U.S. patent number 3,681,713 [Application Number 05/010,882] was granted by the patent office on 1972-08-01 for high q circuits on ceramic substrates.
This patent grant is currently assigned to RCA Corporation. Invention is credited to Robert Stephen Degenkolb, Eugene Raymond Skaw.
United States Patent |
3,681,713 |
Degenkolb , et al. |
August 1, 1972 |
HIGH Q CIRCUITS ON CERAMIC SUBSTRATES
Abstract
High Q circuit for operation in the UHF band comprising a
ceramic substrate having on one major surface a pattern of metal
particle-glass frit conductors having a coating of copper thereon,
and on the other major surface a metallic ground plane of similar
structure.
Inventors: |
Degenkolb; Robert Stephen
(Indianapolis, IN), Skaw; Eugene Raymond (Indianapolis,
IN) |
Assignee: |
RCA Corporation (New York,
NY)
|
Family
ID: |
21747865 |
Appl.
No.: |
05/010,882 |
Filed: |
February 12, 1970 |
Current U.S.
Class: |
333/219; 333/238;
427/125; 257/E21.534; 257/E27.115 |
Current CPC
Class: |
H01P
3/081 (20130101); H01L 21/705 (20130101); H01L
27/013 (20130101); H05K 3/246 (20130101); H05K
1/092 (20130101) |
Current International
Class: |
H01L
21/70 (20060101); H01L 27/01 (20060101); H01P
3/08 (20060101); H05K 3/24 (20060101); H01p
007/00 () |
Field of
Search: |
;117/212,217,215,160,38,71R,7A ;252/514 ;333/84M,82R
;204/52R,23,24,38B,38C ;317/242,258 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Leavitt; Alfred L.
Assistant Examiner: Weiffenbach; Cameron K.
Claims
1. A high Q circuit for operation at ultra high frequencies
comprising:
a ceramic substrate having two major surfaces,
a fired pattern of conductors of the silver particle-glass frit
mixture type on one of said surfaces,
a ground plane composed of a fired silver particle-glass frit
mixture type composition on the other of said surfaces,
said fired pattern of conductors and said ground plane normally
each having surfaces characterized by a myriad of minute surface
irregularities,
a layer of copper plated on and integrally united to the exposed
surface of said fired pattern of conductors and to the surface of
said ground plane such that said surface irregularities tend to be
filled in by said copper,
the combination of said metal pattern, said ground plane and said
substrate being dimensioned such that it will resonate at a
particular frequency
2. A circuit according to claim 1 in which said copper layer is
about
3. A circuit according to claim 2 in which said silver
particle-glass frit
4. A circuit according to claim 3 in which said ceramic substrate
has a thickness of 0.050 inch.
Description
BACKGROUND OF THE INVENTION
Circuits designed to oscillate at frequencies within the UHF band
have previously utilized coaxial conductors and stripline units
composed of layers of metal foil laminated to opposite sides of a
strip of insulating material. The need for lower cost circuits
adaptable to mass production techniques, however, has brought about
a change to a circuit comprised of layers of metallic inks
screen-printed on opposite sides of a fired ceramic plate.
The metallic inks which have been used heretofore have generally
comprised a high percentage of silver particles suspended in a
vehicle made up primarily of a glass frit, organic plasticizers and
solvents. These inks are designed to have good thixotropic
properties rendering them suitable for screen printing.
The circuits made from these inks have been found to have certain
disadvantages. One of these is that, under high humidity
conditions, many of the circuits fail due to silver migration.
Silver migration can occur between two silver electrodes when a
continuous film of water extends between them on the substrate and
when they are under DC bias.
The mechanism by which the silver migrates is that when a DC field
is applied, silver ions tend to leave the anode. Hydroxyl ions from
the water move toward the anode. Silver ions and hydroxyl ions
react to form silver oxide which is precipitated as a dark ring
along the edge of the anode. And, silver hydroxide, which is also
present, is quite soluble in water and allows silver ions to
migrate to the cathode where the silver is discharged and
precipitates in a dendritic form.
Another disadvantage of previously-used UHF circuits composed of
silver inks is that their Q is not as high as desired. One reason
for the low Q value is that films of metallic inks have a myriad of
minute surface irregularities. A measure of the Q of a circuit is
the width of the frequency band at which it can be caused to
resonate at a given value of db in response to a signal of given
strength. For many uses it is desirable that a circuit exhibit a
very narrow-band frequency response so that it can be sharply
tuned.
