U.S. patent number 3,664,422 [Application Number 05/064,271] was granted by the patent office on 1972-05-23 for well fracturing method employing a liquified gas and propping agents entrained in a fluid.
This patent grant is currently assigned to Dresser Industries, Inc.. Invention is credited to Ronald S. Bullen.
United States Patent |
3,664,422 |
Bullen |
May 23, 1972 |
WELL FRACTURING METHOD EMPLOYING A LIQUIFIED GAS AND PROPPING
AGENTS ENTRAINED IN A FLUID
Abstract
The formations surrounding a well bore are subjected to
hydraulic fracturing. A liquified gas and a fluid containing
entrained propping agents are injected into the formations. The
liquified gas returns to its gaseous state and is therefore easily
removed from the formation.
Inventors: |
Bullen; Ronald S. (Calgary,
Alberta, CA) |
Assignee: |
Dresser Industries, Inc.
(Dallas, TX)
|
Family
ID: |
22054756 |
Appl.
No.: |
05/064,271 |
Filed: |
August 17, 1970 |
Current U.S.
Class: |
166/283;
166/90.1; 166/308.1 |
Current CPC
Class: |
E21B
43/26 (20130101); F17C 9/04 (20130101); F17C
2221/013 (20130101); F17C 2223/0153 (20130101); F17C
2221/014 (20130101) |
Current International
Class: |
F17C
9/00 (20060101); F17C 9/04 (20060101); E21B
43/25 (20060101); E21B 43/26 (20060101); E21b
043/26 () |
Field of
Search: |
;166/308,280,259,271,281,283 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Novosad; Stephen J.
Claims
The embodiments of the invention in which an exclusive property or
privilege is claimed are defined as follows:
1. A method of treating a subsurface earth formation penetrated by
a well bore, comprising: injecting a liquified gas into the
formation and injecting gelled alcohol containing entrained
propping agents into said formation.
2. The method of claim 1 including the step of injecting a gel
breaker into said formation.
3. The method of claim 1 wherein said gelled alcohol is gelled
methanol.
4. The method of claim 1 wherein said liquified gas is carbon
dioxide.
5. The method of claim 1 wherein said steps of injecting a
liquified gas and said step of injecting gelled alcohol containing
entrained propping agents are performed simultaneously.
6. The method of claim 1 wherein said liquified gas and gelled
alcohol containing the entrained propping agents are blended prior
to injection into the formations.
7. The method of claim 1 wherein said liquified gas and gelled
alcohol containing the entrained propping agents are mixed after
each has been injected into the well bore.
8. The method of claim 1 wherein said gelled alcohol containing the
entrained propping agents is at atmospheric pressure prior to
injection into the well bore.
9. The method of claim 1 wherein the entrained propping agents are
sand.
10. A method of treating subsurface earth formations penetrated by
a borehole, comprising: mixing propping agents with gelled alcohol,
mixing said gelled alcohol containing the propping agents with a
liquified gas and injecting the mixture into the formation
surrounding said borehole.
11. The method of claim 10 including the step of adding a gel
breaker to the gelled alcohol.
12. The method of claim 10 wherein said liquified gas is liquified
N.sub.2.
13. The method of claim 10 wherein said liquified gas is liquified
CO.sub.2.
14. A system for treating subsurface earth formations
comprising:
means for mixing propping agents with gelled alcohol;
means for blending the propping agents and gelled alcohol mixture
with a liquified gas; and means for injecting the blend into said
subsurface earth formations.
Description
BACKGROUND OF THE INVENTION
This invention relates to the art of hydraulically fracturing
subterranean earth formations surrounding oil wells, gas wells, and
similar bore holes. In particular, this invention relates to
hydraulic fracturing utilizing a liquified gas and a fluid
containing entrained propping agents.
