U.S. patent number 3,652,212 [Application Number 04/631,165] was granted by the patent office on 1972-03-28 for multi-step in situ polymer formation to produce fabric having improved soiling characteristics.
This patent grant is currently assigned to Deering Milliken Research Corporation. Invention is credited to Greville Machell.
United States Patent |
3,652,212 |
Machell |
* March 28, 1972 |
MULTI-STEP IN SITU POLYMER FORMATION TO PRODUCE FABRIC HAVING
IMPROVED SOILING CHARACTERISTICS
Abstract
A process for improving soil release characteristics of textile
material which comprises applying thereto a polymerizable compound
and forming in situ a synthetic acid polymer comprising at least 10
weight percent acid calculated as acrylic acid, and the product
produced by this process. Preferably, a textile resin and a textile
resin catalyst also are applied to the textile material and the
treated textile material is subjected to resin curing
conditions.
Inventors: |
Machell; Greville (Spartanburg,
SC) |
Assignee: |
Deering Milliken Research
Corporation (Spartanburg, SC)
|
[*] Notice: |
The portion of the term of this patent
subsequent to April 9, 1985 has been disclaimed. |
Family
ID: |
24530045 |
Appl.
No.: |
04/631,165 |
Filed: |
April 17, 1967 |
Current U.S.
Class: |
8/115.59;
8/DIG.4; 8/115.52; 8/115.62; 8/127.6; 8/186; 8/196; 427/381;
427/393.4; 427/501; 442/71; 8/DIG.21; 8/115.56; 8/115.6; 8/115.7;
8/184; 8/195; 38/144; 427/393.2; 442/63; 442/93; 8/115.58 |
Current CPC
Class: |
D06M
15/263 (20130101); Y10S 8/04 (20130101); Y10T
442/2098 (20150401); Y10T 442/2279 (20150401); Y10S
8/21 (20130101); Y10T 442/2033 (20150401) |
Current International
Class: |
D06M
15/263 (20060101); D06M 15/21 (20060101); D06m
015/36 (); D06m 015/58 (); D06m 015/72 () |
Field of
Search: |
;8/DIG.18,116,116.3,115.7,116,115.5,115.6
;117/93.31,161,139.4,143,138.8 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lesmes; George F.
Assistant Examiner: Cannon; J.
Claims
Having thus disclosed the invention, what is claimed is:
1. A process for imparting soil release and durable press
characteristics to textile material including cellulosic and/or
synthetic fibers which comprises:
a. applying thereto a monomeric cellulosic cross-linking agent
characterized by a vinyl group and an N-methylol amide group and a
catalyst therefor;
b. subjecting the textile material to high energy irradiation;
c. heating the treated textile material to a temperature between
about 100.degree. C. and 300.degree. C.;
d. applying to the textile material an ethylenically unsaturated
monomer having at least one carboxylic acid group and another
ethylenically unsaturated monomer copolymerizable therewith;
and
e. subjecting the textile material to high energy irradiation to
form a synthetic acid copolymer comprising at least 10 weight
percent acid calculated as acrylic acid.
2. The process as defined in claim 1 wherein the polymerizable
compound is a monomeric mixture comprising an acrylic ester and an
acrylic acid.
3. A process as defined in claim 1 wherein the textile resin
catalyst is selected from the group consisting of metal salts and
amino salts.
4. The process as defined in claim 1 wherein the polymerizable
compound is a monomeric mixture comprising about 10 to 80 parts of
an acrylic ester and about 20 to 90 parts of an acrylic acid.
5. The process as defined in claim 1 wherein the polymerizable
compound is a monomeric mixture comprising about 10 to 50 parts
butyl acrylate and about 50 to 90 parts acrylic acid.
6. The process as defined in claim 1 wherein the polymerizable
compound is a monomeric mixture comprising about 20 to 30 parts
butyl acrylate and about 70 to 80 parts acrylic acid.
7. The process as defined in claim 1 wherein the monomeric
cellulosic cross-linking agent is N-methylol acrylamide.
8. The process as defined in claim 1 wherein the textile material
is subjected to an irradiation dosage of about 0.5 to 5
megarads.
9. The process as defined in claim 1 wherein the textile material
is a polyester/cotton blend.
10. A process for imparting soil release and durable press
characteristics to textile material including cellulosic and/or
synthetic fibers which comprises:
a. applying thereto an aminoplast textile resin and a catalyst
therefor;
b. applying to the textile material an ethylenically unsaturated
monomer having at least one carboxylic acid group and another
ethylenically unsaturated monomer copolymerizable therewith;
c. subjecting the textile material to high energy irradiation to
form a synthetic acid copolymer comprising at least 10 weight
percent acid calculated as acrylic acid; and
d. heating the treated material to a temperature between about
100.degree. C. and 300.degree. C.
11. A process for imparting soil release and durable press
characteristics to textile material including cellulosic and/or
synthetic fibers which comprises:
a. applying thereto a monomeric cellulosic cross-linking agent
characterized by a vinyl group and an N-methylol amide group and a
catalyst therefor;
b. subjecting the textile material to high energy irradiation;
c. applying to the textile material an ethylenically unsaturated
monomer having at least one carboxylic acid group and another
ethylenically unsaturated monomer copolymerizable therewith;
d. subjecting the textile material to high energy irradiation to
form a synthetic acid copolymer comprising at least 10 weight
percent acid calculated as acrylic acid; and
e. heating the treated textile material to a temperature between
about 100.degree. C. and 300.degree. C.
12. The process as defined in claim 11 wherein after the
irradiation step (d) and before the heating step (e) a garment is
tailored from the textile material and treated to produce creases
therein.
13. A process for imparting soil release and durable press
characteristics to textile material comprising a blend of
cellulosic and polyester fibers which comprises:
a. applying thereto a methylolated ethylene urea and a metal salt
or amino salt catalyst therefor;
b. heating the treated textile material to a temperature between
about 100.degree. C. and 300.degree. C.;
c. applying to the textile material a monomeric mixture comprising
about 10 to 80 parts of an acrylic ester and about 20 to 90 parts
of an acrylic acid; and
d. subjecting the textile material to a high energy irradiation
dosage of about 0.5 to 5 megarads to form a synthetic acid
copolymer comprising at least 10 weight percent acid calculated as
acrylic acid.
14. A textile material with soil release and durable press
characteristics produced according to the process of claim 13.
15. A textile material with soil release and durable press
characteristics produced according to the process of claim 1.
16. A textile material with soil release and durable press
characteristics produced according to the process of claim 10.
17. A textile material with soil release and durable press
characteristics produced according to the process of claim 11.
