U.S. patent number 3,645,757 [Application Number 05/041,635] was granted by the patent office on 1972-02-29 for food packaging method employing release agent coated packaging material.
This patent grant is currently assigned to Kraftco Corporation. Invention is credited to Arthur L. Gordon, Leonard A. Warwick.
United States Patent |
3,645,757 |
Gordon , et al. |
February 29, 1972 |
FOOD PACKAGING METHOD EMPLOYING RELEASE AGENT COATED PACKAGING
MATERIAL
Abstract
An improved package for moisture-containing food products and a
method for providing improved release properties for such food
products is provided. The release properties are provided by a thin
film or layer of a suitable readily hydrated hydrocolloid. Suitable
hydrocolloids may be selected from pregelatinized starches,
modified cellulose materials or mixtures thereof.
Inventors: |
Gordon; Arthur L. (Des Plaines,
IL), Warwick; Leonard A. (Niles, IL) |
Assignee: |
Kraftco Corporation (New York,
NY)
|
Family
ID: |
21917546 |
Appl.
No.: |
05/041,635 |
Filed: |
May 28, 1970 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
654041 |
Jul 10, 1967 |
3519470 |
|
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Current U.S.
Class: |
426/415; 426/811;
427/415 |
Current CPC
Class: |
B65D
81/24 (20130101); Y10S 426/811 (20130101) |
Current International
Class: |
B65B
25/00 (20060101); B65B 25/06 (20060101); B65b
025/06 () |
Field of
Search: |
;99/171R,171CA,171LP,178
;117/165,166,84,85,92 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lutter; Frank W.
Assistant Examiner: Weinstein; Steven L.
Parent Case Text
The present application is a continuation-in-part of copending
application Ser. No. 652,041, filed July 10, 1967, which has now
issued as U.S. Pat. No. 3,519,470.
Claims
What is claimed is:
1. A method for treating the surface of packaging materials which
are used for packaging moisture containing food products so as to
provide a release coating thereon, which method comprises providing
a dry thin layer of a readily hydrated hydrocolloid or mixture of
readily hydrated hydrocolloids on the surface of packaging
material, wrapping a moisture-containing food material with said
packaging material, and hydrating said hydrocolloid by moisture
transfer from said food material so as to provide a thin
substantially continuous film of said hydrocolloid, said
hydrocolloid being applied at a level sufficient to provide from
about 0.5 to about 5.0 pounds of hydrocolloid on a dry basis per
ream of packaging material.
2. The method of claim 1 wherein the readily hydrated hydrocolloid
is selected from pregelatinized starch, nonionic water soluble
cellulose ethers, and mixtures of the same.
3. The method of claim 1 wherein said moisture-containing food
product is cheese.
4. A method in accordance with claim 1 wherein said dry thin layer
of a readily hydrated hydrocolloid is provided by mixing said
hydrocolloid with an alcohol to provide a dispersion, spraying said
dispersion onto the surface of said packaging material and drying
said dispersion to remove said alcohol.
5. A method in accordance with claim 1 wherein said dry thin layer
of a readily hydrated hydrocolloid is provided by dusting a
substantially dry readily hydrated hydrocolloid powder onto the
surface of the packaging material.
Description
The present invention relates generally to packaging material and
more particularly relates to packaging materials for use in
packaging foods, with improved release properties.
It is desirable to wrap certain foods in a packaging material prior
to distribution. However, various of these foods, such as some
types of cheese, margarine, or some types of candy, tend to stick
or cling to the packaging material when the consumer attempts to
remove the packaging material prior to consumption. Such sticking
or clinging is undesirable in that it may lead to food wastage or
tearing of the packaging material.
Various materials have been used on the interior surface of
packaging materials to prevent blocking. Blocking is defined as
undesired adhesion between touching layers of a packaging material
such as occurs under moderate pressure conditions which occur
during storing or wrapping operations. For example, it is known to
provide a thin coating of dry granular starch on the packaging
material. Such coating of dry granular starch, however, is not
satisfactory in effecting release of the packaging material from
the food product that is wrapped therein.
Accordingly, it is an object of the present invention to provide an
improved packaging material. It is another object of the present
invention to provide a packaging material with improved release
properties when used for food products. It is further object of the
present invention to provide a method for treating packaging
materials which provides easy release of the packaging material
from the food products at the time of consuming.
These and other objects of the present invention will become more
clear from the following detailed disclosure.
