U.S. patent number 3,658,578 [Application Number 05/057,306] was granted by the patent office on 1972-04-25 for dust-retentive article.
This patent grant is currently assigned to Phillips Petroleum Company. Invention is credited to Richard J. Bennett.
United States Patent |
3,658,578 |
Bennett |
April 25, 1972 |
DUST-RETENTIVE ARTICLE
Abstract
Dust-retentive articles, such as tack cloths, dust cloths, air
filters, etc., comprise a porous web or sheet which is impregnated
up to about 10 weight per cent with amorphous polypropylene of
molecular weight in the range of up to about 10,000 and then dried
at ambient temperature.
Inventors: |
Bennett; Richard J.
(Bartlesville, OK) |
Assignee: |
Phillips Petroleum Company
(N/A)
|
Family
ID: |
22009793 |
Appl.
No.: |
05/057,306 |
Filed: |
July 22, 1970 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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673300 |
Oct 6, 1967 |
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Current U.S.
Class: |
15/209.1;
15/104.93 |
Current CPC
Class: |
D06M
15/227 (20130101) |
Current International
Class: |
D06M
15/227 (20060101); D06M 15/21 (20060101); C09j
007/04 () |
Field of
Search: |
;15/104.93,208,209,210
;117/139.5R,14R,155UA,161UH,1,143A,161UF,122R |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Martin; William D.
Assistant Examiner: Lusignan; M. R.
Parent Case Text
BACKGROUND OF THE INVENTION
This application is a continuation-in-part application of my
copending application having Ser. No. 673,300, filed Oct. 6, 1967,
now abandoned.
Claims
I claim:
1. A porous dust-retentive article comprising a porous backing
having from 0.5 to about 10 weight per cent of liquid to
semi-solid, tacky, substantially amorphous polypropylene of
molecular weight within the range of about 2,000 to about 8,000
dispersed thereon, said amorphous polypropylene having been dried
on said backing at ambient temperature.
2. The article of claim 1 wherein said amorphous polypropylene is
evenly distributed throughout said backing.
3. The article of claim 1 wherein said polypropylene comprises at
least about 90 per cent amorphous polymer.
4. The article of claim 1 wherein said backing is natural or
synthetic fibrous webs.
5. The article of claim 4 wherein said backing is a porous paper.
Description
The use of tack cloths for the removal from various surfaces of
dust, lint, and other forms of foreign matter is relatively well
known. Such cloths find wide industrial applications such as, for
example, the removal of foreign matter such as dust, grinding
particles, sanding particles, or the like, from various objects or
surfaces prior to the finishing operations thereof such as painting
or varnishing. Although tack cloths have enjoyed wide industrial
usage, they have heretofore been characterized by certain
objectionable features which have discouraged their more universal
use in the home or office.
Generally, a tack cloth comprises a textile material of relatively
loose weave which has been chemically treated to give the same a
sticky or tacky character. When such a treated cloth is rubbed over
a surface, the undesirable foreign particles adhere to the cloth
and are thus removed from the surface. Although the prior tack
cloths were fairly efficient in removing the foreign particles,
they were invariably characterized by the fact that the chemical
coating tended to rub off onto the hands of the user so that the
user's hands became undesirably sticky and messy. The use of such
messy tack cloths was, of course, particularly objectionable in
non-industrial applications, such as general dusting and cleaning
in the house.
It is, therefore, one object of this invention to provide a
dust-retentive article. It is another object of this invention to
provide a porous or semi-porous article having high retention for
finely divided solids and/or aerosols. It is another object of this
invention to provide a non-messy dust-retentive article. It is yet
another object of this invention to provide dust-retentive web
which is non-messy, highly durable, i.e., retains its adhesive
characteristics over a long period of time, and is easily
regenerable.
SUMMARY OF THE INVENTION
In accordance with one embodiment of this invention there is
provided a backing material such as porous or semi-porous web or
sheet having dispersed thereon up to about 10 weight per cent
amorphous polypropylene. In accordance with another embodiment of
this invention a backing material such as porous or semi-porous web
or sheet is rendered capable of retaining minute solids such as
dust by dispersing thereon either in the form of solution or
aerosol up to about 10 weight per cent amorphous polypropylene and
drying at ambient temperature.
