U.S. patent number 3,679,102 [Application Number 05/008,726] was granted by the patent office on 1972-07-25 for aerosol composition and method for producing same.
This patent grant is currently assigned to L'Oreal. Invention is credited to Roger Charle, Gregoire Kalopissis, Charles Zviak.
United States Patent |
3,679,102 |
Charle , et al. |
July 25, 1972 |
AEROSOL COMPOSITION AND METHOD FOR PRODUCING SAME
Abstract
A sprayable aerosol composition is prepared by encapsulating a
material in a microcapsule and introducing into said microcapsule a
fluid under a pressure essentially equal to the pressure in the
aerosol container from which said composition is dispensed. Also
provided is an aerosol dispenser containing under pressure said
microcapsules dispersed in an aerosol propellant.
Inventors: |
Charle; Roger (Soisy,
FR), Kalopissis; Gregoire (Paris, FR),
Zviak; Charles (Franconville, FR) |
Assignee: |
L'Oreal (Paris,
FR)
|
Family
ID: |
19725896 |
Appl.
No.: |
05/008,726 |
Filed: |
February 4, 1970 |
Foreign Application Priority Data
Current U.S.
Class: |
424/501;
206/524.1; 206/828; 252/364; 264/4.1; 401/132; 424/45; 424/62;
428/402.2; 516/7; 206/205; 206/540; 264/4; 264/4.4; 401/190;
424/47; 424/69; 428/402.22 |
Current CPC
Class: |
B01J
13/025 (20130101); B01J 13/203 (20130101); Y10S
206/828 (20130101); Y10T 428/2984 (20150115); Y10T
428/2987 (20150115) |
Current International
Class: |
B01J
13/02 (20060101); B01J 13/20 (20060101); A61j
003/00 (); A61k 007/12 () |
Field of
Search: |
;424/14,45-47
;252/305,316,364 ;401/132,190 ;222/192,394 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
Miles J. M. et al., J. Soc. Cosmet. Chem. 22: 655-666 (Sept. 17,
1971) Encapsulated Perfumes in Aerosol Products.".
|
Primary Examiner: Rose; Shep K.
Claims
What is claimed is:
1. An aerosol dispenser provided with a valve through which the
contents thereof are discharged therefrom and containing a
propellant under pressure and sprayable microcapsules dispersed
therein, said microcapsules encapsulating a liquid cosmetic or
pharmaceutical material and a fluid under pressure to provide a
liquefied encapsulated pressuring medium, said microcapsules having
walls compatible with and permeable to said aerosol propellant and
having a size ranging from about 50 - 1000 microns in diameter and
being less than the diameter of the valve of said aerosol dispenser
in which said propellant and microcapsules are packaged; said fluid
encapsulated in said microcapsules under pressure and said
propellant in which said microcapsules are dispersed and stored
being essentially the same and comprising a liquefied gas of a
fluorinated hydrocarbon selected from the group consisting of
trichlorofluoromethane, dichlorofluoromethane and mixtures thereof
or a saturated aliphatic hydrocarbon selected from the group
consisting of propane, isobutane, n-butane and mixtures thereof,
said liquid cosmetic or pharmaceutical material being miscible with
said liquefied pressuring medium and the internal pressure of said
microcapsules containing said liquid cosmetic or pharmaceutical
material and said liquefied pressuring medium being essentially
equal to the pressure of said propellant in said dispenser but
greater than the atmosphere into which said microcapsules are to be
sprayed so that said microcapsules without any independent action
of the user upon actuating the valve of the dispenser to discharge
said microcapsules into the atmosphere through the valve of the
dispenser, rupture as soon as said microcapsules come into contact
with the atmosphere thereby releasing said liquid cosmetic or
pharmaceutical material therefrom.
