U.S. patent number 3,678,992 [Application Number 05/061,706] was granted by the patent office on 1972-07-25 for thermal regenerator.
This patent grant is currently assigned to U.S. Philips Corporation. Invention is credited to Alexander Daniels.
United States Patent |
3,678,992 |
Daniels |
July 25, 1972 |
THERMAL REGENERATOR
Abstract
A thermal regenerator having a matrix of a plurality of hollow,
carbon, micro-spheres which are permeable to and contain a gas such
as helium; the matrix having low heat conductivity between the
carbon spheres, but high heat capacity of the helium which
increases as temperatures decrease from 40.degree. K. to about
9.degree. K.
Inventors: |
Daniels; Alexander (Briarcliff
Manor, NY) |
Assignee: |
U.S. Philips Corporation (New
York, NY)
|
Family
ID: |
22037566 |
Appl.
No.: |
05/061,706 |
Filed: |
August 6, 1970 |
Current U.S.
Class: |
165/10; 62/6 |
Current CPC
Class: |
F28D
17/02 (20130101); F25B 9/14 (20130101); F25B
2309/003 (20130101) |
Current International
Class: |
F25J
3/00 (20060101); F25B 9/14 (20060101); F28d
017/00 () |
Field of
Search: |
;165/4,10 ;62/6 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Davis, Jr.; Albert W.
Claims
What is claimed:
1. A regenerator comprising a housing and within the housing a
plurality of carbon heat-storage elements each having walls which
are permeable to gas and which define an interior space into which
a quantity of said gas is diffusible and retainable, and a quantity
of said gas contained within said spaces.
2. A regenerator according to claim 1 wherein said gas is helium
and wherein said walls adsorb a quantity of said helium.
3. A regenerator according to claim 2 wherein said elements have a
spherical outer surface with a diameter in the range of about 5 to
150 microns.
4. A regenerator according to claim 3 wherein said spheres have a
wall thickness in the range of about 1 to 2 microns.
5. A regenerator according to claim 1 wherein the elements within a
housing have bulk density in the range of about 0.13 to 0.14
gm/cc.
6. A regenerator according to claim 1 wherein the housing has an
internal volume and said elements are spheres which occupy about 63
percent of the volume.
7. A regenerator comprising a housing having an internal volume, a
plurality of hollow, thin-walled carbon spheres having diameter in
the range of about 80 to 110 microns and occupying about 63 percent
of the volume within the housing, and helium gas diffused into
hollows of the spheres and adsorbed into the walls thereof.
8. A regenerator according to claim 2 wherein each element defines
a closed geometric outer shape and each element has substantially
only single point outer surface contact with each other immediately
adjacent element.
9. A method of manufacturing a regenerator according to claim 1
comprising the steps:
a evacuating air and any other gases from a plurality of said
carbon heat-storage elements and subsequently,
b. exposing said evacuated elements to helium gas thus diffusing
said gas into the elements and
c. disposing said elements within said housing.
10. A method according to claim 9 comprising the further steps of
heating the elements during said evacuating.
11. A method according to claim 9 comprising the further steps of
pressurizing said helium gas, while diffusing it into the
elements.
12. A regenerative-cycle thermodynamic apparatus such as a
refrigerator, wherein the regenerator housing comprises a matrix of
a plurality of hollow carbon spheres and a quantity of helium gas
contained within the hollows of and adsorbed in the walls of said
spheres, the matrix having a specific heat corresponding to that of
helium gas.
13. In a regenerative-cycle apparatus such as a refrigerator which
includes a regenerator having helium gas contained in hollow,
carbon heat-storage elements, and in which a working gas is flowed
through the regenerator and is subsequently cooled and flowed back
through the regenerator, an improved method of regenerating heat in
the working gas comprising:
a. flowing the working gas into contact with said elements,
b. transferring heat from the working gas through the elements into
the helium gas,
c. storing the heat in the helium gas,
d. subsequently flowing the cooled working gas again through the
regenerator and into contact with said elements, and
e. transferring heat from the helium gas back into the working
gas.
14. A regenerator comprising a housing and within the housing a
plurality of heat storage elements, each element having walls
defining a continuous outer surface and an interior space for
containing helium gas, the walls comprising a material (a) through
which helium is diffusible into said interior space and (b) into
which the helium is adsorbable.
