U.S. patent number 3,638,786 [Application Number 04/875,649] was granted by the patent office on 1972-02-01 for package for preparation and dispensing of heated foam.
This patent grant is currently assigned to E. I. du Pont de Nemours and Company. Invention is credited to William Joseph Borecki, Frederick John Gradishar.
United States Patent |
3,638,786 |
Borecki , et al. |
February 1, 1972 |
PACKAGE FOR PREPARATION AND DISPENSING OF HEATED FOAM
Abstract
A package adapted for preparing and dispensing heated foam,
which comprises a manually openable sealed outer container and a
manually rupturable sealed inner container, said package containing
A. an aqueous dispersion of a foamable composition, B. hydrogen
peroxide, C. a reductant composition, D. an organic propellant
selected from A. 1,2-Dichlorohexafluoropropane B.
1,2-Dichloro-1,2,2-trifluoroethane C. Perfluorodimethylcyclobutane
D. 1,2-Dichloroperfluorocyclobutane Wherein materials (B) and (C)
are isolated from each other in the separate containers of said
package.
Inventors: |
Borecki; William Joseph
(Wilmington, DE), Gradishar; Frederick John (Wilmington,
DE) |
Assignee: |
E. I. du Pont de Nemours and
Company (Wilmington, DE)
|
Family
ID: |
25366138 |
Appl.
No.: |
04/875,649 |
Filed: |
November 12, 1969 |
Current U.S.
Class: |
206/219;
252/183.14; 516/10; 424/45; 424/47; 516/15; 516/19; 510/120;
510/140 |
Current CPC
Class: |
A61K
8/02 (20130101); B65D 81/3272 (20130101); A61Q
5/02 (20130101); C09K 3/30 (20130101); A61Q
9/02 (20130101); A61K 2800/242 (20130101) |
Current International
Class: |
B65D
81/32 (20060101); A61Q 9/02 (20060101); C09K
3/30 (20060101); C09k 003/30 (); A61k 007/14 () |
Field of
Search: |
;252/90,186,305
;424/47,45 ;206/47A ;229/3.5MF |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Guynn; Herbert B.
Claims
What we claim is:
1. A package adapted for preparing and dispensing heated foam,
which comprises a manually openable sealed outer container and a
manually rupturable sealed inner container, said package
containing
A. an aqueous dispersion of a foamable composition selected from
the group consisting of soluble anionic soaps,
B. hydrogen peroxide,
C. a reductant composition which reacts at room temperature with
the said hydrogen peroxide to produce heat, said reductant
composition being an alkali metal sulfite or a mixture of an alkali
metal sulfite and an alkali metal thiosulfate, and
D. an organic propellant for dispensing material (A) selected from
the group consisting of
a. 1,2-Dichlorohexafluoropropane and
b. 1,2-Dichloro-1,2,2-trifluoroethane wherein materials (B) and (C)
are isolated from each other in the separate containers of said
package.
2. A package according to claim 1 wherein the organic propellant
(D) is 1,2-dichlorohexafluoropropane.
3. A package according to claim 1 wherein the organic propellant
(D) is 1,2-dichloro-1,2,2-trifluoroethane.
4. A package according to claim 1 wherein the outer container is
prepared from polyethylene laminated on the outside to aluminum
foil.
5. A package according to claim 1 wherein the inner container is
prepared from polyethylene.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to a package adapted for preparing and
dispensing self-heating foam in which heat is generated by a redox
reaction and in which a normally liquid propellant is utilized.
2. Description of Prior Art
The field of heated foam packages is predominated by rigid, complex
and costly containers and dispensers containing therein foamable
compositions, redox reactants and various propellants. Such
packages normally provide for separate storage of oxidants and
reductants, with one of these reactants combined during storage
with the foamable composition. Mechanical valves, passages, tubes
and the like provide the means for mixing of oxidant, reductant and
foamable composition upon expulsion from the container.
A package has now been invented which allows for the preparation
and dispensing of heated foam from noncomplex, nonrigid containers
which employ normally liquid propellants.
SUMMARY OF THE INVENTION
The present invention comprises a package having a manually
openable sealed outer container and a manually rupturable sealed
inner container, said package containing
A. an aqueous dispersion of a foamable composition,
B. hydrogen peroxide
C. a reductant composition which reacts at room temperature with
the said hydrogen peroxide to produce heat, said reductant
composition being an alkali metal sulfite or a mixture of an alkali
metal sulfite and an alkali metal thiosulfate, and
D. an organic propellant for dispensing material (A) selected
from
A. 1,2-Dichlorohexafluoropropane
B. 1,2-Dichloro-1,2,2-trifluoroethane
C. Perfluorodimethylcyclobutane
D. 1,2-Dichloroperfluorocyclobutane wherein materials (B) and (C)
are isolated from each other in the separate containers of said
package.
