U.S. patent number 3,627,432 [Application Number 04/820,231] was granted by the patent office on 1971-12-14 for reaction vessel for use in photometric measurements.
This patent grant is currently assigned to Eppendorf Geraetebau Netheler & Hinz GmbH. Invention is credited to Wilhelm Bergmann.
United States Patent |
3,627,432 |
Bergmann |
December 14, 1971 |
REACTION VESSEL FOR USE IN PHOTOMETRIC MEASUREMENTS
Abstract
A small vessel having generally cylindrical form is described.
This vessel has a flange at the upper rim and the lower portion is
provided with parallel planar surfaces particularly suitable for
photometric measurement of the contents of the vessel.
Inventors: |
Bergmann; Wilhelm (Hamburg,
DT) |
Assignee: |
Eppendorf Geraetebau Netheler &
Hinz GmbH (Hamburg, DT)
|
Family
ID: |
5701646 |
Appl.
No.: |
04/820,231 |
Filed: |
April 29, 1969 |
Foreign Application Priority Data
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May 2, 1968 [DT] |
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P 17 73 333.4 |
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Current U.S.
Class: |
356/246; D24/224;
250/573; 422/914; 422/562 |
Current CPC
Class: |
G01N
21/03 (20130101); B01L 3/5082 (20130101) |
Current International
Class: |
B01L
3/14 (20060101); G01N 21/03 (20060101); G01n
001/10 () |
Field of
Search: |
;356/244,246 ;250/218
;23/292 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Other References
Henderson et al., Analyt. Chem., Vol. 31, No. 12, Dec., 1959, pg.
2113.
|
Primary Examiner: Wibert; Ronald L.
Assistant Examiner: Sklar; Warren A.
Claims
What is claimed is:
1. A reaction vessel suitable for the photometric measurement of
small quantities of liquid, comprising an upper cylindrical portion
having a longitudinal axis, a lower portion having opposed parallel
planar walls, a connecting portion providing a transition between
said upper and lower portions, and outwardly projecting ribs
extending longitudinally on each side of said opposed parallel
planar walls disposed to leave a flat central portion therebetween,
the outer edges of said ribs establishing points on the
circumference of a circle, said circle being disposed within a
transverse plane through said vessel and orthogonal to said axis,
whereby the outer edges of said ribs form the outline of a
substantially cylindrical configuration.
2. A reaction vessel according to claim 1, wherein the center of
said circle lies on said longitudinal axis.
3. A reaction vessel according to claim 1, wherein said circle has
the same radius as said upper cylindrical portion.
4. A reaction vessel according to claim 1, wherein each of said
opposed parallel planar walls comprise planar portions that define
chords on a circle disposed within a transverse plane through said
vessel and orthogonal to said axis.
5. A reaction vessel according to claim 1, wherein the wall
sections of said vessel between said parallel planar walls are
opposed parallel planar lateral surfaces.
6. A reaction vessel according to claim 5, wherein end ribs project
from said lateral surfaces as prolongations of said first mentioned
parallel planar walls.
7. A reaction vessel according to claim 1, wherein said vessel
tapers at the bottom, said taper being effected essentially by a
chamfer of said projecting ribs, and wherein the interior of said
vessel has a constant rectangular cross section extending to the
bottom thereof.
8. A reaction vessel according to claim 1, having substantially
equal wall thickness throughout.
9. A reaction vessel according to claim 1, wherein the inner cross
section of the vessel is rectangular at least in the region of said
planar walls.
10. A reaction vessel according to claim 9, wherein a projecting
portion extends from the bottom of the vessel and exhibits a
substantially rectangular transverse cross section.
11. A reaction vessel according to claim 10, wherein the longer
axis of said rectangular cross section extends parallel to said
first mentioned parallel planar walls and at least the edges of
said projection are straight in this direction.
12. A reaction vessel according to claim 11, wherein at least on
two sides of said projecting portion, stepped surfaces extend at
right angles to said longitudinal axis.
Description
BACKGROUND OF THE INVENTION
This invention relates to reaction vessels, and more particularly
to reaction vessels adaptable for use in the photometric
measurement of small quantities of liquids.
