U.S. patent number 3,629,097 [Application Number 05/001,002] was granted by the patent office on 1971-12-21 for control system for fluid catalytic cracking process.
This patent grant is currently assigned to Continental Oil Company. Invention is credited to John H. Smith.
United States Patent |
3,629,097 |
Smith |
December 21, 1971 |
**Please see images for:
( Certificate of Correction ) ** |
CONTROL SYSTEM FOR FLUID CATALYTIC CRACKING PROCESS
Abstract
Coke deposition rate in the reactor of a fluid cat cracker is
controlled by varying the severity and conversion level in the
reactor, while maintaining maximum air rate to the regenerator. The
temperature at the outlet of the regenerator, which is an
indication of afterburning and amount of coke buildup, is used to
control reactor temperature and catalyst-to-oil ratio in the
reactor (by resetting the reactor temperature recorder control,
which in turn controls the flow of hot regenerated catalyst from
the regenerator to the reactor), thus controlling coke deposition
to make it commensurate with air supply by controlling the severity
and conversion level in the reactor. The temperature in the
regenerator catalyst bed is held constant by varying the recycle
feed rate to the reactor in response to variations in such
temperature.
Inventors: |
Smith; John H. (Ponca City,
OK) |
Assignee: |
Continental Oil Company (Ponca
City, OK)
|
Family
ID: |
21693918 |
Appl.
No.: |
05/001,002 |
Filed: |
January 6, 1970 |
Related U.S. Patent Documents
|
|
|
|
|
|
|
Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
756659 |
Aug 30, 1968 |
3513087 |
|
|
|
702047 |
Jan 31, 1968 |
|
|
|
|
Current U.S.
Class: |
208/159;
208/DIG.1; 208/164; 208/89; 422/144 |
Current CPC
Class: |
C10G
11/187 (20130101); Y10S 208/01 (20130101) |
Current International
Class: |
C10G
11/18 (20060101); C10G 11/00 (20060101); C10g
013/18 () |
Field of
Search: |
;208/164,159,DIG.1
;23/288 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Levine; Herbert
Parent Case Text
CROSS-REFERENCES TO RELATED APPLICATIONS
This is continuation-in-part of U.S. Ser. No. 756,659, filed Aug.
30, 1968, now U.S. Pat. No. 3,513,087, which in turn was a
continuation-in-part of U.S. Ser. No. 702,047, filed Jan. 31,1968,
and now abandoned.
Claims
I claim:
1. In the continuous process of cracking a hydrocarbon feedstock in
the presence of subdivided catalyst particles, wherein the
hydrocarbon stream effects a fluidized contacting of the particles
in a reactor, conversion products are separated from the contacted
particles, separated catalyst particles containing coke deposited
hereon effect fluidized contacting of air in a separate
regenerator, said air being supplied by an air compressor,
combustion gas products are separated from regenerated catalyst
particles and such regenerated catalyst particles with a reduced
coke content are returned to the reactor for contact with
hydrocarbon feedstock, the air compressor operated at maximum
capacity with all of the air output going into the regenerator, the
coke deposition rate in the reactor is controlled by varying the
reaction severity in the reactor in response to variations in the
air supply from the compressor, the reaction severity in the
reactor is controlled by varying the temperature and the
catalyst-to-feedstock ratio in the reactor in response to the
temperature at the outlet of the regenerator while the temperature
in the regenerator catalyst bed is held constant; the improvement
which comprises holding said regenerator catalyst bed temperature
constant by varying the recycle feed rate in response to variations
in said regenerator catalyst bed temperature.
2. The process of claim 1 in which the temperature and the
catalyst-to-feedstock ratio in the reactor are varied by varying
the flow of hot regenerated catalyst from the regenerator to the
reactor.
3. In a catalytic cracking unit consisting essentially of:
a. A reactor having a first conduit attached to the upper portion
thereof, a stripper attached to lower portion thereof, and a
temperature recorder controller alarm attached to said reactor;
b. a regenerator having attached to the upper portion thereof a
second conduit and means to control the pressure in the
regenerator, and having attached to the lower portion thereof a
third conduit, equipped with a valve, said third conduit extending
up into the lower portion of the regenerator, and a fourth conduit
connected to the lower portion of the regenerator, said fourth
conduit having an air compressor connected thereto;
c. means for controlling the operation of said valve in response to
temperature variations in the reactor;
d. a fifth conduit connecting the lower portion of the reactor with
the bottom end of said third conduit and extending beyond said
connection to connect with a sixth conduit for fresh feed and a
seventh conduit for recycle feed;
e. flow rate control means in each of said sixth and seventh
conduits;
f. temperature-sensing means connected to the upper portion of the
regenerator, said temperature-sensing means being operatively
connected to said means (c);
The improvement which comprises:
g. Temperature-sensing means connected to the lower portion of the
regenerator, said temperature-sensing means being operatively
connected to said flow rate control means in said seventh
conduit.