The term "tackifier" has commonly been given to the substance with
which a textile is treated to render the same sticky or tacky. As
already indicated above, a suitable tackifier must be tacky at
normal temperatures and yet must be sufficiently stiff or viscous
to adhere to the cloth and not come off on the surface being
cleaned or the user's hands. Similarly, the tackifier should
desirably be in the form of a liquid under manufacturing conditions
so that the tack cloth may be simply and inexpensively fabricated
by merely dipping the textile material in a bath of the tackifier
or by spraying a solution of the tackifier onto the surface of a
textile or absorbent paper material.
I have discovered that amorphous polypropylene within a certain
molecular weight range meets all these requirements generally
associated with tackifiers and filter impregnating agents when
dispersed on a suitable web or backing in concentrations of up to
about 10 weight per cent. Amorphous polypropylenes having a
molecular weight above about 10,000 are solid and are only slightly
tacky. Amorphous polypropylenes having molecular weights below
about 10,000 are characterized by being semi-solid to liquid and
are very tacky. Although dispersion of very minute quantities of
this amorphous polypropylene on the intended backing materials
increases their affinity for minute airborn solids, it is presently
preferred that from about 0.5 to about 5 weight per cent of the
amorphous polymer be employed. In addition, it is also preferred
that the molecular weight of the amorphous polypropylene be within
the range of from about 2,000 to about 8,000 in order to provide an
article having the most desirable combination of qualities
including dust retention and freedom from streaking or messy
deposits of any variety. Polypropylene comprising at least about 90
per cent amorphous polymer is presently preferred.
Polypropylene is a synthetic resin which, of late, has enjoyed
greatly increased usage in the preparation of molded articles,
fibers and films. For use in the latter applications it is
desirable that the polypropylene should have a highly crystalline
structure which thereby serves to increase the strength of this
versatile plastic.
Amorphous polypropylene is not readily usable for structural
products because its properties are different from those of the
crystalline polymer.
Many of the processes currently employed for the manufacture of
polypropylene make use of so-called stereospecific catalysts which
are chosen for their ability to produce predominantly crystalline
polypropylene. However, despite the use of these catalysts, present
polymerization techniques still produce a product with a
significant proportion of amorphous polypropylene. The presence of
this non-crystalline fraction detracts from the strength of
articles manufactured therefrom. Therefore, it is the practice in
the art to separate this amorphous portion from the crystalline
material by solvent extraction. Only a few applications have been
found for this amorphous polypropylene residue. Its inherent lack
of high structural stability obviates its use in the preparation of
fibers, films, and molded products, while any use of this material
as an adhesive base is similarly precluded since the resulting
adhesive films are exceedingly soft and display relatively little
strength.
The use of such amorphous polypropylene in the production and
bonding of non-woven fabrics is discussed in U.S. Pat. No.
3,126,297. It is well observed in that disclosure that the
concentrations of amorphous polypropylene dispersed on the
non-woven backing must be relatively high in order to effect the
production of a unitary article. I have found that these
concentrations are unnecessary. This consideration is pointed out
particularly by the examples hereinafter presented.
The amorphous polymer is preferably applied to the backing in the
form of a solution in a suitable solvent by either spraying the
solution onto the backing or dipping the backing into a solution of
the amorphous polymer. Amorphous polypropylene may be dissolved in
a variety of solvents, including aromatic hydrocarbons, such as
toluene, xylene, decahydronaphthalene and tetrahydronaphthalene;
aliphatic hydrocarbons containing from five to 11 carbon atoms,
such as pentane, hexane, and nonane; and chlorinated hydrocarbons,
such as methylene chloride, carbon tetrachloride,
trichloroethylene, perchloroethylene, and also chlorinated aromatic
hydrocarbons such as chlorobenzene. It should be noted that, where
so desired by the practitioner, it is possible to prepare these
solutions with various combinations of any of the above-listed
solvents. The resin solids content of these amorphous solutions
should usually range from about one per cent to about 50 per cent
by weight.
Aqueous emulsions can also be employed and are easily prepared by
adding an emulsifying agent to a polymer solution. Suitable
solutions can be prepared by any of the above-listed solvents.