Small quantities of liquid are often handled in reaction vessels
having a height of approximately 30 mm. and a diameter of
approximately 15 mm. Such vessels are generally of cylindrical form
and have an upper flange rim providing a shoulder which facilitates
handling. Such vessels are of particular usefulness in connection
with automatic processing systems wherein the transfer of the
vessel and the agitation and treatment of the contents are
simplified by the cylindrical form. These vessels are frequently
made of plastic and are dispensable so that they need be used only
once. In general the vessels have heretofore been used for
mechanical treatment of the contents only. When it is necessary or
desirable to execute photometric measurements of the contents, in
particular, comparison measurements, special measuring cuvettes
must be employed. The contents of the original vessel are
transferred into these measuring cuvettes in order to assure that
the optical properties of the vessel exhibit desired
characteristics.
SUMMARY OF THE INVENTION
The present invention provides a reaction vessel which is not only
particularly well suited for the mechanical treatment of the
contents thereof, but at the same time may be employed as a cuvette
suitable for making photometric measurements.
The vessel of the present invention exhibits in cross section a
pair of parallel planar walls on opposing sides. These walls are
disposed along chords of the circle defined by the upper
cylindrical portion of the vessel. Outwardly directed ribs are
arranged on the planar surfaces with a space therebetween. These
ribs project no further than the periphery of said cylindrical
portions.
By retaining the basic cylindrical form of conventional reaction
vessels, the vessels of the present invention are suitable for
handling in automatic systems in the same manner as existing
vessels. On the other hand, as a result of the planar surfaces they
contain, these vessels permit measurements to be made
photometrically.
An object of the present invention is to provide an improved
reaction vessel for both mechanical preparation of the contents and
photometric measurement thereof.
Another object of the invention is to provide an improved reaction
vessel having parallel planar walls.
Another object of the invention is to provide an improved reaction
vessel having parallel planar walls and yet retaining a basically
cylindrical configuration relative to the longitudinal axis
thereof.
It has been found that the provision of reinforcing ribs of the
nature described hereinafter, makes it possible to provide a thin
construction of the planar surface of the vessel without danger of
having the planar surfaces arch following production. It is
possible to use ribs which extend around the circumference of the
vessel perpendicular to the longitudinal axis thereof, however, a
particularly preferred form of construction provides ribs which
extend in a direction parallel to the vessel axis and are arranged
on either side of the planar surface. By longitudinally arranging
the ribs in this fashion, the vessel is better adapted for
insertion into openings or holes and in addition, the ribs provide
some shielding of the planar surface on which measurements will
take place.
Another object of the invention is to provide an improved reaction
vessel having thin parallel planar walls and reinforcing ribs.
Another object of the present invention is to provide an improved
reaction vessel particularly adapted for insertion into openings or
holes without damaging the planar surfaces.
It has also been found desirable that the wall sections between the
previously mentioned planar surfaces be also drawn in and arranged
as parallel planar surfaces that are orthogonally disposed relative
to the first mentioned planar surfaces and which also lie along
chords of the circle defined by the cylindrical portion of the
vessel. Thus, the same vessel provides two different optical
measurement paths. Still further, it is contemplated that the
invention provide an inner core section of the vessel which is
rectangular at least in the region of the aforementioned planar
surfaces. This rectangular section and the plane surface section
being advantageously adjacent to an upper cylindrical wall section
which is directly under a rim flange. Finally, a nose, or bottom
portion, of substantially rectangular section is provided at the
bottom of the vessel.
Another object of the invention is to provide an improved reaction
vessel having two photometric measuring paths.
Another object of the present invention is to provide an improved
reaction vessel having an at least partially rectangular interior
portion in order to provide better mixing in the event of
agitation.
Still another object of the present invention is to provide an
improved reaction vessel having good form stability and heat
transfer characteristics.
Yet another object of the present invention is to provide an
improved reaction vessel including means for facilitating alignment
of the vessel.
With respect to the last mentioned object, it will be noted that
the ribs protect the planar surfaces against mechanical contact,
scratching, and the like, and thereby provide an important function
considering the fact that the vessel may be used for photometric
measurements. These ribs may also be utilized in order to align the
vessel for measurement. On the other hand, there may be provided a
rectangular nose portion, or base portion, at the bottom of the
vessel. According to a preferred form of construction, stepped
surfaces extend at right angles to the longitudinal axis of the
vessel and are arranged on at least two sides of the rectangular
base. These surfaces make it possible to hold the vessel by the
base and support it upon the stepped surfaces so that it is not
inserted too deeply into any openings.
