U.S. patent number 3,675,096 [Application Number 05/130,644] was granted by the patent office on 1972-07-04 for non air-polluting corona discharge devices.
This patent grant is currently assigned to RCA Corporation. Invention is credited to Helmut Gustav Kiess.
United States Patent |
3,675,096 |
Kiess |
July 4, 1972 |
NON AIR-POLLUTING CORONA DISCHARGE DEVICES
Abstract
A corona generating device, adapted to operate in air, to apply
an electrostatic charge to a surface, includes an elongated,
knife-edged, corona-generating electrode enclosed within a housing.
The housing includes a foraminous screen that has an optical
transmission of less than 50 percent to prevent ultraviolet light
produced by the corona from reaching the surface to be charged. The
screen and the interior of the housing are formed, or coated, with
a catalytic material, such as silver, to convert any ozone formed
by the corona discharge, to oxygen, thereby preventing pollution of
the air with toxic ozone.
Inventors: |
Kiess; Helmut Gustav
(Hightstown, NJ) |
Assignee: |
RCA Corporation (N/A)
|
Family
ID: |
22445655 |
Appl.
No.: |
05/130,644 |
Filed: |
April 2, 1971 |
Current U.S.
Class: |
250/326;
101/DIG.37; 423/219; 250/325 |
Current CPC
Class: |
H05F
3/04 (20130101); G03G 15/0291 (20130101); Y10S
101/37 (20130101) |
Current International
Class: |
G03G
15/02 (20060101); H05F 3/00 (20060101); H05F
3/04 (20060101); H01t 019/00 () |
Field of
Search: |
;317/262A,262AE,2F,2R
;204/176,313 ;250/49.5ZC,49.5GC |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
"Guide to Corona Film Treatment" by von der Heide & Wilson, May
1961, issue of Modern Plastics, p. 200.
|
Primary Examiner: Miller; J. D.
Assistant Examiner: Moose, Jr.; Harry E.
Claims
I claim:
1. Apparatus, adapted to operate in air, for applying an
electrostatic charge to a surface, said apparatus comprising:
an electrically conductive housing comprising a foraminous screen
as a portion thereof, said screen being adapted to be disposed
adjacent said surface to be charged,
a corona generating electrode enclosed within said housing and
insulated therefrom, said electrode being disposed adjacent to said
screen and adapted to generate, when energized, a corona discharge
in the general direction of said screen, said corona discharge
producing ozone in air, and
a catalyst within said housing and spaced from said corona
generating electrode for converting said ozone to oxygen.
2. Apparatus, adapted to operate in air, for applying an
electrostatic charge to a surface as described in claim 1,
wherein
said screen has an optical transmission of less than 50
percent.
3. Apparatus, adapted to operate in air, for applying an
electrostatic charge to a surface as described in claim 1,
wherein
said catalyst comprises a metal selected from the group consisting
of silver, gold, nickel, platinum, iron, and alloys thereof.
4. Apparatus, adapted to operate in air, for applying an
electrostatic charge to a surface as described in claim 1,
wherein
said screen comprises a catalyst for converting ozone to oxygen,
said catalyst comprising a metal selected from the group consisting
of silver, gold nickel, platinum, iron, and alloys thereof.
5. Apparatus, adapted to operate in air, for applying an
electrostatic charge to a surface as described in claim 1,
wherein
said catalyst comprises a metal oxide selected from the group
consisting of nickel sesquioxide, barium monoxide, cupric oxide,
and silver peroxide, and
means within said housing containing said metal oxide so that said
ozone may come in contact with said metal oxide.
6. In apparatus, adapted to operate in air, for applying an
electrostatic charge to a surface, wherein a corona generating
electrode is enclosed within an electrically conductive housing,
the improvement comprising:
a foraminous screen comprising a portion of said housing, said
screen being adapted to be disposed adjacent said surface to be
charged, said screen having an optical transmission of less than 50
percent;
said electrode comprising an elongated strip of metal elongated in
a direction substantially parallel to said surface, formed with a
knife edge pointing in the general direction of said screen, said
electrode being adapted to generate, when energized, a corona
discharge with an electric wind in the general direction of said
screen, said corona discharge producing ozone in air, and
a catalyst spaced from said electrode and cooperatively associated
with said housing for converting said ozone to oxygen.
