U.S. patent number 3,670,874 [Application Number 04/881,444] was granted by the patent office on 1972-06-20 for method for irradiating foodstuffs and other consumables, pharmaceuticals and the like, and a package for same.
This patent grant is currently assigned to Sulzer Brothers, Ltd.. Invention is credited to Alfred Brunner.
United States Patent |
3,670,874 |
Brunner |
June 20, 1972 |
METHOD FOR IRRADIATING FOODSTUFFS AND OTHER CONSUMABLES,
PHARMACEUTICALS AND THE LIKE, AND A PACKAGE FOR SAME
Abstract
The material to be irradiated is placed with an oxygen binding
medium into a gas-tight package and irradiated. The oxygen which
may be present in the package becomes bound by the oxygen binding
medium so that the irradiated material and/or the material of the
package do not become adversely effected by the oxygen.
Inventors: |
Brunner; Alfred (Winterthur,
CH) |
Assignee: |
Sulzer Brothers, Ltd.
(Winterthur, CH)
|
Family
ID: |
4430941 |
Appl.
No.: |
04/881,444 |
Filed: |
December 2, 1969 |
Foreign Application Priority Data
|
|
|
|
|
Dec 5, 1968 [CH] |
|
|
18161/68 |
|
Current U.S.
Class: |
206/205; 426/107;
426/124; 426/129; 426/234; 426/240 |
Current CPC
Class: |
B65D
81/267 (20130101); B65D 81/24 (20130101); B65D
81/268 (20130101); A23L 3/263 (20130101); B65B
55/02 (20130101); A23L 3/3436 (20130101); A61L
2/0035 (20130101); A61L 2/08 (20130101) |
Current International
Class: |
A23L
3/26 (20060101); A23L 3/34 (20060101); A23L
3/3436 (20060101); A61L 2/00 (20060101); A61L
2/08 (20060101); B65D 81/24 (20060101); B65D
81/26 (20060101); B65B 55/02 (20060101); B65d
081/18 (); B65d 085/00 () |
Field of
Search: |
;206/46F,46PV
;99/171CA,181R,217 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Dixson, Jr.; William T.
Claims
What is claimed is:
1. A package comprising
a material to be irradiated;
a gas-tight covering enclosing said material in sealed relation;
and
a medium within said covering capable of binding oxygen, said
medium having a surface area exposed to the interior of said
covering and having an oxygen binding capacity which increases upon
irradiation.
2. A package as set forth in claim 1 wherein said medium is a
coating on the interior of said covering.
3. A package as set forth in claim 1 which further comprises a foil
coating the interior of said covering and wherein said medium is
disposed in said foil.
4. A package as set forth in claim 1 wherein said medium is silica
gel.
5. A package as set forth in claim 1 wherein said medium is in the
form of small particulates having relatively large ratioes or
surface area to volume.
6. A package as set forth in claim 1 wherein said medium is in the
form of a porous structure.
7. A package as set forth in claim 1 which further comprises a gas
permeable covering about said medium within said gas-tight
covering.
8. A package as set forth in claim 1 which further comprises a gas
impermeable covering about said medium within said gas-tight
covering; said gas impermeable covering being adapted to be opened
within said gas-tight covering to communicate said medium with said
material.
9. A package as set forth in claim 1 wherein said medium is
bentonite.
10. A package as set forth in claim 1 wherein said medium is
capable of chemically binding with oxygen.
11. A package as set forth in claim 1 wherein said medium is
capable of physically binding with oxygen.
Description
This invention relates to a method for irradiating foodstuffs,
other consumables, pharmaceuticals, medical requirements and the
like as well as a package for the same.
It has been known to irradiate various materials such as
foodstuffs, pharmaceuticals, and the like by packaging the material
in a gas-tight covering and by thereafter exposing the packaged
material to an ionizing radiation, preferably gamma radiation. Such
irradiation has already been successfully employed not only for the
sterilization of catgut, hypodermic syringes of plastic material
but also for the destruction of undesirable micro-organisms on or
in foodstuffs and other consumables. The last mentioned application
refers to a sterilizing treatment which is intended to destroy all
micro-organisms which have an adverse effect on durability or only
those micro-organisms which prevent the substances from being kept
fresh for a short period.
