U.S. patent number 3,637,340 [Application Number 04/794,771] was granted by the patent office on 1972-01-25 for process for the dyeing and printing of textile material made of hydrophobic polyesters.
Invention is credited to Helmut Hohenegger, Karlheinz Keller, Rudolf Keller, Hans Mollet.
United States Patent |
3,637,340 |
Mollet , et al. |
January 25, 1972 |
PROCESS FOR THE DYEING AND PRINTING OF TEXTILE MATERIAL MADE OF
HYDROPHOBIC POLYESTERS
Abstract
Process for dyeing or printing textile materials made from
hydrophobic polyester fibers with dye liquors or inks containing
water-dispersible dyestuff and a liquid auxiliary mixture
comprising a fiber-swelling agent such as o-phenylphenol, a
protective colloid such as polyvinylalcohol, a water-miscible
organic solvent, water and optionally for use in dye liquors
containing nonionogenic additives a sulfosuccinate or the like
anion-active agent whereby foam formation during dyeing or printing
is eliminated or at least greatly reduced.
Inventors: |
Mollet; Hans (Bottmingen,
CH), Hohenegger; Helmut (Riehen, CH),
Keller; Karlheinz (4000 Basle, CH), Keller;
Rudolf (Riehen, CH) |
Family
ID: |
25688190 |
Appl.
No.: |
04/794,771 |
Filed: |
January 28, 1969 |
Current U.S.
Class: |
8/552; 8/477;
8/528; 8/611; 8/613; 8/914; 8/921; 8/922; 524/323; 524/386;
524/395 |
Current CPC
Class: |
D06P
1/928 (20130101); D06P 3/36 (20130101); Y10S
8/922 (20130101); Y10S 8/914 (20130101); Y10S
8/921 (20130101) |
Current International
Class: |
D06P
1/92 (20060101); D06P 3/34 (20060101); D06P
3/36 (20060101); D06P 1/00 (20060101); D06p
005/04 () |
Field of
Search: |
;8/166,173,174,179 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lesmes; George F.
Assistant Examiner: Herbert, Jr.; T. J.
Claims
We claim:
1. A process for the coloring of textile material selected from
fibers of linear high-molecular esters of aromatic polycarboxylic
acids and polyfunctional alcohols and fibers of cellulose
triacetate, comprising dyeing or printing said textile material
with a dye liquor or ink containing:
a. a water-dispersible dyestuff; and
b. an auxiliary mixture consisting essentially of;
.alpha.--a fiber-swelling agent;
.beta.--a polyvinylalcohol;
.gamma.--a water-miscible organic solvent;
.delta.--water, and, optionally;
.epsilon.--a dialkyl sodium sulfosuccinate.
2. Process as described in claim 1, wherein said auxiliary mixture
contains, per 100 parts by weight thereof;
at least 0.1 and not more than about 65 parts by weight of
component (.alpha.);
at least one and not more than 5 parts by weight of component
(.beta.);
at least 30 and not more than 90 parts by weight of component
(.gamma.);
at least two and not more than 20 parts by weight of component
(.delta.); and
from 0 to not more than 10 parts by weight of component
(.epsilon.).
3. A process as described in claim 2, wherein said auxiliary
mixture is present in said dyeing liquor or ink in an amount of 1
to 40 percent calculated on the dry weight of the textile material
to be colored.
4. A process as described in claim 3, wherein said auxiliary
mixture consists essentially of:
o-phenylphenol as component (.alpha.);
polyvinylalcohol as component (.beta.);
ethylene glycol as component (.gamma.);
water, and no component (.epsilon.).
5. A process as described in claim 3, wherein said auxiliary
mixture consists essentially of:
o-phenylphenol as component (.alpha.);
polyvinylalcohol as component (.beta.);
ethylene glycol as component (.gamma.);
water, and dialkylsodium-sulfosuccinate as component
(.epsilon.)
wherein each alkyl has from four to 12 carbon atoms.