Description
BACKGROUND OF THE INVENTION
The textile industry during the past decade has, as a whole, made
important technological advances in the chemical finishing of
textile fabrics. Numerous processes have been developed for
imparting minimum care characteristics to garments and articles
prepared form specially treated textile fabrics. Exemplary of such
advances are the wash and wear fabrics, hereinafter referred to as
precured fabrics, and the durable press fabrics, hereinafter
referred to as post cured fabrics. These characteristics generally
have been imparted to textile fabrics by the application of
resinuous materials. The resinuous materials are applied to the
fabric and are later crosslinked to the fabric by the action of a
suitable catalyst. Depending upon the time at which the
crosslinking reaction occurs, either a wash and wear fabric or a
durable press fabric is produced. The precured fabrics are those
for which the crosslinking reaction has occurred prior to
transformation of the fabric into a garment or other article of
commerce. Post cured fabrics are those fabrics which are subjected
to the crosslinking reaction subsequent to the transformation of
the fabric into a garment or other article of commerce.
Tremendous effort has ensued towards achievement of a garment
containing synthetic and naturally occuring fibers such that
creases in the garment are very durable and are not appreciably
affected by wear or cleaning processes. In other words, after
repeated washings and/or dry cleaning, the creases remain in the
garment in a substantially unaltered condition and further
treatment of the garment, i.e., pressing, is not required for
maintenance of the crease. Likewise, much effort has been expended
towards the attainment of good wash-and-wear fabric.
Additionally, further research has been directed to the attainment
of a garment having improved soil release properties. Numerous of
the synthetically produced fibers that are presently being
incorporated in blends with naturally occurring fibers have a
propensity to accept and retain oily grime and dirt. Accordingly,
when the garment is being worn the soil and/or oily materials
accumulate on the garment and settle in the fabric. Once the
garment becomes soiled, it is then subjected to a cleaning process
for removal of the dirt and/or oily deposits, and only a dry
cleaning process will successfully clean the garment.
The cleaning process normally employed, however, is washing in a
conventional home washing machine by the housewife. During a wash
cycle, it is virtually impossible to remove the soil and/or oily
stains from the garment and, secondly, assuming that the
undesirable materials are removed from the garment or a fairly
clean garment is being washed, soil remaining in the wash water is
redeposited onto the garment prior to the end of the wash cycle.
Hence, when the garment is removed from the washing machine and
subsequently dried, it has not been properly cleaned. Such a
condition, heretofore unavoidable, is quite disadvantageous in that
the garment after being worn never again assumes a truly clean
appearance, but instead tends to gray and/or yellow due to the soil
and/or oily materials deposited and remaining thereon. Further use
and washing of the garment increases the intensity of the graying
to the point that ultimately the garment is unacceptable for
further wear due to its discoloration. The process of the present
invention solves the soiling problem as hereinafter described.
In attempting to solve the problem of soiling in the synthetic
fabrics and blends containing synthetic fibers, a substantial
amount of research has been conducted and numerous patents have
issued as a result thereof. None of these patents, however,
disclose subject matter as relevant to the problem as is instantly
set forth herein. Strong basis for this fact is evidenced by the
publicity being given to products exhibiting even slight
improvement in soil release and/or soil redeposition. Antisoiling
research has been directed along two general avenues, one of which
utilizes inorganic materials and the second employing organic
materials. Set forth below is a brief summary of prior effects.
U. S. Pat. No. 2,999,774 to Schappel features the utilization of
silica particles and a salt of a multivalent metal for the purpose
of rendering a fabric soil resistant. U. S. Pat. No. 2,734,835 to
Florio et al. employes at least two hydrous stable metal oxides
selected from aluminum, silica, titanium, beryllium, cerium,
cobalt, germanium, manganese, tin, zinc and zirconium. U. S. Pat.
No. 3,089,778 to Pierce et al. teaches the utilization of a water
insoluble basic aluminum salt having an ultimate particle size of
less than 0.5 microns. U. S. Pat. No. 2,992,943 to Coover et al.,
while not purely related to inorganic materials is directed to
prevention of dry soiling only. In other words, the Coover et al.
treatment dictates the use of a water-soluble compound (an alkyl
titanate and an organic solvent) and therefore to obtain the
desired soil resistant properties only a dry cleaning process may
be employed.
The organic approach to the soiling problem of synthetic fiber
containing fabrics includes the following patents and their
teachings. It should be noted, however, that some of the patents
incorporated in the following group are not per se directed to
reducing the soil propensity of the synthetic fiber containing
fabric.
U.S. Pat. No. 3,236,685 to Caldwell et al. renders a fabric
antistatic and soil-resistant by coating a fabric with a solution
or solutions containing a polymeric acid defined as containing
--COOH, --SO.sub.3 H and/or --PO.sub.4 H.sub.2 groups.
Additionally, a compound containing a polyol or a compound having
incorporated therein epoxide groups is included which under proper
conditions reacts with the acid to form an ester. U. S. Pat. No.
3,152,920 also to Caldwell et al. is a complement of the above
patent wherein, instead of reacting the polymeric acid with a
polyol or an epoxide, the polymeric acid is reacted with the
reaction product of a polyol and a polyisocyanate. U. S. Pat. No.
3,125,405 to Gardon is directed to the manufacture of a permanent
press garment. N-methylol acrylamide is applied to the fabric with
a free radical acid catalyst and the N-methylol acrylamide is
crosslinked with the cellulose molecule. Additionally, extra
monomers and polymers as set forth in the patent may be
incorporated in the treating solution. U. S. Pat. No. 3,246,946 to
Gardon likewise is directed to the production of durable press
garments. N-methylol acrylamide is employed in conjunction with one
or more condensates of an aldehyde and a free radical acid catalyst
whereby the reactants are crosslinked with the cellulose molecule.
Extra monomers and polymers may be added to the treating solution.
U. S. Pat. No. 3,090,704 to Collins et al. is directed to a
terpolymer for rendering the fabric soil resistant. The terpolymer
consists of (1) a compound having incorporated therein a
crosslinking component, (2) a compound having incorporated therein
an anionic component, e.g., an alkali metal salt of an aromatic
sulfonic acid, and (3) a compound having a component therein that
contains a strong nonionizable, nonhydratable permanent or induced
dipole. U. S. Pat. No. 2,876,141 to Matthews employs a solution
containing (1) mineral oil, (2) base cordage oil, (3) oleic acid,
and (4) a cationic wetting agent, e.g.,
trimethyl-.beta.-oleamidoethyl ammonium sulfate in an effort to
improve the soil resistance of the fabric treated.
The above brief abstracts are set forth to provide an indication of
prior research effort directed to attaining a soil resistant fabric
or a fabric having soil release properties. The problem heretofore
confronted with fabrics including synthetic fibers has been that
the synthetic fibers while hydrophobic are oleophilic and whereas
oil and grime may become embedded in the fiber, its hydrophobic
properties prevent water from entering the fiber to remove the
contaminants therefrom. The efforts of this invention have been
directed to the modification of the properties of synthetic and/or
natural fibers in such a manner that the soil and oily contaminants
may be easily removed.
