U.S. patent number 3,632,415 [Application Number 04/700,386] was granted by the patent office on 1972-01-04 for synthetic organic fiber --asbestos fiber fabric and asphalt impregnated product.
This patent grant is currently assigned to Phillips Petroleum Company. Invention is credited to Marvin L. Franklin, Duane W. Gagle.
United States Patent |
3,632,415 |
Franklin , et al. |
January 4, 1972 |
SYNTHETIC ORGANIC FIBER --ASBESTOS FIBER FABRIC AND ASPHALT
IMPREGNATED PRODUCT
Abstract
A mat or fabric is made of asbestos fiber incorporated with
polyethylene, polypropylene, Nylon and/or polyvinylchloride staple,
split film, fibers or other synthetic organic fiber or subdivided
polymeric material or plastic. The composite product either alone
or impregnated, as with an asphaltic material, is suited for use as
insulation, construction material, molding, and the like.
Inventors: |
Franklin; Marvin L.
(Bartlesville, OK), Gagle; Duane W. (Bartlesville, OK) |
Assignee: |
Phillips Petroleum Company
(N/A)
|
Family
ID: |
24813294 |
Appl.
No.: |
04/700,386 |
Filed: |
January 25, 1968 |
Current U.S.
Class: |
524/62;
210/509 |
Current CPC
Class: |
D06N
5/00 (20130101) |
Current International
Class: |
D06N
5/00 (20060101); B32b 019/02 (); B01d 039/20 () |
Field of
Search: |
;117/126R,168,138.8E,138.8N,138.8F,138.8UA ;106/282 ;162/145
;210/509 ;161/169,170 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Martin; William D.
Assistant Examiner: Cohen; David
Claims
1. An asphalt impregnated composite consisting essentially of (a)
synthetic organic fibrous material in the form of staple, split
film, or fiber, selected from a polyolefin, nylon,
polyvinylchloride, and a fluorocarbon, (b) asbestos fiber, and (c)
asphalt in proportions sufficient to provide
2. A composite according to claim 1 wherein the synthetic organic
fiber is
4. A composite according to claim 1 wherein the asbestos fiber is
short
5. An asphalt impregnated filter cloth consisting essentially of
(a) synthetic organic fibrous material in the form of staple, split
film, or fiber, selected from a polyolefin, nylon,
polyvinylchloride and a fluorocarbon, (b) asbestos fiber, and (c)
asphalt, wherein the asphalt at least partially covers and to an
extent seals together the respective fibers at their points of
contact, thus partially filling the interstices
6. A composite according to claim 5 wherein the synthetic organic
fiber is
7. A composite according to claim 5 wherein the asbestos fiber is
short asbestos fiber.
Description
This invention relates to a product comprising synthetic organic
fiber, asbestos, and/or asphalt or other binding or sealing
material. In one of its aspects it relates to a fabric comprising
synthetic organic fiber, e.g., a polymer, asbestos fiber and/or
asphalt or other binding or sealing material. In another of its
aspects, the invention relates to a mat or fabric made or composed
of asbestos fibers incorporated with a polymer, e.g., a polyolefin,
such as polyethylene and/or polypropylene, Nylon, and/or
polyvinylchloride staple, split-film or other fibrous material. The
fiber or fibrous polymer-asbestos composite or combination in a now
preferred form of the invention is composited or impregnated
together with an asphaltic material or other binding or sealing
material. The several products of the invention are useful for
insulation, packaging materials, construction material and filter
cloth.
The production of improved fabrics for mats or cloths is a constant
desire in the art. A great deal has been done and reported in the
production of composites to produce fabrics or other articles,
mats, or cloths which will have certain desirable properties or
characteristics. For example, it is a constant desire in the art to
produce greatly improved resistance to fire on the part of such
materials which, though they may possess other desirable
properties, they may not possess desirable resistance to fire.
Insulating materials used for insulation against heat must have
certain minimum desirable fire resistance properties. The
production of resilient materials as for packaging or vibration
absorption is also desirable.
The incorporation into asbestos fiber so as to loosen or expand the
felted body and to increase the ratio of interstitial space to
space occupied by asbestos fibers of a sufficient number of stiff,
elastic, hairlike bodies which hold the asbestos fibers from each
other so as to render the asbestos felted sheet more absorptive of
fluid asphalt is known. It is known to produce asbestos roofing
papers or felt, which is emersed in asphalt at about 400.degree. F.