6. A process as described in claim 3, wherein the water-miscible
organic solvent is selected from lower alkanediols, lower
alkoxy-lower alkanols, N-methyl-pyrrolidone, formamide, dimethyl
formamide, dimethyl-acetamide and acetonitrile.
Description
This present invention relates to a process for dyeing or printing
textile material of hydrophobic polyesters, particularly of linear
polyesters, or cellulose triacetate in an aqueous medium in the
presence of a fiber-swelling agent which acts as a dyeing
accelerator. The invention also concerns the dyeing liquors or
printing pastes suitable for the process, the compositions of
substances acting as dyeing accelerators, as well as the material
dyed or printed according to this process.
As is known, special auxiliary agents known as carriers or dyeing
accelerators, have to be used for the dyeing of polyester fibers
and cellulose triacetate fibers by means of dispersion dyestuffs at
temperatures up to approximately 100.degree. C. These carriers are
aliphatic, aromatic or aliphatic-aromatic compounds, ranging from
those which are completely or partially water-soluble to those
which are insoluble in water. These compounds produce a loosening
up of the fiber structure, thus facilitating a diffusion of the
dyestuff into the fibers. Of the materials producing these swelling
effects, the phenylphenols are especially suitable. The
disadvantage of these compounds is, however, that it is
comparatively difficult to produce from them aqueous emulsions
which are stable on heating. Since preparations in paste form of
such swelling agents are difficult to handle, in that they
necessitate the boiling of a stock solution in order to obtain a
fine dispersion in the liquor, liquid carrier preparations have
been developed which can be added directly to the dyeing bath. Such
liquid preparations, for example, consist of solutions of
phenylphenols in organic solvents. The emulsions obtainable in this
manner were often insufficiently stable on heating. Attempts have
been made to overcome the difficulty by adding certain surfactants
or "tensides" to the carrier solution. However, this has the
disadvantage that an undesirable and troublesome amount of foam is
produced during the dyeing process, associated with an unfavorable
effect on the dye yield.
A process has now been found for the dyeing or printing of organic
textile material of hydrophobic polyesters which avoids these
disadvantages. The new process comprises dyeing or printing said
textile material with a dye liquor or ink containing
A. A WATER-DISPERSIBLE MIXTURE; AND
B. AN AUXILIARY MIXTURE COMPRISING
.alpha.--a fiber-swelling agent,
.beta.--a protective colloid,
.gamma.--a water-miscible organic solvent,
.delta.--water, and optionally for use in the dye liquors
Containing nonionogenic additives (.epsilon.) a sulfosuccinate or
the like anion-active agent, whereby foam formation during dyeing
or printing is eliminated or at least greatly reduced.
More in particular, said auxiliary mixture contains, per 100 parts
by weight thereof;
at least 0.1 and not more than about 65 parts by weight of
component (.alpha.);
at least one and not more than five parts by weight of component
(.beta.);
at least 30 and not more than 90 parts by weight of component
(.gamma.);
at least two and not more than 20 parts by weight of component
(.delta.); and
from zero to not more than 10 parts by weight of component
(.epsilon.).
Suitable as hydrophobic polyester textile material are, e.g.,
cellulose triacetate fibers and, in particular, the linear
polyester fibers of aromatic polycarboxylic acids with
polyfunctional alcohols such as, e.g., polyethyleneglycol
terephthalate or poly-(1,4-cyclohexanedimethylol-terephthalate)
fibers. These materials can be used together in the form of mixed
fabrics or together with other fibers, e.g., polyester-wool fabric,
polyester-cotton fabric or polyester-polyacrylonitrile mixed
fabrics.
The water-dispersible dyestuffs used, which are difficultly soluble
in water and which are present in the dyeing liquor mainly in the
form of a fine suspension, can belong to the most varied classes of
dyestuffs, for example, the azo, anthraquinone, acridone, perinone,
quinophthalone, styryl or nitro dyestuffs.
