U.S. patent number 3,642,531 [Application Number 04/880,813] was granted by the patent office on 1972-02-15 for water based fire protective composition applied to electrical cable.
This patent grant is currently assigned to Dyna-Therm Corporation. Invention is credited to Roger L. Peterson.
United States Patent |
3,642,531 |
Peterson |
February 15, 1972 |
WATER BASED FIRE PROTECTIVE COMPOSITION APPLIED TO ELECTRICAL
CABLE
Abstract
A self-extinguishing fire protective composition and cables
coated with such composition are disclosed. The composition
includes a water based resinous emulsion, a chlorinated hydrocarbon
and inorganic noncombustible fibers.
Inventors: |
Peterson; Roger L. (Los
Angeles, CA) |
Assignee: |
Dyna-Therm Corporation (Los
Angeles, CA)
|
Family
ID: |
25377160 |
Appl.
No.: |
04/880,813 |
Filed: |
November 28, 1969 |
Current U.S.
Class: |
428/382; 428/444;
428/383; 428/921 |
Current CPC
Class: |
H01B
7/295 (20130101); C08K 13/04 (20130101); H01B
3/448 (20130101); Y10T 428/31656 (20150401); Y10T
428/2947 (20150115); Y10S 428/921 (20130101); Y10T
428/2945 (20150115) |
Current International
Class: |
H01B
3/44 (20060101); H01B 7/17 (20060101); C08K
13/00 (20060101); C08K 13/04 (20060101); H01B
7/295 (20060101); B44d 001/16 (); B44d 001/18 ();
C09k 003/28 () |
Field of
Search: |
;117/27,75,128.4,128.7,136,137,218,232,233
;260/29.6XA,29.6S,33.8UA,41R,41B,41AG |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
|
|
|
|
|
|
|
791,803 |
|
Mar 1958 |
|
GB |
|
880,198 |
|
Oct 1961 |
|
GB |
|
Primary Examiner: Martin; William D.
Assistant Examiner: Speer; Raymond M.
Claims
I claim:
1. An electrical cable comprising a metal core, a layer of
insulation surrounding said core, and a self-extinguishing fire
protective coating about said layer of insulation, said coating
being the dried residue of an aqueous emulsion and comprising from
about 6 to about 30 weight percent of water emulsified resin
solids, about 1.5 to about 20 weight percent of a chlorinated
hydrocarbon, and about 7.5 to about 75 weight percent of inorganic
noncombustible fibers.
2. The cable of claim 1 in which said water emulsified resin is
polyvinyl acetate.
3. The cable of claim 1 in which said inorganic fibers include,
based on the total weight of the fibers, about 20 to about 80
weight percent of relatively short fibers having a maximum length
of approximately one thirty-seconds inch with the remainder of said
fibers having a maximum length of about one-half inch.
4. The cable of claim 3 in which said relatively short fibers and
said longer fibers are asbestos.
5. The cable of claim 1 in which said chlorinated hydrocarbon is
selected from the group consisting of chlorinated paraffin,
chlorinated napthalene, and chlorinated terphenyl.
6. The cable of claim 1 in which said dried residue includes
approximately 1 to about 20 weight percent of an antimony
containing compound.
7. The cable of claim 1 wherein said dried residue includes
approximately 1.5 to about 7.5 weight percent of a plasticizer for
said water emulsified resin.
8. The cable of claim 1 in which said layer of insulation is
selected from the group consisting of neoprene rubber, butyl
rubber, polyvinyl chloride, and cross-linked polyethylene.
9. The cable of claim 7 in which said dried residue includes about
5 to about 30 weight percent wetting agents and inert materials
consisting of inorganic fillers and coloring agents.
10. The cable of claim 6 in which said dried residue includes
approximately 1.5 to about 7.5 weight percent of a plasticizer for
said water emulsified resin.
11. The cable of claim 1 in which said resin is selected from the
group consisting of polyvinyl acetate, GRS rubber, natural rubber
latex, methacrylates, acrylates, elastomeric polyurethanes,
copolymers of vinyl acetate and vinyl chloride, and epoxy
resins.