In general, in accordance with certain features of the present
invention, packaging materials which are used to package food
products are coated with a hydrocolloid which forms a thin film on
the interior surface of the packaging material. As used herein, the
term hydrocolloid refers to any of several substances which may be
hydrated with water to yield gels and which will subsequently form
thin films upon drying of a thin coating of the hydrated
hydrocolloid. In particular such classes of hydrocolloids as
treated or untreated starches, polysaccharide gums, farinaceous
flours, and modified cellulose materials are suitable for the
practice of the present invention. For example, cornstarch, wheat
flour, guar gum, carrageenan and carboxy methyl cellulose and
combinations of these materials are suitable for the practice of
the present invention.
In accordance with the present invention the hydrocolloid may first
be mixed with cold water to form a paste or suspension. The
suspension is then heated to a predetermined elevated temperature
to promote hydration of the hydrocolloid. The suspension is
maintained at the elevated temperature under stirring conditions
until the hydration is completed and a colloidal solution or gel is
formed. The hydrocolloid gel is then applied to the packaging
materials by any suitable technique. For example, a Gravure
cylinder and knife combination may be used to apply a controlled
thin film layer of the hydrocolloid to a continuous web of
packaging material.
The hydrocolloid material is added to water at a level so as to
provide a suitable viscosity at the temperature of application to
the web of packaging material. For example, when the hydrocolloid
material is cornstarch, the cornstarch is added so as to provide
from about 3 percent to about 10 percent by weight of cornstarch in
water. Suitable levels of other hydrocolloids or mixtures of
hydrocolloids are readily determined by one skilled in the art.
These levels are, in general, from about 2 to about 12 percent by
weight.
After the hydrocolloid suspension has been hydrated by heating, it
is held at a temperature so as to provide the desired viscosity for
application to the packaging material. In general, this temperature
will be from about 15.degree. to about 35.degree. F. below the
boiling point of the hydrocolloid-water mixture.
After application to the packaging material the hydrated
hydrocolloid is dried so as to form a thin continuous film on the
packaging material. This hydrocolloid film is subsequently placed
in contact with the food product during the wrapping operation so
as to provide improved release properties.
Certain readily hydrated hydrocolloid materials such as
pregelatinized starch, which may be derived from any suitable food
source such as rice, potato or tapioca, dextrin, and nonionic water
soluble cellulose ethers may be applied to the surface of the
packaging material in a substantially dry condition.
It is believed that these readily hydrated hydrocolloid materials
have the ability to hydrate so as to form a thin film in situ by
absorption of moisture from the packaged product. Application of
these readily hydrated hydrocolloid materials to the packaging
material may be effected by any suitable method. One such method is
simply dusting of the hydrocolloid material onto the surface of the
packaging material. Another method is to provide a slurry of the
hydrocolloid material in a suitable inert organic carrier, such as
isopropanol or ethanol. The hydrocolloid slurry may then be applied
to the surface of the packaging material and the organic carrier
removed by drying so as to provide a thin, dry layer of the
hydrocolloid material.
The thin, dry film of readily hydrated hydrocolloid material is
subsequently placed in contact with the food product during the
wrapping operation. The thin, dry layer of hydrocolloid material
absorbs moisture from the packaged food product so as to form a
thin substantially continuous hydrocolloid film with improved
release properties.
The hydrocolloid, whether hydrated by heating of a slurry of the
hydrocolloid or whether applied in a substantially dry condition is
applied to the packaging material so as to provide a level of from
about 0.5 to about 5.0 pounds of the hydrocolloid (dry basis) per
ream of packaging material. For purposes of this application a ream
refers to an area of 3,000 square feet. At levels above about 5.0
lbs./ream no substantial additional benefit is derived and the
total cost of the hydrocolloid material used is consequently
greater. However, levels above about 5.0 lbs./ream may sometimes be
used to achieve improved machining and handling properties for the
coated packaging material. While the advantages of the invention
are attained at levels of application within the above indicated
range, higher levels may sometimes be used in commercial practice
of the present invention. Such higher levels are primarily
encountered due to lack of control during application of the
hydrocolloid material with particular commercial application
equipment. Also, variations during application may result in higher
levels of up to about 15 lbs./ream at a particular local point even
when the average level is within the indicated range of about 0.5
to about 5.0 lbs./ream. Local variation in levels of hydrocolloid
present is particularly prevalent when a readily hydrated
hydrocolloid is applied by dusting or by application of a slurry of
the hydrocolloid in an organic carrier. For this reason, it is
preferred that the average level of application of the hydrocolloid
be at the higher end of the indicated range, that is, at a level of
from about 2.0 to about 5.0 lbs./ream. When the average level is
within this preferred range or higher a sufficient margin of error
is established to compensate for local variations due to lack of
control.