7. In apparatus, adapted to operate in air for applying an
electrostatic charge to a surface, as described in claim 6,
said catalyst comprising an oxide selected from the group
consisting of nickel sesquioxide, barium monoxide, cupric oxide,
and silver peroxide;
foraminous means disposed within said housing for containing said
catalyst,
a second foraminous screen, spaced from said first-mentioned
foraminous screen, and comprising another portion of said housing;
and
air moving means cooperatively associated with said housing for
moving ozone within said housing through said second screen.
Description
BACKGROUND OF THE INVENTION
This invention relates generally to apparatus, adapted to operate
in air, for applying an electrostatic charge to a surface; and,
more particularly, to non air-polluting corona discharge devices.
The improved corona discharge devices of the present invention are
particularly useful for electrostatically charging recording
elements employed in the electrostatic printing art.
In electrophotographic printing processes in common use it is
necessary to apply a uniform electrostatic charge, in darkness, to
the surface of a photoconductive layer of a recording element. When
the recording element is exposed to a light image, developed with a
pigmented toner, and fixed, it provides a copy of the image to
which it was exposed. It has been proposed to charge the surface of
the recording element electrostatically by subjecting its
photoconductive surface to a corona discharge, in air, from a
corona discharge device disposed above the photoconductive surface.
While such a corona discharge device is suitable for charging a
photoconductive surface for many practical purposes, it produces an
ultraviolet glow which adversely affects uniform charging. Also,
the production of a corona discharge in air usually generates
ozone, which also adversely affects uniform charging and which,
even in very small quantities, is considered to be toxic to humans.
A concentration of 1 part ozone in 20,000 parts of air irritates
mucous membranes, when breathed, and is poisonous.
I have observed that ultraviolet light and ozone, both formed
during a corona discharge, discharge an electrostatically charged
electrophotographic recording element. In fact, I have observed
that ozone alone, in the absence of light, discharges a charged
photoconductive layer of zinc oxide in a resin binder very quickly,
actually in a matter of about one second. It is believed that the
spurious discharges of a charged photoconductive layer of a
recording element, caused by both the ozone and the ultraviolet
light during an electrophotographic process, produce unwanted,
spurious toning defects in the finished electrophotographic print.
This is especially observable in reversal prints wherein the
spurious discharges cause unwanted toned spots in background
(white) areas of the prints. The spurious toning defects degrade
the quality of the finished electrophotographic print.
SUMMARY OF THE INVENTION
The novel apparatus for applying an electrostatic charge to a
surface comprises a housing, having a foraminous screen as a
portion thereof. The screen is adapted to be disposed adjacent the
surface to be charged. A corona generating electrode is enclosed
within the housing and insulated therefrom. The electrode is
disposed adjacent to the screen and is adapted to generate, when
energized, a corona discharge in the general direction of the
screen. A catalyst is disposed within the housing to convert any
ozone that may be formed during the generation of the corona
discharge to oxygen, thereby preventing toxic ozone from polluting
the atmosphere.
In a preferred embodiment of the novel corona discharge device, the
screen has an optical transmission of less than 50 percent, and a
baffle plate disposed between the electrode and the surface to be
charged to shield the surface from both ultraviolet light and
ozone.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a cross-sectional view, in side elevation, of one
embodiment of a non air-polluting corona discharge device disposed
to apply an electrostatic charge to an electrophotographic
recording element;
FIG. 2 is a cross-sectional view taken along the line 2--2 in FIG.
