U.S. patent number 3,646,749 [Application Number 04/888,002] was granted by the patent office on 1972-03-07 for machine-washable metallized fibrous article and method of making same.
This patent grant is currently assigned to King-Seeley Thermos Co.. Invention is credited to Philip J. Clough, Allen H. Keough.
United States Patent |
3,646,749 |
Clough , et al. |
March 7, 1972 |
MACHINE-WASHABLE METALLIZED FIBROUS ARTICLE AND METHOD OF MAKING
SAME
Abstract
Fibrous article with heat-and-light reflecting quality provided
by a metal coating on synthetic fiber substrates. The metal coating
is undercoated and overcoated with resin systems. The article thus
produced has functional heat and light-reflecting quality and
decorative quality due to the metal coating of the fiber substrates
due to the consistent with substantially retaining hand and
softness of the fibrous article. The article is machine washable
(i.e., retains its metal coat), abrasion and mar resistant, water
repellent and dry cleanable consistent with high-moisture vapor
transmission of the article (breathability).
Inventors: |
Clough; Philip J. (Cape
Elizabeth, ME), Keough; Allen H. (Sudbury, MA) |
Assignee: |
King-Seeley Thermos Co. (Ann
Arbor, MI)
|
Family
ID: |
25392322 |
Appl.
No.: |
04/888,002 |
Filed: |
December 24, 1969 |
Current U.S.
Class: |
442/188; 28/166;
28/169; 139/425R; 427/407.1; 428/378; 428/381; 428/394;
428/413 |
Current CPC
Class: |
D06Q
1/04 (20130101); Y10T 428/31511 (20150401); Y10T
442/3057 (20150401); Y10T 428/2944 (20150115); Y10T
428/2938 (20150115); Y10T 428/2967 (20150115) |
Current International
Class: |
D06Q
1/04 (20060101); D06Q 1/00 (20060101); D02g
003/36 (); B44d 001/14 () |
Field of
Search: |
;117/71R,107,138.8F,138.8N,352,14A,139.4,139.5CE,139.5A,76T
;139/425R ;350/129 ;28/75R ;57/153,164,149 ;161/175,176 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Leavitt; Alfred L.
Assistant Examiner: Weiffenbach; C. K.
Claims
What is claimed is:
1. A metallized fibrous article comprising individual synthetic
fiber substrates which are coated with a multilayer coating
comprising:
a. a base-coat layer of cured resin with a total weight of 3 to 15
percent of the article weight and conforming to individual fiber
surfaces, essentially without bridging adjacent fibers, said cured
resin selected from the group consisting of acrylic and
acrylic-latex polymers and copolymers, epoxy resins, polyvinyl
chloride, cross linkable olefins, vinyl acrylic and vinyl ester
copolymers;
b. a midlayer of vapor deposited metal in sufficient thickness to
afford reflectance to light and heat radiation;
c. a topcoat layer of cured hydrophobic resin with a total weight
of 0.5 to 5 percent of the fiber weight and conforming to
individual fiber surfaces, essentially without bridging adjacent
fibers.
2. The article of claim 1 as a woven fabric.
3. The article of claim 1 with the fibrous article substrate
composition selected from the class consisting of nylon and
polyester.
4. The article of claim 1 with individual fiber substrates
comprising monofilaments.
5. The article of claim 1 with the individual fiber substrates
comprising multifilament yarn.
6. The article of claim 1 with the individual fiber substrates
comprising a monofilament.
7. The article of claim 1 with the base-coat layer completely
surrounding the fiber substrates in cross section.
8. The article of claim 1 with the hydrophobic topcoat layer
completely surrounding the fiber substrates in cross section.
9. The article of claim 1 wherein the base-coat layer is acrylic
resin and the topcoat layer is silicone resin.
10. The article of claim 1 wherein portions of the base-coat layer
and the topcoat layer extend beyond the midlayer such that the
base-coat and topcoat layers are directly bonded to each other.
Description
This invention relates to fibrous articles e.g., fabric (including
woven, nonwoven or bonded or felt and including also a "beam" of
fibers, a fibrillated or slit film) or a single fiber (including
filament or yarn) to be formed into fabric and particularly to
fibrous articles coated with metal to provide heat and light
reflectance for decorative and functional (insulation and
reflection) purposes. Related applications are Ser. No. 794,399
filed Jan. 24, 1969 now abandoned and Ser. No. 796,930 filed Feb.
