U.S. patent number 3,650,882 [Application Number 04/841,004] was granted by the patent office on 1972-03-21 for multi-ply paper towel.
This patent grant is currently assigned to Kimberly-Clark Corporation. Invention is credited to Gordon D. Thomas.
United States Patent |
3,650,882 |
Thomas |
March 21, 1972 |
MULTI-PLY PAPER TOWEL
Abstract
A multi-ply absorbent creped cellulose wadding paper tissue
material in which an elastically extensible inner web of creped
tissue paper has on its major faces at least one embossed paper
tissue material of greater dryer basis weight and lesser
extensibility. The outer webs are bonded to the inner web (or webs)
in spaced regions to provide unbonded zones between bonds. The
adhesive is sufficiently water resistant to permit retention of the
webs when wetted so that the inner creped web may expand and fill
the unbonded zones providing good bulk in the wet product. Methods
of effecting the web combinations are described.
Inventors: |
Thomas; Gordon D. (Neenah,
WI) |
Assignee: |
Kimberly-Clark Corporation
(Neenah, WI)
|
Family
ID: |
25283772 |
Appl.
No.: |
04/841,004 |
Filed: |
July 11, 1969 |
Current U.S.
Class: |
428/154; 156/290;
428/198; 156/209; 428/166; 428/212 |
Current CPC
Class: |
A47K
10/16 (20130101); Y10T 428/24942 (20150115); Y10T
428/24562 (20150115); Y10T 428/24826 (20150115); Y10T
156/1023 (20150115); Y10T 428/24463 (20150115) |
Current International
Class: |
A47K
10/00 (20060101); A47K 10/16 (20060101); B32b
003/28 (); B32b 007/14 () |
Field of
Search: |
;156/183,209,219,290,291,229 ;264/282-283
;161/73,74,128,129,119-124,DIG.3,148,127,130 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Ansher; Harold
Assistant Examiner: Epstein; Henry F.
Claims
I claim:
1. A multi-ply cellulosic wadding tissue paper wiping material
having a capacity for the retention of liquids and exhibiting good
bulk characteristics in the wet and dry state, said material
comprising an inner web of absorbent creped tissue paper which is
extensible in at least one planar direction of the product and at
least one outer web of absorbent creped tissue paper on each major
face of the said inner web, and each outer web having embossments,
adhesive bonds securing the outer webs to the inner web at
embossments in spaced regions to provide unbonded zones of the
wiping material between bonds, said outer webs of creped tissue
paper being somewhat inextensible relative to the inner web in the
said one planar direction so that the outer webs are capable of
restricting extension of the inner web to zones between bonds when
the material is wetted.
2. A multi-ply material according to claim 1 in which the
extensibility of the inner web is at least about two times that of
an outer web.
3. A multi-ply material according to claim 1 in which the inner web
has a dryer basis weight which is approximately one-half to
three-quarters of the basis weight of an outer web.
4. A multi-ply material according to claim 1 in which the outer
webs have a dryer basis weight of between about 9 and 15 pounds and
the inner web has a dryer basis weight of between about 5 and 9
pounds per 2,880 sq. ft. and the elongation of said inner web at
break is at least about two times that of an outer web.
Description
BACKGROUND OF THE INVENTION
Field of the Invention
This invention relates to absorbent creped cellulosic wadding or
paper wiping products, particularly multi-ply paper towels, and to
methods of producing such products.
A general object of the invention is to provide an improved paper
toweling medium which, with respect to currently commercially
available products, has materially greater liquid absorbency and
towel bulk as well as better wet and dry dimensional stability and
softness, tensile strength, stretch and quantity of fluid
absorbency.
Another object of the invention resides in the provision of novel
methods for the production of paper toweling.
The approved toweling material in accordance with the invention
employs a multi-ply structure of creped cellulosic wadding sheet
material. An inner web of absorbent creped tissue paper is
characterized by having considerable extensibility in at least one
planar direction of the towel. Water resistant bonds secure at
least one outer web of creped tissue to the inner web in spaced
regions and on each major face of the inner web. The outer webs of
creped tissue are extensible but much less so than the inner
web.
