U.S. patent number 3,663,269 [Application Number 04/731,025] was granted by the patent office on 1972-05-16 for self releasable nonmoisture activated wall covering.
This patent grant is currently assigned to Combined Paper Mills, Inc.. Invention is credited to Raymond P. Fischer, John F. Whalen.
United States Patent |
3,663,269 |
Fischer , et al. |
May 16, 1972 |
SELF RELEASABLE NONMOISTURE ACTIVATED WALL COVERING
Abstract
A wall covering, such as wallpaper, having a coating of dry,
encapsulated adhesive on the back surface which is made tacky by
the application of heat and/or pressure in the absence of moisture,
and a method of manufacturing wallpaper which includes applying the
encapsulated adhesive in the paper making machine or in a separate
coating operation.
Inventors: |
Fischer; Raymond P. (Wheaton,
IL), Whalen; John F. (Appleton, WI) |
Assignee: |
Combined Paper Mills, Inc.
(Combined Locks, WI)
|
Family
ID: |
24937735 |
Appl.
No.: |
04/731,025 |
Filed: |
May 22, 1968 |
Current U.S.
Class: |
428/346; 428/349;
428/342; 428/355R; 428/355AC |
Current CPC
Class: |
D21H
27/20 (20130101); B05C 1/083 (20130101); Y10T
428/277 (20150115); Y10T 428/2813 (20150115); Y10T
428/2891 (20150115); Y10T 428/2852 (20150115); Y10T
428/2826 (20150115) |
Current International
Class: |
D21H
27/20 (20060101); B05C 1/08 (20060101); D21H
27/18 (20060101); C09j 007/04 () |
Field of
Search: |
;117/122H,122P,122PA,76A,33 ;161/413 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Martin; William D.
Assistant Examiner: Pianalto; Bernard D.
Claims
I claim:
1. A decorative wallpaper, said decorative wallpaper including
a conventional, flexible hanging base stock,
a preliminary coating applied to the working surface of said
hanging base stock,
said preliminary coating consisting of a composition containing
kaolin clay and latex,
a final coating of adhesive material in dry form applied over the
preliminary coating,
said adhesive material being partially encapsulated in unbroken
capsules,
said adhesive material further being tackifiable by the application
of heat or pressure, or a combination of heat and pressure, in the
absence of moisture.
2. The decorative wallpaper of claim 1 further characterized in
that the partially encapsulated adhesive is heat activatable.
Description
This invention relates to wall covering having a dry adhesive on
its working surface which does not require moistened adhesive at
the time of its application to a wall surface, and a method of
manufacture thereof. The adhesive material may be applied to the
working surface at any stage during manufacture but for economic
reasons it may be preferable to apply the adhesive to the working
surface before the converter prepares the decorative surface.
Accordingly, a primary object of the invention is to provide a wall
covering which does not require a moistened adhesive at the time of
its application to a wall surface.
Although the invention is applicable to a wide variety of wall
coverings it will be described as applied to wallpaper. It should
be understood, however, that upon suitable modification the
invention can be adapted for use with cloth, wood veneer, plastic
or combinations thereof.
Another object is to provide a wallpaper as above described, or at
least the base stock therefor, which can be manufactured either
entirely on existing paper making machines utilizing presently
known methods of coating application whereby extensive
modifications of the paper making machines and processes can be
avoided, or, alternatively, partially on an existing paper making
machine followed by a coating operation separate from the paper
making machine, in which event very little or no modification need
be made in the paper making machine.
Another object is to provide a wallpaper as above described which
may be easily applied by a paper hanger and in which the
undesirable pattern matching problem common to wallpapers which
require moistened adhesive during application is eliminated.
Another object is to provide a wallpaper as above described which
can be made tacky by the application of heat or pressure, or a
combination of both heat and pressure, but which is sufficiently
insensitive to the temperatures and pressures encountered in the
manufacture, shipment and storage processes to resist premature
activation.
Another object is to provide a wallpaper as above described which
has the characteristic of being self releasable so that it may be
easily removed after a period of years. If a heat activatable
adhesive is used, it will only be necessary to reapply heat to
strip the paper from the wall or other base surface to which it has
been applied.