5, 1969, both of common assignment with the present
application.
The principal known fabric or fiber metallizing methods are (1)
application of metal flakes in a plastic matrix, e.g., U.S. Pat.
Nos. 2,630,620; 2,767,104 and 3,220,871 embodied Milium (registered
trademark of Deering-Milliken Company) and (2) vacuum metallizing
of a fabric or fiber, e.g., British Pat. Nos. 663,251; 721,879;
800,093; 816,906; and U.S. Pat. Nos. 2,912,345; 2,921,864;
2,907,678 and German Pat. No. 1,182,631 embodied in Metalon and
Insalume (registered trademarks) fabrics (see Man Made Textiles
Magazine-Jan. 1965 and Textile World Magazine-May 1965).
Both of these processes have significant limitations in regard to
abrasion and mar resistance and launderability of the metal coating
and/or moisture vapor transmission (breath ability). It is the
primary object of this invention to provide commercially sufficient
machine washability to a metallized polyamide (nylon) fibrous
article as measured by visually observed retention of substantially
all metal throughout the class II machine washability test of the
American Association of Textile Chemists & Colorists (AATCC)
consistent with retaining full breathability of the article. It is
a further object of the invention to similarly improve other
metallized synthetic fibers.
It is a further object of the invention to provide improved
metallized fibrous articles characterized by improved abrasion and
mar resistance, corrosion resistance, launderability, dry
cleanability and water repellence consistent with high-moisture
vapor transmission of the articles.
It is a further object of the invention to provide very high heat
and light reflectance consistent with the foregoing objects.
It is a further object of the invention to provide an economical
method of manufacturing such an article.
In general the improved fibrous article is made by precoating a
fibrous article with a resin, metallizing the fibrous article in a
vacuum chamber, removing the article from the vacuum chamber and
top-coating it with a hydrophobic resin.
The process may be practiced on individual fibers such as
monofilament fiber or yarn or slit or fabrillated film, which
fibers are later formed into a fabric or felt, or practiced
directly on a woven or bonded fabric or felt. The latter is
preferred in cases where abrasion of weaving or bonding would
remove metal coating despite resin protection e.g., in working with
glass fiber substrates. The fiber involved should be synthetic but
maybe part of a mixture of natural and synthetic fibers as in
cotton-polyester woven fabrics. It is preferably wholly synthetic,
preferably nylon, to realize the machine washability object to the
highest degree.
Preferably the metal is applied to a thickness of about
10.sup..sup.-6 inches but may be as thin as 10.sup..sup.-7 or as
thick as 10.sup..sup.-4 inches. The metal forms a single-thin film
continuous layer along the individual fibers on at least one side
of the fibrous article but without bridging gaps or openings
between fibers in the article, to leave the breathability (moisture
vapor transmission) of the article unhindered. The continuity of
the film provides a better reflectance than a flake coating or a
similar metallized film which simulates a flake coating due to
crocking or crazing or removal of intermittent portions thereof due
to abrasion or laundering or the like. The metal is vapor
deposited, preferably vacuum deposited; it may be applied also
through sputtering, pyrolytic or chemical vapor deposition or
electroless vapor plating. Broad areas of the substrate may omit
metal (through masking during deposition or removal of metal) for
functional or decorative purposes.
The invention will be best understood from the following specific
description taken in conjunction with the accompanying drawings
wherein
FIG. 1 shows a portion of a woven fabric with one of the fibers in
cross section and
FIG. 2 shows a typical textile process flow chart including as a
portion thereof the use of the present invention.
In FIG. 1, the fibers shown in the article W (a woven fabric) are
warp W and fill F with a high spot of the weave indicated at H. In
the cross section, it is seen that the fiber comprises in this
instance a monofilament synthetic, e.g., nylon (polyamide). A first
under-or base-coat layer 12 of resin surrounds the fiber substrate.
A midlayer 14 of metal is deposited over the base-coated fiber and
a topcoat of hydrophobic resin 16 imparts water repellency.
The metal layer is applied by vacuum evaporation of metal and
condensation of it on the fibrous article W. The metal vapors move
in the direction M, through crossover points of the fabric as
indicated at C are masked and receive no metal. However such points
do receive top and base-coats if applied by immersion.