DESCRIPTION OF THE DRAWINGS
FIG. 1 is a top view of a package of this invention.
FIG. 2 is a cross section of the package of FIG. 1 along the lines
2--2.
CDESCRIPTION OF THE INVENTION
It is now been discovered that heated foams can be prepared and
dispensed from noncomplex, nonrigid containers employing therein a
normally liquid propellant heated to a temperature above its
boiling point by redox reaction. The complexity and cost of the
prior art containers comprises rigid walls, mechanical valves,
passages, etc., are thus avoided.
The package of this invention in its preferred embodiment, as shown
in FIGS. 1 and 2, intended for single use, comprises a manually
openable outer container 1 prepared from a plastic or plastic
laminated on its outside to metal foil which container is sealed 5
and contains a foamable material and a reductant or reductants 2
selected from an alkali metal sulfite alone or in a mixture with an
alkali material thiosulfate. Within this outer container is a
smaller manually rupturable inner container 3 which is sealed 6 and
contains hydrogen peroxide 4 in an amount chemically equivalent to
or preferably slightly less than equivalent to the amount of
reductant contained in the mixture with the foamable material. The
hydrogen peroxide may be optionally thickened as described in the
examples. Thickened hydrogen peroxide, while producing more stable
foams, is however more difficult to mix. Other embodiments are of
course possible, e.g., the containers could be prepared from
flexible molded plastic provided that the inner container is still
rupturable.
It is readily apparent also that the order of storage of the
reactants may be reversed, that is, the hydrogen peroxide may be
contained in the outer container and the other materials in the
inner container. Further, as taught by Seglin et al., in French
Pat. No. 1,468,909, the hydrogen peroxide may be stored in mixture
with selected soaps which do not decompose the hydrogen peroxide.
The reductants are, of course, stored in a container separate from
the hydrogen peroxide container within the package thus isolating
the two reactants from each other while in storage.
It will occur to one skilled in the art that various materials can
be used to prepare the containers of the package of this invention.
A primary consideration, however, is that the material of the
hydrogen peroxide containing container not catalytically decompose
hydrogen peroxide, nor should the hydrogen peroxide attack or
rapidly permeate the container material. The material of
construction of the nonhydrogen peroxide containing container is
less critical. Polyethylene, for example, is a suitable material
and if the nonhydrogen peroxide containing container is the outer
container, polyethylene laminated to a stronger film such as
polyethylene terephthalate may be used.
In utilizing one embodiment of this invention, the inner sealed
container is first ruptured manually, e.g., by the application of
pressure between the fingers; the package is then shaken to allow
the reactants to contact one another thus effecting the heat
generating redox reaction; the outer sealed container is then
manually opened, e.g., by puncturing or tearing off a corner, and
the heated foam extrudes from the package through the opening thus
created.
The term "aqueous dispersion of a foamable composition" referred to
herein means an aqueous solution or dispersion of a foam-producing
agent capable of forming a foam when dispensed from the package of
this invention. There are no special limitations on the nature of
the foamable composition except that it should not contain any
materials which would interfere with the redox reaction, e.g., it
should not contain oxidants which would oxidize the sulfite or
thiosulfate reductant dissolved therein. Strongly acid materials
which would alter the reductants are also undesirable. Strongly
alkaline materials can, however, be utilized for they do in fact
accelerate the redox reaction. These strongly alkaline materials
may be particularly effective when utilized as oven cleaners and
the like. Materials which strongly catalyze the decomposition of
hydrogen peroxide, such as those described in Seglin et al., French
Pat. No. 1,468,909, are avoided because the heat produced by
hydrogen peroxide decomposition is less than that produced by redox
reaction on an equal weight basis. The best type and concentration
of foam-producing agent in the composition for a particular
application can be readily determined by one skilled in the art and
is not critical for purposes of this invention; however, the
composition usually contains about 30 to 35 percent by weight of
foam-producing agent. Useful foam-producing agents are exemplified
by the soluble anionic soaps, for example the potassium, ammonium
and soluble amine soaps of stearic acid, as well as vegetable oils
soaps, various synthetic materials known as wetting agents or
surfactants and fibrous alumina monohydrate in combination with a
foam coactive. The foamable composition should be nongelling at
room temperature, and contain additives known in the art such as
glycerine, light mineral oil, perfume, antifreeze agents, silicon
fluids, viscosity controlling agents and the like. Products to be
applied to the body, such as shaving lathers, hair conditioners,
etc., must, of course, contain only physiologically acceptable
materials and the pH must be near 7.
