U.S. patent number 3,679,784 [Application Number 04/865,542] was granted by the patent office on 1972-07-25 for method of making decorative articles from plastisol.
This patent grant is currently assigned to Flo-Tech Corp.. Invention is credited to Karl M. Rosenberg.
United States Patent |
3,679,784 |
Rosenberg |
July 25, 1972 |
METHOD OF MAKING DECORATIVE ARTICLES FROM PLASTISOL
Abstract
A method of making decorative articles from plastisol is
disclosed. In one of its forms, the method is performed by placing
bodies of liquid or semi-liquid plastisol of different color on the
surface of a pool of liquid material immiscible with the plastisol
and having a density in excess of the density of the plastisol. The
bodies of plastisol are intermingled as they float on the pool to
form a mass having a variegated marblelike appearance. The mass may
then be gelled, or alternatively, fused, and then removed from the
pool. One aspect of the disclosed method is a step of compressing
ungelled plastisol prior to or during gelling to preclude the
presence of bubbles in the finished article.
Inventors: |
Rosenberg; Karl M.
(Philadelphia, PA) |
Assignee: |
Flo-Tech Corp. (Wilmington,
DE)
|
Family
ID: |
25345741 |
Appl.
No.: |
04/865,542 |
Filed: |
July 23, 1969 |
Related U.S. Patent Documents
|
|
|
|
|
|
|
Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
812795 |
Apr 2, 1969 |
|
|
|
|
Current U.S.
Class: |
264/73; 264/236;
264/331.15; 264/216; 264/298 |
Current CPC
Class: |
B29C
48/9135 (20190201); B29C 48/91 (20190201); B44F
9/04 (20130101); B29C 48/08 (20190201); B05D
1/20 (20130101); B29C 48/07 (20190201) |
Current International
Class: |
B29C
47/88 (20060101); B44F 9/00 (20060101); B44F
9/04 (20060101); B05D 1/20 (20060101); B29d
007/02 (); B29c 025/00 (); B29c 005/00 () |
Field of
Search: |
;264/73,74,75,331,298,180,216,236,212,165 ;117/39 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: White; Robert F.
Assistant Examiner: Thurlow; Jeffery R.
Parent Case Text
This application is a continuation-in-part of application Ser. No.
812,795, filed Apr. 2, 1969, now abandoned.
Claims
I claim:
1. A method of making a decorative article from plastisol
comprising the steps of providing a body of liquid material
immiscible with the plastisol and having a density in excess of the
density of the plastisol, placing and spreading quantities of
different-colored plastisol on the surface of the body, stretching
the plastisol after it is placed on the body of liquid so that its
film thickness is reduced substantially, and then compressing the
plastisol so that the original film thickness of the plastisol is
substantially restored, then intermingling the plastisol of
different colors to obtain a variegated color pattern, heating the
plastisol while it is supported on the body to gel the plastisol,
and removing the resulting plastisol article from the surface of
the body.
2. A method in accordance with claim 1 wherein said step of
stretching is performed to the extent that the film thickness of
the plastisol is reduced by about one-half, said compressing step
being performed by displacing opposite lateral edges of the
plastisol toward each other to the extent that the film thickness
of the plastisol is restored to at least about 80 percent of its
original thickness.
3. A method in accordance with claim 1 wherein the plastisol is
gelled but not fused while the plastisol is supported on the body
of liquid, and then fused after removing of the resulting plastisol
article from the surface of the body.
4. A method of making a decorative article from plastisol,
comprising the steps of providing a body of liquid material
immiscible with the plastisol and having a density in excess of the
density of the plastisol, placing and spreading quantities of
different-colored plastisol on the surface of the body so that the
plastisol is supported thereon, maintaining the body of liquid in
continuous motion in a given direction and at a given rate so that
the quantities of plastisol supported thereon move therewith,
compressing the plastisol at least before the plastisol completely
gels, whereby the tendency of the plastisol to form bubbles is
decreased, intermingling the plastisols of different colors to
obtain a variegated color pattern, terminating the compression of
the plastisol and allowing the plastisol to relax prior to
gelation, heating the plastisol while it is supported on the body
of liquid to gel but not to fuse the plastisol, placing a moving
substrate of flexible sheet material in surface contact with the
body and the gelled plastisol so that the gelled plastisol article
adheres to the substrate, conveying the gelled plastisol article on
the substrate away from the liquid body, and then further heating
the article to fuse the plastisol.