The fibrous article substrate is preferably, and with distinct
advantage in the combination selected from nylon and polyester
(e.g., Dacron brand) fiber. The fiber may be in the form of
multifilament yarn or in monofilament form, but the latter is
particularly advantageous in connection with the invention. A woven
fabric substrate provides the best utilization of the invention's
breathability retaining and high-reflectance characteristics.
The base coat layer 12 has a weight of 3-15 percent of the weight
of the fibrous article (nylon fabric) and conforms to individual
fiber surfaces, essentially without bridging adjacent fibers. The
base coat is the polymenzation product of a hydrophillic polar
unsaturated resin deposited in an emulsion bath and cured after
deposition to form a surface coating on the fiber of improved level
(smoothness) compared to the uncoated surface. The midlayer 14 of
vapor deposited metal has sufficient thickness, as indicated above,
to afford reflectances to light and heat radiation. Curing of the
base coat should be complete so that it does not outgas during
metallizing and interfere with metal adhesion. The top coat layer
16 is a cured hydrophobic resin with a weight of 0.5 to 5 percent
of the fibrous article weight (including base coat and metal).
It is preferred and distinctly advantageous to have the top coat
extend beyond the metallized area of the fibrous article to prevent
edge attack by water in washing or usage of the article. Preferably
the top coat surrounds the fibers. The base coat should also extend
beyond the metallized area, under the top coat and preferably
completely surrounding the fibers to provide a bondable surface for
the top coat.
FIG. 2 diagrammatically illustrates the method of producing the
machine washable metallized fibrous article of the invention. The
diagram in part includes steps beyond the intended scope of the
invention and old in the art, which are listed for purposes of
establishing context of the invention.
Step A is conventional production or selection of fiber.
Step B is convention consolidation of fibers through weaving,
bonding or the like.
Step C is the conventional cleaning and sizing e.g., "scour and
heat set" of the fibrous article whether it be a fiber or fabric.
Conventional textile processing procedures are involved and the
resultant fibrous article is then said to be "ready for finish"
e.g., through water proof coats, "hand" and finish modifying coats,
strengthening coats, etc. If a fiber is to be eventually
incorporated into a fabric it is preferable to complete the fabric
production prior to the coating steps listed below to avoid damage
to the coatings through abrasion, heat and chemical attack inherent
in weaving procedures.
The present process invention includes as a first step (d) the
precoating of the fibrous article. Preferably, this is done by
immersion in an emulsion containing an acrylic resin in prepolymer
form, squeezing (or otherwise removing excess emulsion pickup) and
heating in an air oven to dry and polymerize the resin coat. It is
preferred to support side edges of a long web on a tenter frame
during this curing step. However the step may include other means
of application and drying and choices of coating offering
equivalent functioning in the total coating system described
herein. To the extent practical, it is preferred to consolidate
portions of (or eliminate redundant portions of) the steps of
cleaning and sizing (c) and of precoating (d). For instance, the
conventional cleaning step which generally involves immersion in a
solvent cleaner, rinsing and drying could be modified to insert the
precoating immersion step after rinsing, and before drying
(heat-set sizing) to eliminate one redundant drying step.
The metallizing step involves placing the precoated fibrous article
in a vacuum chamber, evacuating the chamber, outgassing the
precoated fibrous article if necessary and then exposing the
fibrous article to a source of evaporating metal in the chamber
which metal condenses on the fibrous article. In commercial
practice a roll of fabric yard goods constitutes the fibrous
article and it is metallized in apparatus of the kind shown in U.S.
Pat. No. 2,971,862 of Baer et al. The roll of goods is unrolled,
passed over the metal source at speeds of several hundred feet per
minute and rerolled. Prior to metallizing the goods should be
unrolled and rerolled in vacuum to assure freedom from outgassing.
It is sufficient if the outgassing does not raise chamber pressure
above 10-.sup.3 torr. For small scale runs, a bell jar coater can
be used with no relative movement of substrate (the precoated
fibrous article) and metal source. The metallization increases
opacity by about 75 percent. It is checked for adequate adhesion by
the conventional Scotch tape test. At this point, the metallized
article is hand washable and dry cleanable.
The metallized fibrous article is then topcoated preferably by
immersion in a solution containing a silicon resin in prepolymer
form, squeezing and heating in an air oven to dry and polymerize
the resin, as in the precoat process. This renders the article
machine washable and water repellent.
Subsequent steps can include cutting, stitching and other
processing of the fibrous article.
The preferred embodiments of the invention are now further
illustrated through the following nonlimiting examples.
