U.S. patent number 3,652,329 [Application Number 05/006,328] was granted by the patent office on 1972-03-28 for method of treating textiles.
This patent grant is currently assigned to Nalco Chemical Company. Invention is credited to Peter H. Vossos.
United States Patent |
3,652,329 |
Vossos |
March 28, 1972 |
METHOD OF TREATING TEXTILES
Abstract
Covers textile treating compositions and a method of improving
the strength and other desirable properties of textiles by
contacting said textile with an organosol comprising a non-polar
organic solvent having uniformly dispersed therein discrete, dense
colloidal particles of amorphous silica having an average particle
diameter of 3-150 millimicrons and an average surface area of from
about 20 M.sup.2 /g. to 1,000 M..sup.2 /g., said silica particles
having absorbed upon their surfaces a quaternary ammonium salt or
hydroxide, with the weight ratio silica, expressed as SiO.sub.2 to
the quaternary ammonium salt or hydroxide being at least 2:1,
wherein the quaternary ammonium compound has the formula: wherein
R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrocarbon groups
containing one-22 carbon atoms, with the total number of carbon
atoms in said quaternary ammonium compound being at least 10, and X
is an anion selected from the group consisting of chloride,
bromide, iodide and hydroxide.
Inventors: |
Vossos; Peter H. (Lisle,
IL) |
Assignee: |
Nalco Chemical Company
(Chicago, IL)
|
Family
ID: |
21720361 |
Appl.
No.: |
05/006,328 |
Filed: |
January 27, 1970 |
Current U.S.
Class: |
428/372;
252/8.86; 252/8.61; 427/445; 428/393; 428/395; 428/375; 428/394;
516/34 |
Current CPC
Class: |
D06M
11/79 (20130101); Y10T 428/2967 (20150115); Y10T
428/2965 (20150115); Y10T 428/2969 (20150115); Y10T
428/2927 (20150115); Y10T 428/2933 (20150115) |
Current International
Class: |
D06M
11/79 (20060101); D06M 11/00 (20060101); C10m
005/20 () |
Field of
Search: |
;252/8.8,309
;117/139.5CQ,139.5CF |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rosdol; Leon D.
Assistant Examiner: Pitlick; Harris A.
Claims
I claim:
1. A method of improving strength and other desirable properties of
textiles which comprises the steps of treating textile fibers with
an organosol consisting essentially of a non-polar organic solvent
selected from the group consisting of pentane, hexane, heptane,
octane, nonane, iso-octane, decane, pentyne, toluene, chiorinateo
hydrocarbons, a vegetable oil, an animal oil, a marine oil, a
mineral oil and a synthetic oil having uniformly dispersed therein
discrete, dense colloidal particles of amorphous silica having an
average particle diameter of 3-150 millimicrons and an average
surface area of from about 20 M.sup.2 /g to 1000 M.sup.2 /g, said
silica particles having absorbed on their surfaces a quaternary
ammonium salt or hydroxide, with the weight ratio silica, expressed
as SiO.sub.2 to the quaternary ammonium salt or hydroxide being at
least 2:1 wherein the quaternary ammonium compound has the
formula:
wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are aliphatic
hydrocarbon groups containing one-22 carbon atoms, with the total
number of carbon atoms in said quaternary ammonium compound being
at least 10, and X is an anion selected from the group consisting
of chloride, bromide, iodide and hydroxide, said organosol
containing from about 0.1 percent to about 60 percent by weight of
said silica having absorbed quaternary ammonium compound thereon,
said textile being treated with from about 0.10 percent to about 2
percent by weight of said organosol based on the weight of the
textile.
2. The method of claim 1 wherein said solvent is a low viscosity
oil selected from the group consisting of a vegetable oil, an
animal oil, a marine oil and a synthetic oil.
3. The method of claim 1 wherein said organosol contains 10-60
percent by weight of silica containing absorbed quaternary ammonium
salt or hydroxide.