Advantageously, the vessel tapers at the bottom, the taper being
produced essentially by chamfering of the ribs, while the interior
of the vessel has a constant rectangular cross section extending
through to the bottom. This tapering facilitates the easy
introduction of the vessel into openings. It is to be noted however
that the planar surfaces do not participate in this tapering effect
and that they are always parallel with one another.
The above objects and features of the invention will be more
clearly understood and appreciated from the following description
which is made in connection with the drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a side elevation of a vessel embodying the present
invention, half of this elevation being in section along the line
I--I shown in FIG. 2;
FIG. 2 is a top view of a vessel embodying the present
invention;
FIG. 3 is a side elevation of the vessel shown in FIG. 1, rotated
through 90.degree., and having a portion in cross section taken
along the line III--III shown in FIG. 4; and
FIG. 4 is a bottom view of the vessel embodying the invention, half
of said view being in section taken along the line IV--IV in FIG.
3.
DESCRIPTION OF THE PREFERRED EMBODIMENT
The figures disclose a vessel which is open at the top and which
may be provided with a variety of closure means. In usual
embodiments, the vessel may have a height of approximately 30 mm.
and the outside diameter of the upper flange rim may be
approximately 18 mm. The upper portion of the vessel includes an
outwardly extending flange 1 below and adjacent to which is a
recessed cylindrical wall section 2. Below the cylindrical wall
section 2, the vessel walls are disposed inwardly and establish
parallel planar surfaces. Two opposing surfaces 3 and 4 are created
having somewhat greater width than the lateral interconnecting
surfaces 5 and 6 which extend therebetween at right angles. The
plane surfaces 3 and 4 have disposed thereon pairs of
perpendicularly extending ribs 7, 8 and 9, 10, which are spaced
from the center of the surfaces and extend orthogonally therefrom
to terminate in the outer contour defined by the upper cylindrical
portion 2 of the vessel. These ribs may also form a smooth
transition into the cylindrical section 2. The outer edges of the
ribs are accordingly designed obliquely to their major axis.
The surfaces 5 and 6 are also flanked by pairs of ribs 11, 12 and
13, 14. In this case, the ribs 11-14 lie in prolongation of the
wall portions forming the plane surfaces 3 and 4. In accordance
with this design, the inner cross section of the vessel at the
level of the plane surfaces 3 and 4 is rectangular as illustrated
at 15 in FIG. 2. It will also be noticed from FIGS. 1 and 2 that
the transitions 16 and 17 from the cylindrical vessel wall section
2 to the section with the inner cross section are formed by oblique
transition surfaces; the inclination of the surfaces 16, 17 being
different due to the different retraction of the plane surfaces 3
and 4 on the one hand and of the lateral surfaces 5 and 6 on the
other. As a result of this, the ribs 11-14 are somewhat flatter
than the ribs 7-10.
At the bottom of the vessel, there is a projecting nose or base
portion 18 which has a substantially rectangular cross section.
FIG. 4 illustrates that the lower limiting edges 19 and 20 under
the lateral surfaces 5 and 6 may be slightly rounded. This results
from the amount of taper of the vessel downwardly. In any event,
the longer edge 21 shown in FIG. 4, and the corresponding edge on
the opposite side (not shown), under the plane surfaces 3 and 4 are
straight and parallel to the plane surfaces so that they may be
used for alignment of the vessel.
FIGS. 1 and 3 also illustrate that the nose 18 tapers downwardly so
that its introduction into a correspondingly profiled opening may
be facilitated. In particular, as shown in FIG. 1, stepped surfaces
22 and 23 are provided parallel to the longitudinal edges of the
nose 18. These surfaces provide for aligned vertical placement and
make it possible to place a vessel with the nose 18 only in a
prepared opening. These stepped surfaces may continue into the
lower region of the ribs 7-10 so that a relatively large support
surface is provided.
The taper of the lower vessel edge is produced in particular at the
circumferential sections at which the plane surfaces 3 and 4 are
located, by chamfers 24 and 25 of the ribs. The vessel body may
also be bevelled, as for example at 26 in FIG. 3, this chamfer will
lie below the bottom surface 27 of the vessel.
A particular embodiment of the invention has been shown and
described. Clearly, the dimensions recited herein, and even the
relative dimensions of the various sides of the vessel, are not
necessarily germane to the invention. It is contemplated that those
skilled in the art may make many modifications within the spirit
and teachings of this disclosure. Accordingly, the invention is
intended to be only limited by the scope of the appended
claims.
* * * * *