Hydraulic fracturing has been widely used for stimulating the
production of crude oil and natural gas from wells completed in
reservoirs of low permeability. Methods employed normally require
the injection of a fracturing fluid containing suspended propping
agents into a well at a rate sufficient to open a fracture in the
exposed formation. Continued pumping of fluid into the well at a
high rate extends the fracture and leads to the build-up of a bed
of propping agent particles between the fracture walls. These
particles prevent complete closure of the fracture as the fluid
subsequently leaks off into the adjacent formations and results in
a permeable channel extending from the well bore into the
formations. The conductivity of this channel depends upon the
fracture dimensions, the size of the propping agent particles, the
particle spacing, and the confining pressures.
The fluids used in hydraulic fracturing operations must have filter
loss values sufficiently low to permit build-up and maintenance of
the required pressures at reasonable injection rates. This normally
requires that such fluids either have adequate viscosities or
contain filter-loss control agents which will plug the pores in the
formation. The use of fracturing fluids having relatively low
viscosities in conjunction with additives which provide the low
filter-loss values needed avoids excessively high friction losses
in the tubing and casing. The well head pressures and hydraulic
horsepower required to overcome such friction losses may otherwise
be prohibitive.
Fracturing of low permeability reservoirs has always presented the
problem of fluid compatibility with the formation core and
formation fluids, particularly in gas wells. For example, many
formations contain clays which swell when contacted by aqueous
fluids causing restricted permeability, and it is not uncommon to
see reduced flow through gas well cores tested with various
oils.
Another problem encountered in fracturing operations is the
difficulty of total recovery of the fracturing fluid. Fluids left
in the reservoir rock as immobile residual fluid impede the flow of
reservoir gas or fluids, to an extent that the benefit of
fracturing is decreased or eliminated. The removal of the
fracturing fluid may require the expenditure of a large amount of
energy and time, consequently the reduction or elimination of the
problem is highly desirable.
DESCRIPTION OF THE PRIOR ART
In attempting to overcome the filter-loss problem, gelled fluids
prepared with water, diesel and similar low viscosity liquids have
been useful. Such fluids have apparent viscosities high enough to
support the propping agent particles without settling and yet low
enough to give acceptable friction losses. The gelling agents also
promote laminar flow under conditions where turbulent flow would
otherwise take place and hence in some cases, the losses may be
lower than those obtained with low viscosity-base fluids containing
no additives. Certain water-soluble poly-acrylamides, oil soluble
poly-isobutylene and other polymers which have little effect on
viscosity when used in low concentration can be added to the
ungelled fluid to achieve similar benefits.
In attempting to overcome the problem of fluid compatibility when
aqueous fracturing fluids are used, chemical additives have been
used such as salt or chemicals for pH control. Salts such as NaCl,
KCl, or CaCl.sub.2 have been widely used for fracturing water
sensitive formations. Where hydrocarbons are used, light products
such as gelled condensate have seen a wide degree of success, but
are restricted in use due to the inherent hazards of pumping
volative fluids.
Low density gases such as CO.sub.2 or N.sub.2 have been used in
attempting to overcome the problem of removing the fracturing
liquid. The low density gasses are added at a calculated ratio
which promotes fluid flow subsequent to the fracturing. This back
flow of load fluids is usually due to reservoir pressure alone,
without mechanical aid from surface, because of the reduction of
hydrostatic head caused by gasifying the fluid.
SUMMARY OF THE INVENTION
The present invention provides a method of well stimulation with
little or no reservoir contamination and a high percentage of load
fluid recovery. A liquified gas and a fluid containing entrained
propping agents are injected into the formations. Since the two
aforementioned fluid phases are completely miscible they may be
either blended prior to well entry, or injected separately and
blended in the well. The fluids are injected until a fracture of
sufficient width to produce a highly conductive channel has been
formed. Particles of the propping agent, suspended in the mixture,
are carried into the fracture. The injected fluid is then permitted
to leak off into the formation until the fracture has closed
sufficiently to hold the particles in place.
In one embodiment of the invention, liquid carbon dioxide
(CO.sub.2) and a high concentration of propping agents in a stream
of gelled alcohol are simultaneously injected into the well bore.