Additionally, by incorporating the process of the present invention
with that of a process to render a garment resistant to creasing, a
garment is produced that has both durable press and soil release
properties. In other words, the ultimate garment is superior both
for the consumer and for the housewife who is confronted with the
problem of rendering the garment clean for further wearing.
In view of the above comments, it should be evident to one skilled
in the art that the problem confronted has been that of rendering a
garment clean if the garment contains synthetic and/or natural
fibers as described herein. Accordingly, by virtue of the teachings
of the present invention, the problems historically present with
the use of garments having incroporated therein both cellulosic
fibers and synthetically produced fibers are alleviated.
It is therefore an object of the present invention to provide a
substrate having improved soil release properties.
Still another object of the present invention is to provide a
process for treating textile material whereby said material easily
releases soil when contacted with a detergent solution.
Still further another object of the present invention is to treat
textile material in such a manner that after said material is
soiled and subjected to washing, less soil and grime from the wash
water will be redeposited thereon.
A further object of the present invention is to provide a durable
press fabric having improved soil-release properties.
Another object of the present invention is to provide a process for
treating a fabric in such a manner that it has both durable press
and soil release properties.
Still another object of the present invention is to treat fabric in
such a manner that after a garment produced therefrom is soiled and
subjected to washing, soil and grime from the wash water will not
be redeposited onto the garment.
Still further another object of the present invention is to provide
a treatment for fabric such that garments produced therefrom will
not become discolored due to repeated wearing and washing.
Another object of the present invention is to treat fabric in such
a manner that a garment produced therefrom has excellent
wash-and-wear and soil release properties.
These and other objects may be readily seen from the following
detailed description of the present invention.
Generally speaking, the present invention is directed to a process
for treating textile material comprising applying thereto a
polymerizable compound and forming a synthetic acid polymer, said
polymer containing at least 10 weight percent acid calculated as
acrylic acid.
Soil removal ability is improved on any textile material when the
acid polymer is formed by polymerization in situ. Suitable textile
materials include synthetic polymers, cotton, wool, mixtures of the
above, etc. Products made from these materials include without
limitation, textile fabric wall coverings; lamp shades, automobile
seat covers; automobile upholstery, e.g., door panels, overhead
liners, etc.; upholstery for furniture; clothing; apparel
accessories, e.g., ties, fabric belts, scarves, hats, etc.; canvas
products, e.g., tents, folding cots, etc.; draperies; throw
pillows; hassocks; sporting goods; fabric garment bags and luggage;
fabric handbags; fabric shoes or shoes made from synthetic
materials; linens; book covers; mattress covers; stuffed toys;
hammocks; deck chairs, etc.
Textile materials which may be treated according to the process of
the invention include those in which the anhydroglucose molecules
are chemically substantially unmodified, e.g., cotton, paper,
linen, jute, flax, regenerated cellulose fibers, including viscose
rayon, in the form of staple, yarn and fabrics. This invention is
directed primarily and preferably to textile fabrics either
knitted, woven, or non-woven, preferably woven. However, the
advantages of this invention can be achieved by treating the
fibers, yarns, or threads employed to produce these fabrics.
Moreover, and more specifically, the process of the present
invention is preferably used for treating textile materials
containing both cellulosic and non-cellulosic fibers, especially if
the non-cellulosic fibers have minimum care characteristics of
their own. For example, the fabrics treated may be formed from a
mixture of polyester, such as poly(ethylene terephthalate),
polyamide such as poly(hexamethylene adipamide) or acrylic fibers,
such as polyacrylonitrile, and copolymers containing at least about
85 percent combined acrylonitrile filaments or fibers, with cotton
or rayon. It should be pointed out, however, that textile material
containing only non-cellulosic fibers such as those listed above is
also within the scope of the present invention.
The soil release properties of pure cellulosic fiber fabrics are
much better than those of synthetic fiber containing fabrics, e.g.,
polyester fibers, in that the synthetic polyester fibers are
hydrophobic and thus prevent the ingress of water that is necessary
for cleaning the fabric and also possess an electrical charge that
attracts soil particles. The present invention is therefore most
primarily directed to fabrics containing a substantial portion of
synthetic fibers, but is not limited thereto. Instead, it has been
determined that the present process can be very successfully
employed with cellulosic fabrics, fabrics containing synthetic
fibers and cellulosic fibers, and fabrics containing only synthetic
fibers.
In many instances, when the substrate is a textile material, an
amino-plast textile resin or a vinyl monomer with dual
functionality will also be applied with the polymerizable compound.
Very unexpectedly, it has been observed that when this combination
is applied to the textile material followed by subjecting the
material to textile resin curing conditions, improved soil release
is realized.
Hence, the present invention is also directed to a process for
treating a textile material by applying thereto an aminoplast
textile resin, a textile resin catalyst and a polymerizable
compound and forming a synthetic acid polymer from said compound,
said polymer containing at least 10 weight percent acid calculated
as acrylic acid and curing of the textile resin.
The term "textile resin" according to the present invention
includes both monomers and polymers which when applied to a textile
material and reacted under proper conditions undergo polymerization
and/or condensation and are transformed to the thermoset state.
Textile resins that may be employed when practicing the present
invention are the aminoplast resins. These nitrogen containing
resins when applied to a textile material in the presence of a
catalyst at temperatures of from about 100.degree. C. to about
300.degree. C. are transformed into the thermoset state. The cured
textile resin on the textile material affords the textile material
a durable press and/or wrinkle resistant characteristic.
Exemplary of the aminoplast textile resins that may be employed
according to the present invention are the urea formaldehydes,
e.g., propylene urea formaldehyde, dimethylol urea formaldehyde,
etc.; melamine formaldehydes, e.g., tetramethylol melamines,
pentamethylol melamines, etc.; ethylene ureas, e.g., dimethylol
ethylene urea, dihydroxy dimethylol ethylene urea, ethylene urea
formaldehyde, hydroxy ethylene urea formaldehyde, etc.; carbamates,
e.g., alkyl carbamate formaldehydes, etc.; formaldehyde-acrolein
condensation products; formaldehyde-acetone condensation products;
diureas, e.g., trimethylol acetylene diurea,
tetramethylol-acetylene diurea, etc.; triazones, e.g.,
dimethylol-N-ethyl triazone, N-N'ethylene-bis dimethylol triazone,
halotriazones, etc.; halo-acetamides, e.g.,
N-methylol-N-methylchloroacetamide, etc.; urons, e.g., dimethylol
uron, dihydroxy dimethylol uron, etc., and the like. Mixtures of
aminoplast textile resins are also within the scope of the present
invention.
