U.S. patent number 3,645,705 [Application Number 05/016,222] was granted by the patent office on 1972-02-29 for transparent combustible material suitable for candle bodies.
This patent grant is currently assigned to Kolar Laboratories, Inc.. Invention is credited to Aaron Miller, William Siegfried.
United States Patent |
3,645,705 |
Miller , et al. |
February 29, 1972 |
**Please see images for:
( Certificate of Correction ) ** |
TRANSPARENT COMBUSTIBLE MATERIAL SUITABLE FOR CANDLE BODIES
Abstract
A transparent combustible candle body material formed by
combining a straight chain aliphatic amide with light mineral oil
and adding alcohol thereto.
Inventors: |
Miller; Aaron (Niles, IL),
Siegfried; William (Oshkosh, WI) |
Assignee: |
Kolar Laboratories, Inc.
(Chicago, IL)
|
Family
ID: |
25762788 |
Appl.
No.: |
05/016,222 |
Filed: |
March 3, 1970 |
Current U.S.
Class: |
44/275;
431/288 |
Current CPC
Class: |
C11C
5/002 (20130101); C10L 7/02 (20130101) |
Current International
Class: |
C10L
7/00 (20060101); C10L 7/02 (20060101); C11C
5/00 (20060101); C10l 005/00 () |
Field of
Search: |
;44/7.5 ;431/288
;260/404.5 ;424/18 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Dees; C. F.
Claims
The invention is defined by the following claims:
1. A transparent composition of matter suitable for a candle body,
comprising:
A. from about 35 percent to about 85 percent by weight of an oil
which is normally liquid at room temperature chosen from the group
consisting of light mineral oil and natural oils having iodine
values substantially within the range of 40-135;
B. from about 7 percent to about 40 percent by weight of a long
chain polyamide having a molecular weight substantially within the
range of 6,000--9,000 and a softening point substantially within a
range of 185.degree. C. -48.degree. C.;
c. from about 7 percent to about 30 percent weight of alcohol
selected from the group comprising 8- to 12carbon primary
alcohols.
2. The transparent composition of matter of claim 1, further
characterized by:
from about 1 percent to about 15 percent weight of a methyl
ester.
3. The transparent composition of matter of claim 1, further
characterized by:
up to about 5 percent by weight of a stearic fatty acid.
4. The transparent composition of matter of claim 1, further
characterized by:
a small amount of an odor masking agent.
5. The transparent composition of matter of claim 1, further
characterized by:
up to about 5 percent by weight of an oxidation inhibiting
agent.
6. The transparent composition of matter of claim 1, further
characterized by:
up to about 5 percent by weight of an acid from the class
consisting of the dimer and trimer acids.
Description
This invention relates to materials suitable for candle bodies, and
refers more particularly to a transparent material for that
purpose.
From time to time formulations have appeared which are said to
provide candle body materials that are transparent, but no such
formulation heretofore proposed has yielded a candle body material
that was both truly transparent and satisfactory for use as a
candle body. The materials of most such formulations that have
possessed the necessary characteristics for candle bodies have been
merely translucent rather than transparent.
When a candle burns, the heat of its flame melts a small pool of
the candle body material around the base of the exposed portion of
the wick, and this molten material is drawn up through the wick by
capillary attraction, to fuel the flame. Thus the process that
takes place in the burning of a candle imposes rather stringent
functional requirements upon the candle body material.
The material of a candle body must be rigid enough to support
itself and a relatively long wick filament, but it should not be
excessively brittle at low room temperatures. Its melting point is
critical, in that it should liquefy at temperatures to which it can
be raised by radiant heat from the candle flame. If its melting
temperature is too low, the candle will drip or, in an extreme
case, the entire candle body will melt, dropping the wick into a
pool of molten body material with the hazardous possibility that
the surface of the pool will ignite when this happens. If too high
a temperature is required to melt the body material, the flame will
be starved because insufficient fuel will be drawn up through the
wick, with the result that the flame will be too small to maintain
itself. When molten, moreover, the candle body material must have a
relatively low viscosity to insure that it will be capable of being
drawn up through the wick by capillary action.
In addition to meeting these requirements the candle body material
must burn with a flame that is both luminous and smokeless, and
such odors as are produced by its combustion should not be
unpleasant and should preferably be faint.
The functional requirements outlined above have of course been met
by various candle body materials that are well known in the art,
but heretofore no known material that meets these requirements has
been transparent. However, the desire for a transparent candle body
material has long persisted, as indicated by the above-mentioned
prior formulations that were intended to provide such a
material.