OBJECTS OF THE INVENTION
One object of the present invention is to provide a circuit for UHF
band use which has a relatively high Q.
Another object of the invention is to provide a high Q circuit
composed in part of silver metallizing ink in which the silver is
prevented from migrating.
The improvements which have been accomplished in the improved
circuits of the present invention have been brought about by
depositing a thin layer of copper on the exposed surface of the
fired silver ink circuit patterns.
THE DRAWING
FIG. 1 is a top plan view of a partially completed test circuit on
one side of a ceramic substrate, in accordance with the present
invention;
FIG. 2 is a bottom plan view of the other side of the substrate of
FIG. 1;
FIG. 3 is a section view taken along the line 3--3 of FIG. 1;
FIG. 4 is a top plan view of the circuit of FIG. 1 in completed
form, and
FIG. 5 is a section view taken along the line 5--5 of FIG. 4.
A method of making a test circuit in accordance with the invention
will now be described. In this example, the circuit dielectric
portion is a ceramic substrate 2 composed of two thin sheets of a
composition consisting of 85 percent alumina and 15 percent calcium
magnesium silicate laminated together. After firing, the substrate
has a thickness of 0.050 inch.
On one side 4 of the substrate a conductive ink pattern 6 in the
shape of a "U" is screen-printed. The dimensions of the screened-on
pattern are chosen such that, after firing, the width of the U is
2.3 cm. and the outside length of each leg is 3 cm. The width of
the lens is 0.4 cm.
The ink composition is not critical but may comprise silver powder
75 percent lead borosilicate glass powder 3 percent, glycerol ester
of hydrogenated rosin 12 percent, nitrocellulose 2 percent and
butyl carbitol acetate 8 percent. In general, the ink should have a
viscosity of 75,000 to 125,000 cps. as measured on a Brookfield
Model HBF Viscometer using No. 4 spindle at 10 r.p.m.
The ink is screen-printed on the substrate using a 325 mesh
stainless steel screen. The wire threads of the screen have a
diameter of 0.0011 inch. The thickness of the print after firing
should be 0.0004-0.0006 inch. Sufficient settling time should be
allowed, after printing, for the ink dots to flow together and form
a uniform layer. This time is usually 3-5 minutes. Lower mesh
screens can be used but the results have been found to be less
desirable if, for example, the number is as low as 80, since there
are more non-uniformities in print thickness under this
condition.
A ground plane 8 of the ink is also deposited over the entire
surface 10 on the back of the plate.
The ink is dried at about 100.degree.-150.degree. C. and fired at
900.degree. C. (a variation from 890.degree.-920.degree. C. being
permissible). The entire time in the furnace from room temperature
to maximum and back to room temperature is about 40 minutes. After
firing, the conductive patterns are about 95 percent silver.
The circuit now has the appearance illustrated in FIGS. 1-3. At a
resonant frequency of 850 Mc/s a large number of circuits tested
had an average Q of 135. In circuits intended for apparatus such as
TV tuners it is desirable that the Q be higher. Also, as stated
previously, it is highly desirable that the tendency for silver
migration, which is present in circuits made as described above, be
reduced or completely eliminated.
In making circuits of the present invention, the next step is to
electroplate a layer of copper 12 on the fired silver ink pattern 6
on the top sides of the substrate 2 and another layer of copper 14
on the fired silver layer 8 on the bottom of the substrate 2. The
plating bath may comprise:
Copper sulfate (CuSO.sub.4.sup.. 5H.sub.2 O) 1.76 lbs./gal. of
solution Sulfuric Acid (98% H.sub.2 SO.sub.4) 206.2 cc./gal. of
solution Water (ion free) remainder of solution
Suitable plating conditions are: a current density of 2 amps/10 sq.
in. of screen-printed conductor to be plated, if the bath is not
agitated, and a plating time of about 10-30 minutes. If the bath is
agitated, a current density of 3.5 amps/10 sq. in. can be used and
the time can be correspondingly decreased. A preferred plating time
in a non-agitated bath is 10 minutes.
The thickness of the copper plating is preferably 0.0002 to 0.0005
inch.