However, it has been found that the presence of oxygen in the
interior of the sealed package prior to irradiation may cause
difficulties which may become greater since the enclosed gaseous
oxygen may be converted under the effect of ionizing irradiation
into ozone or even into nascent oxygen. Oxygen, particularly in one
of the aforementioned highly reactive forms, can give rise to a
wide variety of harmful effects depending on the nature of the
packaged material or of the packaging material itself. In the first
place, there is oxidation of the packaged material itself, also
foodstuffs and other consumables containing fats and albumen for
example fish and meat products can be adversely affected. In other
cases, any oxygen that may be present may unfavorably continue the
ripening process of fruit, for example strawberries, which have
been exposed to a preserving irradiation, thus impairing the visual
condition and taste of the packaged material. Furthermore, in many
cases it is not possible to destroy resistant and durable forms of
micro-organisms, for example spores. A correspondingly increased
radiation dose or duration of radiation or radiation intensity also
increases the danger of harmful oxidation of the packaged material
in conjunction with the formation of ozones or nascent oxygen.
Oxygen in an irradiated package for foodstuffs and other
consumables may also have an adverse effect on aromatic
substances.
In addition to the above disadvantages in the preserving treatment
of foodstuffs and other consumables, it has been found that in the
sterilizing irradiation or medical material and medical apparatus,
the plastics material usually employed for forming the package or,
as in the case of catgut, the packaged material itself has been
adversely affected by the irradiation due to the oxygen present in
the package. For example, the oxygen may embrittle the plastics
packaging material owing to oxidation. Similar detrimental effects
may also be observed in the irradiation of natural or synthetic
catgut.
It is known in connection with the difficulties described
hereinabove to partially eliminate the quantity of oxygen present
in the package by evacuation or to displace it by means of an inert
gas. However, such measures are expensive and involve complicated
packaging machines so that this method of solving the indicated
problems efficiently is possible only in very few cases.
Accordingly, it is an object of the invention to permit the
application of an irradiation method in which the harmful effects
of oxygen, increased by the use of ionizing radiation on the
material disposed in the closed packaged or on the package itself
is substantially eliminated.
It is another object of the invention to protect a packaged
material against adverse effects from oxygen during
irradiation.
It is another object of the invention to maintain a packaged
foodstuff in a protected state for a relatively long period of
time.
Briefly, the invention provides a method and a package which
preserves materials such as foodstuffs, consumables,
pharmaceuticals, and the like over long time periods without
adverse effects from entrapped oxygen in the package upon the
package being subjected to radiation and the like.
The method resides in the steps of packaging the material to be
irradiated in a gas-tight covering along with a medium capable of
binding oxygen and of exposing the sealed material to an ionizing
irradiation. During the time of irradiation, as well as thereafter,
any gases in the interior of the covering come into contact with
the oxygen binding medium and become bound.
In the method according to the invention, the oxygen can be bound
either chemically or physically. For example, adsorption media are
particularly suitable for physical binding. Also, since it is known
that irradiation causes adsorbing substances and chemical
substances to have an increased binding capacity; media such as
silica gel which is particularly activated as regards its oxygen
binding capacity by ionizing radiation can be used. With such
characteristics, it is in some cases possible to dispense with
special measures which protect the oxygen binding medium against
premature contact with atmospheric oxygen while the package is not
yet sealed.
In carrying out the invention, is is advisable to use the oxygen
binding medium in small, particulate or porous form, both for
chemical as well as for physical binding as the increased surface
area obtained by this measure accelerates and intensifies the
binding process.
The package of the invention includes the material to be
irradiated, the oxygen binding medium and a gas-tight covering
enclosing the material and medium therein in sealed relation.
In one embodiment, the interior of the gas-tight covering is
constructed as a support for the oxygen binding medium.