2. An aerosol dispenser provided with a valve through which the
contents thereof are discharged therefrom and containing a
propellant under pressure and sprayable microcapsules dispersed
therein, said microcapsules encapsulating a liquid cosmetic or
pharmaceutical material and a fluid under pressure to provide a
liquefied encapsulated pressuring medium, said microcapsules having
walls compatible with said aerosol propellant and having a size
ranging from about 50 - 1000 microns in diameter and being less
than the diameter of the valve of said aerosol dispenser in which
said propellant and microcapsules are packaged; said fluid
encapsulated in said microcapsules under pressure and said
propellant in which said microcapsules are dispersed and stored
being essentially the same and comprising a liquefied gas of a
fluorinated hydrocarbon selected from the group consisting of
trichlorofluoromethane, dichlorofluoromethane and mixtures thereof
or a saturated aliphatic hydrocarbon selected from the group
consisting of propane, isobutane, n-butane and mixtures thereof,
said liquid cosmetic or pharmaceutical material being miscible with
said liquefied pressuring medium and the internal pressure of said
microcapsules containing said liquid cosmetic or pharmaceutical
material and said liquefied pressuring medium being essentially
equal to the pressure of said propellant in said dispenser but
greater than the atmosphere into which said microcapsules are to be
sprayed so that said microcapsules without any independent action
of the user upon actuating the valve of the dispenser to discharge
said microcapsules into the atmosphere through the valve of the
dispenser, rupture as soon as said microcapsules come into contact
with the atmosphere thereby releasing said liquid cosmetic or
pharmaceutical material therefrom.
3. A method for producing and dispensing a sprayable aerosol
composition contained under pressure in an aerosol dispenser
provided with a valve through which the contents thereof are
discharged therefrom into an atmosphere having a pressure less than
the pressure in said aerosol dispenser, said composition comprising
an aerosol propellant and sprayable microcapsules dispersed
therein, said microcapsules encapsulating a liquid cosmetic or
pharmaceutical material and a fluid under pressure to provide a
liquefied encapsulated pressuring medium, said microcapsules having
walls compatible with and permeable to said aerosol propellant and
having a size ranging from about 50 - 1000 microns in diameter and
being less than the diameter of the valve of said aerosol dispenser
in which said propellant and microcapsules are contained, the steps
comprising microencapsulating said liquid cosmetic or
pharmaceutical material in said microcapsules; placing said
microcapsules in an atmosphere containing said fluid at a pressure
sufficient for said fluid to permeate the microcapsule walls so
that fluid is contained within said microcapsules as a liquid to
provide a liquefied encapsulated pressuring medium; dispersing at
said pressure the resulting microcapsules containing said liquid
cosmetic or pharmaceutical material and liquefied pressuring medium
in an aerosol propellant, liquefied pressuring medium and said
aerosol propellant in which said microcapsules are dispersed and
stored being essentially the same and comprising a liquefied gas of
a fluorinated hydrocarbon selected from the group consisting of
trichlorofluoromethane, dichlorofluoromethane and mixtures thereof
or a saturated aliphatic hydrocarbon selected from the group
consisting of propane, isobutane, n-butane and mixtures thereof,
said liquid cosmetic or pharmaceutical material being miscible with
said liquefied pressuring medium; and confining under pressure said
microcapsules, containing said liquefied cosmetic or pharmaceutical
material and liquefied pressuring medium, dispersed in said aerosol
propellant in said aerosol dispenser, the internal pressure of said
microcapsules containing said liquefied cosmetic or pharmaceutical
material and said liquefied pressuring medium being essentially
equal to the pressure of said aerosol propellant in said dispenser
but greater than the atmosphere into which said microcapsules are
to be sprayed so that said microcapsules without any independent
action of the user upon actuating the valve of the dispenser
rupture as soon as said microcapsules come into contact with the
atmosphere thereby releasing said liquid cosmetic or pharmaceutical
material therefrom.