1; and
FIG. 3 is a cross-sectional view, in side elevation, of another
embodiment of a non air-polluting corona discharge device disposed
to apply an electrostatic charge to a recording element.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Referring now to FIGS. 1 and 2, there is shown, in cross-section, a
non air-polluting corona discharge device 10 for applying an
electrostatic charge to a surface 12 of a photoconductive layer 14
of a recording element 16. The recording element 16 is of the type
commonly used in the electrostatic printing art. The recording
element 16 comprises a relatively electrically conductive substrate
18, such as paper, and the photoconductive layer 14, such as of
zinc oxide in a suitable resin binder thereon. The recording
element 16 is on an electrically conductive support plate 20,
disposed beneath the corona device 10, and adapted to be moved, by
any suitable means, in the direction of the arrow 52.
The corona discharge device 10 comprises an enclosed, electrically
conductive housing 22, formed by a downwardly extending shield 24,
a horizontally extending foraminous screen 26, a horizontally
extending baffle plate 28, and an upwardly extending foraminous
screen 30. The positional orientation described herein is merely
relative with respect to the horizontally disposed recording
element 16. It is within the contemplation of the present
invention, however, to orient the recording element 16 and the
corona discharge device 10 in positions other than horizontal. The
screens 26 and 30 are fixed to the shield 22 and to the baffle
plate 28 by any suitable means, as, for example, by welding or
soldering.
Means are provided to generate a corona discharge, that is, a
source of ions, when energized by a suitable power supply. To this
end, an elongated, corona generating electrode 32 is disposed
within the interior 34 of the housing 22. The electrode 32 is an
elongated band, or strip, formed with a knife edge 36 pointing in
the general direction of the screen 26, for the purpose hereinafter
appearing. The electrode 32 is insulated from the conductive baffle
plate 28 by insulating threaded studs 38 that extend upwardly from
the baffle plate 28. The studs 38 may be adhered to the baffle
plate 28 by any suitable means, such as by epoxy glue, and the
electrode 32 may be adjustably mounted on the threaded studs 38
with nuts.
The screens 26 and 30 should have an optical transmission of less
than 50 percent. The term "optical transmission," as used herein,
is defined as "the ratio of the area of the holes to the area of
both the holes and the non-holes of the screen, considering the
screen as a two dimensional planar object." Thus, the optical
transmission of a foraminous screen is essentially the percentage
of light it will transmit when exposed to light. I have found that
the optical transmission of the screen 26 should be less than 50
percent to prevent both ultraviolet light and ozone that may be
formed during the generation of a corona discharge from passing
from the interior 34 of the corona discharge device 10 onto the
surface 12 of the recording element 16. Also, the electrode 32 and
the baffle plate 28 are disposed with respect to each other so that
the baffle plate 28 prevents ultraviolet light, emanating from the
knife edge 36 of the electrode 32, from reaching the surface 12 of
the recording element 16. Thus, the baffle plate 28 is disposed
between the surface 12 of the recording element 16 and the
electrode 32. The junction 40, between the baffle plate 28 and the
screen 26, is disposed so that any ultraviolet light emanating from
the knife edge 36 of the electrode 32 does not reach the surface 12
to be charged.
Means are provided to energize the corona discharge device 10. To
this end, the negative terminal of a unidirectional power supply
42, represented symbolically herein as a battery, is connected to
the electrode 32 by a conductor 44 that passes through an insulator
46 positioned in the screen 30. The positive terminal of the power
supply 42 is connected to a point of reference potential, such as
ground. The shield 24 of the housing 22 is connected to ground
through a variable resistor 48 so that the potential of the shield
24 may be biased with respect to the positive terminal of the power
supply 42. The support plate 20 is connected to ground through a
variable voltage source 50, the positive terminal of the voltage
source 50 being connected to the plate 20 and the negative terminal
being grounded. Thus, the substrate 18 of the recording element 16
can be biased positively with respect to the electrode 32 and the
housing 22 to cause a negative corona discharge to be attracted to
the positively biased surface 12 of the recording element 16.