The present invention has as its object to provide a candle body
material which possesses all of the necessary functional
characteristics and which, moreover, is truly transparent.
It is also an object of this invention to provide a candle body
material which has the transparency of glass, with no cloudiness or
opacity whatsoever, and which can be colored if desired or can be
left uncolored, so that it can be formed into candles having the
clear, sparkling esthetic qualities of fine glassware.
Another object of this invention is to provide a transparent
material which is in the gel phase and which is combustible with a
luminous, smokeless flame and passes into a low viscosity liquid
phase at temperatures on the order of those near the base of a
flame produced by the combusting material.
From the fact that the material of this invention is in the gel
phase it is at once apparent that it is basically very different
from those heretofore used for candle bodies, which have generally
been crystalline solids. As will also be apparent from the fact
that it is in the gel phase, the material of this invention has a
smooth, highly reflective surface and is readily molded and hence
leads itself well to use for candle bodies.
It is also an object of this invention to provide an oil gel that
has as its base a light mineral oil, an inexpensive nature oil, or
a combination of such oils, and which oil gel has a nongreasy
surface and feel and sufficient rigidity to be self-supporting at
room temperatures.
With these observations and objectives in mind, the manner in which
the invention achieves its purpose will be appreciated from the
following description, which exemplifies the invention, it being
understood that such changes may be made in the precise embodiments
of the invention herein disclosed as come within the scope of the
appended claims.
In general the composition of matter of this invention comprises
light, clear mineral oil and/or a natural oil as the gel base, a
polyamide resin as the gelling agent, and an 8-10-, or 12- carbon
primary alcohol. Without the alcohol, the oil-polyamide gel system
burns with an unsatisfactorily small flame and has a greasy
appearance and feel. The inclusion of alcohol in the formulation
overcomes these deficiencies. Preferably the material also includes
in its composition small percentages of a methyl ester, a fatty
acid and a reducing agent.
Natural oils that have been found satisfactory are: castor oil,
peanut oil, safflower oil, corn oil and cod liver oil. All of them
work well, either as the whole oil constituent of the composition
or when combined with up to an equal amount of mineral oil.
However, except in unusual circumstances, there appears to be no
advantage in utilizing the natural oils, and light, clear mineral
oil is preferred for the whole of the oil content inasmuch as it is
generally cheaper than the natural oils and yields a composition
which is at least as satisfactory in all respects as any containing
a natural oil or natural oils. If a natural oil is to be used, it
should have an iodine value in the range of 40 to 135 and a titre
of 1.degree.- .degree. C. Castor oil is preferred.
The polyamide, which serves to get the oil, can be one of a number
of long chain linear amide resin polymers derived from the reaction
of dimerized linoleic acid with di- or polyamines. Polyamides are
usually used as adhesives, for heat seals and in decorative
coatings and sealants. The polyamides useful for formulating the
composition of this invention are those having molecular weights in
the range of 6,000 to 9,000. These polyamides are capable of
producing a gel structure in oil when the solubility of the
polyamide in the oil is exceeded; although without other additives
the gel thus produced tends to be objectionably greasy or oily and
burns with a poor flame in a candle system. The polyamide that is
preferred is available commercially as a product of General Mills,
sold under the trade name Versamide 940.
The proportion of polyamide in the composition determines its
melting point. With Versamide 940, 7percent by weight appears to be
the lower limit of concentration from an asthetic and functional
standpoint, yielding a gel having a softening point of about
60.degree. C.; while 50 percent appears to be an upper limit of
concentration, producing a gel with a softening point of about
100.degree. C. Most satisfactory candle body materials are obtained
when the polyamide constitutes about 30 percent by weight of the
total composition.
As mentioned above, the addition of an alcohol to the oil-polyamide
gel serves to overcome the objectionable greasy or oily surface
characteristics that the gel would otherwise have, without in any
wise detracting from its appearance. Furthermore, the addition of
the alcohol materially improves the combustion characteristics of
the composition in a candle system. Alcohols of less than eight-
carbon have been found to have too low a flash point for most
candle bodies, in that the candle body material around the wick
tends to catch fire from the candle flame; and such alcohols also
tend to evaporate out of the body material during an extended
period of storage. The preferred alcohols are 8-, 10-, or 12-
carbon primary alcohols, or a combination of one or more of these
with myrystyl alcohol. The percentage of alcohol by weight should
be not less than about 7 percent nor more than about 30 percent of
the total material, the preferred range being 10 percent to 20
percent.