5. A method in accordance with claim 4 wherein the step of
compressing the plastisol is performed by displacing opposite
lateral edges of the plastisol toward each other to cause an
increase in the film thickness of the plastisol.
6. A method in accordance with claim 4 wherein the plastisol is
stretched after it is placed on the body of liquid but before it is
compressed and gelled, so that the film thickness after stretching
is substantially reduced.
7. A method in accordance with claim 6 wherein said step of
stretching is performed to the extent that the film thickness of
the plastisol is reduced by about one-half, said compressing step
being performed by displacing opposite lateral edges of the
plastisol toward each other to the extent that the film thickness
of the plastisol is restored to at least about 80 percent of its
original thickness.
Description
This invention relates to a method of making decorative articles,
and more particularly, to a method of making a flat article of
variegated or marble-like appearance from material such as vinyl
plastisol.
The term plastisol is used to describe a suspension of finely
divided vinyl chloride polymer or copolymer in a liquid plasticizer
which has little or no tendency to dissolve the resin at room
temperature, but becomes a solvent for the resin when heated.
Typically, plastisols take the form of viscous liquids,
semi-liquids or pastes at room temperature. Fillers, colorants or
stabilizers may be added, but volatile solvents and diluents are
maintained at less than ten percent.
Upon heating, the plastisols form an initial gelatinous structure,
and ultimately a solid, inert, more or less flexible mass.
Plastisols have found increasingly wide commercial acceptance and
usage. For example, products may be made from plastisols by
spreading the material on substrates, dipping forms to be coated
into the plastisol, or by casting in stationary or rotary molds. In
one common application, plastisols have been used to produce hollow
articles by well-known "slush casting" techniques.
The present invention is directed to a method of making from
plastisol a decorative article, particularly suited for
incorporation into flooring or the like. Decorative polymeric
flooring materials, such as vinyls, are not per se new. Typically,
such materials are formed into floor materials by conventional
techniques of casting, or extrusion or calendering. With the
present method, patterns not obtainable by any other known method
may be obtained. Moreover, such patterns may be obtained on a
repetitive basis and at production rates making commercial usage
feasible. The present method overcomes a well-recognized and
longstanding problem in the use of plastisols, namely the problem
of unwanted bubbles or gaseous inclusions.
In view of the foregoing, it is an object of this invention to
provide a novel method of making decorative articles from
plastisol.
It is another object to provide a method wherein variegated
polymeric articles having predictable decorative patterns may be
produced from plastisol.
It is yet another object to provide a method of making decorative
articles from plastisol, especially suited for use in the
manufacturing of flooring materials.
It is yet another object of this invention to provide a method of
making decorative articles from plastisol, the articles being of
uniform composition, without bubbles or unwanted gaseous
inclusions.
It is a still further object of this invention to provide a method
of making flooring materials, using plastisols.
Other objects will appear hereinafter.
Briefly stated, in one of its variations, the present method
involves placing a body of plastisol on a pool of liquid material
having a density in excess of the density of the plastisol and with
which the plastisol is immiscible. An area of the pool is
maintained at a temperature in excess of the temperature at which
the plastisol gels. The plastisol is left on the surface of the
pool for a time sufficiently long for gelation to occur. The gelled
article is then removed from the supporting liquid, and subjected
to further heating until solidified. Separate bodies of plastisol
of different color may be placed on the surface of the pool, and
intermingled to produce a variegated, marble-like effect. Such
intermingling of the different colored plastisols is made to occur
prior to gelation.
In another variation of the method, the plastisol is brought to its
fused, solidified state by the heat of the supporting liquid.
In other variations of the method, heat sources other than the
supporting liquid are used to gell or fuse the plastisol while it
is supported on the supporting liquid.
The problem of bubbling, it has been found, may be overcome by
compressing the plastisol prior to or during gelation.
The above-described process may be performed as a batch operation,
but for production purposes, a continuous operation is preferred.
In such case, the plastisol supporting liquid is a continuously
moving pool of recycled liquid (is a continuously moving pool of
recycled liquid.) The plastisol body moves with the supporting
liquid as the bubble-preventing and intermingling steps are
performed. The gelled plastisol body can then be removed from the
supporting liquid by bringing it into contact with a continuously
moving web of flexible substrate material.