Other objects and advantages of the invention will become apparent
from the following description wherein a preferred embodiment is
described in detail.
The invention is illustrated more or less diagrammatically in the
accompanying figures wherein:
FIG. 1 is a section of a conventional paper making machine which
has been slightly modified to carry out the invention;
FIG. 2 is a diagrammatic view of an air knife coater; and
FIG. 3 is a section of a conventional paper making machine in which
an air knife coater has been incorporated.
Like reference numerals will be used to refer to like parts
throughout the following description of the invention.
Wallpaper stock is currently manufactured by making a base stock in
a conventional manner on a paper making machine. The base stock is
then subjected to a conversion process which may include printing,
coating, and/or embossing operations. In the case of prepasted
wallpaper, which is considered to be adhesive coated wallpaper
which is moisture activated, adhesive materials are placed on the
working surface of a moving web of paper, generally during the
conversion process and after the coating, printing and/or embossing
operations. If the adhesive materials are applied from a liquid
solution thereof the liquid carrier is dried to yield a dry
backing. The paper hanger activates the adhesive material by
applying moisture to the working surface of the paper just prior to
its placement on a wall surface.
In the process which is included in this invention adhesive
material containing an activating agent in encapsulated form is
applied to the back or working surface of a moving web of paper.
The paper hanger activates the dry adhesive on the paper by the
application of heat and/or pressure in the absence of moisture.
Under certain conditions, as in humid climates or when it is
expected that the paper will be subjected to artificially created
humid conditions, it may be preferable to moisten the paper just
prior to application to ensure against buckling and cockling at
high relative humidities. It should be understood, however, that
the moisture, if used, is for the purpose of, in effect,
prestretching the paper, and not for the purpose of activating the
adhesive. Even if moisture is used, however, the paper will be far
easier to handle and apply than conventional prepasted wallpaper
which requires moisture to make the adhesive sticky or tacky.
It is quite possible to apply the adhesive material at any point in
the manufacture of the finished product, including a point in time
subsequent to the final printing or embossing, that is, during the
conversion process. Since the application of the adhesive is one of
the less expensive operations in the entire process it is
preferred, however, to apply the adhesive material early in the
manufacturing process.
Accordingly, in one embodiment of the invention encapsulated
adhesive material is applied to the working surface of the moving
web of paper at a station in the conventional paper making machine,
preferably at a location just ahead of the dryer. This mode of
application is illustrated in FIG. 1 wherein a portion of the paper
making process is diagrammatically illustrated.
A moving web of paper is indicated generally at 10. The web, at the
left edge of FIG. 1, is approaching a conventional breaker stack 11
which consists of a number of rolls. At the time the paper reaches
the breaker stack it may be moving at a lineal speed of from 400 to
2,000 feet per minute and may have a moisture content of about 20
percent to 5 percent.
As the web 10 leaves the breaker stack it passes under a guide
roller 12 and then three additional guide rollers 13, 14 and 15
which are so positioned as to guide the web downwardly into a
coating station indicated generally at 16 at which, as illustrated
in the drawing, the coating is applied directly to the aforesaid
back or working surface of the paper.
After passing through the coating station 16 the web enters a drier
section indicated generally at 17. In order to provide sufficient
time for the setting of the coating station, a drying roll 18 is
placed a convenient distance from the coating station, which in
this instance is somewhat below the conventional drying rolls 19,
20, 21, 22 and 23. This arrangement is desirable because the wire
side of the web to which the coating has been applied comes into
direct contact with the surface of a drying roll in the dryer
section and enough time must be provided to dry the coating
sufficient to avoid sticking. It will be noted that by virtue of
the illustrated arrangement of rolls the coated working surface
does not come into contact with a roll until it reaches roll 19 in
the cluster of five rolls in the dryer section.
After passing through the dryer section the web direction is
changed by idler roll 24 and the web then passes through a
conventional calendar section 25 and leaves the machine.
It is, of course, possible for the coated web to go immediately
into the conversion process but it will be understood that usually
the stock will be coiled in roll form and shipped to the
converter.
