U.S. patent number 3,663,775 [Application Number 05/022,250] was granted by the patent office on 1972-05-16 for vacuum interrupter with contacts containing a minor percentage of aluminum.
This patent grant is currently assigned to General Electric Company. Invention is credited to Fordyce H. Horn, deceased, Joseph W. Porter, Joseph L. Talento.
United States Patent |
3,663,775 |
Horn, deceased , et
al. |
May 16, 1972 |
VACUUM INTERRUPTER WITH CONTACTS CONTAINING A MINOR PERCENTAGE OF
ALUMINUM
Abstract
Discloses a vacuum-type electric circuit interrupter having its
contacts formed of a porous refractory metal matrix and an alloy
filling the pores of the matrix consisting essentially of copper,
aluminum, and bismuth. In the alloy, the aluminum is present in a
quantity of between 9 and 15 percent by weight of copper-aluminum,
and the bismuth is present in a quantity of less than 5 percent by
weight of the total alloy.
Inventors: |
Horn, deceased; Fordyce H.
(late of Schenectady, NY), Porter; Joseph W. (Media, PA),
Talento; Joseph L. (Media, PA) |
Assignee: |
General Electric Company
(N/A)
|
Family
ID: |
21808639 |
Appl.
No.: |
05/022,250 |
Filed: |
March 24, 1970 |
Current U.S.
Class: |
218/130; 218/132;
200/266 |
Current CPC
Class: |
H01H
1/0203 (20130101) |
Current International
Class: |
H01H
1/02 (20060101); H01h 033/66 () |
Field of
Search: |
;200/144B,166C |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Macon; Robert S.
Claims
What I claim as new and desire to secure by Letters Patent of the
United States is:
1. A vacuum-type electric circuit interrupter comprising:
a. an envelope evacuated to a pressure of 10.sup..sup.-4 mm. of
mercury or less,
b. a pair of contacts within said envelope relatively movable into
and out of engagement,
c. said contacts being substantially free of absorbed gases and
surface contaminants,
d. at least one of said contacts having its circuit-making and
breaking regions formed of a porous refractory metal matrix and an
alloy filling the pores of said matrix consisting essentially of
copper-aluminum and bismuth,
e. the aluminum being present in a quantity of between 9 and 15
percent by weight of the copper-aluminum, and
f. the bismuth being present in a quantity of less than about 5
percent by weight of the total alloy and in a sufficient quantity
to inhibit contact-welding, and being distributed throughout said
alloy.
2. The vacuum-type circuit interrupter of claim 1 in which the
aluminum is present in a quantity of between 11 and 13 percent by
weight of the copper-aluminum.
3. The vacuum-type circuit interrupter of claim 1 in which the
aluminum is present in a quantity of about 12 percent by weight of
the copper aluminum.
4. The vacuum type circuit interrupter of claim 1 in which said
refractory metal is tungsten.
5. A vacuum-type electric circuit interrupter comprising:
a. an envelope evacuated to a pressure of 10.sup..sup.-4 mm. of
mercury or less,
b. a pair of contacts within said envelope relatively movable into
and out of engagement,
c. said contacts being substantially free of absorbed gases and
surface contaminants,
d. at least one of said contacts having circuit-making and breaking
regions formed of a porous refractory metal matrix and an alloy
filling the pores of said matrix consisting essentially of
copper-aluminum and a weld-inhibiting metal having substantially no
solid-state solubility in copper or aluminum and having an
effective freezing temperature below that of copper-aluminum,
e. the aluminum being present in a quantity of between 9 and 15
percent by weight of the copper-aluminum, and
f. the weld-inhibiting metal being present in a quantity of less
than about 5 percent by weight of the total alloy and in a quantity
sufficient to inhibit contact-welding, and being distributed
throughout said alloy.