4. The combination of claim 3 wherein said temperature sensing
means (g) comprises temperature control means for changing the
control setting of said flow rate control means in response to
temperature variations in the lower portion of the regenerator.
Description
This invention is an improved control system for a conventional
fluid catalytic cracker. The improvement consists of a method and
apparatus for maximizing the coke burning rate in the regenerator
by operating the air compressor at maximum capacity and controlling
the coke deposition rate in the reactor by varying the reaction
severity in response to variations in air supply from the
compressor. More specifically, the improvement consists of method
and apparatus for controlling the temperature in the regenerator
catalyst bed by varying the recycle feed rate to the reactor.
BACKGROUND
The background of this invention is explained in U.S. Ser. No.
756,659, filed Aug. 30, 1968, which application is hereby
incorporated in its entirety into this application.
SUMMARY OF THE INVENTION
This invention is a specific variation in the concept disclosed and
claimed in U.S. Ser. No. 756,659 and is directed to a method of
maintaining a constant temperature in the regenerator catalyst bed
in fluid catalytic cracking units which do not have feed preheating
furnaces. In U.S. Ser. No. 756,659 the unit included feed
preheating furnace 6, and the temperature in the regenerator
catalyst bed 10 was maintained constant by means of TRC 11 which
automatically reset TRCA 8 to control the fuel to furnace 6. In
this invention the unit does not contain a furnace 6 and the
regenerator catalyst bed temperature is held constant by regulating
or varying the recycle feed rate in response to variations in the
regenerator catalyst bed temperature. In other respects the concept
and method and apparatus for operating the unit is the same as that
of U.S. Ser. No. 756,659.
DESCRIPTION OF THE DRAWING
The FIGURE is a simplified flow diagram of a fluid catalytic
cracking unit embodying my invention.
DETAILED DESCRIPTION
Referring to the drawing, compressor 1 runs at maximum speed on
governor control, delivering all the air it can compress into
regenerator 2 in which the pressure is held constant (preferably at
about 10-30 p.s.i.g.) by a pressure recorder controller (PRC) 3a
operating a back pressure valve in the flue gas exit line 3. Fresh
feed and recycle gas oil streams 4 and 5 each on flow rate control
(FRC) 4a and 5a, join and pass into the reactor feed riser 7. The
temperature in the dense phase 10 of the regenerator is held
constant by a temperature recorder controller (TRC) 11 which resets
the control point of FRC 5a, which in turn controls the recycle
feed rate.
Steam and slurry recycle from the fractionator (not shown) may also
be charged to the reactor feed riser at constant rates as
indicated. Regenerated catalyst from the dense phase in regenerator
2 flows via a standpipe 12 and slide valve 13 into the lower end of
the reactor feed riser 7 where it mixes thoroughly with the steam
and fresh feed and recycle feed streams. By virtue of its higher
temperature (about 1,220.degree. F.), the regenerated catalyst
surrenders heat to the combined oil feed stream, bringing it to the
desired temperature to effect vaporization and cracking of the
latter. The resultant vapors and steam flow up through the reactor
feed riser into reactor 14, entraining the catalyst therewith. The
temperature within the reactor is controlled to maintain a reactor
temperature preferably within the range of about
890.degree.-960.degree. F., by a temperature recorder controller
alarm (TRCA) 15 which regulates the position of the slide valve 13
in the regenerated catalyst standpipe 12.
The amount of afterburning which occurs in regenerator 2 is
controlled by controlling its flue gas exit temperature with a
temperature recorder controller (TRC) 16 which resets the control
point on TRCA 15 which directly controls the reactor
temperature.
Spent catalyst from reactor 14 gravitates through stripper 17
wherein it is countercurrently swept with steam fed to the base of
the stripper via line 18 controlled by a flow recorder control
(FRC) 19. This steam stripping removes adsorbed and entrapped oil
vapors from the spent catalyst and returns them to the reactor from
whence they ultimately flow to the fractionator.
Stripped spent catalyst gravitates from the base of stripper 17
into regenerator 2 via spent catalyst standpipe 20 and slide valve
21. The position of slide valve 21 is regulated by a level recorder
controller 22 to maintain a constant head of catalyst above the
base of stripper. The catalyst level may extend up into the reactor
if desired.
Except for very short term deviations, the heat input to a
catalytic cracker must equal the heat output; otherwise system
temperatures might rise or fall to damaging levels. The sum total
heat input via combustion within the regenerator 2 must equal the
sum of the radiation losses, the sensible heat surrendered to the
flue gas leaving the regenerator, and the sensible, latent, and
reaction heats surrendered to the product vapors from the reactor
14.