4. The method of claim 1 wherein said textile treated is
cotton.
5. The method of claim 1 wherein said quaternary ammonium salt is
tricaprylyl methyl chloride.
6. The method of claim 1 wherein said quaternary ammonium salt is
dicoco dimethyl ammonium chloride.
7. The method of claim 1 wherein said quaternary ammonium salt is
dihydrogenated tallow dimethyl ammonium chloride.
8. The method of claim 1 wherein said quaternary ammonium salt is
lauryl trimethyl ammonium chloride.
9. The method of claim 1 wherein the discrete, dense colloidal
particles of amorphous silica have an average surface area of from
150 M.sup.2 /g. to 190 M.sup.2 /g.
10. The method of claim 1 wherein the discrete, dense colloidal
particles of the amorphous silica have an average particle diameter
of from 16 to 20 millimicrons and an average surface area of from
150 to 190 M.sup.2 /g., and wherein the weight ratio of silica,
expressed as SiO.sub.2, to quaternary ammonium salt or hydroxide is
from 3:1 to 10:1.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention is concerned with compositions useful in
treating textiles such as cotton to improve their strength and
other valuable properties, and the mode of treatment.
2. Description of the Prior Art
Many textiles such as cotton do not have the desired degree of
strength, and are often therefore chemically treated to improve
this property. Essentially, the chemical treatment is effected to
increase the inter-fiber friction characteristics of spun textile
fibers. By improving frictional properties, one may achieve either
greater strength for the same amount of twist or produce yarns at
lower twists but at a higher rate. In the latter situation, overall
production is thus improved.
However, in many instances, the chemical treatment, while improving
strength, deleteriously affects other desirable properties of the
thus treated textile fibers. In a typical case, while strength is
improved via the chemical treatment, the property of elongation is
adversely affected. It would therefore be a considerable advance in
the art if a method of treating cotton or other textiles were
discovered whereby fiber strength is increased, and yet other
desirable properties such as elongation and the like are not
deleteriously affected at the same time.
It therefore becomes an object of the invention to provide a method
of treating textiles such as cotton and the like.
A more specific object of the invention is to chemically treat
textiles such that their strength is materially increased without
adversely affecting other desirable properties of the treated
textile.
Another object of the invention is to chemically treat textiles to
improve the strength thereof by resort to a liquid chemical
composition which may be applied to the textile via a number of
conventional ways such as by spraying and the like.
Other objects, features and advantages of the invention will be
readily apparent from the following description of certain
preferred embodiments thereof, although variations and
modifications may be effected without departing from the spirit and
scope of the novel concepts of the disclosure.
SUMMARY OF THE INVENTION
Broadly speaking, textiles such as cotton, are treated to improve
their strength and other desirable properties by contacting the
textile with an organosol comprising a non-polar organic solvent
having uniformly dispersed therein discrete, dense colloidal
particles of amorphous silica having an average particle diameter
of 3-150 millimicrons and an average surface area of from about 20
M.sup.2 /g. to 1,000 M.sup.2 /g., said silica particles having
absorbed upon their surfaces a quaternary ammonium salt or
hydroxide, with the weight ratio silica, expressed as SiO.sub.2 to
the quaternary ammonium salt or hydroxide being at least 2:1,
wherein the quaternary ammonium compound has the formula:
wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrocarbon
groups containing one-22 carbon atoms, with the total number of
carbon atoms in said quaternary ammonium compound being at least
10, and X is an anion selected from the group consisting of
chloride, bromide, iodide and hydroxide.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The products used to treat textiles are silica organosols
consisting of an organic solvent which contains uniformly dispersed
therein discrete, dense colloidal particles of amorphous silica. In
the organic solvent are uniformly dispersed discrete, dense
colloidal particles of amorphous silica. These silica particles are
from 0.1 percent to 60 percent by weight of the total composition.