6. A vacuum-type electric circuit interrupter comprising:
a. an envelope evacuated to a pressure of 10.sup..sup.-4 mm. of
mercury or less,
b. a pair of contacts within said envelope relatively movable into
and out of engagement,
c. contacts being substantially free of absorbed gases and surface
contaminants,
d. at least one of said contacts have circuit-making and breaking
regions formed of a porous refractory metal matrix and an alloy
filling the pores of said matrix consisting essentially of
copper-aluminum-bismuth, or silver-aluminum-bismuth, or
nickel-aluminum-bismuth,
e. the aluminum being present in a quantity of: between 9 and 15
percent by weight of the copper-aluminum in the case of
copper-aluminum-bismuth, between 5 and 10 percent by weight of the
silver-aluminum in the case of silver-aluminum-bismuth, and between
8 and 13 percent by weight of the nickel-aluminum in the case of
nickel-aluminum-bismuth,
f. the bismuth being present in a quantity of less than about 5
percent by weight of the total alloy and in a quantity sufficient
to inhibit contact-welding, and being distributed throughout said
alloy.
7. A vacuum-type electric circuit interrupter comprising:
a. an envelope evacuated to a pressure of 10.sup..sup.-4 mm. of
mercury or less,
b. a pair of contacts within said envelope relatively movable into
and out of engagement,
c. said contacts being substantially free of absorbed gases and
surface contaminants,
d. at least one of said contacts having its circuit-making and
breaking regions formed of a refractory metal matrix and an alloy
filling the pores of said matrix consisting essentially of: (1)
copper-aluminum containing 9 to 15 percent by weight of aluminum,
or (2) silver-aluminum containing 5 to 10 percent by weight of
aluminum, or (3) nickel-aluminum containing 8 to 13 percent by
weight of aluminum, and a weld-inhibiting metal,
e. said weld-inhibiting metal having substantially no solid-state
solubility in the primary metal of the alloy or aluminum and having
an effective freezing temperature below that of the primary
metal-aluminum alloy,
f. said weld-inhibiting metal being present in a quantity less than
about 5 percent by weight of the total alloy and in a quantity
sufficient to inhibit contact welding, and being distributed
throughout said total alloy.
8. A vacuum-type electric circuit interrupter comprising:
a. an envelope evacuated to a pressure of 10.sup..sup.-4 mm. of
mercury or less,
b. a pair of contacts within said envelope relatively movable into
and out of engagement,
c. said contacts being substantially free of absorbed gases and
surface contaminants,
d. at least one of said contacts having its circuit-making and
breaking regions formed of a porous refractory metal matrix and an
alloy filling the pores of said matrix consisting essentially of
(1) copper-aluminum containing 9 to 15 percent by weight of
aluminum, or (2) silver-aluminum containing 5 to 10 percent by
weight of aluminum, or (3) nickel-aluminum containing 8 to 13
percent by weight of aluminum.
9. The vacuum-type circuit interrupter of claim 8 in which said
alloy consists essentially of copper-aluminum.
10. The vacuum-type circuit interrupter of claim 8 in which said
alloy consists essentially of silver-aluminum.
11. The vacuum-type circuit interrupter of claim 8 in which said
alloy consists essentially of nickel-aluminum.
Description
In our U.S. Pat. No. 3,497,652, there is disclosed and claimed a
vacuum-type electric circuit breaker having contacts formed of an
alloy consisting essentially of copper, aluminum, and a
weld-inhibiting metal, such as bismuth, that is substantially
insoluble in copper or in aluminum in the solid state. Contacts
having their circuit-making and breaking regions formed entirely of
such an alloy have been found to provide exceptional ability to
withstand a high transient voltage immediately following a
contact-separating operation that fractures a weld between the
contacts. Such ability is of special importance during capacitance
switching operations inasmuch as a voltage building up to twice
normal peak voltage is applied between the contacts during the
half-cycle following arc-extinction at current zero.
Contacts having their circuit-making and breaking regions formed
entirely of this alloy are, however, subject to the disadvantage
that their operational life may be too short, because of arc
erosion, to permit their commercial use for highly repetitive
switching applications.
