U.S. patent number 3,686,701 [Application Number 05/008,720] was granted by the patent office on 1972-08-29 for cosmetic composition containing microencapsulated solvents for nail enamel.
This patent grant is currently assigned to Societe anonyme dite: L'Oreal. Invention is credited to Roger Charle, Gregoire Kalopissis, Charles Zviak.
United States Patent |
3,686,701 |
Charle , et al. |
August 29, 1972 |
COSMETIC COMPOSITION CONTAINING MICROENCAPSULATED SOLVENTS FOR NAIL
ENAMEL
Abstract
A cosmetic composition for removing nail enamel comprises a
shaped cosmetic applicator containing a multiplicity of rupturable
microcapsules, a portion of which contain a first solvent for the
enamel and the remainder containing a second solvent exhibiting a
solvent action on the enamel greater than said first solvent and a
perfume to mask the odor of said solvents.
Inventors: |
Charle; Roger
(Soisy-sous-Montmorency, FR), Zviak; Charles
(Franconville, FR), Kalopissis; Gregoire (Paris,
FR) |
Assignee: |
Societe anonyme dite: L'Oreal
(Paris, FR)
|
Family
ID: |
19725909 |
Appl.
No.: |
05/008,720 |
Filed: |
February 4, 1970 |
Foreign Application Priority Data
Current U.S.
Class: |
15/104.93;
401/132; 424/401; 428/402.22; 252/364; 424/61; 428/402.2 |
Current CPC
Class: |
A61K
8/0208 (20130101); C09D 9/00 (20130101); A61K
8/11 (20130101); A61Q 3/04 (20130101); Y10T
428/2984 (20150115); Y10T 428/2987 (20150115); A61K
2800/412 (20130101) |
Current International
Class: |
C09D
9/00 (20060101); A61k 007/04 () |
Field of
Search: |
;424/14,16,31,38,61
;252/316,364 ;15/104.93 ;401/132 ;132/88.7 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rose; Shep K.
Claims
What is claimed is:
1. A cosmetic composition for removing nail enamel comprising a
shaped cosmetic applicator support adapted to be applied locally to
the nail and containing a multiplicity of rupturable microcapsules,
a portion of said microcapsules encapsulating a first solvent for
said enamel, which otherwise has a disagreeable odor, evaporates
excessively on storage and exhibits a moderate solvent action on
said enamel, the remainder of said microcapsules encapsulating (1)
a second solvent for said enamel which otherwise has a disagreeable
odor, evaporates excessively on storage and exhibits a solvent
action on said enamel greater than said first solvent and (2) a
perfume effective to mask the otherwise disagreeable odor of said
solvents, said portion of microcapsules containing said first
solvent being readily ruptured by mechanical pressure so that the
solvent action of said first solvent cannot occur until sufficient
mechanical pressure has been exerted at the moment of application
of said composition, said remainder of microcapsules containing
said second solvent and perfume being ruptured by mechanical
pressure greater than that necessary to rupture said portion of
microcapsules containing said first solvent so that the solvent
action of said second solvent and the masking action of said
perfume occurs after release of said first solvent whereby release
of said perfume indicates that said remainder of said microcapsules
has been ruptured, the density of said microcapsules being
substantially equal to the density of said applicator to provide
uniform distribution of said microcapsules in said composition,
said walls of said microcapsules being inert to said solvents and
said perfume and being formed of a material selected from the group
consisting of polystyrene/maleic acid, polyethylene,
polyethylene/ethyl cellulose mixture, polyurethane, polyester,
gelatin, natural wax, paraffin wax, polyamide, urea formaldehyde,
acetal homopolymers and copolymers, casein, epoxy resin,
polypropylene and cellulose acetophthalate.
2. The cosmetic composition of claim 1 wherein said shaped cosmetic
applicator is a textile fabric or paper support, said microcapsules
being adhered thereto.
Description
The present invention relates to a solvent cosmetic composition for
nail enamel, characterized in that the solvent activity of the
solvent cannot be brought into effect until mechanical pressure has
been exerted on the composition at the moment of its
application.
