U.S. patent number 3,653,932 [Application Number 04/853,889] was granted by the patent office on 1972-04-04 for electrostatic printing composition comprising didodecyl sebacate.
This patent grant is currently assigned to Teletype Corporation. Invention is credited to James M. Berry, Gary P. Corpron.
United States Patent |
3,653,932 |
Berry , et al. |
April 4, 1972 |
**Please see images for:
( Certificate of Correction ) ** |
ELECTROSTATIC PRINTING COMPOSITION COMPRISING DIDODECYL
SEBACATE
Abstract
Printing is effected with a hot melt type ink comprised of
coloring material and a vehicle therefor and having a resistivity
within the range of about 10.sup.6 to about 10.sup.11
ohm-centimeters and a viscosity in a range with an upper limit of
about 50 centipoises when in a liquid phase. To that end, a stream
of ink drops are drawn across and deflected in a span between an
ink supply and a carrier for impingement thereon. The vehicle of
the ink is comprised of at least one compound which is solid at
room temperature, and has the general formula: in which each R and
R' is an alkyl group containing from one to 12 carbon atoms.
Inventors: |
Berry; James M. (Deerfield,
IL), Corpron; Gary P. (Skokie, IL) |
Assignee: |
Teletype Corporation (Skokie,
IL)
|
Family
ID: |
25317146 |
Appl.
No.: |
04/853,889 |
Filed: |
August 28, 1969 |
Current U.S.
Class: |
106/31.29;
106/272; 347/99; 106/266; 106/31.58 |
Current CPC
Class: |
C09D
11/34 (20130101) |
Current International
Class: |
C09D
11/00 (20060101); C09d 011/00 (); C09d
013/00 () |
Field of
Search: |
;106/19-32,243,38O
;117/93.4-93.44 ;252/62.1,62.5 ;8/83,93 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Evans; Joan B.
Claims
We claim:
1. An ink composition of the hot melt type consisting essentially
of a coloring material including a dye, and 85-97.5 percent by
weight of a vehicle consisting essentially of a mixture of a major
proportion of didodecyl sebacate with a minor proportion of a
second dialkyl sebacate selected from the class consisting of
dimethyl sebacate and dibutyl sebacate, the ink composition being
further characterized in that the vehicle is solid at room
temperature and is proportioned with the coloring material such
that the ink composition, when a liquid phase, has a resistivity
within the range of about 10.sup.6 to 10.sup.1 ohm-centimeters and
a viscosity in a range with an upper limit of about 50
centipoises.
2. A composition according to claim 1 in which the amount of
coloring material is in the range of about 2.5 to 28 percent by
weight and the amount of the vehicle is in the range 97.5 to 72
percent by weight.
3. A composition according to claim 1 in which the coloring
material is selected from the group consisting of C. I. solvent
yellow 29, methyl violet tannate, C. I. solvent black 12, and
mixtures of the foregoing.
4. A composition according to claim 1 in which the vehicle consists
of a mixture of didodecyl sebacate in an amount in the range of
about 46 to 72 percent by weight and said second sebacate in an
amount in the range of about 24 to 12 percent by weight.
5. A composition according to claim 1 in which the melting point of
the ink does not exceed about 54.4.degree. C. and the freezing
point is not below about 30.degree. C.
6. As a hot-melt ink composition for electrostatic ink-jet printing
in which the ink composition in a fluid phase at a printing
temperature of approximately 53.degree. to 59.degree. C. is
electrostatically formed into a stream of droplets which are
deposited on a paper sheet to form characters, the composition
consisting essentially of approximately 12 percent by weight of
coloring material including a dye, and approximately 88 percent by
weight of a vehicle consisting of approximately 67 percent by
weight of didodecyl sebacate and approximately 21 percent by weight
of dimethyl sebacate.
7. A composition according to claim 6, wherein the coloring
material consists of approximately 9 percent by weight of methyl
violet toner and approximately 3 percent by weight of C. I. solvent
yellow 29.
Description
BACKGROUND OF THE INVENTION
This invention relates to electrostatic printing. Particularly it
relates to the art of printing with an ink which electrostatically
is moved across and deflected in a span between an ink supply and a
record carrier for forming intelligence patterns thereon.
This art has been the subject of considerable investigation and is
exemplified by U.S. Pat. No. 3,060,429 issued to C. R. Winston,
Oct. 23, 1962. However, a dearth of literature available relative
inks which can be effectively transferred thereby tends to limit
practice of the processes because many, if not most, compositions
which might be considered suitable in the art will not produce
commercially satisfactory graphic products when used in heretofore
known apparatuses. The inadequacy of such compositions results from
absence therein of physical and electrical properties compatible
with known processes.