It is also known that fibrous mineral filler is more effective in
affording high flow resistance than is a nonhigh fibrous mineral
filler in the art dealing with asphalt saturated organic fiber
felt. Further, it is known to add asbestos fiber to asphalt to
retard liquid flow tendency of the material when heated. The
properties, generally speaking, of certain organic synthetic
materials are known.
We have now discovered that synthetic organic fiber-asbestos fiber
can be combined to produce improved fabrics or mats or filter
cloths. We have also found that such a material can be impregnated
with asphalt and that there can be produced an asphalt-filled
material which is quite uniform in texture in the sense that there
are no pinholes present therein. Such composites can be produced
with asbestos of white, filtration grade. This is of particular
importance when one considers that the filtration grade asbestos
used can have short as well as long fibers, i.e. the composite can
be prepared from fibers which are, relatively speaking, short,
considerably shorter than those of filtration grade, which are long
enough to be woven into filter cloth. We have found by the use of
the organic, synthetic fiber such as polypropylene fiber that
short, asbestos fibers can be made into filtration "cloth." These
short asbestos fibers are not suitable for use alone to be made
into filter cloth. We have further found that the synthetic organic
fiber-asbestos fiber material composited according to the
invention, e.g. polypropylene fiber-asbestos fiber, can take up or
absorb about twice as much asphalt as can conventional materials
such as Kraft paper, cotton fiber, wool fibers and the like. It is
noteworthy that synthetic organic fibers such as polyolefin fibers
particularly polypropylene, are rot proof, while the conventional
materials deteriorate in use.
The asbestos fabric loaded with asphalt emulsion very readily and
did not show pinholes as had been obtained employing polyolefin,
e.g. polypropylene fabric alone. The impregnated fabric or
composite resists flow exceptionally well at temperatures as high
as 140.degree. F. and are therefore especially valuable for
application on inclined surfaces, e.g. steep roofing.
Further, we have found using a fabric such as Loktuft (a trademark
for polypropylene fabric) treating the same with added asbestos and
asphalt raised melt flow from an original 120.degree. F. to
approximately 180.degree. F. over use of asphalt on the fabric
alone. This was done using an asphalt-asbestos mix which penetrated
the Loktuft which is a nonwoven fabric, instead of packing on its
surface. It is also possible to mix the asbestos with the nonwoven
material and to then add the asphalt.
The short asbestos fibers to which reference has been made herein
are only 1/4 -inch to 3 inches in length and are intimately
intermixed in the polypropylene staple as by some roughening up or
mixing process and can be prepared by needle punching.
Particularly, we have found that a superior filter cloth can be
prepared by the incorporation of asbestos fibers in nonwoven
synthetic organic fabrics such as nonwoven polypropylene. The
well-known filtering capability of the asbestos fibers combines
with the desirable filtration properties of the organic fiber to
give an improved filter effectiveness in applications wherein
either the organic fiber, e.g., polypropylene or the asbestos can
be used separately. However, the fabric will provide the release
properties that the mass filter media do not possess without undue
loss and expensive backwashing problems. Longer filter service can
be obtained for any liquid which must be separated from solids. The
fabric of the invention can be effectively used for cartridge types
either baffled or packed. Moreover, the organic fiber or split-film
material, e.g., split-film polypropylene provides support for the
asbestos fibers in drum, vacuum, precoat, or other type filters
used for clarification operations wherein asbestos is particularly
well suited and desired.
Economies can be realized by combining asbestos and a synthetic
organic fiber at a lesser cost on a weight basis than can be
obtained by asbestos alone. Although a polyolefin material such as
polypropylene as herein described is a now preferred synthetic
organic fiber, the other materials known in the art as are
mentioned herein and others can be used to effect the overall
concepts of the invention; thus, in addition to those already
named, fluorocarbon resin fibers can be used in the system; for
example, in a nonwoven system as a carrier and to augment asbestos
filtration.
A particularly noteworthy advantage of the combination of the
synthetic organic fiber and the asbestos is found in the
heat-sealing of the asbestos fibers, especially short asbestos
fibers into the synthetic organic fiber mass. This is particularly
advantageous where maximum durability and resistance to handling,
etc., and/or strenuous use is desired.
Where heat-sealing is practiced and impregnation with asphalt is
also desired, the heat-sealing is preferably practiced prior to the
impregnation with asphalt.