When the liquid carbon dioxide reaches the formations, it gasifies,
leaving only a low fluid residual of alcohol to recover. This
alcohol, in turn, is soluble in reservoir gas (methane) and is
essentially returned as a vapor. The propping agents are added to a
separate side stream of alcohol at atmospheric pressure and
subsequently blended with the liquid carbon dioxide for injection
into the well. A suitable alternate to alcohol is a light oil,
condensate, or reformate (aromatic refinery by-product) gelled with
additives such as aluminum stearate and time-dependant
breakers.
It is therefore an object of the present invention to provide a
method of fracturing the formations surrounding a well bore wherein
propping agents contained in a suitable fluid are added to a
liquified gas and injected into the formations.
It is a still further object of the present invention to provide a
fracturing method wherein propping agents are added to a suitable
fluid at atmospheric pressure and the fluid containing the propping
agents is subsequently mixed with a liquified gas and injected into
the formations surrounding a well bore.
It is a still further object of the present invention to provide a
well fracturing method that prevents any fluid of questionable
compatibility from contacting either the formation or reservoir
fluids.
It is a still further object of the present invention to provide a
well fracturing method that allows extension of the shut-in period
of the well to an indefinite period of time for fracture healing,
also allowing flow-back and evaluation at the operator's
convenience.
It is a still further object of the present invention to provide a
well fracturing method that includes a combination of alcohol,
surface active agents and liquified carbon dioxide to be injected
into the formation surrounding a well bore.
The above and other objects and advantages will become apparent
from a consideration of the following detailed description when
taken in conjunction with the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 depicts a pressure enthalpy chart for CO.sub.2 in the region
of interest of oil well servicing.
FIG. 2 shows the viscosity of CO.sub.2.
FIG. 3 shows the thermodynamic properties of saturated carbon
dioxide.
FIG. 4 shows the rate of reaction of gel breaker on the gelled
alcohol.
FIG. 5 is a schematic representation of a system used in this
invention.
FIG. 6 shows a fracturing manifold that may be used to inject the
fluids into the well bore.
DETAILED DESCRIPTION OF THE INVENTION
In the preferred embodiment of the present invention liquid carbon
dioxide (CO.sub.2) is the primary fracturing fluid in a well
fracturing method. Simultaneous injection of gelled alcohol
(methanol) is used to carry the propping agent.
Referring now to FIG. 1, a pressure enthalpy chart for carbon
dioxide in the region of interest in oil well servicing is shown.
The probable path followed during a fracturing job is depicted by a
"dash line." Liquid carbon dioxide is pumped from a delivery
transport at approximately 300 psi and 0.degree. F. It is pumped to
an elevated pressure where it is comingled with gelled alcohol and
propping agents. The temperature of the combined fluids rises due
to mixing with warm fluid and as the mixed stream goes down the
well, it picks up additional heat from the borehole and additional
pressure due to hydrostatic head. At the perforation, pressure is
at its peak and it declines after formation fracturing as fluid
enters the reservoir. As the critical temperature of the carbon
dioxide (87.8.degree. F.) is exceeded, it changes to the vapor
stage. When pressure is relieved at the well head after completion
of the treatment, the gaseous carbon dioxide expands along a path
similar to that shown, until it emerges as a gas at the well head
at atmospheric pressure.
Referring now to FIG. 2, the viscosity of carbon dioxide determined
by the method of "Uyehara and Watson" was calculated over the range
of 0.degree. to 300.degree. F. for pressures from 100 to 30,000
psi. This information may be used in calculating the friction
pressure drop which may be encountered when pumping pure liquid
carbon dioxide into a well. The density of carbon dioxide is
calculated from the equation PV = 0.243ZTM where P equals pressure
in psia; V equals volume in cubic feet; Z equals compressibility
factor; T equals temperature in degrees Rankin; M equals weight in
pounds. This equation was solved for temperatures from 0.degree. to
200.degree. F. and pressures from 100 psi to 10,000 psi.