Further exemplary of the vinyl monomers having dual functionality
within the scope of the present invention are acrylamides, e.g.,
N-methylol acrylamide, N-methylol methacrylamide,
N-methylol-N-methacrylamide, N-methylmethylolacrylamide, N-methyl
methylene-bis-(acrylamide), methylene-bis-(N-methylol acrylamide),
etc.; haloethylene acrylamide; and compounds which conform to the
following structural formulae. In each of the following formulae
the variables may be selected as follows:
R.sup.1 : hydrogen, lower alkyl or residue of saturated or
unsaturated aldehyde
R.sup.2 : hydrogen, lower alkyl or -CX-CR.sup.3 =CHR.sup.4
R.sup.3 : hydrogen or methyl
R.sup.4 : hydrogen or lower alkyl
R.sup.5 : hydrogen, lower alkyl, or CHR.sup.1 OR.sup.4, at least
one R.sup.5 being CHR.sup.1 OR.sup.4
R.sup.6 : lower alkyl or hydroxy alkyl
R.sup.7 : hydrogen, hydroxyl or lower alkyl
R.sup.8 : hydrogen, lower alkyl, alkylol or alkenol
X: sulfur or oxygen ##SPC1##
The amount of textile resin or vinyl monomer with dual
functionality applied to the fabric is primarily determined by the
ultimate use of garments or articles prepared from the fabric. Very
small amounts will afford some improvement and large amounts even
greater improvements, but the larger amounts generally adversely
affect the hand of the fabric. Hence, the amount employed is
preferably that which will afford good crease retention and flat
dry properties while not adversely affecting the hand. For the
purposes of the present invention, the amount of textile resin or
vinyl monomer in the pad bath may vary between about 2 and 30
percent. The proportion present on the fabric should be in the
range of about 2 to 20 percent based on the dry weight of the
fabric and preferably in the range of about 4 to 9 percent.
Catalysts employed within the scope of the present invention depend
upon the specific textile resin or vinyl monomer that is applied to
the textile material. For instance, if the textile resin has a
functional group that is reactive under acidic conditions, then an
acid catalyst is used. Likewise, when a functional group is present
that is reactive under alkaline conditions, then a base catalyst is
used. Furthermore, both acid and base catalysts may be used when
both type functional groups are present in the textile resin. In
this instance, the catalyst may be added separately or together.
When they are added together, one must be a latent catalyst, i.e.,
one that will not initiate its reaction during the opposite type
reaction, but may be activated subsequently under proper catalytic
conditions.
The catalysts useful in activating the acid or base reactive groups
are those conventionally used to activate the reaction of textile
resins containing the same group for reaction with hydroxy groups
of cellulose. Preferably, latent acid or base acting catalysts are
utilized, that is, compounds which are acidic or basic in character
under the curing conditions. The most common acid acting catalysts
are the metal salts, for example, magnesium chloride, zinc nitrate
and zinc fluoroborate and the amino salts, for example,
monoethanolamine hydrochloride and 2-amino-2-methyl-propanol
nitrate.
The base acting catalyst preferably is a compound which does not
initiate substantial reaction between the base reactive group and
hydroxy groups of cellulose under normal acid conditions, but does
initiate substantial reaction under prescribed conditions, such as
elevated temperature or some other activating means, as through use
of another chemical compound. For example, an alkali metal sulfite
can be padded onto the fabric and be decomposed into strongly basic
alkali metal hydroxide by including small amounts of formaldehyde
in the steam used for curing.
The latent base acting catalyst utilized herein preferably
comprises alkali-metal salts, such as alkali-metal carbonates like
sodium carbonate, which is neutral to mildly alkaline, for example,
pH of about 8.5 on the fabric but decomposes at temperatures in
excess of about 80.degree. C. to form the stronger base sodium
oxide which will initiate substantial reaction at the elevated
temperatures utilized during curing. Sodium carbonate may be
utilized if desired since the pH in the fabric produced by this
compound in normal conditions is generally insufficient to initiate
the desired degree of reaction under normal temperature
conditions.
If fabrics containing a base reactive group are maintained at pH
levels above about 10, however, degradation occurs, so that
essentially neutral or mildly alkaline catalysts are preferred when
base reactive compounds are utilized.
Additional base acting catalysts include potassium bicarbonate,
potassium carbonate, sodium silicate, alkali metal phosphates, such
as sodium or potassium phosphates, barium carbonate, quaternary
ammonium hydroxides and carbonates, for example, lauryl trimethyl
ammonium hydroxides and carbonates and the like.
The amount of catalyst to be utilized is that conventionally used
in activating the reaction, for example, up to about 15 percent by
weight of an acid acting catalyst in the application bath with the
preferred range being from about 1 percent to about 7 percent. A
preferred range for the base acting catalyst is again the
conventional amount and is generally between about 0.2 percent to
about 16 percent, preferably about 2 to 16 percent. The amount of
catalyst to be utilized will further depend in part on the
temperature at which the reaction is conducted and the amount of
catalyst consumed in the reaction. For example, when base catalysts
are utilized and if a highly acidic group is released during the
reaction, the amount of base applied to the textile material should
be at least sufficient to provide an excess of base in addition to
that which is consumed by the highly acidic group.
The term "soil release" in accordance with the present invention
refers to the ability of the fabric to be washed or otherwise
treated to remove soil and/or oily materials that have come into
contact with said material. The present invention does not per se
prevent the attachment of soil or oily materials to the fabric, but
hinders such attachment and renders the heretofore uncleanable
fabric now susceptible to a successful cleaning operation. While
the theory is still somewhat of a mystery, soiled, treated fabric
when immersed in the detergent containing wash water experiences an
agglomeration of the oil at the fabric surface. This water is basic
in nature and it has been determined that soil release is best
realized in wash water that is basic in nature. These globules of
oil are then removed from the fabric and rise to the surface of the
wash water. This phenomenon takes place in the home washer during
continued agitation, but the same effect has been observed even
under static conditions. In other words, a strip of
polyester/cotton fabric treated according to the process of the
present invention and soiled with crude oil, when simply immersed
in a detergent solution will lose the oil without agitation. The
oil just balls up on the fabric, dislodges therefrom, and rises to
the surface of the solution.
An added feature of the present invention is the prevention of soil
redeposition from the wash water. One of the greatest disadvantages
of the synthetic polymers is the feature that even after removing
the soil by washing, there is the continued danger that the soil
will be redeposited onto the fibers from the wash water before the
garment is removed therefrom. It has been observed that the soil
release ability of the presently treated fabric diminishes after
repeated washings. Even after the ability to remove soil from the
fabric has diminished, however, the observation has been made that
the prevention of redeposition of soil from wash water remains
potent. This phenomenon likewise is unexplainable, but it has been
established that the troublesome soil is negatively charged and
presumably there remains enough acid on the fabric to repel the
negatively charged soil.