I am aware that paints, inks, and the like have in the past been
applied to paper or cloth substrates by first floating them on
supporting liquids. Such techniques have not heretofore been used
in polymeric flooring or the like.
For the purpose of illustrating an apparatus capable of performing
the method of the present invention, there is shown in the drawing
a form which is presently preferred; it being understood that the
invention is not limited to the precise arrangements and
instrumentalities shown.
FIG. 1 is a side elevation view of an apparatus for performing the
present inventive method on a continuous basis.
FIG. 2 is a detail view of a portion of the apparatus in FIG.
1.
FIG. 3 is a cross-sectional view taken along the line 3--3 in FIG.
2.
FIG. 4 is a view similar to FIG. 3, showing the apparatus in a
different operative position.
FIG. 5 illustrates one form of variegated article obtainable with
the present method.
Practice of the present method requires the provision of a pool of
supporting liquid. Such liquid, of course, must have a density in
excess of the density of the plastisol, and be immiscile therewith.
Liquid metals, such as low melting alloys having melting points
below the gel temperature of the plastisol, and preferably in the
range of 115.degree. to 130.degree. F., may be used. One suitable
low melting alloy is the alloy sold under the trademark "CERRO
ALLOY NO. 97" by Belmont Smelting & Refining Co. In addition to
the above, glycerin has been found suitable for use as the
supporting liquid. Also, mercury may be used, although it is not
preferred due to its obvious toxicity hazard.
In one form of the method, an area of the supporting liquid is
maintained at a temperature in excess of the gel temperature of the
plastisol. Such gel temperature depends on the formulation of the
plastisol. For a discussion of the effect of formulation upon gel
temperature, see the book Plasticizers, published by Rohm &
Haas Company, 1960. The plastisol must remain on the support liquid
for a time sufficiently long for substantial gelation to occur. In
other words, the plastisol must be heated to a temperature above
gel temperature, and must remain at such temperature until
substantial gelation occurs.
After gelation, the article maybe removed from the supporting
liquid. A presently preferred technique for removing the gelled
article from the supporting liquid involves bringing a substrate
into surface contact with the supporting liquid and the gelled
article, and then lifting the substrate. The substrate and gelled
article can then be brought to the fusion temperature of the
plastisol. Such heating may be accomplished in conventional ovens
or through the use of radiant energy techniques, such as heat lamps
or the like.
Numerous materials can be used as the substrate. For example,
paper-like materials or woven textile fabrics may be used. As will
be explained later, especially desirable results may be obtained by
using flexible plastic polymeric substrates, such as sheet
vinyl.
In a variation of the method, the temperature of the supporting
liquid and time interval during which the plastisol is supported
thereon are such that both gelation and fusion of the plastisol
occur while it is on the support liquid. The fused plastisol is
thereafter removed from the supporting liquid in the
above-described manner.
In the above-mentioned forms of the method, the plastisol is heated
directly by the supporting liquid. In a further variation of the
method, external heat sources, such as heat lamps may be used to
bring the plastisol to the desired temperature.
A significant aspect of the present process is the manner in which
bubbles or gaseous inclusions in the plastisol are eliminated. In
this regard, it has been found that compression of the plastisol
after it has been placed on the supporting liquid before or during
gelation substantially eliminates any bubbling tendency. When
placed on the supporting liquid, the plastisol tends to spread to a
rest configuration, dependent upon its viscosity, its composition,
and the viscosity of the supporting liquid. Typically, a body of
plastisol may spread to form a film having a thickness of about 50
mils. In one form of the method the body is "stretched" beyond its
rest position to substantially thin the film, and then, by applying
force to its edges, "compressed" to a thickness approaching its
original rest thickness, its tendency to bubble is substantially
decreased. In the case of a body of plastisol having a 50 mil
thickness, it was found that stretching to the point where the film
had a thickness of about 20 mils, followed by compression to about
40 mils produced the desired result. It is of course difficult to
quantitatively assess the results of the above-described procedure.
The relative lack of bubbles in the finished articles obtained when
the foregoing procedure is followed, as compared to articles in
which it is not, is readily observable, however. Simple
compression, without this initial stretching may also be used.
