U.S. patent number 3,626,410 [Application Number 04/841,055] was granted by the patent office on 1971-12-07 for moving indicator electrochemical display.
This patent grant is currently assigned to General Time Corporation. Invention is credited to Heinz deKoster.
United States Patent |
3,626,410 |
deKoster |
December 7, 1971 |
MOVING INDICATOR ELECTROCHEMICAL DISPLAY
Abstract
A moving indicator electrochemical display which may be used for
a linear, or for a circular display device such as a clockface. A
plurality of conductive electrodes are provided on an insulating
substrate in a regular pattern and covered with a shallow layer of
electrolyte containing ions of a visible electrodepositable
material. Electrical circuitry is provided which applies a
potential between a pair of adjacent electrodes making one an anode
and one a cathode, the potential being sufficient to cause plating
of the visible electrodepositable material on the cathode to
produce a visible indicator. Switching means cause the potential to
shift between successive electrode pairs giving the appearance of a
moving indicator device.
Inventors: |
deKoster; Heinz (Stamford,
CT) |
Assignee: |
General Time Corporation
(Stamford, CT)
|
Family
ID: |
25283902 |
Appl.
No.: |
04/841,055 |
Filed: |
July 11, 1969 |
Current U.S.
Class: |
340/815.83;
205/263; 359/297; 205/149; 359/228; 368/240; 968/950 |
Current CPC
Class: |
G04G
9/06 (20130101); G02F 1/1506 (20130101) |
Current International
Class: |
G02F
1/01 (20060101); G02F 1/15 (20060101); G04G
9/00 (20060101); G04G 9/06 (20060101); G04c
017/00 (); C23b 005/26 () |
Field of
Search: |
;340/373,378R,379,366R
;58/23R,5R,126R ;23/23LC ;204/23,45R,46,15,18R
;350/267,269,160 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
New York Times Magazine 9-2-56 page 23. copy in 58/23 C .
Science- News p. 598 Vol. 93/22 June 1968. LC digest cl.
350.
|
Primary Examiner: Richardson; Robert L.
Claims
Having described my invention, what I claim as new and desire to
secure by Letters Patent is:
1. A moving indicator electrochemical display system comprising, in
combination:
A. a nonconductive substrate,
B. a plurality of electrically conductive electrodes spaced in a
predetermined pattern on said substrate,
C. a layer of electrolyte covering said electrodes and containing
ions of an electrodepositable material, and
D. energizing means for applying an electrical potential between
adjacent electrodes to make one an anode and the other a cathode,
said potential being sufficient to deposit a visible layer of said
electrodepositable material on said cathode, and including
switching means for sequentially switching said potential to
successive electrode pairs whereby said deposited layer appears to
transfer from electrode to electrode in the manner of a moving
indicator.
2. A display system as defined in claim 1 wherein each said
electrode is separated into a plurality of discrete segments and
including energizing means for each group of corresponding
segments.
Description
BACKGROUND OF THE INVENTION
Numerous so-called solid-state display devices have been devised in
recent years for use as high-speed computer readouts,
instrumentation dials, clockfaces and the like. These solid-state
devices are attractive from the standpoints of small size,
relatively low power requirements, and the elimination of moving
parts which make for ease of manufacture and efficient and
economical operation.
The prior art devices have relied on a variety of solid state
phenomena for their operation; for example electroluminescence,
thermoluminescence, thermochromic reactions, molecular alignment
such as is disclosed in my copending application Ser. No. 718,823
filed Apr. 4, 1968, now Pat. No. 3,524,726 and ionization of gas as
disclosed in copending application Ser. No. 705,793 filed Feb. 15,
1968, now U.S. Pat. No. 3,500,121. Many of the prior art devices,
however, suffer disadvantages which make them impractical for
particular applications. Some have relatively large power
requirements making them impractical for use, for example, in
battery powered devices. Others are temperature-sensitive. Still
others have been limited by their nature to static displays and
cannot be used for a continuous readout of information, for
example, as on a dial face instrument.
Accordingly, representative objects of the present invention are to
provide an electrochemical display device which can be used in a
moving indicator display, which is operable under low power, and
which is simply constructed and efficient and economical in
operation.
Other objects of the invention will in part be obvious and will in
part appear hereinafter.
SUMMARY OF THE INVENTION
The present invention relates to a moving hand electrochemical
display device in which a thin but visible film of electrodeposited
material is shifted from electrode to electrode in the display to
produce one or more moving hand indicators.