The provision of adhesive bonds in spaced regions provides unbonded
zones of the towel structure between bonds. The less extensible
outer webs of tissue paper confine the expansion or the
extensibility of the inner web largely to the unbonded zones and,
upon wetting in towel use, the normal release of the crepe of the
inner web tends to cause the unbonded zones to be filled with an
expanded inner creped web. This tends to bulk the towel in the wet
state which is the converse of that which commonly occurs when
towel structures are wetted. Accordingly, the bulking action gives
a stability to the toweling material and assists in attaining a
product of improved hand.
It is to be noted that in the toweling material the outer webs or
plies of the multi-ply structure are provided with embossments to
further aid bulk and to impart softness and conformability to the
material. Embossing decreases the stretch of a web to some degree
but is not generally detrimental. Also, the embossments of the
outer webs may lie in directly opposed relation but such is not
necessary to the invention. The inner more extensible web may also
be embossed if desired. This inner web is a ply of much lighter
basis weight than the outer plies, a factor which further is
important in the attainment of towel drape and flexibility.
Adhesive employed to bond the outer webs to the inner and more
extensible web should be sufficiently water resistant that the
bonds will be retained for a length of time to permit the expansion
of the inner web relative to the outer webs and for toweling
material of the inner web to fill out in the unbonded zones against
the outer webs. The pattern of adhesive application will affect the
extent of bulking but is not a critical factor, it simply being
desirable to have a sufficient number of bonded zones to hold the
multi-ply structure together in manufacture and use. Many adhesives
will serve the purposes, and polyvinyl alcohol is a typical
commercial and useful material. Other suitable adhesives are
polyvinyl acetate, dextrin, acrylic latexes and the like.
The inner creped tissue web should not only be extensible but, for
many methods of production, should be resiliently so in order to
permit its passage through conventional manufacturing equipment
without significant loss of stretch. Additionally, if desired, the
inner ply may be attached to the outer plies while the resilient
inner ply is in a stretched condition relative to the outer plies.
Upon release, the outer webs will then be bulked further in the
unbonded zones by the retraction of the material, and such unbonded
zones will be further receptive to the expanding material of the
inner web when the towel is wetted.
In practice, I have found that it is desirable that, in the
finished product, the inner ply should be stretchable to at least
about two times that of the stretch of the outer plies, all
elongations being measured at break.
The invention will be more fully understood by reference to the
following detailed description and accompanying drawings
wherein:
FIG. 1 is a schematic representation of apparatus on which
multi-ply toweling of the present invention may be formed;
FIG. 2 is a fragmentary view in plane of toweling in accordance
with the invention and with portions of the upper ply removed and
portions of the inner ply turned back;
FIG. 2A is an exploded view illustrating the creped unembossed
wadding plies useful for formation of the structure of FIG. 2;
FIG. 3 is an enlarged and edge view taken along line 3--3 of FIG.
2;
FIG. 4 is an enlarged view taken along line 4--4 of FIG. 2;
FIG. 5 is a view similar to that of FIG. 3 but illustrating the
product after it has been wetted;
FIG. 6 is a view similar to that of FIG. 4 but illustrating the
product after it has been wetted;
FIG. 7 is an enlarged view in section illustrating another method
of combining the plies of the multi-ply toweling but generally
similar to that of FIG. 1;
FIG. 8 is a view like that of FIG. 7 but involving a combining nip
in which the lower of the combining rolls is a soft foam
rubber;
FIG. 8A is a cross section of toweling material produced using the
combining nip illustrated in FIG. 8 and showing a random adherence
of the plies of the toweling material;
FIG. 9 is a view of another embodiment of toweling material
produced with a combining nip as illustrated in FIG. 8 but showing
a somewhat different adherence relation of the plies;
FIG. 10 is a sectional view, enlarged, of toweling material
produced with another adhesive arrangement for securing the webs
together; and
FIG. 11 is an apparatus arrangement illustrating another method of
forming toweling material in accordance with the invention.