The reductants of this invention react with hydrogen peroxide at
room temperature, e.g., alkali metal sulfites or a mixture of an
alkali metal sulfite and alkali metal thiosulfate. The preferred
reductants are potassium sulfite and a mixture of potassium sulfite
and potassium thiosulfate because there is less likelihood that the
potassium salts will gel soap solutions. In the case of a mixture
of the sulfite and thiosulfate salts, the mol ratio of potassium
thiosulfate to potassium sulfite is not critical; however, for best
results the ratio should be from about 3 to 5 to about 2 to 3,
respectively. Furthermore, for best results, the amount of
reductant mixture present in admixture with the aqueous dispersion
of a foamable composition, if in fact they are admixed, while not
critical, usually ranges from about 6 to 10 percent by weight. When
the reductant utilized is potassium sulfite salt alone and it is
admixed with the aqueous dispersion of a foamable composition, the
amount of said reductant in admixture is usually from about 6 to 10
percent.
Several physical properties appear to affect the suitability of a
normally liquid propellant for use in this invention. The most
important of these properties appears to be the boiling point of
the propellant, and the choice of propellant based on boiling point
properties is affected by the temperature at which the package is
to be heated. In the system of this invention, this temperature is
fixed by the amounts of oxidant and reductant, the choice of
reductant, the heat capacity of the materials of package
construction, the heat loss from the package and the latent heat of
vaporization of the propellant. A comfortable temperature for
application of foam to the human skin is from about 120.degree. to
about 150.degree. F.
The overall stability of the heated foams produced appears to be
related to less clearly defined physical properties such as the
ability of the propellant to disperse in the foamable composition.
The stability of the foam appears to be related not only to its
composition as known in the art but also to the permeation rate of
the propellant through the cell walls, condensation of the
propellant within the cells upon cooling of the foam, etc.
It has been found that chlorofluorocarbons and perfluorocarbons
having boiling points of from about 80.degree. to about 115.degree.
F. are suitable propellants for use in this invention. While
propellants having boiling points above this range, i.e., to about
140.degree. F., are sometimes operable. The range described above
is preferred and the most preferred boiling point is about
95.degree. F. The following normally liquid propellants, arranged
in the order of decreasing preference, are effective when utilized
in the present invention.
Boiling Point Propellant .degree. F.
__________________________________________________________________________
1,2-dichlorohexafluoropropane 94.1
1,2-dichloro-1,2,2-trifluoroethane 82.8
Perfluorodimethylcyclobutane 114.0 (mixed isomers)
1,2-dichloroperfluorocyclobutane 139.8
__________________________________________________________________________
About 12 to 18 percent of propellant is usually used based on the
combined weight of propellant and foamable composition. The amount
of propellant utilized may, however, be greater depending upon the
containers used.
EXAMPLES
The following examples are intended to be merely illustrative of
the invention and not in limitation thereof. Unless otherwise
indicated, all quantities are on a weight basis. The composition of
foamable materials used in the following examples is not critical
to the operability of the invention; for other formulations, known
in the art, are operable. Utilizing these foamable materials, three
soap formulations were prepared each in three parts designated A,
B, and C below. Percent values are based on the total soap
formulation comprising all three parts in combination.
---------------------------------------------------------------------------
PART A
formu- Formu- Formu- lation 1 lation 2 lation 3 wt. % wt. % wt. %
Acetylated lanolin.sup.1 0.8 0.8 0.8 Cetyl alcohol 0.5 0.5 0.5
Sorbitol monostearate.sup.2 0.5 0.5 0.5 Mineral oil 0.5 0.5 0.5
Polyoxyethylene sorbitan 4.5 4.5 4.5 monostearate.sup.3
__________________________________________________________________________
---------------------------------------------------------------------------
PART B
formu- Formu- Formu- lation 1 lation 2 lation 3 wt. % wt. % wt. %
Coconut fatty acid 1.0 1.0 Stearic acid 9.0 7.0 7.0 Stearyl Alcohol
1.0 Lauric Acid 1.0
__________________________________________________________________________
---------------------------------------------------------------------------
PART C
formu- Formu- Formu- lation 1 lation 2 lation 3 wt. % wt. % wt. %
Deionized Water 66.1 69.1 68.1 Triethanolamine 3.5 3.5 3.5
Potassium Hydroxide 1.2 1.2 1.2 Potassium Sulfite .sup.. 2H.sub.2 O
5.0 5.0 9.0 Potassium Thiosulfate 3.0 3.0 Sorbitol, 70 wt. % in
Water.sup.4 3.0 3.0 3.0 Perfume 0.4 0.4 0.4
__________________________________________________________________________
The hydrogen peroxide solutions were prepared by dilution with
deionized water of commercial concentrated hydrogen peroxide
containing conventional inhibitors. The thickened hydrogen peroxide
formulations containing 13 wt. percent hydrogen peroxide were
prepared as follows:
Ingredient Wt. % Hydrogen peroxide, 35 wt. % 37.0 Cetyl alcohol 2.5
Glycerol monostearate 2.5 Deionized water 58.0
The deionized water at 70.degree. C. was slowly stirred into a
70.degree. C. melted mixture of cetyl alcohol and glycerol
monostearate. The mixture was allowed to cool while stirring
whereupon 35 percent hydrogen peroxide was added with stirring
until blended. Deionized water was then added to make up
evaporation losses.