A negative electrostatic charge is applied to the surface 12 of the
recording element 16 by the corona discharge device 10 as follows:
A negative voltage of at least 5,000 volts with respect to ground
is applied to the electrode 32. The variable resistor 48 is
adjusted so that the voltage of the housing 22 is between 0 and
-500 volts with respect to ground. The variable voltage source 50
is adjusted so as to provide a voltage to the support plate 20 of
between about 0 and +400 volts with respect to ground. The support
plate 20 should be maintained at a positive potential with respect
to the housing 22. The corona discharge device 10 is disposed so
that the baffle plate 28 and screen 26 are parallel to, and about
5mm above, the surface 12 of the recording element 16. Under these
conditions, a negative corona discharge enanates from the knife
edge 36 of the electrode 32 in the direction of, and through, the
screen 26. The electric wind produced by the corona discharge blows
the negative ions on the corona through the screen 26 and onto the
surface 12 of the recording element 16.
The recording element 16 is usually adapted to be moved in the
direction of the arrow 52. It is also within the contemplation of
the present invention to move the corona discharge device 10 with
respect to either a fixed or a moving recording element 16. Any
radiation in the form of light that may emanate from the knife edge
36 of the electrode 32 during the generation of the corona
discharge is prevented from reaching the surface 12 by both the
baffle plate 28 and by the screen 26 (because of its limited
optical transmission of less than 50 percent).
I have observed that ozone is generated within the corona discharge
device 10 during the generation of the corona discharge. I have
also observed that ozone, alone and in darkness, discharges a
charged recording element 16. It is also well known that ozone,
even in the relatively small quantities of 50 parts of ozone to 1
million parts of air, is toxic to humans. An important feature of
the novel corona discharge device 10 is its provision for
preventing, or substantially reducing, the pollution of the
atmosphere by the ozone formed during the generation of the corona
discharge. To this end, the inner surface of the shield 24 and the
inner surface of the baffle plate 28 are coated with a catalytic
coating 54 of a catalyst for converting to oxygen any ozone that
may be formed. I have found silver to be substantially the best
coating 54 for catalyzing the chemical reaction:
Other suitable catalysts for the catalytic coating 54 are gold,
nickel, platinum, iron, and their alloys. Certain oxides are also
suitable catalysts. These are, for example, nickel sesquioxide
(Ni.sub.2 O.sub.3), barium monoxide (BaO), cupric oxide (CuO), and
silver peroxide (Ag.sub.2 O.sub.2). Some of these metal oxides may
be formed by first plating the shield 22 and the baffle plate 28
with a layer of the metal of the oxide and then oxidizing the
deposited metal layer to form the required metal oxide. For
example, a layer of nickel when heated at a temperature of between
400.degree. and 480.degree. C. is converted partially to the nickel
sesquioxide (Ni.sub.2 O.sub.3). Cupric oxide may be formed, for
example, by heating a copper coating in air until the surface of
the copper turns black.
The catalytic coating 54 of platinum can be formed by coating the
interior of the corona discharge device 10 with platinum, treating
the coating with aqua regia having an excess of nitric acid,
evaporating the acid, and heating the treated surface until it
turns black. The screens 26 and 30 are also either coated with, or
comprise, at least one of the aforementioned catalytic materials.
Hence, ozone formed within the interior 34 of the corona discharge
device 10 is acted upon by the catalytic coating 54 and the
catalytic material on the screens 26 and 30 to convert the ozone to
oxygen.
Referring now to FIG. 3, there is shown an improved corona
discharge device 60 which differs from the corona discharge device
10 in that the corona discharge device 60 does not have a baffle
plate to function as a light shield. The corona discharge device
60, however, employs a screen 62, similar in structure and function
to the screen 26 of the corona discharge device 10 with the
exception that the screen 62 may have an optical transmission that
is less than that of the screen 26. Thus, the optical transmission
of the screen 62 is between about 20 percent and 50 percent. Parts
of the corona discharge device 60 in FIG. 3 that are similar to
those of the corona discharge device 10 in FIG. 1 in both structure
and function are given the same reference numerals.