In a copending application of R. J. Dunlavey and C. R. Winston,
Ser. No. 853,825 filed Aug. 28, 1969, which is a continuation in
part of Ser. No. 513,196, filed Dec. 13, 1965 and assigned to the
assignee of the present application, parameters of viscosity and
resistivity of inks suitable in the referenced art are set forth.
But all however, additionally, should be of the hot melt type with
a melting point at a sufficiently low level to enable manipulation
without special clothing or equipment.
SUMMARY OF THE INVENTION
According to one aspect of the invention, a process wherein a
stream of a hot melt type ink comprised of coloring material and a
vehicle therefor electrostatically is drawn across and deflected in
a span between a supply nozzle and a carrier on which the ink
impinges for forming record patterns is characterized by the
vehicle. The latter is a material selected from class of compounds
having the general formula
in which each R and R' is an alkyl group containing from one to 12
carbon atoms. In another aspect of the invention, the vehicle is
proportioned such that the ink has a resistivity in the range of
about 10.sup.6 to about 10.sup.11 ohm centimeters and a viscosity
in a range with an upper limit of about 50 centipoises.
DESCRIPTION OF THE DRAWING
The ensuing detailed description of the invention refers to the
accompanying drawing which is a perspective of a scheme of
apparatus for effecting a process embodying the invention.
DETAILED DESCRIPTION OF THE INVENTION
Referring now to the drawing, apparatus generally designated 10
comprises ink supply means or source shown as a reservoir 12
fluidally coupled to a nozzle 14. Heating means here shown as a
heating element 16 is mounted relative the reservoir to maintain
ink used in the process in a fluid phase to the end that continuous
flow may be maintained to the nozzle tip and thereafter for
printing on a carrier 18.
As used herein the term "printing" is not limited to intelligence
formation by alphanumeric symbols but includes any graphic
representation in the form of, for example, script and other
pattern and symbol formation. The term "ink" means any material
with which printing can be effected. The term "hot melt" defines
ink and means in a solid phase at room temperature and in a liquid
phase at some higher temperature, generally, to enable flow during
transfer to a carrier.
In the illustrated apparatus, the nozzle is electrically conductive
and has an inside diameter at its tip of about 0.0065 inch.
Hydrostatic pressure of the ink for the process is sufficient to
cause formation of a convex meniscus at the nozzle tip to the end
that the ink will intrude into the electrostatic field generated
according to ensuing description. Neither the nozzle diameter nor
the level of hydrostatic pressure exerted in the direction of the
carrier 18 is critical in the invention, as an ink stream suitable
for printing can be drawn electrostatically from a puddle.
In accordance with the present invention ink is drawn in a single
file stream 26 of drops electrostatically in a span 21 between the
tip of nozzle 14 and carrier 18 through means including a valving
or metering electrode 22. Said electrode is shown as a plate with a
central aperture 23 aligned horizontally with the nozzle tip such
that the path of flow of the ink will be normal to the plane of the
plate and through said aperture. Herein the electrode is spaced
from the nozzle tip about 0.045 inch.
Circuit means 24 are arranged between electrode 22 and nozzle 14 in
a manner which may be conventional for producing an electrostatic
field therebetween. A field of about 2,450 volts is employed in the
illustrated embodiment to initiate formation of stream 26 and draw
it in a line through aperture 23 from the nozzle. To produce the
effect a DC potential of about -1,900 volts is applied to the
nozzle while a DC potential of about 550 volts is applied to
electrode 22. When the potential difference across the field is
reduced to about 1,900 volts any flow from the nozzle will shut
off.
Stream 26 may be electrostatically deflected vertically and
horizontally in span 21 to form a pattern 29 on the carrier.
Vertical deflection is achieved with a pair of vertical deflection
electrodes 30 and 31 which are spaced downstream of valving
electrode 22. Horizontal deflection is achieved with a pair of
horizontal deflection electrodes 32 and 33 spaced downstream of the
vertical deflection electrodes. The electrodes of each vertical and
horizontal deflection pair are arranged to define the path of fluid
flow toward said carrier.
In the illustrated embodiment, the vertical deflection electrodes
are vertically spaced apart each from the other about 0.02 inch and
spaced from valving electrode 22 about 0.035 inch. A non-deflecting
DC potential averaging about 1,350 volts can be applied on them by
circuit means 34. The horizontal deflection electrodes are spaced
horizontally apart each from the other about 0.025 inch and from
electrode 22 about 0.07 inch. A non-deflecting DC potential of
about 2,100 volts can be applied on them by circuit means 36.
Deflecting signals may be superimposed on the non-deflecting DC
components of the deflecting electrodes by a conventional signal
generator 38 from coded means (not shown) for producing a magnitude
of stream deflection required for forming recognizable variation in
pattern 29 while printing at the rate of 60 alphanumeric characters
per second, horizontally spaced 10 per inch with the horizontal
lines being spaced six per inch and on the carrier supported about
0.43 inch from the nozzle. Variation of about 560 volts between the
electrodes of each pair of deflection electrodes is sufficient for
any character.