It is an object of this invention to produce an improved mat. It is
a further object of this invention to provide an improved fabric.
It is a still further object of this invention to provide an
improved asbestos-containing product. It is a still further object
of this invention to provide an improved mat or fabric containing
asbestos fibers and having improved asphalt absorption and
retention properties. A further object of the invention is to
provide an improved filter cloth. A further object of the invention
is to provide an improved insulation or construction material. A
further object is to provide a resilient or vibration absorption
material. It is a still further object of the invention to provide
a fabric or mat which can be heat-sealed to provide improved
properties. It is a still further object of this invention to
provide a composite containing asbestos fibers which can be
heat-sealed. A still further object of this invention is to provide
such a composite which can be sealed, at least partially, employing
asphalt or some other bonding or sealing material. It is a still
further object of this invention to provide a composite comprising
asbestos which can be molded or heat treated to retain a desired
shape.
Other aspects, concepts and objects of this invention are apparent
from a study of this disclosure and the appended claims.
According to the present invention, there is provided an improved
composite containing asbestos fibers, the asbestos fibers being
incorporated together with a synthetic organic fiber.
According to the present invention, there is provided an improved
composite which has been bonded together and, at least partially,
filled interstitially by adding thereto a bonding or sealing
material and/or by heat sealing the same.
Herein and in the claims the term "fiber" includes any fibers or
filamentatious material including split-film; for example, a tow,
produced by stretching and fibrillation.
Further, according to the present invention there is provided an
improved composite material suitable for various uses as herein
described and delineated, the composite comprising in addition to
synthetic organic fiber an asbestos and impregnating material such
as an asphalt.
The synthetic organic fibers which are applicable for use in this
invention are various. Generally, the fibrous materials now known
in the art are all of them useful to an extent, albeit those herein
more particularly described are now preferred.
Further, though the invention is applicable for use to obtain its
excellent results when the longer filtration grade asbestos fibers
are available it is of especially noteworthy value when only short
fibers as herein described are available. It is known that in the
free world only Rhodesia and South Africa possess filtration grade
asbestos fibers. These African fibers are long enough to be woven
into filter cloth. However, the short fibers which are available
from other asbestos mines cannot be used alone to prepare
filtration cloths.
Referring now to the term "pinholes," the following examples
illustrate a composite according to the invention as well as one
not according to the invention; that is, a composite not containing
asbestos.
EXAMPLE I
An asbestos-polypropylene fabric prepared according to the
invention was asphalt loaded by dipping. This fabric contained
approximately 50 percent polypropylene Loktuft fabric as herein
described and 50 percent AAA asbestos having a weight of
approximately 7 ounces per square yard. After dipping and curing
the asphalt impregnated sample had a thickness of approximately 1
millimeter. When raised to the light, no pinholes were visible to
the naked eye.
EXAMPLE II
Polypropylene fabric not containing any asbestos fibers was asphalt
loaded with the same asphalt by dipping in same manner as in
example I. After dipping and curing, the product had a thickness of
approximately 1 millimeter. When held to the light, there could be
observed quite a scattering of pinholes. That is to say, light
could be seen through holes which were like unto those which might
have been produced by indiscriminately jabbing a pin through the
fabric to obtain as many as 10 and perhaps more holes of
well-defined shape in an area of about 9 square millimeters.
It is noteworthy that the fabric of example I possessed about 3
times the resistance to manual bending as did the fabric of example
2.
EXAMPLE III
A composite of 50 percent polyvinylchloride and 50 percent asbestos
was prepared and found to possess a 5 ounce per square yard weight
for an end product fabric in pressure free form having an
approximate thickness of 3 millimeters and in tightly compressed
form of less than about one-half millimeter.
This fabric was fluffier in texture and appearance than was a 50
percent polypropylene 50 percent asbestos fabric which weighed 6.6
ounces per square yard and which in pressure free form had a
thickness of about 2 millimeters and which in compressed form had a
thickness of less than about one-half millimeter.
A similar fabric was made of 50 percent split-film polypropylene
and 50 percent AAA asbestos. This fabric had a weight of 6.1 ounces
per square yard and a 2 millimeter thickness in pressure free form.
In compressed form it had a thickness of less than about one-half
millimeter. Other similar examples prepared from other synthetic
organic films, fibers or nonwoven fabrics or split-film give
similar properties which can be observed.
