U.S. patent number 3,644,181 [Application Number 04/844,323] was granted by the patent office on 1972-02-22 for localized electroplating method.
This patent grant is currently assigned to Sylvania Electric Products Inc.. Invention is credited to John G. Donaldson.
United States Patent |
3,644,181 |
Donaldson |
February 22, 1972 |
LOCALIZED ELECTROPLATING METHOD
Abstract
An improved electroplating process is disclosed wherein a metal
is deposited in the form of a predetermined pattern upon a
continuously advancing strip of electrically conductive substrate.
The process involves providing a potential difference between an
anode and a cathode wherein the cathode is the strip of
electrically conductive substrate, and the current density at the
cathode is at least about 300 amperes per square foot per feet per
minute of the advance of the cathode, and circulating an
electroplating solution containing the metal to be deposited
between the anode and the cathode at a velocity of at least 6.5
ft./sec. at the cathode. In addition, an apparatus is disclosed
that comprises a means of continuously advancing the strip of
electrically conductive substrate past at least one electroplating
station that comprises a housing having one face adapted for
contact with the strip, an anode recessed in the housing, a channel
having specific dimensions and connecting the anode and the strip
and a pair of passages at opposite ends of the channel that are in
close proximity to the channel, the passages have one end
terminating at the face that is in contact with the strip and the
other end terminating at a face other than the one that is not
adapted for contact with said strip and a container for an
electroplating solution and a means for circulating the
electroplating solution through the electroplating station and a
means for receiving the electroplated strip.
Inventors: |
Donaldson; John G. (Warren,
PA) |
Assignee: |
Sylvania Electric Products Inc.
(N/A)
|
Family
ID: |
25292388 |
Appl.
No.: |
04/844,323 |
Filed: |
July 24, 1969 |
Current U.S.
Class: |
205/118; 204/206;
204/224R; 205/263; 204/211; 205/138; 205/266 |
Current CPC
Class: |
C25D
7/0671 (20130101); C25D 5/02 (20130101) |
Current International
Class: |
C25D
7/06 (20060101); C25D 5/02 (20060101); C23b
005/48 (); C23b 005/58 (); B01k 003/00 () |
Field of
Search: |
;204/15,28,211,46,206 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
|
|
|
|
|
|
|
760,016 |
|
Oct 1956 |
|
GB |
|
1,098,182 |
|
Jan 1968 |
|
GB |
|
Other References
Precious Metal Electrodeposits for Electrical Contact Service
Raymond Vines Plating Aug. 1967 pp. 923-925..
|
Primary Examiner: Mack; John H.
Assistant Examiner: Tufariello; T.
Claims
While there has been shown and described what are at present
considered the preferred embodiments of the invention, it will be
obvious to those skilled in the art that various changes and
modifications may be made therein without departing from the scope
of the invention as defined by the appended claims.
1. In a process for electroplating a metal pattern upon a portion
of one side of a continuously advancing, electrically conductive
substrate, the improvement comprising:
a. providing a potential difference between an anode and a cathode
of a strip of continuously advancing electrically conductive
material;
b. maintaining a current density at said cathode of at least about
300 amperes per square foot per foot per minute of advance of the
strip; and
c. circulating an electroplating solution containing the metal to
be deposited between said anode and the portion of said cathode to
be electroplated at a velocity of at least 6.8 ft. per second.
2. A process according to claim 1 wherein silver is the metal
deposited.
3. A process according to claim 2 wherein the rate of advance of
said metal strip is from about 0.5 ft./min. to about 8.0
ft./min.
4. A process according to claim 3 wherein the rate of advance is
from about 1 ft./min. to about 3 ft./min. and the current density
is at least about 375 amperes per square ft. per ft./min. of
advance and the velocity of said electroplating solution is from
about 6.8 to about 10 ft. per second past the cathode.
5. A process according to claim 1 wherein gold is the metal
deposited.
6. A process according to claim 5 wherein the rate of advance of
said metal strip is from about 0.5 ft./min. to about 8.0
ft./min.
7. A process according to claim 6 wherein the rate of advance is
from about 1 to about 5 ft./min. and the current density is from at
least about 350 amperes per square foot per ft./min. of advance and
the velocity of said electroplating solution is from about 6.8 to
about 10 ft. per second past the cathode.