An object of the present invention is to impart to such contacts
increased operational life without losing their exceptional ability
to withstand high transient voltages immediately following contact
separation which fractures a weld.
In carrying out the invention in one form, we form the vacuum
interrupter contacts of a porous refractory metal matrix and an
alloy of copper, aluminum, and bismuth filling the pores of the
matrix, the aluminum being present in a quantity of between 9 and
15 per cent by weight of the copper-aluminum and the bismuth being
present in a quantity of less than 5 per cent by weight of the
copper-aluminum-bismuth alloy, preferably about 1 percent.
For a better understanding of the invention, reference may be had
to the following description taken in conjunction with the
accompanying drawing, wherein the single FIGURE represents one
embodiment of the present invention.
Referring now to the drawing, there is shown a vacuum-type circuit
interrupter comprising a sealed envelope 11 evacuated to a pressure
of 10.sup..sup.-4 torr or lower. The envelope 11 comprises a
tubular casing 12 of insulating material and a pair of metal end
caps 13 and 14 suitably sealed to the opposite ends of casing
12.
Within the evacuated envelope 11 there are a pair of separable
disc-shaped contacts 17 and 18. Contact 17 is a stationary contact
brazed to the lower end of a stationary conductive contact rod 17a;
and contact 18 is a movable contact brazed to the upper end of a
vertically movable conductive rod 18a. The movable contact rod 18a
projects freely through an opening in the lower end cap 14, and a
flexible metal bellows 20 provides a suitable seal thereabout that
allows vertical movement of the contact rod 18a without impairing
the vacuum inside envelope 11.
All of the internal parts of the interrupter are substantially free
of surface contaminants. These clean surfaces are obtained by
suitable conventional vacuum processing, which involves baking-out
the interrupter during its evacuation.
Closing of the interrupter is effected by driving the contact rod
18a in an upward direction to drive movable contact 18 into
engagement with stationary contact 17. Opening is effected by
returning the movable contact from its engaged position downwardly
to its solid line position shown. When the contacts are separated
during an opening operation, an arc is drawn therebetween. Assuming
an alternating current, this arc persists until a natural current
zero, at which time it vanishes and is prevented from reigniting by
the high dielectric strength of the vacuum in the envelope 12. A
suitable metal shield 21 of tubular form surrounds the contact to
condense the metal vapors generated by the arc, thus assisting in
the interrupting process. A typical gap length when the contacts
are fully open is about one-quarter inch. The opposed forward faces
25 of the contacts 17 and 18 may be thought of as circuit-making
and breaking regions of the contacts.
When the contacts are driven into engagement during closing, they
may bounce apart slightly and draw an arc between their
circuit-making and breaking regions 25 before being driven back
into engagement. This arc tends to produce welding together of the
contacts when they reengage under pressure. The contacts of a
vacuum interrupter have a greater tendency toward such welding than
those of other type interrupters because their surfaces are
exceptionally clean and free of weld-inhibiting films.
One of the problems that the present invention is concerned with is
providing an interrupter that can withstand high transient voltages
immediately following a contact-separating operation that fractures
a weld between the contacts. In the aforesaid U.S. Pat. No.
3,497,652, we disclose and claim a vacuum interrupter that has its
contacts formed of an alloy of copper, aluminum and a
weld-inhibiting metal, such as bismuth, that is substantially
insoluble in copper and aluminum in the solid state and is
distributed throughout the copper-aluminum. The aluminum is present
in this alloy in a quantity of 9 to 15 percent by weight of the
copper-aluminum and the bismuth in a quantity of below 5 percent.
This alloy has shown exceptional ability to meet the
above-described voltage-withstand requirement.