These silica particles have an average particle diameter of from 3
to 150 millimicrons and an average surface area of from 20 M.sup.2
/g. to 1,000 M.sup.2 /g. These silica particles have adsorbed upon
their surfaces a quaternary ammonium salt or hydroxide.
The quaternary ammonium compound has the formula:
wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrocarbon
groups containing from one-22 carbon atoms each, and X is an anion
selected from the group consisting of chloride, bromide, iodide and
hydroxide. For best results, the total number of carbon atoms of
the quaternary should be at least 10 and more often at least 14
Thus, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 in the above formula
may be any hydrocarbon radical such as methyl, ethyl, propyl,
n-butyl, t-butyl, amyl, hexyl, heptyl, octyl, caprylyl, lauryl,
myristyl, palmityl, stearyl, oleyl, etc. In many instances the
quaternary amines are derived from mixtures of fatty acids that
occur in various fats and oils, such as coconut oil, hydrogenated
tallow, castor oil, hydrogenated castor oil, etc. Thus, in such
cases, the R groups will be mixed.
Typical quaternary ammonium compounds which may be adsorbed upon
the silica particles are dicoco dimethyl ammonium chloride,
tricaprylyl methyl ammonium chloride, dihydrogenated tallow
dimethyl ammonium chloride, lauryl trimethyl ammonium chloride and
others.
The solvent for the silica and adsorbed quaternary may be any
appropriate organic solvent which when combined with the silica and
quaternary ammonium compound forms an appropriate organosol. Thus,
such solvents as pentane, hexane, heptane, octane, nonane,
iso-octane, decane, pentyne, toluene, chlorinated hydrocarbons may
be used.
A preferred solvent for the silica is a straight or branched chain
oils such as a vegetable oil, animal oil, marine oil, mineral oil,
or a synthetic oil. Preferably, oils of relatively low viscosity
are employed.
The amount of the quaternary in relation the silica depends upon
the particle size of the colloidal silica. The smaller the particle
size, the more quaternary will be required. In general, the ratio
of SiO.sub.2 to quaternary will be from 25 to 1 to 2 to 1, and more
often will be from 3:1 to 10:1. For an average particle diameter of
20 millimicrons a ratio of about 6 to 1 is typical.
The just-described organosols may be made in a number of ways.
Preferably, the quaternary to be coated upon the silica particles
is first added to a non-polar organic material such as a
hydrocarbon oil. After mixing these two ingredients an aqueous
silica sol is added thereto. Generally, the aqueous silica sol
contains from about 20 percent to about 60 percent by weight of
discrete, dense colloidal particles of amorphous silica. In some
instances, a hydrophilic solvent such as isopropanol is added to
effect dissolution of the mixture and cause a higher degree of
adsorption of quaternary upon the silica. The mixture is then
stirred for about 5-60 minutes. After mixing, two phases are
obtained, the bottom layer generally being the organic containing
quaternary coated silica. The two layers are separated and the
product layer is heated for say 60.degree.-80.degree. C. for 2-20
minutes to drive off the hydrophilic solvent added above, such as
an alcohol. Means for speeding up separation of oil and water phase
would be either resort to centrifugation or application of an
electrical potential across the system.
Normally, the organosols useful here contain from about 0.1 to
about 60 percent by weight of silica which have been coated with
quaternary ammonium salt or hydroxide. More often the organosol
contains 10-60 percent by weight of coated silica.
STARTING AQUEOUS SILICA SOLS
Generally, any aqueous silica sol can be used for this invention.
These are well known to the art. The starting aqueous silica sol
can range from 20 to 60 percent by weight of discrete, dense
colloidal particles of amorphous silica. The average particle
diameter can range from 3 to 150 millimicrons and can have an
average surface area from 20 M.sup.2 /g. to 1,000 M.sup.2 /g. It is
preferred that the starting aqueous silica sol be from 30 to 50
percent by weight of discrete, dense colloidal particles of
amorphous silica. The preferred particle diameter should range from
16 to 20 millimicrons and have an average surface area from 150 to
190 M.sup.2 /g.
The following is a table of commercially available aqueous silica
sols. These are sold by Nalco Chemical Company under the Trademark
Nalcoags. ##SPC1##
The organosol may be applied to a wide variety of textiles
including cotton, wool, synthetic fibers, blends of cotton or wool
and synthetic fibers, such as Dacron (polyethylene terephthalate)
and wool, blends of Orlon (acrylic fiber) and other textiles,
etc.