A conductive platen 40 to which a DC potential of about 10,000
volts is applied by circuit means 42 during the illustrated
printing process provides a backing for carrier 18 which herein is
paper of sheeting thickness and is arranged to be driven
transversely of stream 26 at any selected rate by means (not shown)
which may be conventional. This last voltage is sufficient to
insure movement of the stream in a straight line from the nozzle to
the carrier when deflecting voltages are not applied and will draw
the stream as deflected against the carrier to produce any selected
pattern.
We have found that di-esters of sebacic acid which have been
esterified with alcohols of paraffins having 12 or less carbon
atoms in their chains provide excellent vehicles for pigments and
dyes for producing high quality electrostatic printing. They have
the desired characteristics of viscosity and resistivity at the
operating temperature of the reservoir. That is to say, at such
temperature an ink will have a viscosity within a range having an
upper limit of 50 centipoises and a resistivity within the range of
10.sup.6 to 10.sup.11 ohm-centimeters. These compounds have the
general formula:
in which each R and R' is an alkyl group containing from one to 12
carbon atoms.
However, the esters of the shorter chains, though producing good
inks for electrostatic printing, do not provide solid inks at room
temperature alone or in combination with other shorter chain
esters. Specific compositions of high quality, with compounds of
said general formula as vehicles, but not solid at room temperature
are set forth in the following:
EXAMPLE I Ingredient % by Weight dibutyl sebacate 21.2 dioctyl
sebacate 63.8 methyl violet toner 15.0
EXAMPLE II dibutyl sebacate 92 methyl violet toner 8
In practice and according to the invention, a hot melt type ink,
which will not flow after striking the carrier, is employed.
Each of the inks according to the invention preferably has a
melting point which does not exceed about 51.degree. C. and a
freezing point which is not below 30.degree. C. This insures that
the ink will be in a liquid phase at the operating temperature of
the exemplary reservoir, namely, about 56.degree..+-.3.degree. C.
and will be solid at generally encountered room temperatures to
minimize its flow from the carrier.
Specific inks according to the invention are set forth in the
following:
EXAMPLE III Ingredient % by Weight didodecyl sebacate 48.2 dibutyl
sebacate 12.1 methyl violet toner 13.2 C.I. solvent yellow 29
13.3
EXAMPLE IV didodecyl sebacate 61.2 dibutyl sebacate 18.8 methyl
violet toner 13.3 C.I. solvent yellow 29 6.7
EXAMPLE V didodecyl sebacate 72.0 dibutyl sebacate 18.0 C.I.
solvent black 12 4.0 C.I. solvent yellow 29 6.0
EXAMPLE VI didodecyl sebacate 66.0 dimethyl sebacate 24.0 C.I
solvent black 12 4.0 C.I. solvent yellow 29 6.0
EXAMPLE VII didodecyl sebacate 57.2 dibutyl sebacate 13.1 methyl
violet toner 17.9 C.I. solvent black 12 2.8 C.I. yellow 29 9.0
EXAMPLE VIII didodecyl sebacate 53.8 dimethyl sebacate 13.4 methyl
violet toner 19.2 C.I. solvent black 12 4.0 C.I. solvent yellow 29
9.6
EXAMPLE IX didodecyl sebacate 64.1 dimethyl sebacate 19.4 methyl
violet toner 10.7 C.I. solvent black 12 1.9 C.I. solvent yellow 29
3.9
EXAMPLE X Ingredient % by Weight didodecyl sebacate 66.9 dimethyl
sebacate 21.1 methyl violet toner 9.0 C.I. solvent yellow 29
3.0
EXAMPLE XI didodecyl sebacate 88.6 methyl violet toner 11.4 EXAMPLE
XII didodecyl sebacate 93.0 C.I. solvent black 12 4.2 C.I. solvent
yellow 29 2.8
EXAMPLE XIII didodecyl sebacate 85.2 methyl violet toner 11.0 C.I.
solvent yellow 29 3.8
The inks according to the invention comprise a carrier and a dye or
pigment with proportions which may vary over a wide range. Specific
effective ink compositions illustrative of the range of ingredients
follow:
EXAMPLE XIV Ingredient % by Weight didodecyl sebacate 46.1 dibutyl
sebacate 11.5 methyl violet toner 25.6 C.I. solvent black 12 4.0
C.I. solvent yellow 29 12.8
EXAMPLE XV didodecyl sebacate 97.5 C.I. solvent black 12 1.5 C.I.
solvent yellow 29 1.0
The methyl violet toner of the examples comprises about 40 percent
methyl violet tannate in a transparent yellow mineral oil carrier.
It is a product of Ad-Co Color Company, now merged with Magruder
Color Company of Newark, N. J., and identified as RM-457-50.
* * * * *