U.S. patent number 3,644,167 [Application Number 04/841,578] was granted by the patent office on 1972-02-22 for preparation of corrugating linerboard.
This patent grant is currently assigned to Georgia-Pacific Corporation. Invention is credited to Warren E. Mowry.
United States Patent |
3,644,167 |
Mowry |
February 22, 1972 |
PREPARATION OF CORRUGATING LINERBOARD
Abstract
A corrugating linerboard is prepared from a paperboard made from
waste paper fiber by surface sizing the paperboard with an aqueous
solution of 5 to 30 weight percent solids concentration of an
alkali metal borate treated mixture of lignosulfonate and starch.
The starch is present in the mixture in an amount of from 15 to 25
weight percent of the lignosulfonate solids and the mixture is
treated with the alkali metal borate in an amount of from 1 to 5
weight percent of the lignosulfonate solids.
Inventors: |
Mowry; Warren E. (Bellingham,
WA) |
Assignee: |
Georgia-Pacific Corporation
(Portland, OR)
|
Family
ID: |
25285224 |
Appl.
No.: |
04/841,578 |
Filed: |
July 14, 1969 |
Current U.S.
Class: |
428/182; 156/208;
156/318; 156/328; 427/372.2 |
Current CPC
Class: |
D21H
17/23 (20130101); Y10T 428/24694 (20150115); Y10T
156/1021 (20150115) |
Current International
Class: |
D21H
17/00 (20060101); D21H 17/23 (20060101); D21h
001/04 (); D21h 003/28 () |
Field of
Search: |
;117/156,157,158
;156/307,327,328,332,336,318 ;161/137,238,246,266,125,268
;162/163,175,181A |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Martin; William D.
Assistant Examiner: Lusignan; M. R.
Claims
I claim:
1. In a process for the preparation of a corrugating linerboard
wherein the board is made from an aqueous slurry of cellulosic
fibers obtained substantially from waste paper, the improvement
which comprises applying to the substantially dry linerboard an
aqueous solution consisting essentially of from 5 to 30 weight
percent solids concentration of an alkali metal borate treated
mixture of lignosulfonate and starch, and drying the treated
linerboard, said starch being present in an amount of from 15 to 25
weight percent of the lignosulfonate solids, and said mixture being
treated with the alkali metal borate in an amount of from 1 to 5
weight percent of the lignosulfonate solids.
2. A process according to claim 1 wherein the lignosulfonate is a
spent sulfite liquor.
3. A process according to claim 2 wherein the aqueous solution of
the mixture has a concentration of from 15 to 20 weight percent
solids and is applied to the board in an amount such that the
solids content of the solution applied is in a range of from 0.1 to
3 weight percent of the dry weight of the cellulosic fiber in the
sheet.
4. In a process for the preparation of a corrugated board, wherein
a linerboard made from substantially waste paper pulp is attached
to the fluted papersheet, the improvement which comprises applying
to the surface of the substantially dry linerboard an aqueous
solution consisting essentially of from 5 to 30 weight percent
solids concentration of an alkali metal borate treated mixture of
lignosulfonate and starch, said starch being present in the mixture
in an amount of from 15 to 25 weight percent of the lignosulfonate
solids, and said mixture being treated with the alkali metal borate
in an amount of from 1 to 5 weight percent of the lignosulfonate
solids, drying the so-treated linerboard, and forming the
corrugated board by bonding the corrugated papersheet to the
treated surface of the linerboard.
5. A process according to claim 4 wherein the aqueous solution of
the mixture has a concentration of from 15 to 20 weight percent
solids and is applied to the linerboard in an amount such that the
solids content of the solution applied is in the range of from 0.1
to 3 weight percent of the dry weight of the cellulosic fiber in
the linerboard.
6. A process according to claim 5 wherein the lignosulfonate is a
calcium base spent sulfite liquor.
7. A linerboard obtained by the process of claim 1.
8. A linerboard obtained by the process of claim 2.
9. A corrugated board obtained according to the process of claim
4.
10. A corrugated board obtained according to the process of claim
6.
Description
A relatively large amount of waste paper and other low-quality
cellulosic fiber is available and is repulped and used in the
preparation of low-grade paper products. Only limited use has been
made of the reprocessed waste paper available in the preparation of
paperboard and paper sheet from which a large segment of higher
grade paper products such as containers and other packaging
materials is made. While the paperboard and paper sheet made from
waste paper pulp may meet many requirements such as tensile
strength, stiffness, printability, and appearance required for the
higher grade uses, these materials have found limited acceptance in
these areas mainly due to the difficulties encountered in the use
of these products in high-speed machines. The high speeds desired
for increased production cannot be maintained unless the products
have a high degree of uniformity and the proper working properties
such as gluability, porosity, moisture retention characteristics,
and others. These properties and characteristics of the paperboard
and paper sheet become more critical with increased speeds. For
example, in the manufacture of corrugated paperboard, high-speed
machinery is employed which performs the complete operation of
moisture conditioning the linerboards and corrugating medium,
fluting the corrugated medium, and bonding it to the linerboards at
speeds in the range of 200-600 feet per minute. When a linerboard
made from waste paper is used, the corrugating machine has to be
operated at the lower speeds reducing the production capacity of
the machine.