Knowing viscosity and density, friction pressures of liquid carbon
dioxide may then be calculated using Crittendon's correlation for
pressure drop in oilfield production pipe:
.DELTA.P/L = (518 .sup.0 .sup.79 .sup.0 .sup.207 Q.sup.1
.sup.79)/(D.sup.4 .sup.79)
where
P/L = pressure drop per 1,000 feet
.rho. = density, gm/cc
.mu. = viscosity, cp
Q = injection rate, BPM
D = pipe diameter, inches
An example of friction drop for carbon dioxide at high pressures
was calculated at 15 BPM for 3.548 in. I.D. tubing at 6,000 psi
indicating that the pressure drop for carbon dioxide under these
conditions is only 43 percent less than that of water with 1 cp
viscosity. The addition of the gelled alcohol and sand slurry to
the carbon dioxide injected into a well does not appear to change
the pipe friction appreciably from that calculated, although
variations in perforation friction are proportionate to the
increased density of the slurry according to the equation:
.DELTA.P.sub.fp = 0.323 Q.sup.2 .rho./n.sup.2 D.sup.4
where:
P.sub.fp = perforation friction, psi
Q = injection rate, BPM
.rho. = density, gm/cc
n = diameter of perforation, inches
D = diameter of perforations in inches
Orifice coefficient assumed 0.8
The thermodynamic properties of saturated carbon dioxide are shown
in the Table of FIG. 3. As may be seen from this Table, the latent
heat of vaporization is a function of temperature, ranging from
120.1 BTU/lb. at 0.degree. F. (transport conditions) to 0.0 BTU/lb.
at 87.8.degree. F., when the CO.sub.2 is entirely gaseous.
In a fracture treatment using carbon dioxide as a base fluid, the
total heat absorption from the tubing, casing and formation for a
stimulation incorporating 10,000 gallons of liquid carbon dioxide
would therefore be 1.0 .times. 10.sup.6 BTU. This is usually well
within the tolerable range for cooling effect corresponding to an
average temperature drop throughout the system of only 20.degree.
F. to 30.degree. F. which is quickly replaced by downhole heat
transfer to equilibrium.
Under reservoir temperature and pressure conditions, the specific
volume of carbon dioxide increases from that at the surface. This
volume expansion increases the velocity of the fracturing fluid in
the formation for improved fracture width and penetration. The
volume occupied by 1,000 SCF of carbon dioxide prior to injection
is 1.78 ft..sup.3 (0.degree. F., 300 psi). This volume expands
under reservoir conditions, with the greatest effect at lower
pressures.
The volume of gaseous carbon dioxide in the well reservoir at any
temperature may also be calculated according to the formula:
V.sub.(f) = 0.945 V.sub.(i) .times. (f)/.rho.
where
V.sub.(f) is the final volume,
V.sub.(i) is the initial volume at standard conditions,
f is the compressibility factor at final conditions,
.rho. is the final pressures in atmospheres.
The gelled alcohol used to carry the propping agent may be methanol
or another alcohol with similar properties. Methanol is used as a
proppant carrying agent in view of its compatibility with most gas
and oil reservoirs, its low freezing point, and potential chemical
benefits to the stimulation.
As shown in FIG. 4 the rate of reaction of gel breaker on the
gelled alcohol is rapid, but allows adequate time for the
displacement of the proppant into the formation at a high viscosity
blend. From initial viscosity of 50 to 60 cp the gel breaks back to
2 cp as a final viscosity. By comparison, straight methanol has a
viscosity of 0.6 cp. It is preferred that the alcohol be gelled to
a viscosity of 20 cp or higher in order to be sufficient to carry
the high concentration of propping agent through the pumping
equipment and into the formation. In a low fluid residual
treatment, the alcohol occupies as little as 16 percent of the
total fluid volume. This alcohol is distributed over a total
fracture area of many thousands of square feet, and in actual field
use it is seldom recovered as a liquid.