The coating station 16 consists essentially of a supporting roll 28
which may be approximately 36 inches in diameter, and carries a
rubber cover 29. A small roll is indicated at 30, the small roll
being approximately 12 inches in diameter. The small roll is
mounted in adjustably positionable bearings 31 and is driven by
variable speed driving means 32. A separate speed controller for
motor 32 is indicated at 33 whereby roller 30 may be separately
controlled as to speed, direction of rotation, radial movement
toward and away from the supporting roll 28, and the pressure to be
applied to the web. Preferably the diameter of the small roller 30
is small enough to minimize the area of contact with the web yet
large enough to apply pressure evenly throughout its length and
form, with the web and end pans of customary design (not shown), a
space for a pool of coating.
A coating is continually supplied to the pool formed between the
rollers and end pans by a conventional supply means. A header 34
having openings through which the coating material is discharged
into the pool may be utilized for example. Preferably the coating
is continuously supplied to the pool area, the rate of supply being
controlled to accommodate web speed, paper absorption, and desired
coating weight. Small roll 30 is preferably positioned to engage
the supporting roll 28 above the horizontal plane passing through
the axis of the supporting roll. The nip is thus placed into proper
position with respect to the space requirement of an existing paper
making machine, the angle at which the web travels toward the
supporting roll, and the angle at which the web must leave the
supporting roll. The web must come into supporting contact with the
roll 28 before it enters the pool of coating and it should leave
the supporting roll 28 as close as practical after passing through
the nip in order to prevent the coating from being absorbed through
the web and deposited on the roll. Furthermore, it is desirable to
start the setting and drying of the coated web at the earliest
moment because the coated working surface of the web comes into
bearing contact with dryer roll 19. For a more complete description
of a suitable mode of applying the coating to the working surface
reference is made to U.S. Pat. Nos. 3,146,159 and 3,231,418. It
will be understood, as described in those patents, that the speed
of roll 30 is preferably suitably less than that of roll 28, and
may be as low as 10 percent of the speed of the web.
The amount of dry adhesive material which is coated on the working
surface of the web may vary. Preferably about 16 to 18 pounds of
adhesive material per 3,000 square feet of paper should be
employed.
In the event only a portion of the desired coating may be feasibly
applied at coating station 16, a second coating may be
employed.
Under certain circumstances a greater or lesser amount of adhesive
may be employed. It may be desirable for example to place a
preliminary or barrier coating of latex and kaolin clay or other
material compatible with the adhesive and the paper on the web to
reduce the coat weight of adhesive required. The precoat serves the
additional function of preventing soak-through of the liquid
adhesive coating. The employment of such a precoat may make
possible the reduction of the weight of adhesive required to about
10-15 pounds per 3,000 square feet. This is an important economic
advantage since the adhesive material is relatively expensive at
the present time.
A barrier coating composition of 81/4 parts kaolin clay, 11/4 parts
styrene butadiene latex and 1/2 part starch made at 53 percent
solids and having a viscosity of 3,400 centipoises may be used. The
ratios can be changed somewhat, or functionally equivalent
materials substituted in whole or in part, so long as satisfactory
holdout characteristics are obtained. About 8 to 10 pounds of
barrier coating per 3,000 sq. ft. of paper will efficiently seal
the web and reduce strike in of the subsequent adhesive coating.
When a barrier is applied, another coating station 16 followed by
dryers could be placed in the paper making machine of FIG. 1 just
ahead of the illustrated coating station.
If desired, the adhesive coating may be applied off the machine by
an air-knife coater, and such a variant is indicated in FIG. 2. The
entering web 40 passes between a pair of rolls 41, 42, the bottom
roll 42 being a dip roll which picks up coating 43 from pan 44 and
applies it to the bottom of the web. The web then passes around the
backing roll 45 where an air jet 46 blows off the excess coating.
For a more complete description of an air-knife coater, reference
is made to U.S. Pat. No. 3,341,351. The coating weight can be
controlled by the solids and viscosity of the coating as well as
the air pressure or velocity of air applied to the jet 46. The
paper is then passed around a direction changing roll 47 and is
then carried through a tunnel dryer 48 in which high velocity
heated air is used to dry the paper. A pair of pull rolls are
indicated at 49, 50.