The packaging material of the present invention is particularly
suitable for wrapping process cheese and certain details are
hereinafter described with particular reference to process cheese.
However, it should be understood that the packaging material is
equally suitable for wrapping other food products which have a
tendency to stick or adhere to the packaging material. Such food
products include cream cheese, margarine, caramels, or toffee. When
process cheese is being packaged in accordance with the present
invention it is preferred to select a release agent that provides a
dull, translucent film rather than one which provides a glossy,
shiny finish to the packaging material. Particularly preferred
release agents for packaging process cheese are pregelatinized and
nongelatinized starch and carrageenan.
Process cheese in general is made by grinding and mixing together
by heating and stirring one or more cheeses of the same or of two
or more varieties, together with other ingredients, until a
homogeneous plastic mass is formed. American cheddar cheese and
other American-type cheeses such as colby, and also Swiss, gruyere,
brick, limburger and other cheeses are examples of cheeses which
are used in the production of process cheese.
The cheese for each batch is cleaned and cut into uniform size if
the cheese pieces are large. The cheese pieces are then passed
through a grinder into a steamjacketed kettle or a horizontal
cooker. The other ingredients, such as emulsifiers and flavoring
materials, are added either as the cheese is run through the
grinder or while it is being heated. The cheese is heated and is
held at an elevated temperature for at least 30 seconds. When the
cheese is smooth, homogeneous, glossy and creamy it is
automatically packaged into carbons while in a heated fluid
condition. The cartons are lined with a packaging material which
may be sealed to exclude air. The packaged cheese is then cooled to
room temperature and is placed under refrigeration. The high
temperature attained in heating, together with the heat retained
during the time required to cool the cheese to room temperature
makes the cheese practically sterile, and the cheese keeps well and
does not ripen further. However, the cheese tends to adhere to the
packaging material and subsequent removal of the packaging material
is difficult.
Any suitable packaging material which is commonly used for
packaging food products that tend to adhere to the packaging
material may be used in accordance with the present invention. One
such commonly used packaging material for use in packaging cheese
is a cellophane/aluminum foil/fortified wax lamination. Fortified
wax refers to well-known wax-resin blends, wherein the resin is a
polymer selected to provide desired viscosity or body.
The following examples further illustrate various features of the
present invention but are intended to in no way limit the scope of
the invention which is defined in the appended claims.
EXAMPLE I
Dry cornstarch was added at a level of 5.7 weight percent to water
which had been heated to 85.degree. F. The mixture was stirred
vigorously for 5 minutes until the starch was uniformly dispersed
in the water. The starch mixture was then gradually heated over a
period of about 30 minutes to a boil (212.degree. F.) under
conditions of mild agitation. The starch mixture was held at a boil
for 11/2 minutes to fully gelatinize the starch. Heating was then
stopped and the mixture was then cooled rapidly in less than 1
minute to 190.degree. F. and held at that temperature until
used.
The starch mixture was then applied to a web of cellophane/aluminum
foil/fortified wax laminate packaging material. The starch mixture
was applied with a Gravure cylinder and knife combination so as to
provide starch at a level of one pound per ream of packaging
material (dry basis). The coated packaging material was then dried
to provide a thin film of dry starch adjacent to the fortified wax
layer. The packaging material was then cut and folded to provide an
open-mouthed rectangular package with a flap that could
subsequently be folded over to seal the mouth. The package was
folded to place the starch film on the interior surface of the
package. Process cheese was then introduced into the package at a
temperature of 165.degree. F. to provide a 2 pound block of process
cheese. The packages were then sealed.