Description
BACKGROUND OF THE INVENTION
In cryogenic refrigerators such as those operating on a
regenerative cycle, as the Stirling cycle, the essential
`regenerator` component can be a very limiting factor as regards
the overall efficiency of the apparatus, the lowest temperature
which can be reached, and the cold-production capacity of the
apparatus. Typically in these devices a quantity of gas such as
helium is transported through a series of stages, namely
compression, then cooling to remove heat of compression, followed
by flowing the gas through a regenerator where a significant
quantity of heat is absorbed from the gas and stored; next there is
expansion of the gas to its lowest temperature where cold is
produced, and finally re-cycling the gas back through the
regenerator where it re-acquires the heat previously stored there,
and returning the gas to the compression chamber to begin a new
cycle. Regenerators for apparatus as described above have been made
of a variety of materials and in a variety of configurations. In
each case the design criteria included one or more of the following
factors: the regenerator should have high heat-capacity at the
cryogenic operating temperatures, but low heat conductivity from
the hot side to the cold side; the regenerator should have low
resistance to flow, but also be reasonably small and light; and
finally cost and complexity should be minimized.
It has been found that materials such as copper, gold and lead have
very high heat capacities at temperatures below 40.degree. K., and
accordingly these materials have been commonly used in the
manufacture of prior art regenerators. More particularly these
materials have been formed into matrices comprising wire, mesh or
gauze, or a bundle of fibers, or solid spheres, or metal pellets
secured to a non-heat-conductive spiral band of paper, with the
metal elements absorbing heat upon contact with the gas flowing
through or about them. Certain of the above regenerator structures
are disclosed in U.S. Pat. Nos. 2,797,539; 3,339,627; and 3,384,157
and in other prior art publications, with complex equations having
been evolved in attempts to improve regenerative characteristics;
however in all known devices of this general type the ultimate
efficiency has been limited by the fact that the specific heat of
materials, even including lead, at cryogenic temperatures
diminishes as temperatures decrease, and decline to almost zero at
temperatures below 10.degree. K. Consequently, despite the many
different shapes and arrangements of regenerators, this specific
heat limitation has persisted as factor affecting performance of
regenerative-cycle devices and refrigerators.
SUMMARY OF THE NEW INVENTION
According to the new invention there is provided a regenerator
having a higher specific heat at temperatures below 10.degree. K.
than previously available. This invention became possible with the
development of hollow carbon spheres and the discovery that a gas
such as helium could be diffused into and retained in the spheres.
While heat can be stored in the helium within a plurality of
adjacent spheres, the heat is not readily transferred between
spheres through their carbon walls, so that there is little heat,
or cold leakage between the hot and cold sides of the new
regenerator.
When the new regenerator is situated either in a movable displacer
or at a fixed location in a regenerative-cycle refrigerator, a
working gas such as helium is flowed through the regenerator matrix
of helium-impregnated carbon micro-spheres where there is heat
transfer through the walls of the carbon spheres, and heat storage
by the helium within the walls. Great heat capacity of the new
matrix is obtained because of the unique specific heat
characteristics of helium gas which increases as temperature
decreases; thus the specific heat v. temperature curve of helium
gas in generally opposite that of the three commonly used matrix
materials, copper, gold and lead. At 6.degree. K. for example, the
specific heat of copper declines to almost zero, and lead to about
0.09J/cm.sup.30 K., while the specific heat of helium increases to
about 0.165J/cm.sup.30 K., or nearly double that of lead. Summarily
it can be seen that at a temperature such as 6.degree. K., even
lead, one of the best of the known materials for regenerators, has
no significant heat capacity left, while helium gas has very
substantial heat capacity, which renders the new carbon
sphere-helium matrix far more effective than any prior art
counterpart.
The invention encompasses the new regenerator and method of making
it, and the method of regenerating heat in using this device in a
regenerative-cycle thermodynamic refrigerator. For operation at
cryogenic temperatures of below 15.degree. K. and particularly at
about 6.degree. K., helium is the gas selected for diffusion into
the spheres, with some of this gas also adsorbed by the carbon
walls of the spheres. In manufacturing these matrices the
gas-permeable carbon spheres are first evacuated of air and other
gas, and then the helium gas is diffused into the spheres, with
evacuation and diffusion both being accelerated if the gas is
heated, and diffusion being further accelerated if pressure is
applied to the helium.