The outer container used in the examples consisted of two
approximately 31/2.times. 4 in. sheets of 10 mil thick polyethylene
laminated on the outside to aluminum foil. The inner container,
containing hydrogen peroxide, consisted of two pieces of
approximately 1 mil thick polyethylene sheet about 1 in.
square.
EXAMPLE 1
In the runs reported in Table 1 of this example, the hydrogen
peroxide was charged to the inner container which was then heat
sealed and placed inside the outer container. The soap formulations
and propellant were added to the outer container which was then
also heat sealed. In these runs, the sealed containers were first
shaken vigorously, the inner container was then ruptured and the
contents of both envelopes were mixed by kneading for about 30
seconds whereupon a corner of the outer container was torn off. The
warm foam was expressed into a beaker where its temperature was
measured by a small thermometer in the center of the foam.
The results of the 12 runs are shown in Table 1 below. ##SPC1##
Since heated foams are needed for various applications, all those
formulations above which produced foams of some stability are
regarded as operable. Propellants which in at least one formulation
produced foams of some stability are therefore also regarded as
operable.
It should be noted that when 1,1,2-trichloro-1,2,2-trifluoroethane
was utilized as the propellant in Run No. V, the results were
unsatisfactory; and yet when 1,2-dichlorohexafluoropropane of this
invention was utilized as the propellant with the same formulation
(Run No. IV), the results were quite satisfactory.
For shave lather the components of runs IV and XII are
preferred.
EXAMPLE 2
In another embodiment of this invention, a redox reaction of
hydrogen peroxide and sodium sulfite was carried out separately in
an intermediate container, the heat of reaction therefrom being
transferred through the wall of the intermediate container to warm
the soap solution contained in the outermost container.
The package therefore consisted of three containers, one inside the
other. The innermost polyethylene container, approximately 1 inch
square, contained 0.4 cc. of 30 weight percent H.sub.2 O.sub.2 and
2.6 cc. water and was heat sealed at the edges. The intermediate
container, about 2.times. 3 inches in size and consisting of 4 mil
polyethylene, contained 0.4 grams sodium sulfite and was sealed at
the edges. The outer container containing 5 cc. of an approximately
24 percent aqueous solution of commercial lather shave cream and 2
cc. 1,2-dichloro-1,2,2-trifluoroethane, consisted of a 2 mil thick,
1 qt. capacity polyethylene bag heat sealed at all edges. Air was
excluded from all envelopes before heat sealing.
The innermost container was ruptured and its contents were mixed
with the sodium sulfite of the intermediate container by kneading.
The package was then shaken and warmed foam was expressed from the
outermost container, through an opening which was made therein,
into a graduated funnel. Approximately 80 cc. of foam was realized
which was stable for more than 20 minutes.
The novel package of this invention has a variety of applications
where it is desired to prepare and dispense warm aqueous foam. The
invention is especially useful for preparing warm aqueous foams for
such applications as conditioning areas of a person to be shaved,
and washing the skin or hair. Such utility is particularly
beneficial to campers, yachtsmen and others who often do not have
access to hot water. This novel package is adapted for preparing
warm foam quickly, efficiently and without a need for a source of
electricity, steam, or hot water.
Although the chemical components of this invention have been
described in the examples in terms of potassium and sodium salts,
it is evident that any alkali metal sulfite or a mixture of any
alkali metal sulfite and thiosulfate would be operable. It is
further understood that as many apparently widely different
embodiments of this invention may be made without departing from
the spirit and scope thereof, the invention is not limited to the
specific embodiments thereof.
* * * * *