Process cheese at a temperature of 165.degree. F. was also packaged
in a similar manner into cellophane/aluminum foil/fortified wax
packaging material which had not been treated to provide a thin
film of starch. The packaging material was, however, treated in
accordance with known procedures to prevent blocking of the
packaging material by providing a thin coating of dry, granular,
nongelatinized starch on the fortified wax surface. Such coating of
dry starch is known to prevent blocking of packaging materials. The
coating of dry starch was applied by spraying the fortified wax
surface of the packaging material with a 60 weight percent starch
slurry in alcohol so as to provide a level of 5 pounds of dry
granular starch per ream of packaging material. This packaging
material was then dried, leaving a coating of dry granular starch
on the fortified wax surface. The process cheese which had been
packaged in accordance with the present invention and the process
cheese which had been packaged with a coating of dry granular
starch were compared after various periods of storage at
temperatures of 72.degree. and 45.degree. F. to determine the
release properties. The release properties were visually noted by
observing and rating the amount of cheese which adhered to the
wrapper after a specified period of storage. After each 2 -pound
package of process cheese was unwrapped the condition of the
wrapper was observed and noted according to the following
schedule:
1. Clean (no sign of cheese adherence to the packaging
material)
2. Very slight to clean
3. Very slight
4. Slight
5. Slight to moderate
6 Moderate
7. Moderate to definite
8. Definite (definite signs of cheese adherence to the packaging
material)
The data collected according to the above schedule was used to
prepare the following table: ##SPC1##
The data for the above Table 1 was obtained by unwrapping 16 2
-pound blocks of process cheese at the intervals noted and visually
grading the appearance of each of the packaging materials. The
average of the grades was then recorded in Table 1. As can be seen
from the above grading scale, the lower the average grade the
better the release properties of the packaging material.
It can readily be seen that packaging material treated in
accordance with the present invention to provide a thin film of
release agent material adjacent the surface of the processed cheese
is superior to the known method of applying a dry starch
coating.
EXAMPLE II
A cellophane/aluminum foil/fortified wax packaging material was
coated with a 5.7 weight percent mixture of starch and carrageenan
which had been hydrated in accordance with the method of Example I.
The mixture was applied to the packaging material at a temperature
of 185.degree. F. The ratio of starch to carrageenan was 4 to 1 on
a weight basis. Process cheese was packaged in the packaging
material coated with the starch-carrageenan mixture and was then
compared with the process cheese which had been packaged in
packaging materials which had been coated with dry granular starch
in a manner as heretofore described. The data from the above
investigation was then used to prepare Table 2. ##SPC2##
From the above it can readily be seen that the packaging material
of the present invention which had a hydrated starch-carrageenan
film is superior.
EXAMPLE III
Various other hydrocolloid mixtures were used to coat
cellophane/aluminum foil/fortified wax packaging materials in
accordance with the present invention. Data in connection with the
release properties of these hydrocolloid materials are presented
below in Table 3. ##SPC3##
From the above, it can be seen that various mixtures of
hydrocolloids may be used in the practice of the present invention.
Certain release coating materials are particularly effective in
preventing sticking when the food product is stored at relatively
low temperatures, while others are more suitable for relatively
high-temperature storage, such as at room temperature. A suitable
hydrocolloid or mixture of hydrocolloids for particular conditions
of storage is readily determined by one skilled in the art.
EXAMPLE IV
A cellophane/aluminum foil/fortified wax packaging material was
coated with dry, pregelatinized starch in accordance with the
following procedure. Sixty pounds of pregelatinized starch was
added to 48 pounds of 99 weight percent isopropanol. The
starch-isoproponal mixture was agitated so as to provide a uniform
starch slurry. The starch slurry at a temperature of 70.degree. F.
was applied to the packaging material by means of a Gravure
cylinder. The starch slurry was applied at a rate sufficient to
provide 3 pounds of starch per ream of packaging material (dry
basis). The coated packaging material was then passed through a
10-foot long drying tunnel maintained at a temperature of
200.degree. F. at a rate of 100 feet per minute to evaporate the
isopropanol.
The coated packaging material was then used to package process
cheese. after 90 days storage, the release properties of the
packaging material prepared in accordance with the above procedure
were still excellent.
EXAMPLE V
A cellophane/aluminum foil/fortified wax packaging material was
coated with a mixture of pregelatinized starch and a nonionic water
soluble cellulose ether. One hundred pounds of slurry containing a
mixture of readily hydrated hydrocolloids in an inert organic
carrier was prepared. The slurry contained 5 weight percent of
pregelatinized starch and 8 weight percent of nonionic water
soluble cellulose ether. Isopropanol was used as the inert organic
carrier. The slurry was applied to the packaging material by means
of a Gravure cylinder so as to provide 0.8 pounds of the
hydrocolloid mixture (dry basis) per ream of the packaging
material. The coated packaging material was then passed through a
ten foot long oven at a rate of 100 feet per minute. The oven was
maintained at a temperature of 175.degree. F.
Process cheese was then packaged in the coated packaging material
and the packaged process cheese was stored at a temperature of
45.degree. F. The release properties of the packaging material were
excellent after 90 days storage.
It can be seen that a superior release coating material and method
have been supplied by the present invention.
* * * * *