While not necessary to a candle body material that is satisfactory
for most purposes, the inclusion of up to about 15 percent by
weight of a methyl ester has been found to improve the stiffness
and hardness of the material and to limit the oiliness of its
surface. Methyl ricinoleate and methyl oleate are preferred, in an
amount of about 7 percent to 10 percent. Methyl palmitate and
methyl caprylate have also been found satisfactory.
Up to about 5 percent of a fatty acid can be incorporated in the
material to cheapen it, improve its stiffness and improve its
burning characteristics. Stearic acid in an amount of about 2
percent to 5 percent is preferred. Satisfactory results have also
been obtained with 12- hydroxy stearic.
To inhibit discoloration or the development of objectionable odor
during storage, in the case of compositions subject to these
disadvantages, up to about 1 percent of a reducing agent such as
stearic hydrazide or butylated hydroxiditoluene can be
advantageously incorporated in the material.
To inhibit discoloration at the base of the flame of a burning
candle made of the body material of this invention, up to about 5
percent of a dimer or trimer acid can be added to the composition,
the preferred amount being 1 percent to 2 percent, weight.
Specific dimer and trimer acids found to be useful are produced by
the polymerization at midmolecule of two or more unsaturated
monobasic acids of 18 carbon atom chain lengths. These are sold
under the trade name "Empol" by Emory Industries. "Empol 1010" has
been found very satisfactory in practice. The dimer or trimer acid
may be substituted in whole or in part for the aforesaid reducing
agent, inasmuch as it has the further advantage of inhibiting
discoloration or the development of objectionable odor of the body
material during storage.
The inclusion in the composition of certain alcohols that produce
otherwise desirable properties may result in a material that burns
with an acrid or pungent odor. In such cases a small amount of an
odor masking agent can be incorporated in the composition. The
material sold by Fritzsche, Dodge and Olcott as its No. 41984 has
been found satisfactory when incorporated in the composition in
amounts up to about 0.2 percent by weight. The odor-masking agent
is desirable when less expensive alcohols are used and may be
unnecessary if the alcohols are highly refined, but from the
standpoint of cost, the use of the cheaper alcohols and an
odor-masking is indicated and produces satisfactory results. If
desired, a small amount of perfume can be added to the composition
to complete the odor-masking effect.
A composition found to have very desirable properties as a candle
body material is the following:
polyamide (Versamid 940 ) 30% Stearic acid 5% Methyl 12 -hydroxy
stearate 5% 10 -carbon primary alcohol 5% (Continental Oil Co.
Alfol. 10) Myrystyl (Shell Chemical Co. 10% Neodol 25) Empol 1010
2% Stearic hydrazide 0.1% Odor masking agent (Fritzsche, 0.2% Dodge
& Olcott 41984 ) Light while mineral oil q.s. 100%
All of the materials except the polyamide are mixed at room
temperature. This mixture is then heated gradually, with gradual
addition of the polyamide, and with agitation beginning with
commencement of the addition of the polyamide. In the proportion
required, the polyamide does not become fully soluble until the
mixture reaches a temperature of about 220.degree. F. A temperature
on the order of 220.degree. F. to 230.degree. F. is maintained,
with continuous agitation, until the polyamide is fully dissolved.
Since higher temperatures promote solution of the polyamide, this
temperature range can be slightly exceeded with some advantage, but
care must be exercised in going to temperatures above this range
because the alcohol tends to boil off the cause discoloration.
As soon as the polymide has dissolved completely, the mixture can
be poured into molds, following the conventional practice in the
manufacture of molded candles. As it cools, it of course hardens.
As a rule no difficulty is experienced in freeing the candles from
the molds, but, as with other gels, release of the product from a
mold can be facilitated by briefly heating the mold to soften the
surface of the material that is in contact with the mold.
Irregularities in the surface of a molded candle can be corrected
by the application of sufficient heat to soften the gel, or in the
event of a complete molding failure the entire body can be reheated
to flowable condition and remolded.
The material of this invention leads itself well to coloring by
means of conventional dyes. If no color is added to it, it has the
transparency of glass with a slightly yellow cast.
From the foregoing description it will be apparent that the
invention provides a transparent combustible material that is in
the gel phase and which is in all respects suitable for candle
bodies.
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