Various surface sizings, sizings, and fillers have been proposed
for treatment of paper and paperboard. Most of the materials are
not suitable for the treatment of linerboard made from waste paper
to improve the high-speed machine operation. In addition to cost,
many of the coatings, while materially changing the properties of
the board, may have little effect upon the operability of the board
in the machine operation. For example, a surface treatment of the
paperboard with starch may substantially decrease the porosity and
improve the surface uniformity but will have only a limited
influence upon the speed that it may be used in a corrugating
machine. Spent sulfite liquor or lignosulfonates, and salts
thereof, have been suggested for coating and surface sizing of
paper to stiffen the paper or to improve the flexural strength.
However, such treatments of paperboard made from waste paper will
likewise have only a limited effect upon the paperboard with
respect to speed of its use in a corrugating machine.
Therefore, it is an object of this invention to provide a process
for the preparation of a linerboard made from pulp slurries
substantially of waste paper having properties which would permit
it to be used in high-speed machine operation. A further object is
to provide a process for treatment of paperboard and paper sheet to
enhance the properties of the products to permit their use in
high-speed machine operations. A still further object is to provide
a corrugating linerboard made from substantially waste paper
pulps.
The above and other objects are attained according to this
invention by applying to the substantially dry paper sheet made
from waste paper pulp an aqueous solution containing from 5 to 30
weight percent concentration of a borate treated mixture of
lignosulfonate and starch. The starch is present in the mixture in
an amount of from 15 to 25 weight percent of the lignosulfonate
solids and the mixture is treated with the alkali metal borate in
an amount, on a water of hydration free basis, of from 1 to 5
weight percent of the lignosulfonate solids. The aqueous solution
is applied to the substantially dry paperboard in an amount such
that the solids content of the solution applied is from 0.1 to 3
weight percent, preferably from 0.5 to 1.5 weight percent of the
dry weight of the cellulosic fiber or pulp.
While the film or coating on the so-treated surface of the paper
sheet is hygroscopic and may increase the moisture absorption and
retention of the sheet upon long exposure to high levels of
moisture, the so-treated surface is not materially affected by
variations in moisture on contacts of short duration. Thus, the
paper maintains a more uniform distribution and retention of
moisture which alleviates many of the difficulties encountered in
high-speed operations, especially in operations involving changes
in moisture content, such as that obtained in corrugated paperboard
manufacture. The treatment also imparts a more uniform surface to
the paperboard which likewise improves high-speed operations.
The lignosulfonates used in the preparation of the surface-size may
be obtained by sulfonation, by the various known methods, of lignin
obtained from any source. Lignin is a polymeric substance of
substituted aromatics found in plant and vegetable tissue
associated with cellulose and other plant constituents. Thus,
vegetable and plant tissue are lignin-containing materials which
are the principal sources of lignin.
One of the main sources of lignosulfonate is the residual pulping
liquors from the pulp and paper industry where lignocellulosic
materials, such as wood, straw, corn stalks, bagasse, and the like,
are processed to separate the cellulose or pulp from the lignin. In
the sulfite pulping process, the lignocellulosic material is
digested with a sulfite or bisulfite to obtain a sulfonated
residual pulping liquor commonly referred to as "spent sulfite
liquor" in which the sulfonated lignin is dissolved. In other
pulping processes, the residual pulping liquor as obtained from the
process may not be a sulfonated product. However, the residual
liquors or products containing the lignin portion of the
lignocellulosic materials from the other processes and also from
the sulfite process may be treated by the various known methods to
sulfonate the product to the degree desired. For example, the
residual liquor obtained from alkali pulping processes such as
kraft, soda, and others may be sulfonated and used.
The lignosulfonate product obtained from the sulfite pulping
process or by sulfonation of other residual pulping liquors or
lignin-containing material may contain other constituents besides
sulfonated lignin. For example, spent sulfite liquor may contain
from 60 to 70 percent sulfonated lignin with the remainder of the
solids being carbohydrates, degradation products of carbohydrates,
and resinous materials as well as other organic and inorganic
compounds. While all or part of these materials may be removed, it
is not necessary to do so. The liquor may be fermented to remove
the carbohydrates or fractionated by dialysis, solvent extraction,
or other means used to obtain not only a substantially purified
lignosulfonate product but a product of a particular molecular
weight range.
Thus, the terms "lignosulfonate" or "lignosulfonates" as used
herein, as commonly used, include the purified sulfonated lignins
as well as the unpurified sulfonated lignin products such as spent
sulfite liquor and sulfonated residual pulping liquors.