The amount of organosol added to the fibers may be widely varied.
However, usually from about 0.10 percent by weight to about 2
percent by weight of organosol is added based on the weight of the
fibers, and more often 0.2-1 percent. In the usual case, the
textile is thus treated with from about 0.05 percent to about 0.6
percent silica expressed as SiO.sub.2.
The organosol may be coated on the fiber such as by resort to
spraying techniques including mist, fog and fine spraying. In like
manner, the fibers may be treated by dabbing the organosol thereon.
Preferably, the organosol compounds are applied to the textile
fibers by spraying. One excellent point of treatment of the textile
fibers during processing is at the picking operation where textile
fibers such as cotton are formed into a continuous sheet known as a
picker lap. Thereafter, the laps are then carded into a silver or
continuous tow. This orients the fibers in a parallel direction.
The card sliver is then ganged from a number of individual slivers
and redrawn into a single sliver. This sliver is then converted to
roving on a roving frame. It is during this operation that an
initial twist is given. Specifically, the card sliver is drafted to
produce a very coarse yarn suitable for handling on a spinning
frame. The roving is then processed into yarn on a spinning frame
where the major portion of twist is given to the yarn, thereby
resulting in the desired strength. It is at this point that the
advantages of the treatment are particularly apparent. By resort to
the organosols the thus coated fibers either exhibit greater
strength for the same amount of twist or one can produce yarns at
lower twists but at a higher rate. Since the spindles of the
spinning frame revolve at an essentially constant speed, the amount
of treated yarn built upon the spindle in a given time can be
increased by increasing the speed of the front roller of the
spinning frame. This, in turn, results in the production of yarn of
lower twist. In essence, therefore, one can materially increase
production rates by more rapidly producing yarn of lower twist but
of acceptable strength.
As noted above, in addition to increasing the strength of textile
fibers via the treatment of the invention, other desirable
properties are not adversely affected. Specifically, it has been
noted that elongation is not deleteriously affected via the
treatment. Yet, in many prior art chemical treatments in order to
increase the desired degree of strength, elongation is
lessened.
In point of fact, in addition to increasing strength, it has been
noted that the chemical treatment here actually reduces the number
of thick and thin imperfections. In addition, use of the organosols
reduces the number of "ends down" in the spinning operation. Ends
down refers to the number of breaks of the yarn which is being
spun. In other yarns made from fibers treated with the compositions
here, ends down can be cut in half compared to non-treated cotton
fibers.
Similarly, dyeing, sizing, cutting and similar operations are not
adversely affected and in some instances improvements in these can
be noted.
It has been found here that it is essential that the organosol be
substantially anhydrous. If even small amounts of water are present
the water tends to load the cards and hamper processing.
It has also been discovered that the presence of the adsorbed
quaternary ammonium compound on the silica is an essential
requirement. A non-modified silica treatment tends to deposit
silica on the machine, load cards, shut down production and create
a number of other processing problems. Resort to silica alone, even
silica dissolved in an organic solvent or hydrocarbon oil, is not
satisfactory due to the fact that silica will not spread on or wet
the fiber.
The following examples illustrate the preparation of typical
organosols useful in treating fibers, and as well demonstrate the
efficacy of the invention in promoting fiber strength. It is
understood, of course, that these examples are merely illustrative,
and that the invention is not to be limited thereto.
