stored in an aerosol can containing, for
example, alcohol juice (sic) containing the microcapsules 50 Freon
12 dichlorodifluoromethane 50
As in the case of Example 2, is necessary to agitate the aerosol
can just before use.
EXAMPLE 4 Dry aerosol deodorant lotion A solution is prepared
containing: isopropyl myristate 60 butyl sterate 5 acetone 30
perfume 5
As in Example 3, hexachlorophene is microencapsulated in
microcapsules having the same dimensions.
To prepare a deodorant solution there is added 5 percent by weight
microcapsules to the original mixture, and this is stored as
aerosol as in Example 3, the can to be agitated just before
use.
The anhydrous deodorant composition is deposited on the skin at the
selected places: the microcapsule envelopes dissolve with
appearance of sweat, thus effecting the desired deodorizing
action.
EXAMPLE 5 Stick deodorant A perfumed vehicle is prepared
containing: sodium stearate 10 glycerol 10 propylene glycol 15
colorant in 1% solution 0.15 96.degree. alcohol to make up 100
perfume sufficient quantity
The whole is melted in a water bath at a temperature close to
50.degree. C and allowed to cool: the mixture becomes pasty.
There is incorporated in it 0.5 percent hexachlorophene
microencapsulated in an acetophthalate cellulose polymer, the size
of the microcapsules being of the order of 30 to 50 microns.
By suitable agitation the microcapsules are uniformly distributed
in the pasty mass which is extruded, cooled and cut into sticks
which are then packaged.
The delayed deodorant action is obtained in the same conditions as
in the preceding examples.
EXAMPLE 6 Deodorant sanitary napkin The following solution is
microencapsulated: isopropyl myristate 60 2-octyl 2-decanol 38
Cetavlon (cetyl trimethyl ammonium bromide) 0.2 salicylanilide
(Anobial) 0.2 hexachlorophene 1.4
Microencapsulation is effected with polyvinyl acetate, the size of
the microcapsules being on an average 30 to 50 microns.
The microcapsules are homogeneously distributed in the body of a
napkin made of cellulose batting or else they are distributed in
alternating layers on a fabric of paper or cotton.
Destruction of the microcapsules and their bactericidal and
fungicidal action is effected at the proper time.
* * * * *