EXAMPLE IV
The composites of the preceding paragraphs will all of them take up
asphalt into which they can be dipped. Or, the asphalt can be
otherwise applied as may be desired as by spraying, preferably as
an emulsion.
EXAMPLE V
A fabric according to example I is applied to a filter screen
backing plate and is found to retain particles of solid which are
of the order of submicron in size.
In application Ser. No. 666,994, filed Sept. 11, 1967, now U.S.
Pat. No. 3,505,260, there are described and claimed blends of
finely divided fibers of a homopolymer or copolymer of ethylene or
propylene and asphalt, the blend containing approximately "10-85"
weight percent asphalt and approximately "15-90" weight percent of
the finely divided fibers.
The following paragraphs are given by way of disclosure to be
helpful to one skilled in the art to more fully understand and to
better apply the invention for concepts herein set forth.
The asphalts employed for spraying or dipping or other application
to the fibrous materials can be in the form of emulsions which can
be cationic, anionic or nonionic or mixtures thereof. These
emulsions can be prepared by any method suitable and known to those
skilled in the art.
The asphalts used in the system include any of those bituminous
materials used heretofore and known in the prior art, such as
natural asphalts or those derived from petroleum refining, for
example, by vacuum distillation, steam refining and/or air blowing,
and the like. Asphalts characterized by penetrations (ASTM D-5-51)
from 0 to about 300 or even higher and preferably from about 40 to
300 and having softening points (ASTM D-36-26) in the range of
90.degree. to 250.degree. F. and preferably 100.degree. to
150.degree. F., represent suitable asphalts that can be employed.
These asphalts can be cut back with various hydrocarbon solvents to
make the known rapid-curing, medium-curing, and slow-curing road
oils which can be used for treating the fabric.
The asphalts used in the preparation of the emulsion include any of
those bituminous materials used heretofore and known in the prior
art, such as natural asphalts or those derived from petroleum
refining, for example, by vacuum distillation, steam refining
and/or air blowing, and the like. Asphalts characterized by
penetrations (ASTM D-5-51) from 0 to about 300 or even higher and
preferably from about 40 to 300 and having softening points (ASTM
D-36-26) in the range of 90.degree. to 250.degree. F., and
preferably 100.degree. to 150.degree. F., represent suitable
asphalts that can be employed.
The relative amounts of the various components of the asphalt
emulsions can vary but in general the asphalt is present in an
amount in the range of 50-70, preferably 60-65 weight percent; the
emulsifier is present in an amount in the range of 0.1 to 4,
preferably 0.25 to 1; and water is present in the amount between 50
and 25, preferably 32-39 weight percent based on the total
blend.
The asphalt emulsions employed can be prepared by any method known
to those skilled in the art, for example, by preparing a soap
solution comprising water, either soft or hard, and an emulsifying
agent, either cationic, anionic, or nonionic. The soap solution is
then mixed in a colloid mill or the like with the asphalt phase,
the latter being preferably heated to reduce the viscosity.
Usually, the emulsifiers and any modifiers or promoters are
dispersed in the water to form a soap solution which is then warmed
to a temperature of 90.degree. to 200.degree. F., preferably
90.degree. to 125.degree. F. The asphalt can be heated to a
temperature in the range of 150.degree. to 350.degree. F.,
preferably 250.degree. to 300.degree. F. The warm soap solution and
hot asphalt are then proportioned to a colloid mill to emulsify the
mixture during which milling the temperature of the mixture can be
in the range of 100.degree. to 210.degree. F., preferably
150.degree. to 200.degree. F. The completed emulsion is then cooled
to a temperature below 150.degree. F. before being used or
transferred to storage. The method of preparing an emulsion will
have some effect on the properties thereof and the intended
application or utility of the emulsion will dictate which
particular method one should use to get the desired properties.
A polyolefin material such as Loktuft has already been mentioned.
Generally, there can be used fibers of polyolefins, particularly
finely divided fibers of polymers of mono-1-olefins having from two
to eight carbon atoms per molecule, preferably polymers of ethylene
or propylene including both homopolymers and copolymers, which can
be mixed with asbestos as described and/or impregnated with or
coated with an asphalt or an asphalt emulsion such as hereinbefore
described. In addition, the asphalt emulsion or blend of emulsion
and asbestos fibers can be applied to a cloth or mat made from
fibers that have been previously woven or matted into a cloth or a
structure resembling same to form a (waterproof) structure. The
water in the emulsion is then removed by any suitable method such
as air drying or drying in an oven or by the heat employed in the
molding operation.