Water is then added with vigorous agitation, the amount of water
added depending on the solids content desired in the resulting
emulsion. The organic solvent can then be removed from the emulsion
by any suitable method such as distillation. The resin solids
content of these emulsions usually ranges from about two per cent
to about 65 per cent by weight.
It should be mentioned that various additives, such as defoamers,
resinous wet strength modifiers, lubricants, and the like, may be
added to the amorphous polypropylene binder formulations.
Essentially, any variety of backing material, either non-porous,
porous, or semi-porous, can be employed for the purposes of this
invention. It is, of course, desirable to utilize some of these
materials in preference to others depending on the particular
application to which these finished articles were intended. For
example, where it is desirable to produce an article suitable for
application as an industrial tack cloth or dust cloth intended for
household use a suitable backing material could comprise
essentially any cloth fabric, natural or synthetic fiber in
addition to preferably highly porous paper. However, the production
of air filters would preferably require the utilization of a more
structurally stable backing such as coarsely interwoven or
fibrillated polymer fibers, fiberglass, comminuted solids, etc.,
which could be retained in a suitable frame or housing.
After application of the polymer to the backing, the dust-retentive
article produced is dried at ambient temperature of about
50.degree. to about 100.degree. F. It has been found that elevation
of the temperature at which the article is dried tends to decrease
the tackiness of the article in relation to the degree of
temperature elevation. Thus, by drying the article at an elevated
temperature or by later heat treating a dust-retentive article that
has been initially dried at room temperature, an article treated
with amorphous polypropylene by this invention can be rendered so
non-tacky that the improved dust-retentive characteristics are
lost.
Another substantial advantage of the dust-retentive article of this
invention, in addition to their high durability and relative lack
of messiness, is the ease by which they can be regenerated after
continued use. For example, industrial tack cloths, household dust
cloths, air filters, and the like can be reimpregnated after a
substantial period of use simply by applying additional amorphous
polypropylene in the form of aerosol, for example, from an aerosol
can, and allowing the solvent to evaporate.
The several advantages of this invention are listed in part by the
following examples.
EXAMPLE I
A 12 by 18 inch paper towel was submerged in a solution of
amorphous polypropylene having a molecular weight of about 5,000,
drained, and dried at ambient temperature to produce a dust cloth
having dispersed thereon 2 weight per cent amorphous polypropylene.
The feel of this article was found indistinguishable from that of
the original article. In addition, the treated cloth did not streak
or leave any perceptible deposits on highly polished wooden
surfaces and glass. It was, however, completely effective in
removing dust deposits from these surfaces in a single pass.
EXAMPLE II
A 25 per cent solids solution of amorphous polypropylene was
prepared using 58.3 grams of amorphous polypropylene, having a
molecular weight of about 6,000, which was obtained from the xylene
soluble fraction of production process polypropylene and had not
been specially purified, and 174.9 grams of toluene. Three cotton
cloths were saturated with the solution and air dried at ambient
temperature, i.e., about 75.degree. F. The cloths retained on their
fibers approximately 14 grams of amorphous polypropylene per square
foot. One cloth was thereafter placed in an oven at 280-300.degree.
F for one hour. The amorphous polypropylene solution treated cloth
had a slight tacky feel. The cloth subjected to further heat had a
dry feel.
EXAMPLE III
A dust-like material was prepared by drying soil at 325.degree. F
for 20 minutes and passing it through a 200 mesh screen. This dust
was spread over a glossy table surface. A 12 square inch sample of
each of the amorphous polypropylene coated materials was placed on
the dusty surface without pressure for 10 seconds and removed
without any wiping action. The polypropylene coated cloth that had
not been heat-treated picked up more dust than the heat-treated
cloth.
EXAMPLE IV
The test was repeated using fresh sample squares and applying the
pressure of equal weights to each sample. The cloth that had not
been heat treated readily picked up dust, substantially more than
the completely untreated control cloth. The heat-treated cloth
picked up dust no better than the completely untreated control
cloth.
EXAMPLE V
Fresh squares of the heat-treated and non-heat-treated cloths were
loaded with dust by wiping a dust coated surface. Both dust laden
cloths were placed on clean surfaces. The heat-treated cloth
readily released the dust. The non-heat-treated cloth retained
almost all the dust it had picked up.
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