Numerous of the textile materials that may be treated according to
the process of the present invention may not be feasibly removed
from their environment and washed in a washing machine. Further,
there are also textile materials that may be treated which when
subjected to the action of a washing machine are adversely affected
either in structure or in looks. Articles within these classes may
still be easily cleaned in place or otherwise by scrubbing the
soiled area lightly with a solution of a commercial detergent and
water.
The soil release polymer of the present invention which will also
be hereinafter referred to as "acid polymer," is formed in situ on
the textile material from the polymerizable compound applied
thereto. This acid polymer may be formed from a large number of
compounds. The acid polymer formed advantageously is capable of
forming a film around the fibers that constitute the textile
material. Further, the film may have hydrophilic properties and be
at least partially insoluble in water. The film, if water soluble,
would, of course, be easily washed from the fabric. The polymer
likewise may be water soluble if the textile material is such that
the soil removal io only required once. Acid content of the polymer
is likewise important and at least 10 weight percent of the acid
polymer should be acid calculated as acrylic acid and preferably at
least 20 weight percent. It has further been observed that all of
the acid polymers formed in situ that afford soil release have a
carbon atom to acid group ratio in the repeat group in the range of
2:1 to 30:1, and that an air dried film cast therefrom has a water
of imbibition of at least 89 percent.
Synthetically produced acid polymers within the scope of the
present invention may be formed in situ on the textile material
from any of the polymerizable organic acids, i.e., those having
reactive points of unsaturation. These polymerizable compounds may
be acids, or mixtures of an acid and other monomers copolymerizable
therewith so long as at least 10 weight percent acid monomer is
present in the polymer formed. Exemplary of polymerizable acids
that may be used, are acrylic acid, maleic acid, fumaric acid,
methacrylic acid, itaconic acid, crotonic acid, cinnamic acid,
polymerizable sulfonic acids, polymerizable phosphoric acids, etc.
Monomers that may be interpolymerized with the acids include any
monomers capable of copolymerizing with the acids and which will
not detrimentally affect the soil release properties of the
polymer. Suitable monomers include, esters of the above acids
prepared by reacting the particular acid with an alkyl alcohol,
e.g., ethyl acrylate, methyl acrylate, propyl acrylate, isopropyl
acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate,
2-ethyl hexyl acrylate, etc.; alkyl fumarates, maleates,
crotonates, cinnamates, etc.; vinyl halides; monomers having
vinylidene groups; e.g., styrene, acrylonitrile, methylstyrene;
substituted vinyl monomers, e.g., chlorostyrene; butadiene, etc. In
all of the polymers formed from the above listed monomers, there
should be at least 10 weight percent acid calculated as acrylic
acid. Furthermore, salts of the acid polymers, e.g., sodium,
potassium, lithium, ammonium, etc., will afford the desired soil
release characteristics.
Examples of some of the synthetic acid polymers that may be formed
in situ from ethylenically unsaturated monomers are polymerization
products of:
ethyl acrylate:acrylic acid
ethyl acrylate:acrylic acid:acrylamide
butyl acrylate:acrylic acid
ethyl acrylate:methacrylic acid
ethyl acrylate:itaconic acid
methyl methacrylate:acrylic acid
2-ethyl hexyl acrylate:acrylic acid
acrylamide:acrylic acid
butyl acrylate:acrylic acid:acrylamide
ethyl acrylate:acrylic acid:N-methylol acrylamide
ethyl acrylate:acrylic acid:styrene
ethyl acrylate:acrylic acid:hydroxy propyl methacrylate
ethyl acrylate:acrylic acid:divinyl benzene
ethyl acrylate:acrylic acid:allyl acrylamide
ethyl acrylate:acrylic acid:glycidyl acrylate
ethyl acrylate:itaconic acid
ethyl acrylate:sodium styrene sulfonate
ethyl acrylate:crotonic acid
styrene:acrylic acid
ethyl acrylate:acrylic acid:hydroxy ethyl methacrylate
hydroxy ethyl methacrylate:acrylic acid:acrylamide
butyl acrylate:ethyl acrylate:acrylic acid and the like.
Some acid polymer systems work better than others, however, and
these are preferred. Examples of the preferred acid polymers
include (1) copolymers of an acrylic ester and an acrylic acid that
are prepared by polymerizing on the textile material a co-monomer
mixture of from about 20 to 80 parts of the acrylic ester and about
20 to 80 parts of an acrylic acid; (2) copolymers of ethyl propyl
or isopropyl acrylate and acrylic acid wherein the copolymers are
prepared by polymerizing a monomer mixture of from about 40 to 80
parts of the acrylate and about 20 to 60 parts of acrylic acid; (3)
copolymers of butyl acrylate and acrylic acid prepared by
polymerizing a co-monomer mixture of from about 30 to 70 parts of
butyl acrylate and about 30 to 70 parts of acrylic acid; (4)
copolymers of 2-ethyl-hexyl acrylate and acrylic acid prepared by
polymerizing a co-monomer mixture of from about 10 to 40 parts of
2-ethyl hexyl acrylate and about 60 to 90 parts of acrylic acid;
(5) copolymers substantially identical to the ones listed above
with the exception that methacrylic acid is substituted for acrylic
acid and the esters are methacrylates instead of acrylates; (6) a
copolymer of ethyl acrylate and itaconic acid prepared by
polymerizing a monomer mixture comprising about 70 parts ethyl
acrylate and about 30 parts itaconic acid; (7) copolymers of the
acrylic acid set forth above wherein the acrylates are substituted
by methacrylates; (8) a copolymer of acrylamide and acrylic acid
prepared by polymerizing a monomer mixture comprising about 10
parts acrylamide and about 90 parts acrylic acid; and (9)
terpolymers comprising ethyl acrylate, acrylic acid and acrylamide
prepared from monomer mixtures of ethyl acrylate, at least 10 parts
acrylic acid and up to 20 parts acrylamide.
As the acid polymer is formed in situ on the textile material, soil
release ability is created. For unknown reasons, further treatments
and/or ingredients will enhance the soil release ability of the
textile material. If the textile material having the acid polymer
thereon is subjected to textile resin curing conditions, the
durability of the soil release ability is enhanced. Likewise, the
presence of a textile resin catalyst during the textile resin
curing conditions further improves soil release durability.
Furthermore, there may be some crosslinking between the cellulose
molecules and the acid polymer or there may be just an enhanced
physical bond between the textile resin and the acid polymer above
and beyond their reactivity.