EXAMPLE I
A scoured and heat set nylon woven fabric cloth of 90 .times. 108
taffeta weave was precoated by immersion in a bath containing the
following constituents (with percentages indicated on a weight
basis):
Rohm & Haas HA-8 acrylic emulsion (50% solids in water) 30 %
oxalic acid catalyst 0.15% Philadelphia Quartz "N" sodium silicate
0.25% water balance
The bath was maintained at a temperature of 75.degree. F. The cloth
was squeezed between nip rolls after immersion and passed through a
drying chamber, containing air heated at 315.degree. F., in 90
seconds. The precoating produced, after drying, a solids pickup of
6 percent of weight of the original cloth.
After precoating, the cloth was passed through a vacuum coater and
vacuum aluminized to produce a metal coating of about 10-.sup.6
inches on one side. The coating corresponds to what would be a 2
ohm per square coating on a film substrate.
Then the cloth was immersed in another bath having the following
ingredients (by weight):
Silicon (Dow Corning FC-227) 30 % Catalyst (Dow Corning 27) 0.6%
Adhesive (Dow Corning X(-4-2067) 0.9% Toluene balance
The bath was at 75.degree. F. Drying was accomplished as in the
precoat step to produce a solid weight pickup of 1% (based on the
precoated and metallized cloth).
The cloth was successfully machine washed in accordance with
AATCC-II Test. No loss of metal was observed. The fabric was as
breathable as before treatment.
EXAMPLE II
Processing as in Example I with a topcoat mix of
Silicone 20 % Catalyst 0.4% Adhesive 0.6% Toluene balance
(including metallizing and base coating as in I) was apparently
similarly successful on white nylon cloth, but showed spots of blue
in metallized blue cloth after washing, leading to the observation
that the total coating system cracks or abrades at high spots
(which is functionally acceptable but esthetically less
desired).
EXAMPLE III
The results of Examples I and II were repeated in processes in
which the base coat composition was varied to
UCar 891 acrylic-latex copolymer emulsion (50% in water) 20 %
diammonium phosphate powder 0.5% water balance
Unsuccessful results re machine washability (i.e., failure to hold
metal through AATCC-II Test) were obtained when the systems
described in the above cited patent applications Ser. Nos. 794,399
and 796,930 were used. Unsuccessful results were obtained from:
a. direct metallizing with no base coat or top coat
b. precoat plus metallizing without top coat
c. top coated metallized cloths without precoat
d. acrylic base (as in Example I), metallize, acrylic top coat
e. silicon base, metallize, silicone top coat
It is desirable to assure uniformity of base and top coats, e.g.,
by the use of rubber surfaced nip rolls in the drying process and
avoidance of abrasion in handling the cloth. In the above examples,
handling conditions were less than ideal, including use of a chrome
surfaced nip roll.
Addition of fireproofing agents to the base coat is also desirable.
Chlorinated resin substitutes for the base coat resin accomplish
this. Dispersion of fireproofing salts in the base coat as in
Example III, above, is another way to accomplish the same
result.
It is thus apparent that there is a synergistic effect in the
combinations of the type illustrated in the above examples.
Alternative ingredients for the base coat in lieu of or with
acrylic and acrylic-latex polymers and copolymers are epoxy resins,
polyvinyl chloride, cross linkable olefins, vinyl acrylic,
vinylester copolymers. Alternative ingredients for the top coat in
lieu of or with silicone are epoxy resins. Urethane resin top coat
may be utilized but is less advantageous because it reduces
transmission of infrared heat radiation to a substantially greater
extent than silicone resin.
Water repellent resin coating systems are described in U.S. Pat.
Nos. 3,081,193; 3,398,017; 3,326,713; 2,588,366; 3,434,875 and
3,076,926. See also the references cited above at the beginning of
this specification.
The scope of the invention includes various other metals copper,
zinc, tin, gold, silver, bright platinum, bronze, Wood's metal and
equivalent metals. The metal coating may also be in sublayers
providing iridescent reflective effects, but such sublayers would
add up to a single-thin deposited layer in contrast the three
dimensional structure of Milium coatings which have overlapping and
nonparallel metal flakes in a plastic matrix.
Still further equivalents within the scope of the invention will be
apparent to those skilled in the art once given the benefit of the
foregoing disclosure. Accordingly it is intended that the foregoing
disclosures shall be read as illustrative and not in a limiting
sense.
* * * * *