4. A method for producing and dispensing a sprayable aerosol
composition contained under pressure in an aerosol dispenser
provided with a valve through which the contents thereof are
discharged therefrom into an atmosphere having a pressure less than
the pressure in said aerosol dispenser, said composition comprising
an aerosol propellant and sprayable microcapsules dispersed
therein, said microcapsules encapsulating a liquid cosmetic or
pharmaceutical material and a fluid under pressure to provide a
liquefied encapsulated pressuring medium, said microcapsules having
walls compatible with said aerosol propellant and having a size
ranging from about 50 - 1000 microns in diameter and being less
than the diameter of the valve of said aerosol dispenser in which
said propellant and microcapsules are contained, the steps
comprising microencapsulating said liquid cosmetic or
pharmaceutical material in admixture with said fluid in said
microcapsules at a sufficiently low temperature and at a pressure
so that said fluid provides a liquefied pressuring medium
encapsulated therein; dispersing the resulting microcapsules,
containing said liquid cosmetic or pharmaceutical material and
liquefied pressuring medium, in an aerosol propellant, said
liquefied pressuring medium and said aerosol propellant in which
said microcapsules are dispersed and stored being essentially the
same and comprising a liquefied gas of a fluorinated hydrocarbon
selected from the group consisting of trichlorofluoromethane,
dichlorofluoromethane and mixtures thereof or a saturated aliphatic
hydrocarbon selected from the group consisting of propane,
isobutane, n-butane and mixtures thereof, said liquid cosmetic or
pharmaceutical material being miscible with said liquefied
pressuring medium; and confining, under pressure, said
microcapsules, containing said liquid cosmetic or pharmaceutical
material and liquefied pressuring medium, dispersed in said aerosol
propellant in said aerosol dispenser, the internal pressure of said
microcapsules containing said liquid cosmetic or pharmaceutical
material and said liquefied pressuring medium being essentially
equal to the pressure of said aerosol propellant in said dispenser
but greater than the atmosphere into which said microcapsules are
to be sprayed so that said microcapsules without any independent
action of the user upon actuating the valve of the dispenser to
discharge said microcapsules into the atmosphere through the valve
of the dispenser, rupture as soon as said microcapsules come into
contact with the atmosphere thereby releasing said liquid cosmetic
or pharmaceutical material therefrom.
Description
This invention relates to a method for producing a sprayable
aerosol composition containing a self-releasable encapsulated
material and to an aerosol dispenser containing said encapsulated
material dispersed in a propellant.
More particularly, the present invention relates to the production
of an aerosol composition containing an encapsulated material which
can be released therefrom without the need of mechanical, chemical
or thermal means.
The present invention has been found to be particularly useful in
the cosmetic and pharmaceutical industry and in the packaging of
maintenance products, for projecting active ingredients onto the
surface where they are to act, and to obtain automatic liberation
of these ingredients on the said support.
The present invention is a method for producing a sprayable aerosol
composition containing a self-releasable encapsulated material
which comprises encapsulating the material to be sprayed in the
form of an aerosol in a rupturable microcapsule having a size
ranging from about 50 to 1000 microns in diameter and introducing
into said microcapsule a fluid under sufficient pressure so that
when said microcapsule, dispersed in an aerosol propellant, is
sprayed into an atmosphere having a pressure less than the pressure
of the fluid in said microcapsule, the microcapsule ruptures,
thereby releasing the material contained therein.
Preferably, in the present invention the propellant in which the
microcapsules are dispersed and stored and the fluid contained in
the microcapsules under pressure are essentially the same. Thus,
this fluid and propellant can conveniently be a fluorinated
hydrocarbon and particularly a fluorochloroalkane such as
trichlorofluoromethane and dichlorofluoromethane or their mixtures.
Moreover, the propellant can be a saturated aliphatic hydrocarbon
such as propane, isobutane, n-butane or the like. The aerosol
dispenser in which the propellant and microcapsules are packaged
will have a valve provided with a diaphragm, having a diameter
greater than the maximum diameter of the microcapsules.
In one embodiment of the present invention, a fluid having
sufficient pressure to rupture the micro-capsule when sprayed into
the atmosphere is introduced into the microcapsule in the liquid
state in admixture with the material to be released therefrom on
rupturing. In this case, microencapsulation is carried out at a
sufficiently low temperature and pressure so that the fluid is in
the liquid. When the material being encapsulated is itself a
liquid, it must be miscible with the liquified pressuring medium,
especially when the releasable material is an alcohol solution, and
the liquified pressuring medium gas is a mixture of
fluorochloroalkanes.
In another embodiment of the present invention, the material to be
released is initially microencapsulated in the absence of any
pressurizing medium, and the micro-capsules are then placed in an
atmosphere of the desired pressurizing medium at a pressure
sufficient for the said pressurizing medium to permeate the
microcapsule walls in a time ranging from a few minutes to a few
days.