The display comprises a substrate preferably formed of electrical
insulating material such as glass or ceramic, or coated with such
an electrical insulating material. The substrate is provided with a
plurality of electrodes in the shape of indicator hands on the
surface thereof. The electrodes are formed of an electrically
conductive material and arranged in a regular pattern; for example,
they may radiate from a common center as the spokes of a wheel or
be arranged linearly in a parallel configuration. Preferably the
electrodes and the substrate surface are treated to visually blend
together and render the bare electrodes essentially invisible. A
shallow layer of electrolyte containing ions of an
electrodepositable material is provided over the electrodes and the
entire assembly preferably sealed under a transparent cover
plate.
The display is energized by suitable electrical circuitry which
applies an electrical potential or voltage between adjacent
electrodes, making one a strong anode and the other a cathode. The
remaining electrodes are maintained weakly anodic as compared to
the cathode to prevent extraneous plating. The potential is
adjusted to a value which causes the electrodepositable material to
plate out as a visible coating on the cathode. Preferably, the
potential difference is applied as a relatively short pulse which
plates out only as much material as is required for clear
visibility. The electrical circuitry includes switching means for
switching the potential difference to successive pairs of
electrodes so that the previous cathode becomes an anode and the
next successive electrode becomes the cathode. As a result of such
switching, the material previously deposited on the old cathode
redissolves into the electrolyte while a new coating is
substantially simultaneously deposited on the new cathode. By
continuing such switching between each successive pair of
electrodes, the appearance of a moving indicator is obtained
without any actual moving parts.
Preferably, an electrolytic solution is used having current and
voltage requirements for plating which are sufficiently low to
permit the use of battery power to drive the display.
The display as described above may be used as a circular or linear
dial readout for a measuring instrument or the like. The circular
configuration may similarly be used as a clockface. Preferably,
when used as a clockface, each electrode is separated axially into
discrete segments for hour, minutes and second indications.
BRIEF DESCRIPTION OF THE DRAWINGS
For a fuller understanding of the nature and objects of the
invention, reference should be had to the following detailed
description taken in connection with the accompanying drawings in
which:
FIG. 1 is a top plan view of a circular, moving indicator
electrochemical display in accordance with the invention.
FIG. 2 is a partial sectional view taken along line 2-2 of FIG. 1
or line 2-2 of FIG. 6.
FIG. 3 is a partial top plan view of the display of FIG. 1 with a
schematic of the circuitry used to drive the display.
FIG. 4 is a schematic of an equivalent circuit representing the
electrochemical reaction between two electrodes in the display.
FIG. 5 is an isometric view partly in section of a clockface
display in accordance with the invention.
FIG. 6 is a top plan view of a linear display in accordance with
the invention.
Similar reference characters refer to similar parts throughout the
several views of the drawings.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Referring now to FIGS. 1 and 2, the display of the invention
comprises a substrate 10 which is preferably formed of an
electrical insulating material such as glass, ceramic, plastic or
the like. Alternatively, substrate 10 may be coated with such an
electrical insulating material. A plurality of electrodes 14 are
provided on one surface 12 of substrate 10 to serve as the basis
for the moving hand indicator. Electrodes 14 are typically arranged
on substrate 10 in a regular pattern; they may radiate from a
common center as shown for a circular dial or clockface, or be
arranged linearly in a parallel configuration for a linear display
as shown in FIG. 6.
As shown in FIG. 2, electrodes 14 are preferably recessed into
surface 12 so that the electrode tops are flush therewith. In this
way material is electrodeposited only on the upper visible surface
thereof where it is needed. Electrodes 14 are preferably formed by
thin or thick film techniques directly on surface 12 and from a
nonreactive metal such as platinum or palladium. However, other
metals and conductive nonmetals such as carbon may be used.
Alternatively, electrodes 14 may comprise discrete strips of
conductive material which are secured by adhesive or the like
within the recesses in surface 12.
Electrodes 14 should blend with surface 12 of substrate 10, but
should contrast in color with the material to be deposited thereon
so that a readily visible display results only upon plating. The
black color of carbon electrodes, for example, will blend readily
with a flat black painted surface 12, but will contrast sharply
with the color of most electrodeposited metals. However, where the
electrodes are metallic, they may require further treatment to
provide contrast. For example, platinum electrodes may be
conveniently platinized to a deep black colored surface of platinum
black for contrast.
Surface 12 of substrate 10 is preferably provided with a
surrounding upstanding rim 16 (FIG. 2) so as to provide a
receptacle area for liquid directly over electrodes 14. Into this
area there is placed a shallow layer of electrolyte 18, typically
about 0.2 millimeter to about 1 millimeter in depth over electrodes
14, containing ions of an electrodepositable material. The
electrolyte used may be any one of numerous plating solutions
commonly used for electroplating, the important consideration being
that the deposited material form a visible layer on the electrodes
and be visible through the electrolytic solution. Typically,
electrolyte 18 will comprise a solution of a soluble salt on one of
the more readily platable metals such as, but not limited to, gold,
platinum, silver, copper, nickel, chromium or zinc.