There is seen in the drawings, FIGS. 1 to 4, an apparatus for
performing the present method on a continuous basis. Referring to
FIG. 1, the apparatus, designated generally by the reference
numeral 10, includes a flat-bottomed tray-like vessel 12 for
containing the support liquid 14. The support liquid 14 is fed
continuously to the vessel 12 through a conduit 16. A pump 18,
having suitable characteristics, is provided to circulate the
support liquid 14. A motor 20 is provided to drive the pump 18.
Spaced upstanding baffles 22, 24 extend across the vessel 12. The
baffle 22, an end wall of the vessel 12, and portions of the side
wall of the vessel 12 define a chamber in communication with the
conduit 16. The baffle 24, an end wall of the vessel 12, and other
portions of the side walls of the vessel 12 define a second chamber
28, in communication with a drain stand 30. A filter 32 may be
provided across the mouth of the drain 30.
It should now be apparent that support liquid brought into the
vessel through the conduit 15 flows through the baffle 22, along a
major portion of the length of the vessel 12 over the baffle 24,
and into the drain stand 30. From the drain stand 30, the support
liquid may be recycled through the vessel 12. If the support liquid
is to be liquid metal, as described above, heating apparatus, not
shown, is provided to maintain the material in its liquid state
throughout its circulation. The pool of support liquid 14 between
the baffles 22 and 24 provides a steadily flowing but non-turbulent
pool to which the plastisol may be applied.
Referring to FIG. 2, nozzles 34 and 36, whose openings are
preferably about flush with the surface of the support liquid 14 in
the vessel 12, provide one means for applying plastisol to the
support liquid 14. Referring once again to FIG. 1, a reservoir 38
for plastisol is seen diagrammatically in fluid communication with
the nozzle 34. Conventional flow regulating means, not shown, may
be provided to control the flow of plastisol through the nozzles 34
and 36. As is seen in FIG. 2, plastisol emerging from the nozzles
34 and 36 spreads on the surface of the support liquid 14 to form
bodies of random outline. As illustrated, the body 42 is formed of
plastisol having a color different from the color of the body
40.
Referring now to FIGS. 2, 3 and 4, representative apparatus for
performing the steps of stretching and compressing the plastisol
bodies to prevent bubble information is shown.
Plates 44 and 46, generally parallel to the sides of the vessel 12,
are provided on opposite sides of the vessel 12. Remotely operable
mechanical means, such as hydraulic cylinders 48 and 50, may be
provided to move the plates 44 and 46 in a direction transversely
of the vessel 12.
The operation of the plates 44 and 46 and hydraulic cylinders 48
and 50 to treat the plastisol bodies 40 and 42 is as follows:
Referring to FIG. 3, the initial positions of the plates 44 and 46
is shown in dotted line. When applied to the support liquid 14, the
bodies 40 and 42 spread into contact or near-contact with the
plates 44 and 46. The plates 44 and 46 may then be withdrawn
through the urging of the hydraulic cylinders 48 and 50 to the
position shown in full line in FIG. 3. It has been found that
viscosity effects, hydraulic forces caused by withdrawal of the
plates 44 and 46, or a combination of both, results in the
plastisol of the bodies 40 and 42 following the plates 44 and 46 as
they move. The result is a stretching of the bodies 40 and 42, with
a resultant thinning of the plastisol film. Next, the hydraulic
cylinders 48 and 50 are reversed, to move the plates 44 and 46
inwardly toward the center of the vessel 12 to positions close to
the initial positions. Opposite outer lateral edges of the bodies
40 and 42 are displaced inwardly toward each other. The result is a
squeezing or compressing effect on the bodies 40 and 42, and a
thickening of the plastisol film. Juxtaposed inner edges of the
plastisol bodies 40 and 42 meet at an irregular but clearly defined
interface 52. Alternatively, the bodies 40 and 42, by a simple
inward or inward and outward movement of the plates 44, 46, are
compressed.
Also seen in FIG. 2 is an exemplary means whereby a variegated or
marble-like pattern may be obtained from the plastisol bodies 40
and 42. A pulley 54, driven by the shaft 56 of a motor 58 is
coupled to an endless belt 60 extending transversely across the
vessel 12. A pulley 62, spaced from the pulley 54 and pivoted on
the vessel 12 by a pivot 64, also receives the belt 60.