Contacts having their circuit-making and breaking regions formed
entirely of this alloy are, however, subject to the disadvantage
that their operational life may be too short, because of
arc-erosion, to permit their commercial use for highly repetitive
switching applications. We overcome this disadvantage, and, in
particular, do so without losing the exceptional ability of the
contacts to withstand a high transient voltage after weld-fracture
by constructing the contacts 17 and 18 of a porous refractory metal
matrix having its pores filled with the aforesaid alloy. As a
specific example, we construct the contacts of a refractory metal
matrix of tungsten having its pores filled with an alloy of
copper-aluminum-bismuth, with the aluminum present in a quantity of
12 percent by weight of the copper-aluminum and the bismuth in a
quantity of 1 percent by weight of the copper-aluminum-bismuth
alloy. For the reasons explained in our aforesaid U.S. Pat. No.
3,497,652, the aluminum content of this alloy should be between
about 9 and 15 percent by weight of the copper-aluminum. The
bismuth content should be less than 5 percent by weight of the
alloy and, preferably, as low as possible, consistent with the need
to reduce contact-welding to an acceptable level. The bismuth is
distributed throughout the copper-aluminum.
These contacts are made by employing the following steps in the
sequence stated: (1) pressing tungsten powder in air to about 60
percent density; (2) sintering the pressed tungsten powder in
hydrogen at a temperature of 2,300.degree. F.; (3) impregnating the
resultant structure in hydrogen with the copper-aluminum-bismuth
alloy at about the same temperature; (4) cooling the composite in
hydrogen to solidify the alloy; (5) reheating the composite in an
inert gas such as argon to a sufficient temperature to remelt the
alloy and for a sufficient period to accomplish degassing of the
composite structure; (6) allowing the composite to cool in the
argon atmosphere; and (7) machining off the excess material and
machining to size. The alloy is substantially freed of gas before
it is used to impregnate the tungsten. The degassing step, in
driving off the hydrogen from the composite, leaves the composite
substantially free of absorbed gas.
Although tungsten is preferred for the refractory metal, other
refractory metals are also suitable for this purpose, e.g.,
molybdenum, tungsten carbide, and molybdenum carbide.
Although we have described the invention specifically with respect
to a refractory metal matrix filled with an alloy of
copper-aluminum-bismuth, the invention in its broader aspects is
applicable to the other aluminum-containing alloys disclosed and
claimed in our aforesaid patent. These other alloys are
silver-aluminum-bismuth and silver-aluminum-lead, each containing
about 5 to 10 per cent aluminum by weight of the silver-aluminum,
and nickel-aluminum-bismuth, containing about 8 to 13 per cent
aluminum by weight of the nickel-aluminum. The tertiary metal is
present in each of these alloys in less than 5 per cent by weight
of the total alloy for weld-inhibiting purposes and is distributed
throughout the alloy. The first-mentioned or major constituent of
each alloy is referred to as the primary metal.
The weld-inhibiting agent in each of the alloys discussed
hereinabove has a lower freezing temperature than the primary
metal-aluminum alloy, is substantially insoluble in the other
constituents of the alloy in the solid state, and is distributed
throughout the alloy. In referring to weld-inhibiting agents that
are substantially insoluble in the other constituents in the solid
state, we are referring to weld-inhibiting metals that have a solid
state solubility in the other constituents of less than about 2
percent by weight of the alloy considered at the eutectic
temperature of said alloy or the freezing temperature of the
weld-inhibiting constituent if there is no eutectic.
In those applications where a moderate amount of weld strength can
be tolerated, the weld-inhibiting metal can be entirely, or almost
entirely, eliminated from the final contact material. This can be
done by performing the aforementioned manufacturing steps (5) and
(6), i.e., the reheating and cooling steps, in a vacuum instead of
in the argon atmosphere. The reheating in vacuum evaporates
substantially all of the low-melting-point weld-inhibiting metal,
e.g., bismuth, leaving the contact substantially free of the
weld-inhibiting metal.
While we have shown and described particular embodiments of our
invention, it will be obvious to those skilled in the art that
various changes and modifications may be made without departing
from our invention in its broader aspects; and we, therefore,
intend herein to cover all such changes and modifications as fall
within the true spirit and scope of our invention.
* * * * *