The mixture of auxiliary agents which can be used as dyeing
accelerators according to the invention, may be composed of the
following components: a finely dispersed fiber-swelling agent, a
protective colloid, a water-miscible organic solvent and water.
Suitable as the fiber-swelling agent are the usual compounds which
can be used for the dyeing of polyester and cellulose triacetate
textiles, principally however phenylphenols, especially
o-phenylphenol or its water-soluble alkali metal salts.
As protective colloids, hydrophilic polymers, for example, gum
arabic, gelatine, but especially polyvinyl alcohol or other
analogously acting compounds, can be used.
As water-miscible organic solvents those may be used, in which the
carrier, in particular, o-phenylphenol, is soluble, for example,
lower alkanediols, such as 1,3-propanediol, or especially ethylene
glycol; lower alkoxy-lower alkanol, such as 2-ethoxy ethanol; also
N-methyl pyrrolidone, as well as formamide, dimethyl formamide,
dimethyl acetamide, acetonitrile and similar dipolar, aprotic
solvents.
"Lower" used in this application and the appended claims in
connection with an aliphatic radical means that such radical has at
most five carbon atoms.
An especially advantageous composition of the mixture of the
auxiliary agents, comprises o-phenylphenol, polyvinyl alcohol,
ethylene glycol and water.
The new auxiliary mixture for use in dye liquors containing
nonionogenic additives contain a sulfosuccinate or the like
anion-active agent.
Suitable as sulfosuccinates are, in particular, the dialkyl esters
of the sodium salt of sulfosuccinic acid, wherein each alkyl
radical has from four to 12 carbon atoms, e.g.,
di-isobutyl-sodium-sulfosuccinate, di-n-amyl-sodium-sulfosuccinate,
di-n-hexyl-sodium-sulfosuccinate, di-n-octyl-sodium-sulfosuccinate,
di-n-dodecyl-sodium-sulfosuccinate and, in particular,
di-iso-octyl-sodium-sulfosuccinate.
In this case a particularly advantageous composition of the mixture
of auxiliary agents comprises o-phenylphenol, polyvinyl alcohol,
ethylene glycol, water and at least one part by weight of
dialkyl-sodium-sulfosuccinate wherein each alkyl has from four to
12 carbon atoms.
The mixture of auxiliary agents is produced by first dissolving,
while heating, the polyvinyl alcohol and optionally the dialkyl
sulfosuccinate in the appropriate amount of water. A solution of
o-phenylphenol in ethylene glycol is prepared at the same time and
the two solutions are combined, while stirring, at 50.degree. to
60.degree. C. The aqueous polyvinyl alcohol solution can also be
mixed with the ethylene glycol and the o-phenylphenol and
optionally the dialkyl sulfosuccinate dissolved in this mixture. A
clear to slightly opalescent, almost colorless solution is obtained
in both cases.
Relative to the dry weight of the fibers to be colored, the dye
bath or ink can contain 1 to 40 percent, preferably 5 to 20 percent
of these mixtures of auxiliary agents, depending on the ratio of
liquor to material.
In addition to the dyestuff and the mixture of auxiliary agents,
the dyebath can optionally contain further additives commonly used
for the dyeing or printing of polyester and cellulose triacetate
fibers. These additives can be, for example, compounds which
increase the color yield and brilliancy of the dyeings, such as
condensation products from naphthalene sulfonic acids and
formaldehyde, condensation products from higher fatty acids with
aminoalkyl sulfonates, such as taurine, or sulfated addition
products of ethylene oxide with higher fatty acids, also salts such
as sodium sulfate, ammonium sulfate, sodium or ammonium phosphates
and ammonium polyphosphates, acids such as sulfuric acid, acetic
acid or formic acid.