Description
BACKGROUND OF THE INVENTION
This invention relates to a process and equipment useful in
electroplating a metal upon a continuous strip of electrically
conductive material. More particularly it relates to an improved
process and equipment that will continuously selectively
electroplate a metal upon the strip of electrically conductive
substrate in a desired pattern.
In the manufacture of various material, notably in the manufacture
of parts useful in the electronic industry, it is often desirable
to have a particular pattern of a metal deposited upon a base of
electrically conductive material generally metallic. The substrate
is often a long continuous metal strip that can be formed in a
particular fashion to have perforations in a particular manner, or
can be a solid continuous strip of material. It is often desirable
to have a pattern of a different or similar metal deposited in a
pattern upon the strip, as for example, a stripe of metal deposit
extending the length of the strip but covering only a narrow width
of the total metal strip. The methods heretofore used have several
disadvantages. For example, one method employed a rotating wheel
that contained a reservoir of electroplating solution that rotated
in the same direction and the same speed as the continuously
advancing strip. The electroplating solution is applied to the
metal strip via ports in the wheel and an anode is immersed in the
solution and the advancing strip serves as a cathode. While the
pattern that is formed is suitable for some purposes, the method
outlined above has some serious disadvantages. For example, close
uniform contact between the rotating wheel and the advancing strip
of metal is hard to maintain. The result is that a uniform pattern
is not achieved, that is, the pattern can vary in thickness and in
width. As can be appreciated, uniformity is desired from both a
functional and economic standpoint.
Other methods that have been tried but have serious disadvantages,
include depositing the metal or solution over a larger pattern than
desired then removing the undesired portion of the pattern. The
removal can be done in a variety of ways, however, in practice a
nonuniform pattern has been achieved, or adherence is poor or
production rates are low. In many instances, mechanical damage to
the base material can occur. These deficiencies are caused by a
number of reasons. For example, often the electroplating solution
is applied at one station, excess portion removed at another
station and electroplated at a third station. Application, removal
or electroplating steps can each effect the finished product.
It is an object of this invention to provide an improved process
for electroplating a predetermined pattern of a metal upon an
electrically conductive substrate.
It is a further object of this invention to provide apparatus for
conducting an improved electroplating process.
It is still a further object of this invention to provide an
improved electroplating station.
It is an additional object of this invention to provide an
apparatus that can be used to deposit a uniform pattern upon a
continuously advancing strip of electrically conductive
substrate.
It is a further object of this invention to provide an apparatus
that can be used upon substrates that are either solid or
perforated.
SUMMARY OF THE INVENTION
In accordance with one aspect of this invention, there is provided
a process comprising (a) providing a potential difference between
an anode and a cathode that is a continuously advancing strip of
electrically conductive material and the current density at said
cathode is at least about 300 amperes per square foot per feet per
minute of advance of the strip or cathode, and (b) circulating an
electroplating solution containing the metal to be deposited
between said anode and said cathode at a velocity of at least about
6.5 feet per second at the cathode. In accordance with another
aspect of this invention there is provided an apparatus for
continuously depositing a relatively uniform metal pattern upon a
strip of electrically conductive material, said apparatus
comprising (a) means for continuously advancing a strip of
electrically conductive material, (b) at least one electroplating
station that comprises a housing of an electrically insulative
material, one face of the housing being in contact with the strip
of material, an anode recessed in the housing, a channel connecting
the anode and the strip, the width of the channel being
approximately equal to the width of the desired pattern and the
length of the channel preferably being approximately equal to the
length of the anode, and a first and second passage for the
electroplating solution at opposite ends of the channel, one end of
each passage terminating in close proximity to the corresponding
ends of the channel and the other end of each passage terminating
at one of the faces that is not the face that is in contact with
the strip, (c) a container for an electroplating solution, (d)
means for circulating the electroplating solution from the
container and to the following elements in series, the first
passage, the channel and the second passage and (e) means for
receiving the electroplated strip after it has past the
electroplating station.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is an elevational view of the apparatus with parts in
section;
FIG. 2 is a cross-sectional view of the electroplating station
taken along the line 2--2 of FIG. 1;
FIG. 3 is a cross-sectional view of an alternate embodiment of an
electroplating station for use in electroplating a solid strip of
electrically conductive material;
FIG. 4 shows a segment of a preformed strip that has been processed
by this invention; and
FIG. 5 shows a segment of a solid strip that has been processed by
this invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
For a better understanding of the present invention, together with
other and further objects, advantages and capabilities thereof,
reference is made to the following disclosure and appended claims
in connection with the above description of some of the aspects of
this invention and the above-described drawings.