12. An electrical cable having a self-extinguishing fire protective
coating on the exterior surface to protect said cable from the
destructive effects of fire and to prevent the propagation of
flames, said cable comprising a metal core, a layer of insulation
surrounding said core, and said fire protective coating surrounding
said layer of insulation, said coating being the dried residue of
an aqueous emulsion and comprising from about 6 to about 30 weight
percent of water emulsified thermoplastic resin solids, about 1.5
to about 20 weight percent of a chlorinated hydrocarbon, and about
7.5 to about 75 weight percent of inorganic noncombustible
fibers.
13. The coated cable of claim 12 in which said dried residue
includes approximately 1 to about 20 weight percent of an antimony
containing compound and about 1.5 to about 7.5 weight percent of a
plasticizer for said water emulsified resin.
14. The coated cable of claim 12 in which said dried residue
includes about 5 to about 30 weight percent wetting agents and
inert materials consisting of inorganic fillers and coloring
agents.
15. The coated cable of claim 12 in which said resin comprises a
vinyl acetate polymer.
16. The coated cable of claim 15 in which said dried residue
contains approximately 20.25 weight percent of said resin solids,
approximately 7.98 weight percent of said chlorinated hydrocarbon,
about 3.99 weight percent of said plasticizer, approximately 39.40
weight percent of said inorganic fibers, approximately 19.06 weight
percent of said inert materials, and approximately 9.31 weight
percent of said antimony compound.
Description
BACKGROUND OF INVENTION
In electrical utilities and other installations where large numbers
of electrical cables are used, there is a constant, very serious
danger of fire developing due to the heavy current passing through
the cables and the heat which is produced when overloading occurs.
Also, such cables frequently are operated under high voltage which
can cause arcing among adjacent cables.
Since a typical utility may contain thousands of linear feet of
cable, the danger thus created by the fire is enormous. Moreover,
the cables are totally destroyed which results in a loss of
production and also necessitates a sizable expenditure to replace
the cables and other damaged equipment or buildings. In the case of
nuclear generating stations, the danger posed by the threat of fire
is further and dramatically increased.
When the electrical cables have a coating of polyvinyl chloride,
there are additional disruptive results of fires. The high-chlorine
content of polyvinyl chloride (which may have a theoretical
hydrochloric acid content of about 56 percent by weight) is freed
and combines with the humidity of the air or with water which is
used for fire extinguishing to form hydrochloric acid which can
penetrate concrete foundations and attack the steel
reinforcement.
To protect the cables against fire and to minimize the destructive
results of fires, a coating of a fire protective material can be
applied to the exterior surface. One example of a formulation which
has performed well is a chlorinated rubber composition described in
U.S. Pat. No. 2,938,937. Such composition, however, is formulated
with a volatile organic solvent such as toluene or naphtha. The use
of organic solvents, of course, is not desirable since solvent
fumes can be hazardous to applicators of the coating. This is
especially undesirable when the cables are in underground vaults.
Organic solvents have also been found to cause neoprene and butyl
rubber insulation on the cables to swell when a thick coating is
applied.
It is accordingly highly desirable to have a fire protective
composition which does not require the use of an organic solvent
and which contains as little chlorine content as possible. To
provide such a composition, however, which also is capable of
providing satisfactory fire protection when applied to electrical
cables, is exceedingly difficult since the composition must protect
the cable for several minutes, in some instances as long as 30
minutes, during the fire and prevent propagation of flames beyond
the original heat source. The composition must also be capable of
providing a coating on the cable which is sufficiently flexible to
allow handling of the cables without breaking of the coating and to
permit access to and removal of individual cables from a cable
tray. The composition should also be capable of protecting
electrical cables against the hazards of fire after immersion in
water for prolonged periods of time, and should not significantly
diminish the current carrying capability of the cables, i.e., the
coating will not cause significant heat buildup within the coated
cables.