Clearly, the polyolefin fabrics which can be used are various.
However, presently preferred is a fabric or mat made of
polypropylene, especially polypropylene produced by the so-called
low-pressure process. "Loktuft," a nonwoven fabric of polypropylene
fiber available from Revonah Spinning Mills, Trenton and Castor
Avenue, Philadelphia, Pennsylvania, 19134, is a now preferred
fabric which is available in rolls of about 6 feet width and
lengths of about 200 to 300 lineal feet. This fabric has a weight
of about 4 to 6 ounces per square yard, a tensile strength in the
"warp" direction of 80-90 pounds and a tensile strength in the fill
or woof direction of about 90-100 pounds. This fabric will hold up
to 4 times as much asphalt material as will burlap mats, cotton
fibers, woven cloth, etc. Other forms of polypropylene or
polyolefin can be used according to the invention. For example,
various length fibers composing a nonwoven mat or woven fabric can
be used. The polyolefin of which "Loktuft" is made is known in the
trade as a Marlex (Trademark) polyolefin. Such a polyolefin can be
prepared according to a process set forth in U.S. Pat. No.
2,825,721, John P. Hogan and Robert L. Banks, issued Mar. 4, 1958.
The disclosure of said patent is incorporated herein by reference.
The polyolefins of said patent are known as high-density
polyolefins. Although various polymers and copolymers of the
several olefins described in said patent can be used, as can be
others, to execute the various embodiments of the invention here
described or variants thereof, it is now preferred to use a
polypropylene material as described.
A particularly useful class of cationical emulsifying agents are
salts of organic bases characterized by the presence of at least
one basic nitrogen atom in the cation portion and where the latter
contains a long chain aliphatic hydrocarbon radical of at least 12
and as many as 24 carbon atoms, preferably a straight chain fatty
aliphatic group. A particularly useful subclass of such cationic
emulsifying agents are the tetra-substituted quaternary ammonium
compounds such as those of the formula: ##SPC1##
where R.sub.3 is a long alkyl chain of at least 12 and as many as
24 carbon atoms, and the R.sub.4 's are shorter alkyl radicals or
benzyl radicals, the presence of which is sufficient to impart oil
solubility and emulsifying properties to the salt material, X' is a
hydroxyl or an anion such as nitrate, sulfate, secondary phosphate,
acetate, benzoate, salicylate and preferably a halogen, such as
chlorine or bromine, v is the valence of said hydroxyl or anion,
and x is an integer equal to said valence. Another particularly
useful subclass of cationic emulsifying agents is the salts of
heterocyclic nitrogen bases, such as alkyl pyridine, alkyl
quinoline, alkylisoquinoline and alkyl imidazoline, a particularly
useful group of the latter being represented by the general
formula: ##SPC2##
where R.sub.3 is an aliphatic radical selected from the group
consisting of alkyl and alkenyl radicals, preferably having 12 to
24 carbon atoms, R.sub.4 is selected from the group consisting of
hydrogen and alkyl radicals, preferably having 1 to 4 carbon atoms,
and X" is an anion such as nitrate, sulfate, secondary phosphate,
acetate, benzoate, salicylate and preferably a halogen, such as
chlorine and bromine, n is an integer equal to the valence of the
anion and x is an integer of 1 to 3. Primary, secondary and
tertiary mono-amines and diamines are also useful, particularly the
fatty acid diamines of the general formula R.sub.3
NH(CH.sub.2).sub.m NH.sub.2, where R.sub.3 is as defined above in
formula (2) and m is an integer in the range of 1 to 3.