In a practical application of this invention the new regenerator is
incorporated into a regenerative-cycle refrigerator; then working
gas is flowed through the regenerator where it contacts the spheres
and heat is transferred through the sphere walls into the helium
gas where the heat is stored. Subsequently in the thermodynamic
cycle, the cooled working gas is flowed back through the
regenerator where stored heat is transferred back to the working
gas.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a chart showing specific heat vs. temperature curves for
helium, lead, gold and copper;
FIG. 2 is a sectional view of a Stirling-cycle refrigerator with a
regenerator of this invention, and
FIG. 3 is a fragmentary sectional view of the new regenerator.
DESCRIPTION OF THE PREFERRED EMBODIMENT
The new invention has been developed because of the available
properties of helium gas at cryogenic temperatures as shown in FIG.
1, namely high specific heat at low temperature. The specific heats
of lead, gold and copper are similar in that they decline steeply
with reduced temperature in the range of 0.degree. to 40.degree. K.
And, in the area of 6.degree. K., which is of practical interest,
the specific heats of gold and copper are almost zero, and that of
lead is about 0.08 which is essentially impractical. The chart then
shows the remarkably contrasting specific heat curve of helium gas
which rises as temperature decreases, and most significantly is
about 0.165 at 6.degree. K., or almost double that of lead.
While it was thus known that helium had a high specific heat at the
low cryogenic temperatures of interest, there was no known manner
of utilizing this property; furthermore since the working gas in
typical, Stirling regenerative-cycle refrigerators was also helium,
developments in regenerator construction were generally restricted
to metal and other solid materials.
By this invention, it was discovered that carbon micro-spheres
having diameter in the range of 90 to 100 microns could be
permeated with helium gas after air and any other gas was removed.
Then these spheres become the matrix disposed in a housing, to form
the regenerator component of a cold-gas refrigerator. By their
inherent geometry the spheres will occupy about 63 percent of the
volume in which they are housed, as shown in FIGS. 2 and 3. The
size of the spheres available, from 5 to 150 microns, and thus the
quantity per unit volume of space, affect both potential heat
transfer and pressure drop of gas flowing through such a matrix.
Smaller spheres permit greater heat transfer, but cause greater
pressure drop; while larger spheres result in poorer heat transfer,
but a lower pressure drop. These parameters are variable to
establish optimum conditions of each refrigerator.
In FIG. 3 the Stirling-cycle refrigerator 15 has a compression
piston 16 and compression chamber 17, a piston rod 18, and a cooler
19. The cold finger 20 has three expansion stages 20, 21, and 22
and correspondingly a displacer with three stepped diameters 23,
24, and 25, and finally freezer 26 adjacent the final expansion
stage. A displacer rod 27 extending through the compression piston
and rod, 16 and 18, is connected to the base of the displacer at
28, and encompassing the cold finger 20 is outer casing 29 and
vacuum space 30.
Within the displacer sections are regenerator 31, 32 and 33, with
at least one of these regenerators having a matrix of helium-filled
carbon spheres 34 of the new invention. The gaseous working medium
of this refrigerator is helium transported from the compression
space 17 to the first, second and third expansion spaces 20, 21,
and 22. In passing through the new regenerator, the gas contacts
the carbon spheres and transfers heat to the helium gas within the
spheres. Another significant characteristic of the new regenerator
matrix is that there is very low heat flow between spheres, due to
the mere point contact between each pair of adjacent spheres, and
also because the porous carbon is a poor conductor of heat. Thus,
there is small heat flow from the hot to the cold end of the
regenerator, and thus very little leakage or loss of cold produced
at each expansion stage. Furthermore the heat storage capacity is
somewhat enhanced by the fact that helium gas is adsorbed by the
carbon walls, in addition to being contained within the
spheres.
With the new regenerator low temperatures around 6.degree. K. will
be attained, which is a particularly significant achievement in
small or miniature cryogenic refrigerators. In the operation of
these apparatus other working gas parameters are generally the
same, namely a working gas average charging pressure of 50 to 75
psig, and a pressure drop of about 5 psi.
In manufacturing matrices for the new regenerator suitable carbon
spheres are sold under the name "Carbo-Spheres" by the General
Technologies Corporation, 1821 Michael Faraday Drive, Reston, Va.,
22070.
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