The present invention is also related to an aerosol dispenser
containing a suitable propellant and the microcapsules defined
above. Thus, when these components are sprayed from the pressurized
dispenser, it will be evident that when the user depresses the
valve of the dispenser, the microcapsules, having dispersed therein
the propellant having an internal pressure at least equal to the
pressure of the propellant in the dispenser but greater than the
atmosphere into which they are sprayed will rupture as soon as they
come in contact with the atmosphere. Packaging will thus be
achieved in which the microcapsules exist during storage and which
do not have to be destroyed by any independent action of the user
at the time of dispensing the same onto the desired surface.
The microcapsules used in the present invention can be made of any
conventionally employed material in the microencapsulation field.
Representative of polymeric materials to produce the microcapsules
are such polymers as polyvinyl alcohol, polyethylene,
polypropylene, polystyrene, polyacrylamides, polyethers,
polyesters, polyamides, polybutadiene, polyisoprene, epoxy resins,
polyurethanes, ethylcellulose, carboxymethylcellulose and the like.
Preferably, the microcapsules are made from a thermoplastic polymer
such as low melting polyethylene; the latter is particularly
applicable when the pressurizing gas is a mixture of
fluorochloroalkanes and when this mixture of fluorochloroalkanes is
introduced into the microcapsules by using the permeability
characteristics of the wall. The nature of the walls will generally
be chosen for its compatibility with the propellant in which the
microcapsules are placed. Generally, the ratio of the weight of the
wall to the total weight of the filled microcapsule ranges between
3-10:100.
Any convenient technique of microcapsule fabrication can be used,
particularly microencapsulation by mechanical means such as
centrifugal microencapsulation. In this method droplets of the
material to be encapsulated are formed by the centrifugal force of
a turntable which then traverse by means of the velocity which they
thus acquire, a thin film of fluid product designed to form the
wall of the microcapsule. A conventional wall-hardening treatment
can be employed which, in the case where the wall is prepared from
a thermoplastic material, can simply be a sudden cooling of the
microcapsules formed. Representative suitable microencapsulation
operations can be found in the literature, for instance in U.S.
Pat. No. 3,015,128.
The material encapsulated in the microcapsules can be, for
instance, such cosmetic preparations as hair dyes, bleaches,
dressing composition or the like, pharmaceutical preparations
including antiseptics, topical anesthetics, or such products as
stain-removing agents, finely divided solid inorganic absorbents
such as talc and the like.
In order to gain a better understanding of the invention, the
following example is provided.
EXAMPLE
Mechanical centrifuging is used to prepare microcapsules with
average dimensions of approximately 400 microns from low melting
polyethylene. The microencapsulated liquid has the following
composition:
nonylphenol condensed with 4 molecules of ethylene oxide 23 g
nonylphenol condensed with 9 molecules of ethylene oxide 25 g copra
diethanolamide 6 g butyl glycol 2 g propylene glycol 16 g 20%
ammonia 12 ml paratoylenediamine 0.9 g paraaminophenol 0.9 g
m-diaminoanisole sulfate 0.06 g m-aminophenol 0.2 g resorcinol 0.5
g nitroparaphenylenediamine 0.002 g hydroquinone 0.10 g sodium salt
of diethylene- triaminepentaacetic acid 1.5 g sodium bisulfite 1.2
ml water 100 g
The microcapsules thus formed are placed in a atmosphere of a
fluorochloralkane at a relative pressure of 1.5 kg/cm.sup.2. This
pressure is maintained for several days, after which the
microcapsules are transferred, the external pressure being kept the
same, to a liquid medium compatible with the wall, such as, for
example, trichlorofluoromethane, dichlorodifluoromethane, or
dichlorotetrafluoromethane. The liquid medium containing the
microcapsules is then placed in a pressurized "aerosol can" type
container at a pressure above 1.5 kg/cm.sup.2 by means of a
fluorochloroalkane. The liquid present in the pressurized container
is dispensed directly onto hair to be dyed by the action of the
container valve; the diaphragm associated with the valve having an
aperture 1 mm in diameter. An oxidant is added to the dye thus
placed on the hair. Alternatively, an oxidant can be included in
the propellant. After 15 minutes, a chestnut brown coloration is
obtained on 70 percent white hair.
* * * * *