Representative cationic emulsifying agents which can be used in
this invention include cetyltrimethylammonium bromide,
cetyldimethylammonium bromide, "tallow" trimethylammonium chloride
(the term "tallow" referring to the radical of a mixture of fatty
acids derived from tallow), n-dodecyltrimethylammonium chloride,
n-dodecyltrimethylammonium bromide, n-dodecyltriethylammonium
hydroxide, n-tetradecyltrimethylammonium chloride,
n-hexadecyltripropylammonium iodide, n-octadecyltri-n-butylammonium
nitrate, n-octadecyltriethylammonium chloride,
n-hexadecyltrimethylammonium chloride, n-eicosyltrimethylammonium
chloride, n-tetracosyltrimethylammonium acetate,
n-pentadecylethyldimethylammonium chloride,
n-docosylpropyldimethylammonium chloride,
n-tricosyl-n-decyldiethylammonium benzoate,
n-tetradecyl-n-heptyldimethylammonium chloride,
n-octadecyl-n-decyldimethylammonium chloride,
n-heptadecyldipropylmethylammonium chloride,
n-nonadecyl-di-n-octylmethylammonium chloride,
n-hexadecylethyldimethylammonium chloride,
n-dodecylbenzyldimethylammonium chloride,
n-pentadecylbenzyldiethylammonium fluoride,
n-octadecylpropyldimethylammonium salicylate,
n-dodecyl-n-butylbenzylmethylammonium bromide,
n-nonadecyldiethylmethylammonium sulphate,
n-eicosyltrimethylammonium orthophosphate,
1-(2-aminoethyl)-2(4-tetradecenyl)-4,5-di-n-butyl-2-imidazoline,
1-(2-aminoethyl)-2(1,1-diethyl-5,7-dodecadienyl)-4,5-dimethyl-2-imidazolin
e, 1-(2-aminoethyl)-2-n-octadecyl-4-ethyl-2-imidazoline,
1-(2-aminoethyl)-2-n-eicosyl-2-imidazoline,
1-(2-aminoethyl)-2-(1,1-dimethyldecyl)-2-imidazoline,
1-(2-aminoethyl)-2-(12-heptadecenyl)-2-imidazoline,
1-(2-aminoethyl)-2-(5,7-heptadecadienyl)-2-imidazoline, and the
like, including mixtures thereof.
There are a number of commercially available cationic emulsifying
agents which can be used, including: Nalcamine G-39M, which is a
mixture of 1(2-aminoethyl)-2-n-aliphatic-2-imidazolines where the
aliphatic groups are heptadecenyl and heptadecadienyl; Hyamine
1622, octylphenoxyethoxyethyl-dimethylbenzylammonium chloride;
Hyamine 2389, methyldodecylbenzyltrimethylammonium chloride;
Hyamine 10-X, octylcresoxyethoxyethyldimethylbenzylammonium
chloride; Nalquate G-8-12, 1-(2-oxyethyl)-2-n-alkyl-1 (or 3)
-benzyl-2-imidazolinium chlorides; Diam 11-C (n-alkyl-1,3-propylene
amines); Aliquat 26 nonotallowtrimethylammonium chloride; Alamine
26, primary tallow amine; Duomeen T. N-alkyltrimethylenediamine;
and the like. In addition, an acid, such as hydrochloric acid,
sulfuric acid, acetic acid or sulfamic acid, can be incorporated
into the asphalt emulsion to enhance the surface active properties
of the cationic emulsifying agent and impart an acid pH below 7 to
the emulsion. Generally, pH's in the range of 2 to about 6.5,
preferably 3 to 5, are suitable for these acidic emulsions. The
amount of the acid will generally be 0.1 to 1, preferably 0.2 to 1,
weight percent of the emulsion, but can be considered and
calculated as part of the cationic emulsifying agent. Sulfamic acid
is especially useful where the asphalt used is of an aromatic
nature and has an oil fraction which has an A.P.I. gravity not
exceeding 15.5, and preferably not exceeding 15, and is useful
where the asphalt emulsion must pass the modified miscibility test
or the cement mixing test, which are described hereinafter.
Suitable nonionic emulsifying agents include those of the general
formula:
where R is selected from the group consisting of hydrogen, aryl,
and alkylaryl radicals; and x, y and z are integers, such that (1)
when x is zero, y is also zero, z is in the range of 6 to 11,
inclusive, and said R is one of said aryl and alkylaryl radicals,
and (2) when x and y are each greater than zero, the sum of x and z
is in the range of 20 to 40, inclusive, and y is in the range of 40
to 60, inclusive.