The top of the display is preferably sealed by a transparent cover
plate 20 (FIG. 2) to protect against spillage and contamination,
and permit use of the display in a vertical plane. Cover plate 20
may be of glass or plastic and is conveniently mounted in a ledge
22 formed in rim 16, and secured with adhesive or by clamping or
the like.
Silver nitrate makes a particularly attractive electrolyte for use
in the display since electrodeposited silver is a bright, almost
white colored metal which is quite visible on a dark electrode such
as one of platinized platinum. Accordingly, the operation of the
display will be described in conjunction with the use of silver
nitrate electrolyte and platinized platinum electrodes. It will be
understood, however, that the display may be operated in a similar
manner with other combinations of electrolyte and electrode
compositions, the principal differences being in the voltages
necessary to effect plating.
Referring now to FIG. 3, there is shown a portion of the display
face with a schematic of a simple circuit for energizing the
display. An electrically conductive lead 24a, 24b, 24c, etc. is
provided from a point on each electrode 14 to a point on substrate
10 where electrical contact may be conveniently made with a
switching means 26. Leads 24 in the case of a circular display will
normally extend from the converging ends of electrodes 14 toward
the display center where switching means 26 may be conveniently
located; however, the leads may extend from other points and in
other directions. Alternatively, switching means 26 may directly
contact electrodes 14. Leads 24 are preferably formed directly on
substrate 10 by printed circuit or thin film techniques; they may
however comprise discrete lengths of electrically conductive wire
or foil.
Still referring to FIG. 3, switching means 26 may comprise a simple
double pole stepping switch having one pole 28 connected to the
positive side and the other pole 30 connected to the negative side
of a direct current source 32 such as a battery. The contact ends
of poles 28 and 30 are spaced to correspond to the spacing between
adjacent leads 24. In this way contact is simultaneously made
between poles 28 and 30 and two adjacent leads 24 when switch 26 is
closed. Poles 28 and 30 may conveniently form part of a wiper arm
31 carrying brush contacts 27 and 29 which rotate about the center
of the display in response to the output of a measuring instrument,
or at a predetermined rate as with a clock mechanism. In a linear
display the wiper arm will of course move linearly. Alternatively,
switching may be accomplished electronically.
At the instant in time depicted in FIG. 3, positive pole 28 is in
contact with lead 24a making electrode 14a an anode.
Simultaneously, negative pole 30 contacts lead 24b making electrode
14b a cathode. The application of a sufficient voltage pulse from
source 32 under these conditions will cause silver to plate out on
electrode 14b (shaded portion) to produce a visible display
indicator.
The voltage value necessary to cause visible plating can be
determined from the electrochemical reactions taking place in the
display. As shown in FIG. 3, platinum electrodes 14a and 14b in the
surrounding silver nitrate electrolyte, and before application of
any potential, comprises an electrolytic cell which can be
symbolized as:
Pt/AgNO.sub.3 - AgNO.sub.3 /Pt
This electrolytic cell is represented by the equivalent circuit
shown in FIG. 4 where e.sub.1 and e.sub.2 represent respectively
the equal potentials of platinum electrodes 14a and 14b in silver
nitrate electrolyte, and R.sub.c is the electrical resistance of
the electrolyte between electrodes 14a and 14b. When a
predetermined voltage is applied between terminals A and B, a small
current i.sub.p can be made to flow through the cell and
equilibrium is upset. Electrodes 14a and 14b then respectively
become polarized into an anode and cathode. This causes anode 14a
to become saturated with a layer of oxygen atoms and cathode 14b to
become covered with a layer of silver atoms. The voltage required
to produce this result is called the precipitation voltage E.sub.p.
In this condition the cell can be symbolized as:
Pt,Ag/AgNO.sub.3 - AgNO.sub.3 /O.sub.2,Pt
The potentials of the now dissimilar anode and cathode in silver
nitrate become unequal and their algebraic difference is the
polarization potential e.sub.p, or:
e.sub.p = e.sub.1 - e.sub.2
This polarization potential e.sub.p is always directed against the
precipitation voltage E.sub.p which created it. In addition to the
polarization potential e.sub.p, the electrolytic resistance R.sub.c
creates another potential directed against E.sub.p which may be
symbolized by (i.sub.p R.sub.c). These two potentials counteract
E.sub.p to block further current flow and therefore prevent any
visible plating.
Accordingly, referring back to FIG. 4, in order to get current to
pass through the cell to plate out silver, E must be greater than
the two potentials directed against it, or:
E>(e.sub.p +i.sub.p R.sub.c)
Stated differently E must be greater than E.sub.p.