The corona discharge device 60 comprises an enclosed housing 64 of
which the screen 62 is a part. The housing 64 comprises a
rectangular box-like structure having side walls 66 and 68 and end
walls (not shown). A top wall 70 of the housing 64 comprises a
screen 70 similar in structure and function to the screen 30. An
elongated electrode 72 is disposed within the interior 74 of the
housing 64. The electrode 72 is supported within the interior 74 by
electrically insulating rods 76 and is disposed so that a knife
edge 78 of the electrode 72 causes a corona discharge therefrom to
flow in the general direction of the screen 62 and onto the surface
12 of the recording element 16.
The corona discharge device 60 is energized from a source 42 of
unidirectional voltage, the negative terminal of the voltage source
42 being connected to the electrode 72 through an insulator 80 in
the wall 66, the positive terminal being connected to a point of
reference potential, ground. The housing 64 is connected to ground
through a variable resistor 48 to bias it negatively with respect
to ground. The support plate 20 is connected to the positive
terminal of a voltage source 50, the negative terminal being
grounded.
In operation, the corona discharge device 60 is adapted to provide
a negative electrostatic charge onto the surface 12 of the
recording element 16 through the screen 62. The electrode 72 is
maintained at a voltage of at least 5,000 volts with respect to
ground; the resistor 48 is adjusted to provide a negative bias of
between 0 and -500 volts to the housing 64, and the variable
voltage source 50 is adjusted to provide voltage of between 0 and
+400 volts to the support plate 20. When thus energized, a corona
discharge is directed onto the surface 12 by the electric wind
produced, providing the surface 12 with a uniform negative
electrostatic charge. Because the optical transmission of the
screen 62 is less than 50 percent, most of the ultraviolet light
emanating from the knife edge 78 of the electrode 72 is
substantially filtered (blocked) so that only a relatively small
amount of the ultraviolet light reaches the surface 12. The values
of voltage and dimensions given herein are not critical. They are
merely illustrative and are not to be construed in a limiting
sense.
The corona discharge device 60 is provided with means to convert
ozone formed during the corona discharge to oxygen in a manner
similar to that described for the corona discharge device 10. Thus,
the inner surface of the enclosed housing 64 is coated with a
catalytic coating 54 of one of the aforementioned catalytic
materials that catalyzes the chemical reaction wherein oxone is
converted to oxygen. Both of the screens 62 and 70 are either made
of, or coated with, a catalytic material of the type described,
such as silver, gold, nickel, platinum, iron, or their alloys,
nickel sesquioxide, or copper oxide, for example.
Some catalytic materials 82, in the form of compounds, such as
barium monoxide and silver peroxide, that do not lend themselves
easily to being applied in the form of the catalytic coating 54 may
be disposed within the interior 74 of the housing 64 in foraminous
screen containers 84. The screen containers 84 may be secured, by
any suitable means, to the insulating rods 76, for example. The
screen containers 84 may be refilled if the catalytic materials 82
should become poisoned in time and with use.
A fan 86 is disposed by any suitable means adjacent to the screen
70 and adapted to rotate in a direction, when suitably energized,
to cause air to flow gently through the housing 64 in a direction
indicated by the arrows 88. Thus, the fan 86 comprises air moving
means to cause ozone to flow through the catalytic materials 82,
wherein the ozone is converted to oxygen, as well as means to
prevent ozone from reaching the surface 12 to be charged. Although
the fan 70 is illustrated in FIG. 3 as being outside of the housing
64, it may be included within the housing 64 and disposed to cause
air to flow from the interior of the housing 62 out through the
screen 70, in the direction of the arrows 88.
While the novel corona discharge device 10 and 60 have been
described in circuits wherein negative corona discharges were
produced, it is also within the contemplation of the present
invention to reverse the polarities of the voltage sources so that
the novel corona discharge devices 10 and 60 produce positive
corona discharges.
* * * * *