After the copper plated circuit is removed from the plating bath,
it is thoroughly rinsed in de-ionized water, and then dried either
by centrifuging for 2 minutes or being pressed against absorbent
tissue, and being subjected to forced air in an oven at
90.degree.-120.degree. C. for 1/2 hour.
A large number of circuits tested at a resonant frequency of 850
Mc/s were found to now have an average Q of 160. One of the reasons
for the improvement in Q values is that the copper tends to fill in
the surface irregularities of the metal ink film, resulting in a
much more uniform layer.
A number of identical test circuits having the same shape shown in
the drawing and having the same dimensions and made by the same
method described in the example were tested for their Q before and
after the copper plating step. The results are set forth in the
table below.
In making the test, the frequency of maximum resonance (maximum db
output) was determined. This data is noted in the column "f center"
in the table below. Then, at the same signal strength input, the
signal was tuned off the center frequency both higher and lower,
and the frequencies noted where the oscillation output was 3 db.
down from that of the center frequency. The high and low
frequencies for each center frequency are given in the columns
marked "f high" and "f low" in the table.
The Q for the circuit is then found by dividing the center
frequency by the difference between the measured high frequency and
the measured low frequency.
The data given in the first 5 columns of the Table is that obtained
for each sample after copper plating. For comparison purposes, the
Q measured for each circuit sample before copper plating is given
in the 6th column. The Q data in the 6th column were obtained
exactly as described for the copper plated circuits, but, to save
space, the actual frequency measurements have not been included in
this Table.
The 7th column of the Table shows the percentage increase in Q
obtained by copper plating each sample. The percentage increase
varies because of variations in such parameters as coating
thickness, coating uniformity, substrate imperfections, and the
like.
TABLE
Before % Plating After Copper Plating Copper .DELTA.Q Conditions
Pltg. 4 v. 1.4 Time .sup.f center .sup.f high .sup.f low .sup.f
H-.sup.f L Q Q amp (min)
__________________________________________________________________________
No. std. 864.49 867.57 862.17 5.90 160 1 843.13 846.05 841.10 4.95
170 121 39% " 30 2 844.92 847.53 842.73 4.80 176 118 47% " 30 3
843.36 846.33 841.28 5.05 167 131 27% " 30 4 842.76 845.48 840.35
5.13 164 120 35% " 30 5 841.33 844.11 839.09 5.02 167 118 40% " 30
6 842.87 845.70 840.77 4.93 170 145 16% " 20 7 842.58 845.31 840.20
5.11 164 120 37% " 20 8 841.15 844.18 838.89 5.29 159 121 31% " 20
9 842.42 845.22 840.11 5.11 164 130 25% " 20 10 843.32 846.19
840.97 5.22 161 144 12% " 20 11 846.01 848.93 843.80 5.13 164 129
27% " 20 12 843.39 846.28 841.12 5.16 163 149 09% " 10 13 845.28
848.26 843.02 5.24 161 149 07% " 10 15 842.10 845.01 839.59 5.42
155 149 03% " 10 15 837.00 840.10 834.52 5.58 150 139
.differential.% " 10 16 838.82 841.98 836.42 5.56 150 117 28% " 10
17 840.31 843.33 837.93 5.40 155 135 15% " 10 18 840.43 843.61
838.12 5.49 153 113 34% " 10 19 839.48 842.61 857.34 5.27 159 123
29% " 10 20 836.60 840.51 843.90 6.67 125 113 10% " 10 21 837.31
840.53 835.00 5.53 151 124 21% " 10
__________________________________________________________________________
In order to compare silver migration in circuits which had been
copper plated as described above, with migration in circuits that
had not been plated, two sets of plates were made up with a
standard printed electrode migration test pattern. Both sets of
plates were printed with the same silver ink and put through
identical processing steps except that one set of plates was copper
plated and the other was not.
Both sets of plates were subjected to test conditions as
follows:
Time of testing 1663 hours Temp. of testing 40.degree. C. Relative
humidity 95-98% Voltage bias between plates 150
Samples in the group that had not been copper plated failed at
about 89.5 hours and were removed from the test oven. The set that
had been plated with copper had no failures at the end of the
test.
After copper plating, the circuits may be given further processing
which does not substantially affect their Q. For example, certain
areas may have solder applied so that connections may be made; and
protective resin coatings may also be applied everywhere except
where connections are to be made.
* * * * *