Solvents or solvent compositions for nail polish are well known.
However, these solvent compositions have numerous disadvantages in
use because they are generally liquid and have an unpleasant odor.
Additionally, these compositions are stored in bottles and because
of their solvent property, the obtaining of a complete seal which
is necessary for such bottles presents obvious difficulties that
are further increased by the fact that an applicator brush must
generally be provided. It should also be noted that the use of
these solvents is most often effected with a great excess of the
product because of the difficulty of application with a brush, the
excess being bothersome because of the disagreeable odor of the
utilized compounds. Moreover, the use of an excess of solvent
brings the solvent into contact with the skin around the nails, on
which it has a drying effect. Finally, the solvent mixture
evaporates rather rapidly from the bottles which are difficult for
the user to close tightly.
The present invention is intended to obviate the above mentioned
disadvantages, particularly those resulting from storage, the
disagreeable odor of the solvent, its use in excessive quantities
that are difficult to control, and its gradual evaporation from the
container.
The present invention relates to a new solvent composition for nail
enamel, containing all the usual active elements of a nail enamel
solvent, but whose solvent action cannot occur until sufficient
mechanical pressure has been exerted at the moment of application
of the said composition.
The present invention likewise relates to the process of releasing
the solvent agent at the moment of its application.
The invention also refers to certain forms of storage for the said
cosmetic solvent composition that are especially advantageous.
The invention is also concerned with the preparation of the above
mentioned cosmetic compositions.
According to the invention, it has been found possible to prepare
solvent cosmetic compositions without the above indicated
drawbacks, in that the solvent agents contained in the vehicle of
these compositions can be physically separated from the rest of the
components by the well-know technique of microencapsulation which
consists in surrounding the solvent agents, divided into small
liquid particles, by a suitable envelope.
The process of microencapsulation itself is not part of the present
invention since the microencapsulation of the solvents is effected
separately and the microcapsules are then introduced into a
suitable cosmetic vehicle. Of course, all the other ingredients of
the above mentioned cosmetic preparations can also be
microencapsulated, including perfumes which mask the disagreeable
odor of the solvent. Such perfumes may be contained in separate
microcapsules or in the microcapsules that contain the
solvents.
According to the invention, the new solvent cosmetic compositions
are constituted by a vehicle which may be in one of a variety of
forms such as a liquid, a thickened liquid, a cream, an emulsion, a
powder or a pencil, containing all the conventional ingredients of
the said solvent compositions as well as possible thickeners,
provided, however, that solvent particles distributed in these
compositions have the characteristic that they are surrounded by an
envelope that cannot be destroyed by contact with the vehicle of
the solvent composition. These envelopes can, however, be torn by a
sufficient mechanical pressure in spreading.
The microcapsules, here designated by C, incorporated in the
cosmetic composition contain substantially solvent agents such as
ethyl acetate, isopropyl acetate, butyl acetate, amyl acetate,
butyl propionate, ethyl lactate, butyl stearate, associated or not
with oils or with high boiling point compounds e.g., ethylene
glycol monoethylether, diethylene glycol monoethylether,
.gamma.-valerolactone, castor oil, olive oil, etc.
The said microcapsules are prepared by conventional processes, but
according to the invention they are characterized by the nature of
their envelope, their dimensions and their thickness or by the
ratio R between the weight of the envelope and the total weight of
the microcapsule.
The compounds which form the said envelopes, here designed by E,
can particularly be any one of the following:
polystyrene/maleic acid
polyethylene and polyethylene/ethyl cellulose mixtures
polyurethanes
polyesters
gelatin
natural waxes such as carnauba wax, beeswax, candelilla wax, Japan
wax
paraffin wax
polyamide
formaldehyde urea
acetal homopolymers and copolymers
casein
epoxy resins
polypropylene
cellulose acetophthalate
Microcapsules are used whose dimensions vary from 10 to 600
microns, although by preference microcapsules of 20 to 250 microns
are used. The thickness of the envelopes is also variable according
to their mechanical strength, the ratio R usually being from 1 to
10 percent and preferably 3 to 6 percent by weight. However, the
resistance of the microcapsules to mechanical pressure must always
be sufficient so that, depending upon the kind of storage, the
microcapsules will not be torn before they have been spread on the
nail from which the film of enamel is to be removed.