The precipitation potential E.sub.p for plating silver from a
dilute solution of silver nitrate is about 0.8 volt. Visible
plating can be effected by applying as little as 0.1 volt more, or
0.9 volt between electrodes 14a and 14b (FIG. 3). For the rapid
switching needed in a display, however, it is preferable to apply a
greater voltage, for example, of about 1.8 volts.
The precipitation potential E.sub.p of a particular electrolyte and
therefore the voltage necessary to cause plating can be reduced if
desired by adding a more ionic, complex salt to the electrolyte to
form a redox-system. For example, a complex salt mixture such as
KAg(CN).sub.2 + KI may be added to silver nitrate electrolyte for
this purpose. However, redox-systems are somewhat temperature
dependent so that preferably E.sub.p should not be reduced below
about 0.1 volt. At lower values of E.sub.p, temperature
fluctuations may adversely affect plating and dissolution on the
electrodes.
Still referring to FIG. 3, the deposited silver layer on electrode
14b can be shifted to electrode 14c by a clockwise rotation of
poles 28 and 30 respectively into contact with leads 24b and 24c.
This switch makes electrode 14b an anode and 14c a cathode. Under
these conditions and with the proper voltage E, the silver on 14b
quickly dissolves and substantially simultaneously a new deposit
forms on electrode 14c. This procedure may then be continued in a
clockwise direction to produce the effect of a clockwise moving
indicator as the deposited layer appears to shift from electrode to
electrode. To reverse the direction of movement, the polarity of
each pole 28 and 30 is switched, that is pole 28 is made negative
and pole 30 made positive, and the poles then moved in a
counterclockwise direction. The same procedure is used for a linear
display except that the clockwise-counterclockwise movements of
poles 28 and 30 become linear movements, for example, to the right
and left or up and down.
The display may be used conveniently as a clockface for a watch or
larger clock, thus eliminating the need for actual moving hands.
Referring to FIG. 5, the clockface 34 is constructed similarly to
the display shown in FIGS. 1 and 2, and comprises a plurality of
electrodes 36 on a substrate 38. Substrate 38 may also be provided
with suitable indicia 40. Similarly to the previously discussed
display, a receptacle area for electrolyte is provided on substrate
38 over electrodes 36, and the face may be sealed by a transparent
glass or plastic cover plate 41.
Clockface 34, however, differs from a simple display in that each
electrode 36 is preferably separated into three electrically
insulated segments 36a, 36b and 36c, respectively for hour, minutes
and seconds indications. Material electrodeposited on various
combinations of hour, minutes and seconds segments serves to
indicate the precise time, as for example, 3:00:05 as shown by the
shaded segments in FIG. 5.
Preferably, the hour segments 36a and surrounding electrolyte are
physically isolated from the minutes segments 36b and their
surrounding electrolyte, and both are physically isolated from the
seconds segments 36c and their surrounding electrolyte. This is
done to prevent undesirable cross-plating. Isolation may be
effected by a pair of concentric cylindrical rings 46 and 48
preferably integrally formed on cover plate 41 (FIG. 5). Ring 46
covers the spaces 42 between hour segments 36a and minutes segments
36b, and ring 48 covers the spaces 44 between minutes segments 36b
and seconds segments 36c. The rings should correspond in height to
the depth of the electrolyte to properly isolate each group of
segments.
Clockface 34 has been shown for simplicity having electrodes 36 at
only the 12 -hour positions; however, multiples of 12 electrodes
will be used in a practical case for more precise timing and
realistic indicator movement. Ideally, electrodes are placed at
each minute interval between each hour so that there are a total of
60 segmented electrodes spaced at 6.degree. intervals around
substrate 38.
Clockface 34 may be actuated by an electromechanical system such as
the wiper arm switching means 26 described with reference to FIG.
3. One wiper arm driven at a suitable rate will be provided for
each of the hour, minutes and seconds groups of electrode segments.
Alternatively, clockface 34 may be driven by an electronic control
system of the type disclosed in previously discussed copending
application Ser. No. 705,793 but suitably modified for use in an
electrochemical display.
It will thus be seen that the objects set forth above, among those
made apparent from the preceding description, are efficiently
attained and, since certain changes may be made in the above
constructions without departing from the scope of the invention, it
is intended that all matter contained in the above description or
shown on the accompanying drawings shall be interpreted as
illustrative and not in a limiting sense.
It is also to be understood that the following claims are intended
to cover all of the generic and specific features of the invention
herein described, and all statements of the scope of the invention,
which, as a matter of language, might be said to fall
therebetween.
* * * * *