Referring now the drawings, the numeral 1 in FIG. 1 indicates
schematically a web of creped tissue being moved in the direction
of the arrow around a resilient rubber roll 2 through a nip 3
formed by the resilient roll 2 and a metal, suitably steel, male
embossing roll 4. In the drawings the various webs and rolls move
in the directions indicated by the associated arrows. The web 1 as
it proceeds to a combining nip 5 is embossed in the nip 3 by
indentation of the soft rubber roll 2 (Shore durometer A about 40)
to provide upstanding embossments 11 (FIG. 2) which are supplied
with adhesive by the flexographic type adhesive applicator
indicated generally at 6. The applicator 6 includes applicator roll
7, intermediate roll 8 and pond roll 9 for the application of
adhesive 10 to the embossments of the traveling web 1. The rolls 7,
8 and 9 are respectively rubber covered, steel and rubber covered;
they are plain surfaced rolls but rolls 7, 8 could be patterned if
desired. Adhesive is applied only to the web embossments 11 as the
web proceeds to the nip 5. The adhesive itself is applied in very
thin film form and is not visible to the unaided eye on the web. A
second and similar web 12 is provided to the nip 5 over similar
equipment. The numeral 13 designates a soft rubber roll (Shore
durometer A about 40) which forms the nip 14 with the male embosser
roll 15, adhesive 17 being supplied to the embossments 16 (FIG. 2)
by the action of rolls 18, 19 and 20. The roll 21, like the roll 4,
is a male embosser roll which receives thereover in the nip 5 the
traveling adhesive carrying embossed web 12. Male embosser rolls
21, 4, and 15 are identically patterned and rotate in unison at the
same speeds.
A third web 22 of relatively light dryer basis weight and of high
stretch characteristics (as schematically illustrated generally by
the relatively high crepe frequency in FIG. 1) is fed to the nip 5
between the webs 1 and 12. As illustrated in the drawings, the
coaction of the rolls 4 and 21 serves to bond together the outer
webs 1 and 12 with the inner web 22. It is to be noted that, while
rolls 4 and 21 are suitably rotated in unison, the webs 1 and 12
will not exactly provide their embossments in opposed relation in
the nip 5, and no attempt is made to control sheet 12 to so provide
the embossments in opposition.
Following the combining step in nip 5, the three ply web may be
subjected to a drying operation to set the adhesive and then to
winding into roll form. With many adhesives the drying operation is
not necessary as sufficient bonding of the webs occurs in nip
5.
As shown in FIGS. 2, 3 and 4, well bonded areas of the toweling
material occur at 23, for example. These bonded areas are in well
spaced regions of the material and provide unbonded zones 24
between the bonds 23 (FIGS. 3 and 4). In one specific example the
toweling plies 1 and 12 having respectively the embossments 11 and
16 were of a dryer basis weight of about 11.0 pounds and had a
crepe ratio of about 1:3 or an actual basis weight of 14.3
(11.times.1.3). The stretch of the individual outer webs was about
30 percent. The inner web 22 had a dryer basis weight of about 7.5
at a crepe ratio of about 2.2. Thus, this latter web had a stretch
of about 120 percent. The finished product exhibited a finished
basis weight of about 38 pounds per 2,880 sq. ft. and rupture of
the outer plies occurred at a stretch of about 10 percent. The
inner ply in the product has a much greater percent stretch of
about 80 (dryer basis weight is the weight of the sheet per 2,880
sq. ft. on the Yankee dryer before creping).
The product illustrated in FIGS. 3 and 4, when wetted, had a
structure such as is illustrated in FIGS. 5 and 6. As may be
clearly noted from FIG. 5, the highly creped inner ply 22 expanded
very considerably in the zones 24 abutting against both plies 1 and
12 and tended to retain these plies in bulked or distended
condition. This is clearly shown in FIG. 5 at 25, and somewhat less
so in FIG. 6 wherein the view is transverse to that of the toweling
material and the crepe structure of the webs including web 22.
In FIG. 7 the arrangement is very similar to that of FIG. 1 except
that adhesive has been applied only to some embossments; this is
readily accomplished by providing roll 7 or 8 or 18 or 19 as
patterned rolls (peg rolls). Thus, there is a greater degree of
random ply attachment in this mode of processing.
Another embodiment of the toweling structure is illustrated in FIG.
8A. In this instance the product results from the use of a
patterned adhesive application and a combining nip formed by the
male metal embossing roll 4 and a soft foam rubber covered roll
indicated by the numeral 28. The webs 1, 12 and 22 are fed to this
nip as described in connection with FIGS. 1 and 7 but in this
instance the foam rubber roll 28 yields and there is an increased
attachment of the plies 1 and 12 to the intermediate ply 22 over
that shown in connection with the FIG. 7 modification. Accordingly,
to some extent the unbonded zones indicated at 29 (FIG. 8A) are
somewhat nonuniform and frequently larger than the unbonded zones
of the structure of FIG. 2. Thus, it will be noted that, in FIG. 8A
plies 22 and 12 are attached at 30 but are not attached to web 1 in
this area. More specifically, the bonding in connection with the
structure of FIG. 8A is less uniform, that is, more random, than in
the previously described toweling material of FIG. 2.