The dyeing of the textile material can be carried out applying the
usual carrier-dye process with dispersion dyestuffs, whereby the
standard dyeing equipment is employed, i.e., winch vat, jigger,
star, cheese dyeing or beam-type dyeing equipment. Thus, for
example, the material to be dyed is run through in the bath at
60.degree. to 70.degree. C. with the mixture of auxiliary agents
being used as a dyeing accelerator, whereby the bath has been
adjusted to a pH value of 3-6.5, preferably 5, and optionally
contains the above-mentioned additional additives. The dyestuff is
then added as an aqueous suspension and the temperature
continuously increased up to the boiling temperature and, if
pressure equipment be used, up to 100.degree. C. Dyeing proceeds at
this temperature for 1 to 2 hours. The dyeing is subsequently
washed with water and dried preferably at temperatures above
100.degree. C., e.g., at 120.degree. C.
Also printing of the textile material is carried out using standard
methods. For example, the fabric is printed using the printing
paste, which in addition to the dyestuff, the thickener and the
usual additives, such as e.g., urea, also contains the mixture of
auxiliary agents being used as a dyeing accelerator in accordance
with the invention. The dyestuff is subsequently fixed by steaming
for 15-50 minutes at 100.degree.-120.degree. C. The printing is
completed by rinsing and resoaping.
The advantages of the preparation, applicable according to the
invention, of the dyeing accelerator, lie principally in the fact
that, compared with previously known preparations with a content of
specific tensides, the troublesome foam formation during dyeing is
very greatly reduced or eliminated, and that the color yield with a
given amount of active substance is increased. Furthermore,
undesirable effects are also avoided, which can occur in
consequence of the incompatibility of such tenside with the
dispersion agents already contained in the dye liquors. In addition
there is the fact that the dyeing accelerator, used according to
the invention, is in the form of a liquid which is easy to handle.
Moreover, by using a solution which is clear under the dyeing
conditions, the danger of solid residues remaining on the fiber is
avoided.
The following examples illustrate the invention. The temperatures
are given in degrees Centigrade. EXAMPLE 1
25 g. of polyester fabric are introduced into 1,000 ml. of dyeing
liquor heated to 65.degree. and containing 0.5 g. of ammonium
sulphate, 0.1 g. of sodium pyrophosphate (neutral, anhydrous), 0.5
g. of a condensation product from napthalene sulphonic acid and
formaldehyde, 0.5 g. of a reaction product of methyl taurine with
oleic-acid chloride and 5.0 g. of a mixture comprising 2.25 g. of
o-phenylphenol, 2.05 g. of ethylene glycol, 0.125 g. of
di-iso-octyl sodium sulphosuccinate (85%), 0.125 g. of polyvinyl
alcohol (mean ester number 20-200, viscosity of a 4 percent aqueous
solution: 4-50 c.p.s. at 20.degree.) and 0.45 g. of water. The
textile material is treated for 15 minutes at the same temperature.
To the clear bath are added 50 ml. of an aqueous suspension heated
to ca. 60.degree. and containing 0.5 g. of the dyestuff having the
following formula ##SPC1##
and 0.3 g. of a reaction product of methyl taurine with oleic-acid
chloride. Dyeing is performed for a further 15 minutes at
65.degree. and the temperature is then increased successively
within 45 minutes up to the boiling point with further dyeing for
90 minutes while boiling.
The liquor is then cooled and the fabric rinsed with water at
60.degree., and with water at 20.degree., followed by drying at
120.degree.. A very pure blue dyeing is obtained in this
manner.
The mixture used as dyeing accelerator is produced by firstly
dissolving 2.5 percent by weight of the polyvinyl alcohol in 9
percent by weight of water, while stirring and heating to
60.degree.-80.degree., followed by 2.5 percent by weight of
di-iso-octyl sodium sulphosuccinate. 41 percent by weight of
ethylene glycol are then added and, while stirring and at ca.
40.degree.-50.degree., 45 percent by weight of o-phenylphenol are
dissolved in this mixture. Corresponding solutions of polyvinyl
alcohol and of di-iso-octyl sodium sulphosuccinate in water and
o-phenylphenol in ethylene glycol can also be mixed together while
stirring and at 40.degree.-50.degree..