In another embodiment, the oxygen binding medium is appropriately
disposed within its own gas-permeable covering or sheath such as a
perforated cartridge. This separates the medium from the packaged
material thus preventing undesirable contact between the binding
medium and the material. It is furthermore recommended that the
gas-permeable covering for the oxygen binding material be joined to
the gas-impermeable covering for the material to be irradiated. The
binding medium and the packaged material is then automatically
separated when the package is opened.
In another embodiment, the oxygen binding medium may be disposed in
a gas-permeable foil which is coated onto the gas-tight covering
enclosing the material to be irradiated. Such a gas-permeable foil
is advantageously constructed of polyethylene while the use of
packaging material having aluminum foil is recommended for the
gas-tight covering. Aluminum has a relatively high transmittance
for the ionizing radiation, readily reflects incident heat
radiation and is very suitable as hygienic packaging material.
As oxygen binding media of high binding intensity are naturally
endangered by premature exhaustion of their binding capacity, the
oxygen binding media can, in another embodiment, be brought into
contact with the oxygen only after sealing of the package for the
material to be irradiated. This may be achieved by disposing the
oxygen binding medium in a gas-impermeable covering which is opened
only after sealing of the gas-tight covering for the material to be
irradiated.
The material for the packages of the kind heretofore described can
be easily prefabricated and provided it is protected by a suitable
hermetically sealed packaging against premature exhaustion of the
binding capacity can be stored or transported to the location of
use for any desired period of time.
By means of the invention, it is possible to perform irradiation
for preservation or sterilization without the need for the
complicated and expensive removal of the oxygen from the package
for the material to be irradiated. Instead, the gaseous oxygen
disposed in the package is bound and thus does not cause any
harmful oxidation of the irradiated material or any of the other
detrimental effects. At the same time, it is possible for the
radiation dose to be substantially increased without having to
anticipate any increased oxidation of the irradiated material.
These and other objects and advantages of the invention will become
more apparent from the following detailed description and appended
claims taken in conjunction with the accompanying drawings in
which:
FIG. 1 illustrates a sealed package prepared for irradiation with
an enclosed cartridge containing oxygen binding media according to
the invention;
FIG. 2 illustrates an enlarged view of the cartridge of FIG. 1;
FIG. 3 illustrates an embodiment of the invention in which the
oxygen binding medium is disposed in a gas-permeable covering
joined to the interior of a packaging material;
FIG. 4 illustrates a gas-permeable foil in which the oxygen binding
medium is disposed according to the invention;
FIG. 5 illustrates an embodiment according to the invention in
which the oxygen binding medium is disposed in a gas-impermeable
covering which is opened only after the gas-tight covering for the
material to be irradiated is closed.
Referring to FIG. 1, the package 11 consists of a material which is
as far as possible impermeable to gas, for example, a paper-like
packaging material with an inlaid aluminum foil and a plastic
coating on the interior. The package 11 contains a material 12, for
example fresh meat, and is hermetically sealed by means of a
welding seal 13 so that the material 12 is enclosed in a
substantially gas-tight package. A cartridge 14 of oxygen binding
medium is also enclosed within the interior of the package 11.
Referring to FIGS. 1 and 2, the cartridge 14 comprises a cylinder
15, forming a gas-permeable covering which is closed at the
endfaces by means of lids 16. The interior of the cartridge 14
contains the oxygen binding medium for example, in the form of
granular material 17 which is in physical contact with the gases in
the interior of the package covering by means of apertures 18 in
the wall of the cylinder 15.
After the package 11 has been sealed with the material 12 and
oxygen binding medium 17 therein, the material 12 in the package 11
can be exposed to an ionizing radiation as is known. During such a
time, and thereafter, any oxygen in the package interior is, at
least, partially bound by the medium 17.
Referring to FIG. 3, the package can also be formed of a foil-like
packaging material 21 which forms the gas-tight covering for the
material to be irradiated. The material 21 may be formed of a
plastic foil which can also be lined in any desired manner with
paper or metal foil. This package also includes a tubular chamber
22 on the material side which forms the interior of the package.
This tubular chamber 22 is joined by means of flanges 23 to the
foil 21, namely by welds 24 and, prior to welding, is filled with a
granular medium 25 capable of binding oxygen. The medium 25 comes
into physical contact with the oxygen in the package through
apertures 26 in the chamber wall.