The structure of FIG. 9 is based upon an adhesive application to
the webs 1 and 12 which is more frequent with respect to both webs,
the adhesive bonding areas 33 are more close together and the
frequency of the uniting of all three plies is greater though
commonly only the center ply and one outer ply are united at a
particular area of the sheet.
The embodiment of the toweling material illustrated in FIG. 10 is
suitably produced on an equipment arrangement illustrated in FIG.
11. The combining nip and the presentation of the webs 1 and 12 to
the combining nip is similar to that illustrated in FIG. 1 except
that no adhesive is applied directly to the webs 1 and 12. Rather,
an intaglio roll 39 rotating in the direction indicated by the
arrow in a pan of adhesive 36 and having a suitable doctor blade 37
applies adhesive to the under side of the traveling web 22. A
similar applicator roll 39 applies adhesive from a pond 40 to the
upper side of the traveling web 22. The adhesive is simply wiped on
to the web 22 from the intaglio rolls, the control of the adhesive
being through the medium of the doctor blades 37 and 41, the roll
speed relative to the web and the intaglio pattern. The attachment
of the web 22 to the webs 1 and 12, as illustrated in FIG. 10, is
also somewhat random, the webs being securely attached together as
indicated at 42 or occasionally only the web 12 attaching to the
web 22 as indicated at 43. Also, in some instances there will be an
attachment only to the web 1 by the web 22 as is indicated at
44.
In each of the embodiments described, the center ply of the
toweling material has a distinctively greater elongation
characteristic than does the outer plies. Conveniently, the inner
ply may have a dryer basis weight of about one-half to
three-quarters that of the outer web or between about 5.0 and 9.0
pounds; an extension at break of between about 50 and 150 percent
with a preferred range of 80 to 120 percent. The outer plies may
suitably have dryer basis weights of between about 9 and 15 pounds,
an extension at break of between about 20 and 40 percent. It is not
necessary that the outer plies have the same basis weight although
this is generally preferable in toweling material for home use as
both sides of the toweling material then tend to have the same
characteristics.
The furnish for the webs in the above specifically described
multi-ply toweling structures was of wood pulp as follows:
40 percent by weight of bleached softwood kraft
50 percent by weight of bleached softwood sulfite
10 percent by weight of bleached hardwood kraft
It is to be noted, however, that the furnish for the webs is not
critical, the creped cellulosic wadding furnishes commonly employed
in toweling and wipes generally being suitable, and wet strength
agent to the extent of between about 0.25 to 0.50 percent by weight
of the fiber being customarily incorporated.
Examination of the characteristics of the three ply towel
illustrated in FIGS. 2 to 6 inclusive show that the toweling
has:
1. a compressive modulus of about 899;
2. a Handle-O-Meter MD and CD respectively of about 52.3 and
75.4;
3. a water absorption capacity of about 5.7 grams per 4.times. 4
width, which is more than double (2.01 grams per 4.times.4) that of
two ply towels of similar furnish;
4. Bulk approximately 30 percent greater than that of a two ply
sheet of similar material, the bulk being largely determined by the
nature of the embossing pattern and the receptivity of the sheet to
embossing.
Note: Compressive Modulus is a measure of resistance to compression
and a low compressive modulus is a very general indication of
softness.
Handle-O-Meter is generally a measure of stiffness of a sheet,
higher numerical HOM values indicating greater stiffness.
It is to be noted that the water absorbent capacity is greater than
would be expected from a simple consideration of the additional
amount of material in the three ply structure. Particularly also is
the bulk greater in the wet state, a factor which apparently
contributes to the greater absorbent capacity.
While the foregoing description has emphasized a three-ply toweling
material, it is considered that the interior may be formed of two
or more similar high stretch plies preferably united together for
stretch as a unit. In general, however, an increased dryer basis
weight of the interior ply structure will occasion greater
stiffness and less desirable drape characteristics.
As many apparently widely different embodiments of this invention
may be made without departing from the spirit and scope thereof, it
is to be understood that I do not limit myself to the specific
embodiments thereof except as defined in the appended claims.
* * * * *