An improved selective electroplating process upon a continuously
advancing strip of electrically conductive material is achieved by
maintaining a relatively high current density at the cathode (the
strip) in relationship to the speed of travel of the strip and by
maintaining a relatively high velocity of the electroplating
solutions past the cathode.
In the process of this invention an electroplating solution is
circulated at a relatively high velocity between a cathode and an
anode. The volume between the anode and cathode is kept at a
minimum. The current density at the cathode is thereby maximized
for a given potential. It is to be noted that the volume between
the cathode and anode is reduced from that generally employed and
the current density for a given potential is thereby increased. In
many instances, however, it is necessary for practical design
reasons to keep the volume at a level to keep the pressure drop in
the electroplating solution circulation system at a reasonable
level.
The cathode used is the continuously advancing electrically
conductive strip upon which a pattern of metal is to be deposited.
In general, the process can be employed to electroplate any
electrically conductive material. Such materials suitable for
substrates are known in the art. Materials that have heretofore
been electroplated and are satisfactory cathode materials include
stainless steels, copper, nickel, various alloys, metallic coated
plastics and the like.
The anodes are, in general, the nonconsumable type, that is the
anode does not furnish the metal to be coated. Selection of the
material for the anode will be dependent upon the metal that is
being deposited on the strip of material and are known to those
skilled in the electroplating art. The shape of the anode will
depend upon several factors, such as the width of the pattern, the
length of the channel connecting the anode and cathode and other
features of the particular production unit desired.
A relatively high current density is used. Current densities above
about 300 amperes per square foot (a.s.f.) per foot per minute of
advance of the strip of material are used. It is preferred to
employ a current density of from at least about 375 a.s.f. per
ft./min. of advance of the strip of material when silver is being
deposited and at least about 350 a.s.f. per ft./min. of advance of
the strip of material when gold is being deposited from the
commercially available gold and silver electroplating solutions.
Although higher current density can be used, it will seldom be
necessary to exceed about 1,000 a.s.f. per ft./min. of advance of
the strip.
The electroplating solution is kept at a relatively high velocity
past the cathode, that is a velocity of at least about 6.5 ft./sec.
is maintained. Generally velocities from about 6.8 to about 10
ft./sec. are employed. Lower velocities result in nonuniform
deposits and low production rates. Higher velocities can be used
but no additional beneficial results are achieved, thus increased
power costs result.
It is preferred to have the flow of electroplating solution in an
opposite direction or countercurrent to the direction of movement
of the continuously advancing strip of material. In this manner the
desired velocities of the electroplating solution can be achieved
at less power costs and somewhat better uniformity and adherence is
achieved.
The electroplating solutions that are useful in the process of this
invention are known in the art. For example, gold patterns are
deposited from an electroplating solution containing a gold
concentration of about 8 to 10 ounces per gallon, generally in the
form of basic aqueous solution of potassium gold cyanide. An
example of a suitable gold plating solution is sold by the Sel-Rex
Corporation under the trade name "Temperex." A suitable silver
aqueous electroplating solution comprises about 25 to about 30
ounces per gallon of silver, about 9 to about 12 ounces per gallon
of potassium cyanide and about 2 to about 4 ounces per gallon of
potassium hydroxide. Any metal, such as nickel, tin and the like,
that is generally deposited upon a base metal via electroplating,
can be deposited in the process of this invention.
As was previously mentioned, the current density used is dependent
upon the rate of advance of the strip of material past the
electroplating station. For example, when depositing silver upon a
base metal strip of material when the strip of material is
traveling at about 0.5 ft./min., the preferred current density is
about 200 a.s.f. and at 1.0 ft./min. the preferred current density
is about 400 a.s.f. Although in general the speed of travel of the
strip of material can be increased to any level as long as there is
a corresponding increase in current density to maintain the
before-mentioned relationship of the variable, for practical
mechanical reasons the speed of advance is kept below about 8
ft./min. and generally at about 5 ft./min. In most instances it
will be desired to have the strip of material advancing at a rate
of at least above about 0.5 ft./min. Thus the current density will
be kept within the corresponding level.