If, in the above example, an equivalent amount of the Na-salt of
o-phenylphenol is used instead of o-phenylphenol, it is to be
recommended that ca. 10 percent (relative to the weight of the
dyeing-accelerator mixture) of an organic acid, e.g., 85 percent
formic acid, be added, so that the pH value of the bath does not
exceed 6.5 to 7.
If, in the above example 1, with otherwise the same procedure,
instead of 5 g. of a mixture consisting of 2.25 g. o-phenylphenol,
2.05 g. ethyleneglycol, 0.125 g. di-iso-octyl sodium
sulphosuccinate, 0.125 g. polyvinyl alcohol and 0.45 g. water, 5 g.
of a mixture consisting of:
2.5 g. o-phenylphenol;
0.1 g. polyvinylalcohol;
0.125 g. di-iso-octyl-sodium-sulfosuccinate;
0.4 g. water; and
1.875 g. ethylene glycol; or
7.5 g. of a mixture consisting of
2.25 g. o-phenylphenol;
0.075 g. polyvinylalcohol;
0.15 g. di-iso-octyl-sodium-sulfosuccinate;
0.750 g. water; and
4.275 g. ethylene glycol
is used, then a very pure blue dyeing is also obtained.
EXAMPLE 2
100 g. of a polyester-wool mixed yarn (67:33) are introduced into
1,000 ml. of dyeing liquor heated to 65.degree. and containing 0.5
g. of ammonium sulphate, 0.1 g. of sodium pyrophosphate (neutral,
anhydrous), 1.0 ml. of acetic acid, 1.0 g. of a condensation
product from naphthalene sulphonic acid and formaldehyde and 5.0 g.
of a mixture, consisting of 2.25 g. of o-phenylphenol, 0.125 g. of
di-iso-octyl sodium sulphosuccinate (85%), 2.05 g. of ethylene
glycol, 0.125 g. of polyvinyl alcohol (mean ester number 100-200;
viscosity of a 5 percent aqueous solution: 4-50 c.p.s. at
20.degree.) and 0.45 g. of water. The textile material is then
treated for 15 minutes at the same temperature. To the clear bath
are added 50 ml. of an aqueous suspension heated to 60.degree. and
containing 0.6 g. of a reaction product of methyl taurine with
oleic-acid chloride, 1.0 g. of the dyestuff having the following
formula: ##SPC2##
and 0.6 g. of the 1:2 chromium complex of the dyestuff
2-amino-4-methylsulphonylphenol
1-3'-chlorophenyl-3-methylpyrazol-5-one. Dyeing is performed for a
further 15 minutes at 65.degree. and the temperature is then
increased within 45 minutes up the boiling point with further
dyeing for 90 minutes while boiling. The liquor is then cooled to
60.degree. and the textile material is first rinsed in water at
60.degree. and then in water at 20.degree., followed by drying at
120.degree.. An orange dyeing of high color intensity is obtained
in this manner.
EXAMPLE 3
33.3 g. of a polyester-cotton mixed fabric (65:35) are introduced
into 1,000 ml. of dyeing liquor heated to 65.degree. and containing
0.5 g. of ammonium sulphate, 0.5 g. of a condensation product from
naphthalene sulphonic acid and formaldehyde, 0.5 g. of a reaction
product of methyltaurine with oleic-acid chloride and 5.0 g. of a
mixture consisting of 2.25 g. of o-phenylphenol, 0.125 g. of
di-iso-butyl sodium sulphosuccinate (85percent), 2.05 g. of
ethylene glycol, 0.125 g. of polyvinyl alcohol (mean ester number
100-200; viscosity of a 4 percent aqueous solution: 4-50 c.p.s. at
20.degree.) and 0.45 g. of water. The textile material is treated
for 15 minutes at the same temperature. To the clear bath are added
50 ml. of an aqueous suspension heated to ca. 60.degree. and
containing 0.5 g. of the same dyestuff as in example 1 and 0.3 g.