EXAMPLE I
88 grams of dimethyl-dihydrogenated tallow ammonium chloride was
first dissolved in 154 mls. of isopropanol by means of heat. To
this was added 178 mls. of a colloidal aqueous silica sol, namely,
Nalcoag 1,034A along with 220 mls. of distilled water. A white
pastelike mixture was obtained which was then dried in an oven and
ground to a size such that it would pass through a No. 50 screen
(297.mu., 0.0177 inch opening).
The product analyzed as 40 percent SiO.sub.2 and 5.75 percent
quaternary.
EXAMPLE II
Here a liquid product was prepared from the dry powder of Example
I.
Specifically, 184 grams of the dry powder prepared above was added
slowly to 216 grams of a branched hydrocarbon oil having a B.P. of
280.degree.-350.degree. C. which was heated to 60.degree. C. Mixing
was then effected at this temperature for 2 hours and the product
cooled.
EXAMPLE III
To 517 ml. of Nalcoag 1034A was slowly added 110 grams of lauryl
trimethyl ammonium chloride. A white pastelike mixture was obtained
which was dried and ground. The powder contained 40 percent
SiO.sub.2 and 10 percent quaternary.
EXAMPLE IV
The dry powder of Example III was here prepared in liquid form by
adding 200 grams of the dry powder to 200 grams of hydrocarbon oil
heated at 60.degree. C. The mixture was then heated to 110.degree.
C. and cooled.
EXAMPLE V
Here, 111 grams of dimethyl dicoco ammonium chloride was added to
690 mls. of Nalcoag 1034A. A white liquid was obtained which was
dried and ground, with the final powder containing 40 percent
SiO.sub.2 and 12 percent quaternary.
EXAMPLE VI
Here, an organosol was made from the dry powder of Example V in the
following manner:
To 194 grams of hydrocarbon oil heated to 60.degree. C. was slowly
added 206 grams of the powder of Example V. The resultant product
was then mixed for 2 hours at this temperature and cooled.
EXAMPLE VII
A silica organosol was prepared in hexane which contained 36
percent SiO.sub.2 coated with tricapryl methyl ammonium chloride
(13 percent quaternary based on the weight of the SiO.sub.2). 800
mls. of the hexane sol was then dried and ground.
184 grams of the dried powder prepared above was then added to 216
grams of hydrocarbon oil heated to 60.degree. C.
The product contained 40 percent SiO.sub.2 and 5 percent quaternary
with the remainder being hydrocarbon oil.
EXAMPLE VIII
33.5 parts of hydrocarbon oil was mixed with 4.5 parts of
dihydrogenated tallow methyl ammonium chloride. 50 parts of Nalcoag
1050 was then added with mixing followed by further addition of 12
parts of isopropanol. The total mixing time was 5 minutes.
The two phases were then separated. The bottom layer containing the
product was then heated for approximately 1-1/2 hours at 85.degree.
C. to drive off the isopropanol. This product contained
approximately 40 percent SiO.sub.2, 6 percent quaternary as an
organic coating, and 54 percent hydrocarbon oil.
EXAMPLE IX
This Example illustrates the promotion of strength via treatment of
cotton fibers with various organosols.
Specifically, both low and high micronaire cottons were treated.
After the cotton was cleaned via air cleaners, 20 pounds of cotton
was spread over approximately 300 square feet. One-half of the
organosol was then sprayed onto the cotton by means of an air gun.
Another 20 pounds of cotton was spread over the initial 20 pounds
and the spraying completed. The treated cotton was then processed
in the usual manner and various properties measured as shown in
Tables I and II below.
The low micronaire cotton was treated with 1 percent by weight of
the various organosols and the high micronaire cotton treated with
0.6 percent by weight based on the weight of the cotton. ##SPC2##
##SPC3## ##SPC4## ##SPC5##
Thus, it is apparent from the data above that treatment of cotton
with a number of organosols materially improved strength,
specifically as reflected in increased corrected breakfactor. Such
increase in strength was accomplished without loss of elongation.
In addition, it is to be noted that the number of thin and thick
imperfections were substantially decreased.
* * * * *