If, at any time, the temperature of the dense phase 10 in the
regenerator should tend to drop, it would signify that the rate of
heat removal from the system temporarily exceeded the rate of heat
input; the regenerator TRC 11 would react by decreasing the control
setting of FRC 5a. This in turn would decrease the recycle feed
rate (line 5) to riser 7, thereby reducing the rate of heat
withdrawal from the system and thus bringing heat input and output
back into balance and returning the regenerator temperature to its
control point. It is readily apparent that by reacting in opposite
fashion, the control system just described will limit the degree to
which the regenerator temperature can climb above the control
point.
A typical unit operates at or near the following conditions:
Recycle gravity 25.degree. API Recycle temperature 540.degree. F.
Mean reactor temperature 930.degree. F. Regenerator bed temperature
1,225.degree. F. Regenerator flue gas temperature 1,275.degree. F.
Air to regenerator 200.degree. F. Coke compositions CnHn CO.sub.2
/CO ratio in flue gas 1.0 Net heat of combustion 12,300 B.t.u./No.
coke Heat loss to flue gas 3,100 B.t.u./No. coke Heat to process
9,200 B.t.u./No. coke Air required 140 s.c.f./No. coke Heat to
process 66 B.t.u./s.c.f. air Heat to recycle 100,000
B.t.u./bbl.
From the above it can be seen that the recycle rate must be changed
by 950 barrels a day to compensate for a change in air rate of
1,000 cubic foot per minute.
The control temperature setting on the TRC 16 must be somewhat
higher than that on TRC 11 to insure controlled afterburning. This
difference should be at least 5.degree. F. to ensure reasonable
controllability but should not be so high as to be wasteful of air
that might be better used for burning additional coke which would
result from raising conversion. In some instances it might be
desirable to operate with a flue gas exit temperature 50.degree. F.
or more above the regenerator dense phase temperature to maintain a
high mean oxygen concentration in the gases rising through the
dense phase to reduce the residual coke content on regenerated
catalyst to a lower level than would otherwise be achieved. For
this control scheme to function properly, it is obviously necessary
that the controlled temperature level in the regenerator dense
phase exceed the ignition temperature of carbon monoxide. The
preferred temperature is about 1,200.degree. to 1,225.degree.
F.
If, at any time, the temperature of the flue gas exiting from the
top of regenerator should tend to fall below the control point, it
would signify that there was a reduction in afterburning because of
a drop in oxygen content of the flue gases rising from the dense
phase. This in turn would signify that the means concentration of
coke on catalyst in the regenerator was rising which would means
that coke was being deposited at a faster rate than it was being
burned. The flue gas TRC 16 would immediately lower the control
setting on the TRCA 15 which would, in turn, reposition (reduce the
opening of) the slide valve 13 in the regenerated catalyst
standpipe 12. The combination of lower reaction temperature and
lower catalyst-to-oil ratio would reduce coke deposition rate by
reducing conversion level until coke deposition rate again became
commensurate with regeneration air rate (line 1a). It is readily
apparent that if the flue gas exiting temperature should tend to
rise, it would signify that coke was being deposited at a lesser
rate than it was being burned and that the automatic control action
would be the exact opposite of that just described to increase
conversion rate until the coke deposition and burning rates again
became equal. A change in reactor temperature of about 0.5.degree.
to 1.0.degree. F. will compensate for a change of one percent in
air rate or coke yield tendency of the feed stock.
In actual operation, the system may be simplified further by
substituting potentiometers or other temperature sensing means for
TRC 16 and allowing the operator to manually reset TRCA 15.
The reactor temperature control 15 includes high- and
low-temperature alarms which alert the operator if the temperature
reaches either alarm setting. The operator then takes appropriate
action to bring the reactor temperature back within the prescribed
range. For example, if the high-temperature alarm should sound, he
would take some action to increase the severity of some reaction
control variable other than temperature. This might be an increase
in reactor catalyst level, catalyst activity, or slurry recycle
rate, or a reduction in dilution steam rate to the riser or
regenerator dense phase temperature. If the low temperature alarm
should sound, the operator would take some action opposite to those
just described. Alternatively, the reactor temperature control
might be equipped with one or more reset mechanisms to
automatically effect one or more of the changes indicated.
Although the control system could be made more complex as indicated
in the last paragraph, I prefer the simple version as described and
depicted in the drawing, relying upon the operator to take
appropriate action to keep the reactor temperature within the alarm
settings.
This plan of control will improve the results obtainable with any
feedstock otherwise suitable for catalytic cracking and will be
especially beneficial for any feedstock that varies in quality
during operations.
Suitable catalysts are conventional fluid catalytic cracking
catalysts, which are well known in the art.
What is considered new and inventive in this present invention is
defined in the hereunto appended claims, it being understood, of
course, that equivalents known to those skilled in the art are to
be construed as within the scope and purview of the claims.
* * * * *