According to a modification of the present invention, two solvents
or solvent compositions are used which have a different solvent
strength, contained respectively in microcapsules C.sub.1
surrounded by envelopes E.sub.1, and C.sub.2 surrounded by
envelopes E.sub.2. The capsules here designated C.sub.1 contain a
first solvent agent which has a moderate solvent action and
capsules C.sub.2 contain a second solvent whose solvent properties
are definitely stronger, the said second solvent agent having a
delayed action with reference to that of the first. The delayed
action mechanism is obtained for example by the fact that for
envelopes E.sub.1, E.sub.2 of the same kind and capsules of the
same dimensions, envelopes E.sub.2 are thicker than envelopes
E.sub.1. However, other mechanisms may also be employed, e.g.,
incorporation in capsules C.sub.1 of an agent that is inert with
reference to envelopes E.sub.1 but which destroy envelopes
E.sub.2.
Microcapsules C.sub.2 may additionally contain a perfume whose
release indicates that they have been opened.
The preparation of the cosmetic compositions of the invention is
effected as follows:
In a first stage, a microencapsulation of the solvents or solvent
compositions is effected according to any known microencapsulation
process, care being taken however to select the type of membrane
from the compounds mentioned above.
In a second stage, the cosmetic compositions themselves are
prepared from conventional ingredients with capsules prepared in
the first stage. Operation must always be such as to avoid rupture
of the microcapsules. In a general way, the microcapsules can be
introduced into the cosmetic vehicle at any moment of its
preparation. However, a preferred method of the present invention
resides in preparation first of one or more pre-mixtures being
determined in appropriate fashion depending upon the nature of the
composition and of the microcapsules to be introduced.
To attain a good homogeneity and a good distribution of the
microcapsules in the cosmetic composition of the invention, the
vehicle density of the composition is preferably adjusted to the
density of the microcapsules that are utilized by introduction of
an excess of one of the ingredients or of a suitable substance.
However, it is possible to operate in reverse, adjusting the
density of the microcapsules which contain the solvent agents to
the density of the vehicle of the composition. It is also possible
to select the microcapsules and choose those whose density is
appropriate, since this density varies as a function of the degree
of filling of the said microcapsules and of ratio R defined
above.
The solvents and solvent compositions of the invention may be in
the form of a cream, an emulsion, a powder, a pencil and also of a
flexible support of some kind such as a paper napkin or "blotter"
type, fabric or a porous synthetic material, containing
microcapsules.
In any case, presentation as a pencil is especially advantageous.
In this case, the pencil channel ends in a small spatula with a
triangular tip whose plane is perpendicular or inclined with
reference to the axis of the above mentioned channel, said spatula
serving to spread the cosmetic composition on the nail from which
the coating of nail polish that covers it is to be removed, the
pencil then being stoppered by a small movable cap after use. No
matter what its form of packaging, the solvent composition of the
invention is thus utilized exactly in the desired amounts, it does
not present the disagreeable odor of the old compositions because
of the microencapsulation, or else this odor is very much
attenuated. Moreover, the presence of a perfume either in the
vehicle of the cosmetic composition or in the capsules containing
the solvent agent, makes it possible in all cases if desired to
obtain an agreeable perfumed product.
According to a modification, microcapsules can be used which are
coated inside by thin envelopes here designated E'. The said thin
envelopes are inert with respect to the agent or to the solvent
mixture and/or coated on the outside by thin envelopes here
designated E", which envelopes are inert with respect to the
vehicle of the solvent cosmetic composition. These envelopes
associated with the above mentioned envelopes of the microcapsules
make it possible to make use in the preparation thereof of
compounds which may not have the desired mechanical properties or
other properties necessarily, which permits more ready production
of the microcapsules of the invention. Envelopes E' and E" are
prepared moreover with polymers and colloids that have already been
mentioned.