Although a single electroplating station can be used in many
instances, multiple stations can be used either in series or in
parallel. If a relatively thick pattern is desired, then stations
can be used in series. If parallel patterns are desired, stations
can be used in parallel. Additionally, both sides of a strip of
material can be electroplated by the use of two electroplating
stations.
With particular reference to FIG. 1, there is shown an
electroplating apparatus. An electroplating solution is stored in
the container 10. It is circulated to the electroplating station 12
that comprises a housing 14 having an anode 16 recessed from the
face 18 that is in contact with the continuously advancing strip of
material 20 of the electrically conductive material that serves as
the cathode. The electroplating solution flows from the
solution-circulating means 22 to a first passage 24 in the housing
14. The solution then flows through a channel 26 that connects the
anode 16 and the strip of material 20. The solution is kept at a
velocity of at least 6.5 ft./sec. past the strip or cathode 20. The
electroplating solution exits from another face 27 of the
electroplating station 12 via second passage 28 and returns to the
storage container 10. The strip of material 20 is advanced past the
electroplating station 12 by the advancing means 29. Contact
between the strip of material 20 and the electroplating station 12
is maintained by the guide means 30 and by the plate 31. The
electroplated strip after being electroplated by the station 12 is
received by the receiving means 32.
With particular reference to FIG. 2, there is shown a cross section
of the electroplating station 12 taken along line 2--2 of FIG. 1.
The width of the channel 26 is essentially the same width as the
pattern that is desired on the strip of material 20.
With particular reference to FIG. 3 there is shown an
electroplating station 12 that is adapted for use in electroplating
a solid strip 33. The station is essentially the same as that
described in reference to FIG. 1 with the exception that there is
not provided a plate and the shape of the face is slightly
curved.
In FIG. 4 and FIG. 5 there is shown two types of electrically
conductive strips that can be produced by this invention. With
particular reference to FIG. 4 there is shown a preformed
electrically conductive strip 34 and a pattern 35 in the form of a
stripe is deposited on the preformed strip 34. The width of the
stripe 35 is approximately equal to the width of the channel 26
(shown in FIG. 2). With particular reference to FIG. 5 there is
shown a solid electrically conductive strip 36 upon which a pattern
38 has been deposited.
In order to more fully illustrate the invention, the following
detailed examples are presented. All parts, percentages and
proportions are by weight unless otherwise indicated.
EXAMPLE I
A nickel strip about 1.15 inches wide, is advanced past an
electroplating station at the rate of about 2 feet per minute. An
aqueous silver electroplating solution containing about 20 ounces
per gallon of silver and with a cyanide content of about 21 ounces
per gallon at a temperature of about 180.degree. F., is circulated
to the electroplating station. The solution is circulated at a
sufficient velocity of about 8 ft./sec. past the strip that serves
as the cathode. The current density at the cathode is about 800
amperes per square foot with a rate of strip advance of about 2
ft./min. A stripe of silver of about 0.14 inch wide and about
0.000250 inch thick is deposited in a uniform pattern.
Samples of the strip containing the deposited pattern are placed
upon a hotplate at 900.degree. F. to determine if any blistering
will occur. Samples are additionally subjected to a 90.degree. bend
test to determine the adherence of the deposit. On samples produced
and tested in the above manner no blistering or flaking of deposit
is observed.
Similar runs are made using the following rates of advance and
current densities with equally satisfactory results:
Current density Speed of advance Thickness of deposit (ft./min.)
(millionths of an inch)
__________________________________________________________________________
0.5 200 250 1.0 400 250 1.5 600 250 3.0 1200 250
__________________________________________________________________________
EXAMPLE II
Following the procedure as given in Example I, except that a gold
electroplating solution is used in place of the silver
electroplating solution and the strip is advanced at a rate of
about 2 feet per minute and a current density of about 750 amperes
per square foot is used. The solution is circulated at about 8
ft./sec. A uniform deposit of about 0.00020 inch is achieved.
Samples of the strip, when subjected to the blister and bend tests
as in Example I, showed no blistering or flaking.
* * * * *