Representative examples of the nonionic emulsifying agents include:
phenoxypenta(ethyleneoxy)ethanol, phenoxyocta(ethyleneoxy)ethanol,
phenoxyennea(ethyleneoxy)ethanol, phenoxyennea(ethyleneoxy)ethanol,
phenoxydeca(ethyleneoxy)ethanol,
4-methylphenoxypenta(ethyleneoxy)ethanol,
2,3,6-triethylphenoxyhepta(ethyleneoxy)ethanol,
4(1,1,3,3-tetramethylbutyl)phenoxyhepta(ethyleneoxy)ethanol,
4(1,3,5-trimethylhexyl)phenoxyhexa(ethyleneoxy)ethanol,
4-nonylphenoxyhepta(ethyleneoxy)ethanol,
2,3,4,5,6-penta-n-pentylphenoxyennea(ethyleneoxy)ethanol,
2(1,3,5-trimethylhexyl)-4(1,3-dimethylbutyl)phenoxypenta(ethyleneoxy)ethan
ol, 4(3,5,5-trimethylheptyl)phenoxyhexa(ethyleneoxy)ethanol,
3(3,5,7,7-trimethyl-5-ethylnonyl)phenoxyhepta(ethyleneoxy)ethanol,
4(1,1,3,3,5,5,7,7-octamethyldecyl)phenoxyennea(ethyleneoxy)ethanol,
4-n-pentacosylphenoxypenta(ethyleneoxy)ethanol,
3,5-di-n-decyl-4-n-pentylphenoxydeca(ethyleneoxy)ethanol,
beta-hydroxyethyleneoxytetraconta(propyleneoxy)octadeca(ethyleneoxy)ethano
l,
beta-hydroxyethoxyoctadeca(ethyleneoxy)tetracontra(propyleneoxy)ethanol,
beta-hydroxyethoxyennea(ethyleneoxy)pentaconta(propyleneoxy)deca(ethyleneo
xy)ethanol,
betahydroxyethoxynonadeca(ethyleneoxy)hexaconta(propyleneoxy)nonadeca(ethy
leneoxy)ethanol,
beta-hydroxyethoxytetradeca(ethyleneoxy)pentatetraconta(propyleneoxy)tetra
deca(ethyleneoxy)ethanol,
phenoxyethyleneoxypentapentaconta(propyleneoxy)octatriaconta(ethyleneoxy)e
thanol,
4-methylphenoxydeca(ethyleneoxy)nonatetraconta(propyleneoxy)eicosa(ethylen
eoxy)ethanol,
4(1,3,5-trimethylhexyl)-phenoxyhexa(ethyleneoxy)pentacontra(propyleneoxy)t
riconta(ethyleneoxy)ethanol,
4-n-pentacosylphenoxypentacosa(ethyleneoxy)pentaconta(propyleneoxy)deca-(e
thyleneoxy)ethanol,
2,4,5-trimethylphenoxydeca(ethyleneoxy)pentaconta(propyleneoxy)pentacosa(e
thyleneoxy)ethanol,
2(1,3,5-trimethylhexyl)-4(1,1,3,3-tetramethylbutyl)-phenoxyeicosa(ethylene
oxy)hexatetraconta(propyleneoxy)penta-(ethyleneoxy)ethanol,
4-n-pentacosylphenoxyeicosa(ethyleneoxy)hexaconta-(propyleneoxy)-nonatriac
onta(ethyleneoxy)ethanol, and the like, and mixtures thereof.
In addition, other nonionic emulsified agents may be used including
(a) those of the general formula:
where R is selected from the group consisting of hydrogen, aryl and
alkaryl radicals; and x, y, and z are integers such that (1) when x
is zero, y is also zero, z is in the range of 20 to 60, and R is
one of said aryl and alkaryl radicals, and (2) when x and y are
each greater than zero, the sum of x and z is in the range of 50 to
350, and y is in the range of 40 to 60; together with (b) a smaller
proportion of a cationic emulsifying agent exemplified by the
tetra-substituted quaternary ammonium compounds or the salts of
heterocyclic nitrogen bases, and (c) naphtha.
The nonionic emulsifying agents, as shown by the general formula,
represent a rather narrow class of compounds and they have a
critical balance of hydrophobic component (the R and propyleneoxy
groups) and hydrophilic component (ethyleneoxy groups) necessary to
give the necessary mixing time. Within the general formula given
earlier for these nonionic emulsifying agents, there are two
preferred subclasses that can be represented by the following
general formulas: ##SPC3##
where R.sub.1 is selected from the group consisting of hydrogen and
alkyl radicals having one to 25 carbon atoms, the total number of
carbon atoms in the alkyl radicals preferably does not exceed 25,
and n is an integer in the range of 20 to 60; and
where a and c are integers greater than zero and whose sum is in
the range of 50 to 350, b is an integer in the range of 40 to 60,
and R.sub.2 is selected from the group consisting of hydrogen and
the hydrocarbon radical: ##SPC4##
where R.sub.1 is as defined above.