The following non-limiting examples in which the parts and
percentages refer to weight, are again by way of illustration so as
to permit a better understanding of the present invention.
EXAMPLE 1
Liquid solvent
A cosmetic composition is prepared which is constituted by a
dispersion of microcapsules in an aqueous phase, optionally in the
presence of thickeners, to obtain dropwise application. The
composition comprises an aqueous phase:
carboxymethyl cellulose 2.5 water 97.5
The capsules contain the solvent agent and a perfume, in the form
of the following mixture:
acetone 84.8 ethylene glycol monoethylether 10 butyl stearate 5
perfume 0.2
The capsule envelope is constituted by a natural wax, an acrylic
resin or casein.
The capsule dimension is from 50 to 250 microns. The composition is
prepared by dispersing the capsules in the aqueous phase.
To use the composition, a drop is allowed to fall on the nail from
which the polish is to be removed and rubbed with a small wad of
hydrophilic cotton or a cloth to crush the capsules, releasing
their solvent mixture.
EXAMPLE 2
Solvent paste
A solvent cosmetic composition constituted as a paste and
containing two kinds of solvent capsules C.sub.1 and C.sub.2 is
prepared.
Aqueous phase:
The aqueous phase is constituted by:
ethyl cellulose 3 stearic acid 10 20% ammonia solution 4
water in sufficient quantity to obtain a paste of the desired
consistency.
Capsules:
Capsules C.sub.1 contain the following solvent mixture:
.gamma. valeroacetone 50 ethylene glycol monoethylether 15 ethanol
35
The envelope of the capsules C.sub.1 is constituted by natural wax,
their dimension being from 150 to 250 microns.
Capsules C.sub.2 contain the following solvent mixture:
ethyl acetate 50 acetone 49.8 perfume 0.2
The envelope of the capsules C.sub.2 is constituted by a styrene
polymer/maleic acid, completely hydrolyzed, the dimension being
from 50 to 100 microns.
Capsules C.sub.1 and C.sub.2 are incorporated in equal quantities
in the previously prepared paste and the whole is then stored in a
jar or in a flexible tube with a spatula applicator.
Release of the solvents is effected as indicated in the preceding
description.
EXAMPLE 3
A solvent cosmetic composition is prepared in the form of a shaped
cosmetic applicator, i.e., a pencil constituted in the following
way:
A cosmetic vehicle is used which contains:
beeswax 10 ozocerite 24 carnauba wax 8 paraffin 8 lanolin 10
All the above constituents are melted to prepare the pencil core
whose hardness may be modified by appropriate addition of paraffin
oil.
The capsules contain the solvent agent in the form of the following
mixture:
ethyl acetate 40 acetone 30 amyl acetate 5 ethylene glycol
monoethylether 10 castor oil 14.8 perfume 0.2
The envelope of the microcapsules is constituted particularly of
polyamide, polyethylene/ethyl cellulose or polpropylene, the
dimension being 20 to 100 microns.
The said capsules are dispersed in the above cosmetic vehicle.
Before it sets, it is molded to form a core, using a press. This
core is utilized to constitute a pencil which, because of its form,
allows accurate application of the solvent paste, the microcapsules
then being crushed by simple mechanical pressure on the nail from
which the colored polish is to be removed.
EXAMPLE 4
Textile or paper for solvent microcapsules
Microcapsules containing the following mixture as solvent agent are
prepared:
ethyl acetate 60 diethylene glycol monoethylether 34.8 castor oil 5
perfume 0.2
The compounds forming the envelopes of the microcapsules are of
natural wax, an acrylic resin, casein, hardened gelatin, or
polyethylene/ethylcellulose. Dimension of the capsules is between
50 and 250 microns.
The said microcapsules are projected onto a fabric or paper support
preliminarily treated in conventional fashion to allow adherence,
thus providing another example of a shaped cosmetic applicator.
Fabrics or papers are thus obtained that are solvents for the
lacquer on the nails. It is then sufficient to rub the support thus
prepared locally on the nail to burst the capsules adhering to the
said support and thus to release the solvent contained therein.
The scope of the invention is defined in the following claims:
* * * * *