The series of rolls 51-55 are used to chill the surface of the
paper. Cold water is circulated through rolls 51, 52 and 54 to
reduce the temperature of the paper. It has been found that this
chilling operation reduces the tendency of the coated paper to
block or stick to adjacent layers of paper when it is wound up into
a roll. This same chilling technique might be used advantageously
by the wallpaper converter if embossing is required should sticking
present a problem when an embosser is used. In this event the
chilling rolls would be installed between the festoon dryer and the
embosser.
In FIG. 3, both a barrier coating station 16 and an air-knife
coater, indicated generally at 39, for applying adhesive have been
incorporated into a paper making machine. In this embodiment three
direction changing rolls 36, 37 and 38 are employed to correctly
orient the barrier coated web 40 preparatory to entering the
coater. It will be understood that while this embodiment has the
advantage of completing the manufacture in one run through the
machine, it has the disadvantage of losing production of the entire
machine should a malfunction occur only in the air-knife coater.
Accordingly, the technique used will depend to some extent on the
performance reliability of the equipment and other factors.
The adhesive material applied in coating station 16 is preferably
of the encapsulated type. Thus, encapsulated adhesive materials in
a suitable liquid carrier such as water are coated at the coating
station 16, and the carrier is evaporated in the dryer section
17.
The adhesive material may be either of the heat or pressure
activated type, or a combination of both types. If a heat activated
type is employed the adhesive should not be activatable, or
tackifiable, at a temperature below about 175.degree. F. since the
paper is subjected to temperature up to this value during the paper
making process. The theoretical upper limit of the heat activatable
temperature range is of course the scorching temperature of the
paper which will vary from paper to paper. For wallpaper stock an
appropriate temperature range would be about 190.degree. to
slightly above 200.degree..
Methods of formulation of encapsulated adhesives are illustrated
and described in greater detail in the Green, et al. U.S. Pat. No.
2,800,457, and the Green U.S. Pat. 2,800,458 to which reference is
made for a further description.
In this connection, a heat activatable capsular adhesive
formulation containing 39.4 percent solids by weight and having a
Brookfield viscosity of 60 c.p. with the No. 1 spindle at 60 r.p.m.
may be prepared following the teachings of the aforesaid patents.
Specifically, only about 10 percent to about 20 percent of the dry
particles need be encapsulated. The encapsulated material should
include about one-third of the solid plasticizer which may, for
example, be di-octyl phthalate, although more than one plasticizer
may be used if desired. The dry latex, which may be a ter-polymer,
for example an acetate acrylic, and the remainder of the
plasticizer need not be encapsulated. Such a formulation was
applied to hanging paper stock and the the following observed:
a. When applied at the rate of 181/3 pounds per ream (24 .times. 36
.times. 500) on 433/4 lb./ream hanging paper stock and heat
activated the stock was found to adhere very satisfactorily to a
latex painted wall, 13 lb./ream bond paper, wall board and
Masonite. Block tests run at 106.degree. F. and 1.5 psi were
completely block free, and there was only "light pick" at 8
psi.
b. When a lower coat weight of about 13 lb./ream was employed and
application was made with a house-hold flat iron good adhesion was
achieved.
The above adhesive had substantially no open tack time. This
however is permissible because a paper hanger does not need to
slide the paper on the wall surface to ensure pattern match since
there is no distortion of the paper due to the presence of excess
moisture. A tack time of varying lengths of time may be provided
however, if desired, and it is contemplated that periods of up to 6
minutes may be provided, though as a practical matter one-half
minute or less may be quite adequate.
Alternately, a heat activatable capsular adhesive formulation may
be used which is similar to the one described above except that it
may contain about 50 percent solids by weight. Again, only about 10
percent to about 20 percent of the dry particles need be
encapsulated. The encapsulated material should include about
one-third of the solid plasticizer.
It should also be understood that other modifications may
optionally be employed. For example, in the event the adhesive
coated paper exhibits a tendency to curl, a roll 30 may be used
having a textured surface, a suitable example being disclosed in
co-pending application Ser. No. 547,887 which is assigned to the
assignee of this application. It will be understood that a
continuous film of adhesive has a different expansion and
contraction capability than the paper base stock. Use of such a
textured roll would result in the application of essentially a
noncontinuous film of adhesive which would overcome the tendency to
curl. Such a noncontinuously coated roll would have the additional
beneficial effects of reducing the coating weight necessary, and
allowing the paper to "breath" after it is applied to a wall.