Soil release polymers, like the textile resins, give some
improvement at very low levels on the fabric. Accordingly, as the
amount of soil release polymer is increased, the ability of the
fabric to release soil increases. Thus, the upper limit on the
amount of soil release polymer is determined by economics and
resulting adverse effects on the fabric, e.g., the hand of the
fabric. Furthermore, practically speaking there is a set range of
soil release polymer dictated by commercial success.
Advantageously, there should be from about 1 to 20 weight percent
of acid polymer on the substrate, based on dry weight, and
preferably about 2.5 to 10 weight percent.
The materials used to impregnate the textile material according to
the present invention are not limited to including only the
materials heretofore mentioned, e.g., textile resin, vinyl monomers
with dual functionality, catalyst and polymerizable compound to
form the acid polymer. In addition, other ingredients may be
employed such as, for example, emulsifying agents, wetting agents,
softeners, etc., and numerous other compounds that enhance the
physical characteristics of the fabric. The materials may be
applied to the textile material in any suitable manner. For
instance, application of the polymerizable compound to the fabric
with a roller is preferred because of the soil release
characteristics which can be achieved without curing when
concentrated monomer is applied. The ingredients may also be
sprayed on as liquids; the textile material may be treated with
vapors of the compounds if convenient or the textile material may
be dipped, etc.
In general, the applicator systems provide from 5 to 100 weight
percent wet pickup by the fabric. When the mixture is padded onto
the fabric, good results are obtained by providing a wet pickup of
from 40 to 60 weight percent. With a roller, the wet pickup is
usually between 5 and 50 weight percent and preferably 10 to 20
weight percent.
When an aminoplast textile resin or vinyl monomer with dual
functionality is applied to the textile material along the with the
polymerizable compound, advantageously they are applied
sequentially. Insofar as separate application is concerned, where
the textile resin or vinyl monomer is applied first and the polymer
formed or cured and the polymerizable compound is added separately
thereafter, soil release ability of a higher level is achieved as
compared with simultaneous application or the separate addition
where both are present during curing.
According to the desires of the individual, and the dictates of the
ultimate product, separate or simultaneous application of the
textile resin and the polymerizable compound may be employed. For
instance, when treating a textile fabric which is to be converted
into work clothes, it would be desirable to have as durable a
finish as possible so that the soil release properties will be as
long lasting as possible. For these items it is preferred to first
apply the textile resin and separately after curing of the textile
resin apply the polymerizable compound and subsequently form the
soil release polymer. On the other hand, where the ultimate article
of manufacture is not one that will be washed or cleaned on a
weekly basis, for example, upholstery for automobiles, seat covers,
wall coverings, etc., either a simultaneous addition or a separate
addition where the polymerizable compound is added and the polymer
formed first may be used. It must be emphasized, however, that
under the latter conditions the soil release properties are less
desirable than those attained by the aforesaid sequential
application with the textile resin being cured first.
Advantages afforded by the process of the present invention are
available for textile materials treated in almost any form, e.g.,
fibers, yarns, threads, fabrics or the ultimate product, e.g., a
garment, etc. The presensitizing embodiment, i.e., the textile
resin treatment, when employed, is most advantageously conducted on
textile material in the fabric, etc., form.
Garments made from the fabrics treated according to the process of
the present invention require no steps other than normal for the
preparation of the conventional durable press garments. In other
words, the garment may be folded and pressed on conventional
equipment, for example, a Hoffman press. The pressing cycle
utilized is standard in the industry and generally involves
pressing of the garment for a short period of time, followed by a
curing operation in an oven. Alternatively, the garment may be set
in a desired configuration under hot, dry conditions, such as by
hot pressing without steaming, for example at temperatures of up to
about 200.degree. C. for as long as necessary to cure the
resin.
In general, the textile resin or vinyl monomer with dual
functionality when employed may be selected from several general
types. According to the materials selected, one of the following
processes may be generally followed to achieve the novel garments
produced by the present invention. In each type procedure, the
methods of application and order of application of the various
compounds may be varied as described supra.
TYPE I
1. Apply textile resin and textile resin catalyst to fabric.
2. Dry fabric at temperature that is insufficient to initiate
catalysis of the textile resin.
3. Apply polymerizable compound to fabric.
4. Form soil release polymer.
5. Make garment from fabric.
6. Press garment to produce creases where desired.
7. Subject garment to temperature sufficient to catalyze and cure
the textile resin.
TYPE II
1. Apply textile resin having more than one type of functional
groups, and textile resin catalysts for each functional group to
cellulosic fabric.
2. Subject fabric to conditions whereby one type of functional
group reacts and remaining functional groups remain dormant.
3. Apply polymerizable compound to fabric.
4. Form soil release polymer.
5. Make garment from fabric.
6. Press creases where desired in garment.
7. Subject fabric to conditions whereby the remaining functional
groups are reacted with the cellulose.
TYPE III
1. Apply vinyl monomer having more than one type of functional
groups, one type being sites of ethylenic unsaturation and a
textile resin catalyst to a cellulosic fabric.
2. Dry the fabric at temperatures such that the textile resin
catalyst remains dormant.
3. Apply polymerizable compound to fabric.
4. Subject the fabric to irradiation to form soil release polymer
and attach the ethylenic group in the vinyl monomer to the
cellulose.
5. Make a garment from the fabric.
6. Produce desired creases in the garment.
7. Subject the garment to textile resin curing conditions.
In each of the above types of procedures, the ultimate curing of
the textile resin may be accomplished prior to the manufacture of
the garment whereby a good wash-and-wear fabric having soil release
properties is produced.
Procedures of Types I, II and III, as is evident, relate to the
process of the present invention being applied to a textile
material to afford said textile material soil release and durable
press or wash-and-wear characteristics. Otherwise than above shown,
the polymerizable compound, textile resin catalyst, etc., are just
applied to the desired substrate and dried, subjected to textile
resin curing conditions, etc., according to the specifications
described herein.
The drying temperatures that are insufficient to initiate the
catalysis are, of course, dependent upon the particular catalyst
being employed. In general, however, the drying step is conducted
at a rate of approximately 10 to 70 yards per minute at
temperatures ranging from about 225.degree. to 300.degree. F.
preferably in a tenter frame. The drying temperature range overlaps
to some degree with the curing temperature range set forth below.
When drying in the overlapping portion of the drying and curing
ranges, it is important that there be no premature curing of the
textile resin. Time is the prime variable and when drying the
substrate in the higher end of the drying temperature range, care
must be taken to avoid heating the substrate for a time sufficient
to initiate catalysis that would at least partially cure the
textile resin.
Irradiation techniques may be employed according to the process of
the present invention to polymerize the polymerizable compound and
form the soil release polymer in situ on the textile material. An
insulating core transformer, operated at potential varying between
one hundred thousand electron volts and five hundred thousand
electron volts may be successfully used to irradiate the textile
material. Such a transformer is commercially available from High
Voltage Engineering Corporation, Burlington, Massachusetts. The
amount of ionizing irradiation necessary according to the present
invention is at least 32 electron volts for each ion pair formed.