A particularly preferred nonionic emulsifier is Triton X-305, which
is a mixture of octaphenoxypoly(ethyleneoxy)ethanol having 30
ethyleneoxy groups in the poly(ethyleneoxy) chain.
A particularly suitable combination comprises a mixture of nonionic
and cationic emulsifying agents, particularly when asphalt
emulsions are employed which exhibit lack of stability in the
presence of siliceous aggregates.
Suitable anionic emulsifying agents employed include the
sulfonates, particularly the alkyl aryl sulfonates, such as:
p-dodecylbenzene sodium sulfate, n- or
iso-p-octylphenoxypoly(ethyleneoxy)ethanol sodium sulfonates,
sodium isopropylnaphthalene sulfonate, sodium tetrahydronaphthalene
sulfonate and methylnaphthylene sodium sulfonate (Petro Ag); and
the sulfates: sodium cetyl sulfate (n-hexadecylsodiumsulfate),
ammonium lauryl sulfate, sodium tridecyl sulfate; and the
phosphates: alkylpolyphosphates, complex amidophospho salts, as
well as esters and others such as: sodium diamyl sulfosuccinate and
disodium-N-octadecyl sulfosuccinamate.
Although not essential, other materials may be employed in the
asphalt emulsion, including such stabilizing agents as
hydroxyethylcellulose, aluminum chloride, and calcium chloride.
The fibers of the synthetic organic material as well as the
asbestos fibers can be pretreated as by chopping, carding or other
physical handling as may be desired to achieve an intended
effect.
When desired, heating of the synthetic organic material or polymer
within the composite to a temperature at which it will undergo heat
sealing or combination with the fibrous material and/or asphalt
adjacent to same can be practiced. By selecting desirable thickness
of material and forming it into a desired shape and practicing the
heat sealing, a molded article can be prepared. This is especially
useful when molding roof capping shingles, such as are placed on
ridges. The invention is not limited simply to the molding of
roofing shingles as one skilled in the art will understand. Other
objects or articles can be similarly molded.
Usually the mat made of asbestos fiber incorporated with synthetic
organic fiber is not treated with the asphalt material when used as
filter cloth. However, when the material to be filtered is not a
solvent for the asphalt, the mat can be treated with asphalt in an
amount to not completely close off the openings in the mat so that
a stronger cloth is produced which can filter solids from the
liquid containing them.
The mat made of asbestos fiber incorporated with synthetic organic
fiber can have the inclusion of filter aids such as diatomaceous
earth, cellulose, and the like. These materials can be used in a
fabric or felted form as well as mass filter media.
The mat made of asbestos fiber incorporated with synthetic organic
fiber can be stabilized with epoxy or other hydrocarbon-resistant
compounds by spraying, dipping, or the like.
Various methods can be used for preparation of the mat or fabric.
The asbestos fibers and the synthetic organic fibers are intermixed
such as by air agitation, tumbling in a container or drum, or other
conventional apparatus. The mixture of fibers is then spread over a
base such as cheese cloth, metal screen, or other conventional open
texture fabric material. This spread out staple mix is
conventionally needle tufted, matted, or felted. The mixture of
staple can even be woven. The mat or fabrics can be prepared by
causing the fibers to impinge against each other, such as in a
Micronizer.
The asphalt material, e.g., melted asphalt, cutback asphalt (road
oils), or various asphalt emulsions can be incorporated into the
fabric or mat by such as rolling, brushing, spraying, dipping, or
other conventional applicating methods. The fibers can be forced or
shot into the asphalt emulsion.
Obviously one skilled in the art can determine optimum amounts of
each fiber to use in a particular application after having studied
this invention. Weight ratios of asbestos staple to synthetic
organic staple can vary over a wide range, e.g., 1:100 to 100:1,
preferably 1:50 to 50:1, and more preferably 1:10 to 10:1 whereby
the effect of each fiber will be realized to the extent desired in
the mat or fabric, depending upon the final use of the
material.
Reasonable variation and modification are possible within the scope
of the foregoing disclosure and the appended claims to the
invention, the essence of which is that there have been provided
composites of synthetic organic fibers and asbestos fibers and such
composites impregnated with an asphaltic or other material as
herein described, the composites of the invention as these may have
been prepared being heat or otherwise sealable and with or without
incorporation of said asphalt or other material, and with or
without such sealing being useful as described.
* * * * *