The starch ingredient in the surface-size composition is generally
a modified starch commonly used in surface sizing of paper. The
starch may be a cornstarch or other starches such as tapioca,
potato, sorghum, wheat, and the like. These starches are generally
chemically modified such as by oxidation, hydroxyethylation, or
enzyme conversion to have products which would give aqueous
solutions having lower viscosities simplifying the application to
the paper sheet or paperboard. The starch is used in amounts of
from 15 to 25 percent of the lignosulfonate solids. This amount of
starch gives sufficient penetration of the lignosulfonate-starch
solution, and the film or coating obtained on the surface of the
sheet, while hydrophilic, is sufficiently resistant to moisture to
permit the paper to be stored and handled under normal atmospheric
conditions without becoming tacky.
In the preparation of the lignosulfonate-starch solution, the
starch is generally intermixed with water at a temperature in the
range of 85.degree. to 120.degree. C. to swell the starch prior to
intermixing it with the lignosulfonate. The alkali metal borate is
most conveniently added to the mixture of lignosulfonate and starch
but may be added at any point. After the addition of the borate,
the pH of the solution is adjusted to a pH in the range of 7 to 10
with an alkali metal hydroxide such as sodium or potassium
hydroxide. The mixture treated with the borate has a good pot life
and is not corrosive to the application equipment. Borax, which is
most readily available, is usually used.
The various known methods used for the surface sizing or coating of
paper may be used for the application of the lignosulfonate-starch
mixture to the sheet. Calender sizing may be conveniently used. The
lignosulfonate-starch mixture may be applied at a point in the
drier roll assembly sufficiently back from the end to obtain the
desired moisture content in the product upon leaving the drier
assembly. The concentration of the solution is generally maintained
in the range of from 5 to 30 weight percent of the total solids
content, preferably 15 to 20 percent solids. The solution at the
above concentrations has the proper consistency to be readily
applicable to the surface in the amounts normally used, in the
range of from 0.1 to 3 weight percent of the lignosulfonate-starch
solution solids, based upon the dry paper stock or material. The
amount of the solution applied varies to a certain extent upon the
porosity and other properties of the particular cellulosic material
or stock used. Generally, the solution is applied in amounts such
that the solution solids are in the range of from 0.5 to 1.5
percent of the paper sheet or paperboard on a dry basis. When
expressed on the basis of surface area, the amount will vary from
about 0.1 to 1.5 pounds of the solids content of the solution per
thousand square feet. In the preferred range, the amount used is
generally in the range of 0.25 to 0.5 pounds per thousand square
feet.
To further illustrate the invention, a corrugating machine using a
linerboard made on a cylinder machine from waste paper had to be
operated at speeds of around 170 feet per minute in the preparation
of corrugated board with B flutes. At higher speeds, the edges of
the board became wet resulting in lack of adhesion and formation of
the board in these areas. Apparently, the moisture vaporizing in
the corrugating machine flowed to the edges or the coolest portion
of the machine and condensed at these points resulting in the wet
streaking. With the board treated with the lignosulfonate-starch
solution, the difficulty was avoided and the machine was operated
at a speed of around 300 feet per minute.
The paperboard used as the linerboard had a weight of about 85
pounds per thousand square feet and was made predominantly from old
corrugated boxes with about 5 percent being bags, and 8 percent
newspaper and other mixed waste.
The lignosulfonate-starch solution with which the board was treated
was prepared by intermixing 12 pounds of modified starch with 50
gallons of water and heating the mixture at about 95.degree. C. for
about 20 minutes until the starch had swelled. Dry fermented
calcium base spent sulfite liquor solids were added to the swelled
starch solution in an amount of 75 pounds. Borax (sodium
tetraborate hydrate) was then added in an amount of 4 pounds and
the pH adjusted to a pH in the range of 8 to 9 by the addition of
sodium hydroxide. The above solution was applied to the bottom
surface of the board in the calender stack on roll 2 of a 7-roll
drier. The amount applied was about 0.5 weight percent of the cry
paper fiber or at a rate of about 10 pounds of the
lignosulfonate-starch solution solids per ton of paper. No
difficulty in the application was encountered and the rolls were
operated without any evidence of corrosion or pitting of the
calender stack or equipment.
When the board is coated with a starch solution in the calender
rolls instead of the lignosulfonate-starch solution as above, the
corrugating machine had to be operated at a speed of about 200 feet
per minute. With the starch surface treatment, proper bonding
between the linerboard and the medium could not be obtained at
higher speeds.
Likewise, the treatment of a linerboard with a calcium base spent
sulfite liquor in an amount of 0.5 or 10 pounds of spent sulfite
liquor solids per ton of paperboard has only a limited effect upon
the corrugating operation. The corrugating machine could be
operated up to about 200 feet per minute. At higher speeds, wet
streaks at the edges of the board were obtained which were similar
to that obtained with the linerboard with no surface treatment.
* * * * *