Both high energy particle and ionizing irradiation are useful
according to the present invention. The preferred dosage of
irradiation according to the present invention is in the range of
one thousand rads to one hundred megarads, a rad being the amount
of high energy irradiation of the type which results in energy
absorption of one hundred ergs per gram of absorbing material. More
preferably, however, the irradiation dosage ranges from 0.5 to 5
megarads.
Curing is accomplished by subjecting the textile material to
conditions such that a crosslinking or insolubilizing reaction
occurs. For example, a crosslinking reaction between functional
groups of a textile resin and hydroxyl groups of the cellulose in
the textile material converts the resin to the thermoset state.
Curing the in situ formed acid polymer converts it to an
insolubilized state. Temperature is the prime mover and generally a
temperature in the range of 100.degree. C. to about 300.degree. C.
is sufficient. The curing medium that supports the necessary
temperature may be any substance that is inert to both the fabric
and the ingredients applied thereto, e.g. hot air, steam, etc. In
the instance with a vinyl monomer which possesses two different
types of functional groups, there are actually two reaction steps,
the first being conducted at a temperature lower than the second
and insufficient to initiate the second reaction, e.g., a first
graft polymerization step in which the vinyl monomer becomes
chemically attached to the cellulose, and a subsequent curing step
in which the remaining functional groups on the grafted polymer
react with the hydroxyl groups of the cellulose forming
crosslinks.
The duration of the various processing steps varies diversely with
the particular ingredients employed. In each situation, however,
the treatment time is that necessary to sufficiently cause
insolubilization and/or curing preferably about 0.1 to 30
minutes.
The following examples illustrate preferred embodiments of the
present invention but are not intended to restrict the scope of the
invention. In the examples, parts and percentages are by weight.
The fabrics prepared in accordance with the procedures set forth in
the examples are tested for soil release according to the following
procedures. The soil release values are determined by comparison to
a set of standards having numerical ratings from 1.0 to 5.0, with
1.0 representing no stain removal and 5.0 being complete removal of
the stain. The fabrics are stained with mineral oil. After
staining, the fabric is washed one time in a Kenmore automatic
washer using one cup of All detergent (sold by Lever Brothers) and
a wash water temperature of about 140.degree. F. The fabric is
dried for approximately 40 minutes at a temperature of about
160.degree. F. The stains in the dried fabric are compared with the
set of standards. The values listed in the Tables under the
headings 5 and 10 washes represent staining after 5 or 10 normal
washings and then a single wash to remove the stain.
EXAMPLE I
Seventy parts acrylic acid, 30 parts butyl acrylate and 20 parts
water are combined and the formulation applied to a Dacron/cotton
(65/35) fabric with an applicator roll. The wet pickup on the
fabric is about 25 percent.
After about 1 hour hold time, the fabric is subjected to
irradiation with an insulating core transformer manufactured by the
High Voltage Engineering Corporation of Burlington, Massachusetts.
The fabric is passed through the irradiation equipment in a single
layer at a speed of about 16 feet per minute, with a dosage of
about 3 megarads. The fabric is then laundered at 140.degree. F.
and air dried. The resulting fabric having about 9 percent polymer
thereon is stained and laundered according to the procedure set
forth above to give the soil release ratings reported in Table
I.
EXAMPLE II
The procedure of this example is the same as that of Example I
except that about 4.5 percent zinc nitrate (50 percent aqueous
solution of (Zn(NO.sub.3).sub.2 .sup.. 6H.sub.2 O) is incorporated
in the formulation applied to the fabric, and the treated fabric is
cured by heating for about 11/2 minutes at a temperature of about
160.degree. C. The soiling release results are reported in Table I.
---------------------------------------------------------------------------
TABLE I
Soil Release Ratings After 1 After 5 After 10 After 20 Example Wash
Washes Washes Washes
__________________________________________________________________________
Control 2.5 2.0 2.5 2.5 I 5.0 5.0 4.3 4.3 II 4.5 5.0 5.0 4.5
__________________________________________________________________________
example iii
an emulsion is prepared by combining 300 parts water, 2 parts
sulfonated castor oil, 70 parts acrylic acid and 30 parts butyl
acrylate. The emulsion is padded onto a Dacron/cotton (65/35)
fabric and the fabric irradiated immediately with a dosage of about
2 megarads in the irradiation equipment of Example I. The
irradiated fabric is then cured by heating at a temperature of
about 170.degree. C. for about 15 minutes. The resulting fabric
with about 10 percent polymer is laundered at 140.degree. F. and
air dried. The soil release ratings of the fabric are reported in
Table II.
EXAMPLE IV
To compare the process of the invention with a process employing a
preformed polymer, the procedure of Example III is repeated, except
that the emulsion padded onto the fabric contains a 10 percent
copolymer emulsion of 70 percent acrylic acid and 30 percent butyl
acrylate instead of the acrylic acid and butyl acrylate monomers.
The emulsion is extremely viscous and very difficult to apply to
the fabric. The treated fabric is dried and cured at 150.degree. C.
for 15 minutes, but the irradiation step is omitted since a
preformed polymer is used. The resulting fabric containing about 5
percent polymer is of unacceptable stiffness both initially and
after repeated laundering. The soil release tests show the results
set forth in Table II.
EXAMPLE V
The procedure of this example is the same as that of Example IV
except that the treated fabric is air dried, instead of being
heated at 150.degree. C. for 15 minutes. The test results are set
forth in Table II.
---------------------------------------------------------------------------
TABLE II
Soil Release Ratings After 1 After 5 After 10 Example Wash Washes
Washes
__________________________________________________________________________
Control 2.5 2.0 2.5 III 4.5 5.0 3.8 IV 4.5 4.5 4.5 V 2.5 2.5 2.5
__________________________________________________________________________
example vi
dacron/cotton (65/35) fabric is padded with a formulation prepared
by mixing 18 percent N-methylol-acrylamide (60 percent aqueous
solution) and 4.5 percent zinc nitrate (50 percent aqueous solution
of (Zn(NO.sub.3).sub.2.sup. . 6H.sub.1 O). The treated fabric is
dried by heating at 85.degree. C. for about 21/2 minutes and then
irradiated by passing it through the irradiation equipment of
Example I at a rate of about 48 feet per minute with two passes to
provide a dosage of about 2 megarads.
The resulting fabric is laundered at 140.degree. F. and then an
emulsion containing 75 parts acrylic acid, 25 parts butyl acrylate,
2 parts sulfonated caster oil and 300 parts water is applied.