In use, any oxygen which is entrapped in a package constructed of
the material described hereinabove (FIG. 3) is bound by the medium
25. When the packaged material is removed from the gas-tight
covering 21, automatic provision is made to ensure that the
covering 21 and the packaged material are separated from each
other.
Referring to FIG. 4, the oxygen binding medium 31 can also be
incorporated into a gas-permeable foil 32 so that strips of the
foil 32 can be used in the formation of packages. For example, the
oxygen binding medium 31 in a pulverized or granular form is
disposed in a gas-permeable foil 32 of polyethylene. The foil 32 is
appropriately obtained in such a manner that the small, particulate
binding medium is admixed to the polyethylene during extrusion. By
suitable selection of the particle size and the degree of
admixture, preferably 0.5 to 10 percent, it is possible to
influence the binding rate of the oxygen. A foil-like material 33
for the gas-tight impermeable covering of a package is then coated
with the foil 32. The gas-tight covering 33 and the foil 32
therefore represent a web-like packaging material which can be
easily processed. This type of packaging material is appropriately
stored in reels and the oxygen binding medium is protected against
premature exhaustion due to the ingress of atmospheric oxygen, for
example by hermetic sealing in evacuated containers. In some cases,
it is advisable to omit the coating from those positions which
later coincide with the zone of a welding seam when the package is
formed. In some cases also it is possible to embed the oxygen
binding material directly into the plastics coating of paper-like
packaging materials.
Referring to FIG. 5, the oxygen binding medium can also be stored
within gas-impermeable coverings which are opened only after the
covered medium has been sealed into a package. For example, the
oxygen binding medium 44 in small particulate form is filled in a
container 41 made of fragile gas-impermeable material such as a
thin glass. The container 41 in turn is placed within a small
gas-permeable material such as a small textile bag 43 which is
closed by means of a clip 42. The small bag 43 with the container
41 is then enclosed in the package in place of the cartridge 14
shown in FIG. 1. In order to provide physical contact between the
medium 44 and the oxygen entrapped in the package, the thin wall of
the container 41 is broken from the exterior by applying pressure
or a blow. The medium 44 thus comes into contact with the oxygen
which diffuses through the wall of the small bag 43. In this way,
it is possible to control the timing of the beginning of oxygen
binding by the medium 44. The protective container is appropriately
destroyed immediately after the package is sealed.
Media suitable for binding oxygen include those capable of binding
oxygen chemically as well as those capable of inducing binding by
physical means. All readily oxidizing inorganic material are
particularly suitable as chemically acting media. Metals such as
manganese, aluminum and magnesium in small particulate form are
particularly suitable although it is recommended that the media be
stored in a protective atmosphere, for example nitrogen, in the
interior of a container according to FIG. 5 as a protection against
premature oxidation. However, organic compounds with a suitable
binding activity relative to oxygen are also feasible.
The previously mentioned silica gel having a particle size of for
example 0.01 to 5 mm is very suitable for physical binding of the
oxygen. Silica gel is characterized by the surprising property that
is adsorption capacity relative to oxygen is substantially
increased by irradiation with ionizing rays by virtue of a
structural change resulting from the irradiation. Furthermore, it
is absolutely non-toxic and acts practically without thermal
effects. Another medium for physical binding of oxygen is
bentonite.
In every case, an increase of the surface area of the oxygen
binding medium is recommended by using the medium in small
particulate form such that the ratioes of surface area to volume of
the particulate are relatively large. It would however also be
possible to employ the oxygen binding medium in the form of a
porous or spongy member.
In order to treat the packaged material, the package should be made
as impermeable to gas as is possible. In practice, however, a
certain exchange of gas is possible under some circumstances even
with lined packaging material having a plastics coating and a metal
foil insert. The gas-impermeable property of the covering for the
material to be irradiated is therefore meant to imply
impermeability to gas as obtainable under practical conditions.
Further, in order to improve the impermeability of aluminum foil it
is advisable to apply a lacquer coating on the foil web, at least
on one side.
* * * * *