SUMMARY OF INVENTION
The present invention thus provides a fire protective composition
which, upon application, forms a self-extinguishing fire barrier
and does not significantly retain heat within an electrical cable
during normal operation. The composition includes a water based
resinous emulsion, a chlorinated hydrocarbon, and inorganic
noncombustible fibers.
A principal object of this invention is thus the provision of a
fire protective composition which is highly effective in preventing
propagation of flames and spreading of a fire when applied to
combustible substrates.
Another object of this invention is to provide a fire protective
composition which is capable of being formed into a flexible film
which permits the cable to be handled easily and which may
conveniently be removed from the cable.
A still further object of this invention is to provide a fire
protective composition which does not include an organic
solvent.
Another object of this invention is to provide a fire protective
composition which will not cause swelling of insulation on
electrical cables nor affect the electrical or physical properties
of the cable insulation in any significant manner.
It is yet a further object of this invention to provide a fire
protective composition which contains only a relatively small
chlorine content.
Other objects, features, and advantages of this invention will be
apparent to those skilled in the art after a reading of the
following more detailed description.
DESCRIPTION OF PREFERRED EMBODIMENTS
The water based resinous emulsion is preferably a thermoplastic
such as a polyvinyl acetate emulsion, GRS rubber, natural rubber
latex, methacrylate and acrylate resins, elastomeric polyurethanes,
and copolymers of such materials as vinyl acetate and vinyl
chloride. Water emulsified epoxy resins may also be used. The
composition must have sufficient emulsion to produce a coherent
plastic film or coating when the composition is applied to an
electrical cable and also one which adheres well to the surface of
the cable insulation but which can be easily removed. Accordingly,
at least about 4 weight percent of the emulsion solids will be
used, based on the total weight of the composition. In general, the
quantity of emulsion solids should not exceed approximately 25
weight percent since a minimum of organic binder, consistent with
satisfactory physical properties, is desired to provide a coating
which is tough and sufficiently flexible to permit easy handling of
the coated cables and which contains as little combustible material
as possible. The preferred range of emulsion solids is from about 8
weight percent to about 15 weight percent.
The chlorinated hydrocarbon may be chlorinated paraffin,
chlorinated naphthalene, chlorinated terphenyl, mixtures of such
materials, etc. From about 1 to about 15 weight percent of the
chlorinated hydrocarbon will generally be used, with the preferred
range being from about 4 to about 6 weight percent, based on the
total weight of the composition.
Preferably, the composition includes a plasticizer to provide
flexibility for the coating, although with some emulsions, such as
elastomeric polyurethanes and rubbers, it may not be necessary to
use a plasticizer. If a plasticizer is used, the selection of a
particular plasticizer, of course, depends upon the particular
emulsion which is used, with suitable plasticizers being those
generally used to plasticize such emulsions. If a polyvinyl acetate
emulsion, for example, is used, suitable plasticizers include tris
beta chloroethyl phosphate, chlorinated biphenyl, butyl benzyl
phthalate, dibutyl phthalate, tricresyl phosphate, triphenyl
phosphate, cresyl diphenyl phosphate, tritoyl phosphate or mixtures
thereof. Normally, the quantity of plasticizer will be relatively
small, within the range of from about 1 to about 5 weight percent
based on the total weight of the composition.
The composition also includes inorganic noncombustible fibers such
as asbestos or glass. The total quantity of such fibers in the
composition is generally within the range of from about 5 to about
50 weight percent. In a preferred form, the composition includes
inorganic fibers of different lengths, i.e., short fibers of about
one thirty-seconds inch or less in length and relatively longer
fibers of up to about one-half inch in length, the shorter fibers
generally comprising from about 20 to about 80 weight percent of
the total weight of the mixture of fibers, and preferably from
about 50 to about 70 weight percent. Particularly good results have
been obtained when both the long and short fibers are asbestos as
it is believed that the asbestos fines or short fibers together
with the long fibers form a tough film, that is a dense interwoven
network, which remains about the cable insulation surface after
burning. Such structure, in combination with the carbonaceous
residue of the decomposed binder, is believed to facilitate removal
of heat by radiation and at the same time to limit the access of
oxygen to the flammable cable surface.