Pins 66 or the like extend from an edge of the belt 60 into contact
with bottom surfaces of the plastisol bodies 40 and 42. Rotation of
the pulleys 54, 62 causes side-to-side motion of the pins 66, and
consequently, causes intermingling of the different colored
material forming the bodies 40 and 42.
FIG. 5 and 6 show examples of the variegated marblelike pattern
obtainable with the above-described method and apparatus. In this
connection, it is pointed out that previously, it was thought that
even slight mixing or agitating action of the plastisol material
would result in unwanted bubbles or gaseous inclusions in the
finished product. Quite unexpectedly, when the above-described
bubble-preventing steps are performed on the plastisol, this
undesirable effect is substantially eliminated.
The plastisol body 68 remaining after the intermingling step is
subjected to gelation. The heat necessary to accomplish gelation,
or, alternatively, gelation and fusion, may be provided by the
support liquid 14 itself, or by external means such as heat lamps.
In the illustrated case, a heating element 69, seen in dotted line
in FIG. 1, provides heat for gelation of the body 68. The body 68
passes along the length of the vessel 12, propelled by the flow of
support liquid 14.
In the illustrated apparatus 10, the body 68 is removed onto a
continuous flexible substrate 70. The feed roll 72 of the substrate
material is supported on a stand 74 located adjacent the vessel 12.
Guide rollers 75 and 76 support the substrate 70 and conduct it to
a take-off roller. Substrate 70 passes around the take-off roller
78, and then over a further guide roller 80. As it passes around
the lowest point of take-off roller 78, the substrate 70 is in
tangential lapping contact with the support liquid 14. As the body
68 advances into contact with the moving substrate 70, it is drawn
off the support liquid 14. Substrate 70, with the body 68 thereon,
then passes through a drying chamber 82 wherein any remnant of the
support liquid 14 which may cling to substrate 70 or the body 68 is
blown free by air pressure. Next, substrate 70 is conducted through
a curing oven 84 wherein body 68 is heated to a temperature above
the fusion temperature of the plastisol. In some instances, wherein
the substrate 7 is of a suitable polymeric material, the body 68
may be fused to the substrate 70 as fusion of the plastisol takes
place. Alternatively, the body 68 may be loosely and removably
adhered to the substrate 70.
Plastisol bodies 40 and 42 may be extruded from the nozzles 34 and
36 at timed intervals, to provide a continuous production of bodies
68. The rate of production is determined in part by the properties
of the plastisol formulation used. It is of course necessary that
the formulation gel prior to the time the body 68 arrives at the
take-off roller 78. Also, it is necessary that the speed of the
take-off roller 78 be correlated with the speed of movement of
support liquid 14 in the vessel 12. The body 68, in its gelled but
unfused state, has but limited tensile strength. Accordingly, the
surface velocity of take-off roller 78 and substrate 70 is
preferably such that acceleration of the body 68 as it leaves
support liquid 14 is minimal. In one operative apparatus for
performing the present method, substrate speeds of about 20 feet
per minute have been maintained.
In the illustrated apparatus for performing the present method, the
bodies 68 are removed from the support liquid 14 to a substrate 70.
In fact, it has been found feasible to remove the bodies 68
directly onto a roller. The bodies 68 may then be taken from the
roller by a doctor blade or the like, placed on support sheets of
any suitable material, and then subjected to further
processing.
Bodies 68 may be incorporated whole into a finished product. As an
alternative, they may be cut into smaller particles of a desired
size and shape prior to further processing.
Referring now to FIG. 7, there is seen a representative
manufactured article, namely a flooring tile, using the decorative
article manufactured in accordance with the present process. The
tile 86 includes a substrate member of suitable plastic polymeric
material, such as polyvinyl chloride. Triangular portions 90, cut
from finished bodies 68, are distributed over the substrate member
88. A coating 92 of water-white plastic polymeric material, such as
polyvinyl chloride, overlies the substrate member 88 and
encapsulates the triangular portions 90. Floorings including
transparent overlays, such as the above-described tile 86 are not
per se new. The variegated marble-like appearance of the triangular
portions 90, however, creates a highly decorative effect not
heretofore practicable on a commercial scale.
The present invention may be embodied in other specific forms
without departing from the spirit or essential attributes
thereof.
* * * * *