of sodium-diisobutylnaphthalene-sulphonate. Dyeing is performed for
a further 15 minutes at 65.degree. and the temperature is increased
successively within 45 minutes up to the boiling point. While
boiling, dyeing is performed for 90 minutes. The textile material
is then rinsed with water at 60.degree. and then in a new bath
(ratio of material to liquor 1:30), which contains 3 ml./l. of
sodium hydroxide solution (38.degree. B.), 2 g./l. of sodium
dithionite, 1 g./l. of a condensation product from 1 mol of coconut
oil fatty acid and 2 mols of diethanolamine, the textile material
is treated for 30 minutes at 80.degree.. It is then well rinsed and
the cotton constituent is dyed as usual.
EXAMPLE 4
25 g. of polyester fabric are introduced into 1,000 ml. of dyeing
liquor heated to 65.degree. and containing 0.5 g. of ammonium
sulphate, 0.1 g. of sodium pyrophosphate (neutral, anhydrous), 0.5
g. of a condensation product from naphthalene sulphonic acid and
formaldehyde, 0.5 g. of a reaction product of methyl taurine with
oleic-acid chloride and 5.0 g. of a mixture comprising 2.5 g. of
o-phenylphenol, 2.0 g. of ethylene glycol, 0.15 g. of polyvinyl
alcohol (mean ester number 20-200; viscosity of a 4 percent aqueous
solution: 4-50 c.p.s. at 20.degree.) and 0.35 g. of water. The
textile material is treated for 15 minutes at the same temperature.
To the clear bath are added 50 ml. of an aqueous suspension heated
to ca. 60.degree. and containing 0.5 g. of the dyestuff having the
following formula: ##SPC3##
and 0.3 g. of a reaction product of methyl taurine with oleic-acid
chloride. Dyeing is performed for a further 15 minutes at
65.degree. and the temperature is then increased successively
within 45 minutes up to the boiling point with further dyeing for
90 minutes while boiling.
The liquor is then cooled and the fabric rinsed with water at
60.degree., and with water at 20.degree., followed by drying at
120.degree.. A very pure blue dyeing is obtained in this
manner.
The mixture used as a dyeing accelerator is produced by first
dissolving 3 percent by weight of the polyvinyl alcohol in 7
percent by weight of water, while stirring and heating to
60.degree.-80.degree.. 40 percent by weight of ethylene glycol is
then added and, while stirring and at ca. 40.degree.-50.degree., 50
percent by weight of o-phenylphenol is dissolved in this mixture.
Corresponding solutions of polyvinyl alcohol in water and
o-phenylphenol in ethylene glycol can also be mixed together while
stirring and at 40.degree.-50.degree..
If, in the above example, an equivalent amount of the Na-salt of
o-phenylphenol is used instead of o-phenylphenol, it is to be
recommended that ca. 10 percent (relative to the weight of the
dyeing-accelerator mixture) of an organic acid, e.g., 85 percent
formic acid, be added, so that the pH value of the bath does not
exceed 6.5 to 7.
If, in the above example 4, with otherwise the same procedure,
instead of 5 g. of a mixture consisting of 2.5 g. of
o-phenylphenol, 2.0 g. of ethylene glycol, 0.15 g. of polyvinyl
alcohol and 0.35 g. of water;
5 g. of a mixture consisting of:
2.5 g. o-phenylphenol;
2.0 g. ethylene glycol;
0.1 g. polyvinyl alcohol; and
0.4 g. water; or
5 g. of a mixture consisting of:
2.25 g. o-phenylphenol;
0.125 g. polyvinylalcohol;
2.175 g. ethylene glycol; and
0.45 g. water
is used, then a very pure blue dyeing is also obtained.