Immediately thereafter, the treated fabric is irradiated with a
4-megarad dosage in a four-pass treatment. The fabric is then
dried, pressed on a hot-head press, using a cycle of 5 seconds
steam, 5 seconds bake and 5 seconds vacuum and cured by heating at
305.degree. F. for about 15 minutes.
The resulting fabric which contains about 10 percent polymer is
subjected to staining and laundering tests which are reported in
Table III.
EXAMPLE VII
To compare the process of the invention in durable press fabrics
with a process using preformed polymers, a pad bath solution is
prepared by dispersing in water 18 percent N-methylol-acrylamide
(60 percent aqueous solution); 4.5 percent zinc nitrate (50 percent
aqueous solution of (Zn(NO.sub.3).sub.2.sup. . 6H.sub.2 O); and 10
percent emulsion copolymer comprising 70 percent ethyl acrylate and
30 percent acrylic acid. The above solution is padded onto samples
of Dacron/cotton (65/35) fabric to provide about a 50 percent wet
pickup. The fabric is then dried at about 85 percent C. until the
moisture regain is reduced to approximately 8 percent.
The fabric is then irradiated with a 2-megarad dosage and pressed
on a hot-head press with a cycle of 5 seconds steam, 5 seconds bake
and 5 seconds vacuum. The fabric containing about 1.5 percent
polymer is cured for about 15 minutes at a temperature of about
305.degree. F. The test results are reported in Table III.
---------------------------------------------------------------------------
TABLE III
Soil Release Ratings After 1 After 5 After 10 Example Wash Washes
Washes
__________________________________________________________________________
Control* 1.0 1.5 2.0 VI 5.0 5.0 4.8 VII 3.5 3.0 2.5
__________________________________________________________________________
*with N-methylol acrylamide
EXAMPLE VIII
A 20 percent solution of calcium acrylate is applied to a
Dacron/cotton (65/35) fabric and the fabric irradiated with a
4-megarad dosage. The resulting fabric after being laundered at
140.degree. F. shows a soil release of 5.0 after one wash and 3.3
after five washes.
EXAMPLE IX
A Dacron/cotton (65/35) fabric is padded with a solution containing
about 24 percent dihydroxy dimethylol ethylene urea (50 percent
solution), 2.3 percent zinc nitrate (Zn(NO.sub.3).sub. 2.sup..
6H.sub.2 O), 0.25 percent ethoxylated alkyl phenol and the balance
water. The treated fabric is dried and cured at about 350.degree.
F. for about 90 seconds in a festoon oven. The cured fabric is then
washed with water containing 0.1 percent ethoxylated alkyl phenol,
acidified with a 0.1 percent aqueous acetic acid solution, rinsed
with water and dried.
The resulting fabric is soaked in a 50 percent aqueous acrylic acid
solution maintained at a temperature of about 75.degree. C. for 15
minutes. The fabric is squeezed to remove excess liquid and
irradiated at a dosage of about 4-megarads. The low molecular
weight surface polymer is removed by soaking the irradiated fabric
in a 2 percent aqueous sodium bicarbonate solution, and the fabric
is then laundered at a temperature of 140.degree. F. The resulting
fabric containing about 19 percent polymer shows the soil release
characteristics set forth in Table IV.
EXAMPLE X
The procedure of this example is the same as that of Example IX
except that the treatment with the pad bath solution and the
curing, washing and drying steps associated therewith are omitted.
The resulting fabric containing about 42 percent polymer has the
soil release characteristics set froth in Table IV.
EXAMPLE XI
The procedure of this example is the same as that of Example IX
except that the concentration of acrylic acid in the aqueous
solution is 35 percent. The fabric containing about 7.5 percent
polymer shows the soil release characteristics set forth in Table
IV.
EXAMPLE XII
The procedure of this example is the same as that of Example XI
except that the treatment with the pad bath solution and the
curing, washing and drying steps associated therewith are omitted.
The resulting fabric containing about 26 percent polymer has the
soil release characteristics set forth in Table IV.
EXAMPLE XIII
The procedure of this example is the same as that of Example IX
except that the aqueous acrylic acid solution is replaced with a
solution containing 55 percent acrylic acid, 20 percent butyl
acrylate and 25 percent water. Tests on the fabric with 19 percent
polymer show the results set forth in Table IV.
EXAMPLE XIV
The procedure of this example is the same as that of Example XIII
except that the treatment with the pad bath solution and the
curing, washing and drying steps associated therewith are omitted.
The fabric containing about 35 percent polymer shows the soil
release values set forth in Table IV.
---------------------------------------------------------------------------
TABLE IV
Soil Release Ratings After 1 After 5 After 10 After 20 Example Wash
Washes Washes Washes IX 5.0 5.0 4.8 5.0 X 5.0 5.0 5.0 5.0 XI 5.0
5.0 5.0 5.0 XII 5.0 5.0 4.5 5.0 XIII 5.0 5.0 5.0 5.0 XIV 5.0 5.0
5.0 5.0
__________________________________________________________________________
example xv
a solution containing 75 parts acrylic acid, 25 parts butyl
acrylate, 5 parts benzoyl peroxide and 15 parts water is applied to
a Dacron/cotton (65/35) fabric with an applicator roll to provide a
25 percent wet pickup. The treated fabric is rolled up and sealed
in a polyester film. The sealed roll is heated in an oven at a
temperature of about 80.degree. C. for about two hours. After
removal from the oven the fabric is washed with water, a 2 percent
sodium bicarbonate solution and rinsed with water again. The
resulting fabric containing about 7 percent polymer shows good soil
release characteristics similar to those of Example I.
EXAMPLE XVI
The procedure of the above examples is repeated, utilizing other
fabrics including fabrics containing viscose rayon, Orlon, Acrilan,
acetate, polypropylene, etc., fibers with similar improvements in
soil release characteristics.
It will be noted that the fabric prepared in Examples I, X, XII and
XIV provide outstanding durability of soil release characteristics
even without any curing step. This is an important advantage since
it materially reduces the processing time required to produce
textile material with durable soil release characteristics. In
contrast, the application of a preformed polymer in Example V
without the curing step results in a complete loss of the soil
release polymer in the initial laundering. Example VI illustrates
the combination of a durable press polymer with the in situ formed
soil release polymer, as contrasted with the conventional durable
press polymer-soil release preformed polymer heretofore utilized as
illustrated by Example VII. The superiority of the process of the
present invention in combination with the textile resin is apparent
from the results set forth in Table III.
It is apparent from the above description and examples that the
process of the invention in which a soil release polymer is formed
in situ on the textile material provides benefits and advantages
not attainable with other systems. Moreover, the present invention
provides textile material having improved soil release
characteristics. Also, the invention provides fabric having soil
release characteristics which are much more durable than heretofore
possible. Furthermore, the process of the invention provides such
benefits and advantages in combination with durable press and/or
wash-and-wear characteristics.
* * * * *