Preferably, the fire protective composition also includes an
antimony containing compound, such as antimony trioxide. Generally,
about 0.5 to about 15 weight percent, and preferably from about 2
to about 5 weight percent, of the antimony compound will be used.
The antimony oxide is believed to function in combination with the
chlorinated hydrocarbon during burning by interfering with the
normal combustion process, or to limit burning, possibly by
reacting with the chlorinated hydrocarbon to form antimony
pentachloride, a heavy gas which forms at the boundary of the
burning surface and thus prevents oxygen from getting to such
surface.
The fire protective composition may also include various inert
inorganic fillers, such as calcium carbonate or silica or other
such stable inorganic materials. The quantity of fillers will
normally be kept within the range of approximately 5 to about 20
weight percent, based on the total weight of the composition.
Similarly, the composition may also include organic or inorganic
pigments such as titanium dioxide, ferric oxide, etc., to provide a
desired color. The quantity of such pigment will, of course, be
relatively small, generally no more than approximately 4 weight
percent.
To prepare the composition, polyvinyl acetate or other resinous
emulsion containing at least approximately 50 percent solids in
water is mixed with the chlorinated hydrocarbon and plasticizer
with stirring at room temperature to form a substantially uniform
mixture of the ingredients. The calcium carbonate or other inert
filler, pigment, and antimony oxide compounds are added and
thoroughly mixed therein, after which the asbestos or other
inorganic fibers are added with mixing to provide a substantially
uniform mixture.
The composition may be applied as a fluid or as a mastic by various
methods, including spraying, brushing, trowelling, gunning, etc.
Depending upon the form of the composition, the composition will
contain the requisite amount of water, slightly greater quantities
of water being required if a sprayable composition is to be
produced. The composition may also contain minor amounts of various
additives to stabilize and protect the emulsion, such as wetting
agents, defoaming agents, fungicides, etc. The quantity of such
ingredients will usually be within the range of from about 1 to
about 5 percent by weight.
It is advisable to clean the surface to which the coating is to be
applied if it contains excessive oil or grease contamination. The
surface should also be free of excess loose dirt and dust. When the
composition is applied to electrical cables, the coating should be
approximately one-eighth inch in thickness. To attain such a
coating, the initial thickness should be approximately
three-sixteenths inch when the wet composition is applied as it
will shrink approximately 30 percent in drying. If the fire hazard
is minimal, the thickness of the coating may be only approximately
one-sixteenth inch, and conversely, if a strong fire hazard exists,
the coating may be approximately one-fourth inch thick. Depending
upon the thickness applied and the atmospheric conditions, the
composition will usually dry to touch between 1 and 2 hours, and
after approximately 4 hours, the cable may be handled or removed.
Complete drying requires up to approximately 3 days, and
consequently, fire testing should not take place until at least 3
days after application since traces of moisture left on the inside
of the coating could expand and loosen adhesion.
After drying, the water, of course, will have evaporated and the
resulting coating, in one formulation, will comprise the following
materials in the indicated approximate percentages:
Resin solids 20.25 wt. % Chlorinated hydrocarbon 7.98 wt. %
Plasticizer 3.99 wt. % Inorganic fibers 39.40 wt. % Inorganic
fillers 19.06 wt. % Antimony compound 9.31 wt. %
In general, the dried coating will contain, based on the total
weight of the coating, from about 6 to about 30 weight percent
resin solids from the emulsion, about 1.5 to about 20 weight
percent chlorinated hydrocarbon, about 1.5 to about 7.5 weight
percent plasticizer, about 7.5 to about 75 weight percent inorganic
fibers, about 5 to about 30 weight percent inorganic fillers,
pigments, wetting agents, etc., and about 1 to about 20 weight
percent of the antimony compound.
Referring to the accompanying drawings:
FIG. 1 is a fragmentary perspective view of an electrical cable
having a coating of the composition applied thereto; and
FIG. 2 is a cross section view taken on line 2--2 of FIG. 1.