Another feature which may optionally be used if advantageous is a
spray, applied just prior to winding, to prevent blocking in the
rolls of finished paper. The spraying step may conform in all
pertinent particulars to the conventional Oxidry process, or the
Ortman-McCain hydrosol process, both of which are widely employed
in offset printing to prevent sheets sticking together, and ink
smearing.
Yet another feature which may optionally be used if advantageous is
a breaker bar. By passing the paper having the dried adhesive film
thereon over a breaker bar the film is fractured by the placement
of minute cracks therein. This will be particularly helpful when a
continuous adhesive film has been formed because the cracks permit
the surface to breathe, i.e., since the surface is not completely
sealed the tendency to curl with changes in relative humidity would
be reduced or eliminated. If desired the breaker may be inserted in
a rewinder operation wherein the rolls are slit to the size
required by the customer instead of after the drying operation.
The coated paper may be applied by either radiant or conductive
heat. A flat metal applicator may be used to apply conductive heat.
If a heated roller is employed it should preferably be flattenable
in order to insure a more even application of heat. Any
conveniently constructed applicator may be employed, such as a hot
plate followed by a roller.
One outstanding advantage of the present invention is particularly
apparent during the application process, especially when the paper
is exposed to a dry environment such as the southwestern states. In
such an environment the paper hanger need merely place the paper,
in a dry condition, on the wall surface by a preliminary tacking
operation such as touching the applying instrument to one or two
places near the ceiling of the room. Since no moisture is used the
paper does not stretch and an exact pattern match can be achieved.
As soon as the pattern match is established the applying instrument
is merely passed back and forth over the surface of the paper. In
humid environments, moisture may be applied to ensure prestretching
of the paper, but addition of moisture for this purpose does not
create the usual difficulties associated with prepasted
wallpaper.
From the standpoint of application to a wall surface it will be
apparent that heat activated adhesive may be more desirable from
the standpoint of ease of release from the wall when a change of
paper is desired.
However, a paper having an encapsulated adhesive which is
activatable by a combination of heat and pressure may be very
advantageous under certain conditions. The adhesive selected for
such an application should however take into account the
temperatures and pressures encountered in paper making, converting,
storage, and shipment. Thus, even if one of the two activating
conditions is present, the adhesive will not tackify because the
other condition is absent. A heat and pressure activated adhesive
which requires a temperature of around 175.degree. F. and minimum
pressure of about 5 psi will be quite feasible, and these
conditions may be readily produced by the paper hanger at the time
of application to a wall surface.
It should further be noted that it is not necessary to encapsulate
all components of the adhesive material. Only the adhesive or only
the plasticizer may be encapsulated and in many instances this may
be the preferred mode since at the present time partially
encapsulated adhesives are less costly than fully encapsulated
adhesives. Furthermore, the percent of solids used may vary,
depending on the particle size required and other factors. At the
present time it is contemplated that the percent of solids may vary
from about 20 percent to 50 percent.
One of the greatest advantages of wall covering made as above
described is its ability to be stripped from the receiving surface
after placement thereon. Further, the ability to strip an already
applied wall covering is not time restricted to any substantial
degree. Thus, the applier, who may for example be a home owner as
contrasted to a professional paper hanger, may decide a few minutes
or a few years after the covering has been applied that it does not
appear aesthetically pleasing due to any one of a number of
factors, such as misjudging seam placement or improper measurements
during initial application, or a desire to change patterns after
the passage of time. To strip the covering it is only necessary to
reapply heat and/or pressure to the exposed surface. The
application of the proper medium will retackify the adhesive, and
then the covering can be easily stripped from the wall or receiving
surface. The stripping does not require any intentionally added
moisture.
From the foregoing it will at once be understood that the invention
may be practiced with variations which are obvious to those having
ordinary skill in the art. Accordingly, the scope of the invention
should be limited not by the scope of the aforegoing exemplary
description but solely by the scope of the hereinafter appended
claims.
* * * * *