EXAMPLE 5
100 g. of a polyester-wool mixed yarn (67:33) are introduced into
1,000 ml. of dyeing liquor heated to 65.degree. and containing 0.5
g. of ammonium sulphate, 0.1 g. of sodium pyrophosphate (neutral,
anhydrous), 1.0 ml. of acetic acid, 1.0 g. of a condensation
product from naphthalene sulphonic acid and formaldehyde and 5.0 g.
of a mixture, consisting of 2.5 g. of o-phenylphenol, 2.0 g. of
ethylene glycol, 0.15 g. of polyvinyl alcohol (mean ester number
100-200; viscosity of a 4 percent aqueous solution: 4-50 c.p.s. at
20.degree.) and 0.35 g. of water. The textile material is then
treated for 15 minutes at the same temperature. To the clear bath
are added 50 ml. of an aqueous suspension heated to 60.degree. and
containing 0.6 g. of a reaction product of methyl taurine with
oleic-acid chloride, 1.0 g. of the dyestuff having the following
formula ##SPC4##
and 0.6 g. of the 1:2 chromium complex of the dyestuff
2-amino-4-methylsulphonylphenol
1-(3'-chlorophenyl)-3-methylpyrazol-5-one. Dyeing is performed for
a further 15 minutes at 65.degree. and the temperature is then
increased within 45 minutes up to the boiling point with further
dyeing for 90 minutes while boiling. The liquor is then cooled to
60.degree. and the textile material is firstly rinsed in water at
60.degree. and then in water at 20.degree., followed by drying at
120.degree.. An orange dyeing of high color intensity is obtained
in this manner.
If, in the above example 5, with otherwise the same procedure,
instead of 5 g. of a mixture consisting of 2.5 g. o-phenylphenol,
2.0 g. ethyleneglycol, 0.15 g. polyvinylalcohol and 0.35 g.
water;
7.5 g. of a mixture consisting of:
2.25 g. o-phenylphenol;
0.15 g. polyvinylalcohol,
0.75 g. water and
4.350 g. ethyleneglycol, or
5.0 g. of a mixture consisting of:
2.25 g. o-phenylphenol,
0.05 g. polyvinylalcohol,
0.5 g. water and
2.2 g. ethylene glycol, or
4.0 g. of a mixture consisting of:
2.2 g. o-phenylphenol,
0.08 g. polyvinylalcohol,
0.24 g. water and
1.48 g. ethyleneglycol
is used, then an orange dyeing of high color intensity is also
obtained.
EXAMPLE 6
33.3 g. of a polyester-cotton mixed fabric (65:35) are introduced
into 1,000 ml. of dyeing liquor heated to 65.degree. and containing
0.5 g. of ammonium sulphate, 0.5 g. of a condensation product from
napthalene sulphonic acid and formaldehyde, 0.5 g. of reaction
product of methyltaurine with oleic-acid chloride and 5.0 g. of a
mixture consisting of 2.5 g. of o-phenylphenol, 2.0 g. of ethylene
glycol, 0.15 g. of polyvinyl alcohol (mean ester number 100-200;
viscosity of a 4 percent aqueous solution: 4-50 c.p.s. at
20.degree.) and 0.35 g. of water. The textile material is treated
for 15 minutes at the same temperature. To the clear bath are added
50 ml. of an aqueous suspension heated to ca. 60.degree. and
containing 0.5 g. of the same dyestuff as in example 1 and 0.3 g.
of sodium-diisobutylnaphthalene-sulphonate. Dyeing is performed for
a further 15 minutes at 65.degree. and the temperature is increased
successively within 45 minutes up to the boiling point. While
boiling, dyeing is performed for 90 minutes. The textile material
is then rinsed with water at 60.degree. and then in a new bath
(ratio of material to liquor 1:30), which contains 3 ml./l. of
sodium hydroxide solution (38.degree.B.), 2 g./l. of sodium
dithionite, 1 g./l. of a condensation product from 1 mol of coconut
oil fatty acid and 2 mols of diethanolamine, the textile material
is treated for 30 minutes at 80.degree.. It is then well rinsed and
the cotton constituent is dyed as usual.
* * * * *