In the drawing, the numeral 1 denotes generally a piece of
electrical cable having a coating 2 of fire protective composition
thereabout. In this particular form, the cable core includes a
plurality of metal wires 3 having an insulation coating 4 thereon,
which may be neoprene rubber, butyl rubber, polyvinyl chloride,
cross-linked polyethylene, etc. As shown most clearly in FIG. 2,
the coating 2 of fire protective composition surrounds the cable
and is adhered to the insulation coating 4.
The invention will be better understood by reference to the
following specific but illustrative example.
EXAMPLE
Utilizing the general procedure previously described, approximately
26 percent of a 50 percent solids polyvinyl acetate water emulsion,
about 5 percent by weight chlorinated paraffin and about 2.5 weight
percent tris beta chloroethyl phosphate plasticizer were mixed in
sufficient water to give a final composition containing about 22
weight percent water with stirring at room temperature for
approximately 15 minutes to produce a substantially uniform
dispersion. Approximately 7 percent by weight of calcium carbonate
filler, 3.5 percent titanium dioxide pigment and approximately 6
percent antimony trioxide were then added and mixed thoroughly for
approximately 30 minutes. Approximately 27 percent by weight of
asbestos fibers, consisting essentially of about 16 percent of
asbestos fines having a length of one thirty-seconds inch or less
and about 11 percent of asbestos fibers of up to approximately
one-half inch in length, were then added to the emulsion and mixed
thoroughly for approximately 60 minutes.
After the composition was prepared as above, it was applied by
spraying with standard spray coating apparatus to an 8 foot
horizontal cable tray containing approximately 20 insulated
electrical cables. The coating was applied to one-half of the cable
tray, top and bottom, to provide approximately one-eighth inch
thickness of coating. The remainder of the cable tray and cables
was not coated. The fire protective coating was permitted to dry
for 2 days, and the test rig was then positioned in a wind
protected area so that wind direction would not influence the
results. Burlap bags soaked in transformer oil were then wrapped
around the cables and ignited with a propane blow torch. The
burning time of the heat source was approximately 6 minutes on the
section of the tray which had been coated as described, after which
the fire had burned out. On the uncoated cables, the fire did not
burn out until the insulation had been totally decomposed and the
metal cables charred and badly damaged. In contrast to this, the
coated cables, after being permitted to cool, were inspected and
found to be substantially unharmed and suitable for further
use.
Tests have also been performed on electrical cables coated with the
fire protective composition of this invention to determine whether
the coating affects the current carrying capability of the cable,
as determined by the temperature rise in the cable during
operation. It has been found that such coating does not reduce
significantly the ampacity, the reduction being generally on the
order of only between 2 and about 5 percent, which is not
sufficient to derate the cables, the temperature of the insulation
on the cables increasing only approximately 2 percent with a
one-eighth inch thickness coating of the fire protective
composition.
In addition to the previously described qualities, the fire
protective composition of this invention is odorless and nontoxic
and has a Shore A hardness of up to about 85. An unsupported
1/16-inch thickness film passes a 1.8 inch mandrel bend per ASTM D
1737-62. A 1/16-inch film on aluminum is capable of withstanding an
impact of at least 24 inches per pound on a Gardener Impact
Tester.
As will be appreciated from the foregoing, the fire protective
composition of this invention is very effective in preventing the
spreading of fire and thus of protecting electrical cables from the
destructive effects of fires. Also, the coating provided by such
composition is highly flexible and it does not interfere in any way
with the normal use of the cables. Additionally, the composition
does not cause a significant temperature rise in the cables during
operation and has also been found to be stable as a coating over
long periods of time. Although the composition is particularly
suitable for use as a coating for electrical cables, it is also
quite suitable for use as a fire stop for wall penetrations in
which the composition is applied to the cavity between electrical
cables and walls or ceilings to seal around the cables and thus
prevent the fire from being transmitted to other areas of the
plant.
* * * * *