Total recovery of the methanol without residual fluid saturation is
realized by vaporization during subsequent production of the well.
The saturation of alcohol in methane varies with temperature and
pressure, but is generally over 250 lbs. per million cubic feet of
gas under reservoir conditions.
Referring now to FIG. 5 one embodiment of a system of the present
invention is shown in schematic form. An alcohol storage tank 11 is
connected to a blender 12. The blender 12 may be of the type
conventionally used in oil field fracturing operations and would
normally include paddles, a ribbon mixer or jets for mixing and
suspending propping agents in the gelled alcohol. The alcohol is
gelled in this blender just prior to the addition of the propping
agents. It is generally preferred to operate the blender 12 at a
high speed to prevent buildup and "slugging" of the propping agent
particles. A return line 13 from the blender to the alcohol storage
tank 11 permits circulation to promote initial mixing of the fluid
before the propping agent is added. A suitable propping agent from
container 14 is added to blender 12. Discharge line 15 extends from
blender 12 to high pressure fracturing pump or pumps 16. These
pumps are normally positive displacement, Triplex pumps, truck
mounted and specially equipped for pumping abrasive slurries at
high rates and pressures.
Liquid carbon dioxide from tank or tanks 17 is injected into the
well 18 by means of a pump or pumps 19. Unit 19 may be a pumping
unit similar to that described in connection with pumping unit
16.
The pumps 16 and 19, blender 12, tanks 11 and 17 and other
equipment are normally located some distance from the well 18 to
minimize the danger in case of fire or blowout. Valves are provided
throughout the system to permit control of the fluids and the
disconnection of individual units of equipment as necessary.
Referring now to FIG. 6 another embodiment of the present invention
is shown. A fracturing manifold particularly suited for the present
invention is indicated generally at 20. The gelled alcohol with
proppant enters the manifold 20 at the inlet 21. It receives the
gel breaking mixture which enters at 22 and the mixture then passes
down the tubing 23. The liquid carbon dioxide enters at 24 and
passes down the annulus between tubing 23 and tubing 25. As the
gelled alcohol including the additives exits from tubing 23 it is
completely mixed with the carbon dioxide prior to entry into the
formation 26.
In a typical treatment, alcohol with between 5 to 8 lbs. of
proppant per gallon, depending on the well conditions, is pumped
into a manifold at the rate of 7 barrels per minute. The carbon
dioxide is pumped at 14 barrels per minute into the manifold and a
diluted sand/liquid ratio of approximately 2 lb./gal. is injected
into the well. Additional additives such as surfactants and fluid
loss additives may be added to the alcohol at the blender during
the treatment.
When injecting the alcohol and carbon dioxide separately into the
tubing and casing, a controlled screen-out may be effected at the
conclusion of the fracture treatment. Simultaneous with the flush,
the annulus carbon dioxide rate is reduced to increase the bottom
hole sand concentration. After the sand is displaced into the
formation, the well is shut in for any length of time desired prior
to the flowing back to evaluate treatment.
It is generally recognized that the stimulation benefits resulting
from the present invention are two-fold:
1. highly permeable channels are developed which have the effect of
allowing increased flow into the well bore; and
2. the well bore area itself is cleaned out of water blocks, mud
contamination and emulsions by the scouring and flushing action of
the fluids.
In the second (2) area of stimulation, the action of alcohol,
carbon dioxide and surfactants would have significant benefit. It
has been shown that the injection of alcohol, surfactants and
carbon dioxide restores the permeability of the productive
formation to gas by removing water from the capillary pores of the
formation. The surfactant decreases the surface tension of the
water causing a decrease in capillary pressure which allows the
water to be more easily displaced by injected gas. The alcohol acts
as a drying agent; thus, the combination of surfactant and
dessicant forced into the formation by a gas at high pressure is
very effective for removing a water block in the immediate vicinity
of the well bore.
* * * * *