U.S. patent number 3,624,444 [Application Number 05/051,576] was granted by the patent office on 1971-11-30 for low-pressure mercury vapor discharge lamp.
This patent grant is currently assigned to U. S. Philips Corporation. Invention is credited to Frank Berthold, Rolf Groth, Rudiger Jost.
United States Patent |
3,624,444 |
Berthold , et al. |
November 30, 1971 |
LOW-PRESSURE MERCURY VAPOR DISCHARGE LAMP
Abstract
A low-pressure mercury vapor discharge lamp, having a glass
envelope, whose inner side is provided with a layer of luminescent
material and a light-transmitting layer of conducting tin oxide
provided between this luminescent layer and the glass envelope. The
tin oxide layer is provided with a light-transmitting protective
layer of one or more of the colorless oxides of the elements from
the secondary groups in column 4 and 5 of the periodical system,
e.g. titanium dioxide or zirconium dioxide.
Inventors: |
Berthold; Frank (Witten,
DT), Groth; Rolf (Witten, DT), Jost;
Rudiger (Haaren, DT) |
Assignee: |
U. S. Philips Corporation (New
York, NY)
|
Family
ID: |
5739058 |
Appl.
No.: |
05/051,576 |
Filed: |
July 1, 1970 |
Foreign Application Priority Data
|
|
|
|
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Jul 5, 1969 [DT] |
|
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P 19 34 299.5 |
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Current U.S.
Class: |
313/161; 313/44;
313/485; 313/489; 313/635 |
Current CPC
Class: |
H01J
61/42 (20130101); H01J 61/46 (20130101) |
Current International
Class: |
H01J
61/38 (20060101); H01J 61/46 (20060101); H01J
61/42 (20060101); H01j 061/35 () |
Field of
Search: |
;313/220,221,44,45 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Kominski; John
Claims
What is claimed is:
1. A low-pressure mercury vapor discharge lamp having a glass
envelope whose inner side is provided with a layer of luminescent
material and a light-transmitting layer of conducting tin oxide
provided between this luminescent layer and the glass envelope,
characterized in that the tin oxide layer on the side remote from
the glass envelope is provided with a light-transmitting protective
layer of one or more of the colorless oxides of the elements from
the secondary groups in the columns 4 and 5 of the periodical
system of the elements and that the protective layer has a
thickness of from 0.02-1 .mu.m.
2. A low-pressure mercury vapor discharge lamp as claimed in claim
1, characterized in that the thickness of the protective layer is
0.05-0.15 .mu.m.
3. A low-pressure mercury vapor discharge lamp as claimed in claim
1, characterized in that the protective layer comprises titanium
dioxide.
4. A low-pressure mercury vapor discharge lamp as claimed in claim
1, characterized in that the protective layer comprises zirconium
dioxide.
Description
The invention relates to a low-pressure mercury vapor discharge
lamp and particularly to such a lamp which converts the ultraviolet
radiation generated in the discharge into visible radiation by
means of a luminescent material.
Lamps of the kind described above have been known for a long time
in many forms. Many of these lamps are used for general
illumination purposes, but special types are also used for making
photo copies.
One of the problems occurring in all low-pressure mercury vapor
discharge lamps is that the operating voltage is generally lower
than the ignition voltage. This in itself would not be a drawback
if the ignition voltage were lower than the supply voltage of the
installation, for example, of the mains from which the lamp is fed.
However, this is generally not the case. Therefore auxiliary means
are almost always used for igniting the lamp. One of the well-known
auxiliary means is a so-called starter which generates a voltage
for a short period, which voltage is so much higher than the
ignition voltage that an ignition of the lamp is ensured. Sometimes
also so-called ignition strips are used which are provided either
on the outer side or on the inner side of the envelope of the lamp
and which extend from one to the other electrode. These ignition
strips may optionally be connected to the electrodes.
In a special type of the low-pressure mercury vapor discharge
lamps, the inner side of the glass envelope of the lamp was coated
with a light-transmitting layer of conducting tin oxide on the
entire surface or on a large part of the surface between the
electrodes. In this connection and in the following description the
expression "light-transmitting" is understood to mean that the
useful radiation to be emitted by the lamp is transmitted. In lamps
for general illumination purposes this means that the layer
satisfactorily passes the light generated with the aid of the
luminescent layer. The luminescent layer is always provided on the
side of the tin oxide layer facing the discharge.
Since the discharge space between the electrodes must of course not
be short-circuited, because otherwise no discharge would be able to
occur, the resistance of the tin oxide layer is bound to given
values. The resistance measured between the ends located near the
electrodes is generally between 5,000 and 50,000 ohms. Since tin
oxide in a pure form often has an insufficient conductivity, a
so-called dope, for example, fluorine, is sometimes added to the
tin oxide.
The above-described lamps provided with a tin oxide layer are
distinguished by a very satisfactory ignition behavior over a wide
temperature range and in this respect they are preferred to the
lamps provided with ignition strips. In fact, lamps having a strip
provided on the outer side of the envelope ignite satisfactorily at
low ambient temperatures; lamps having a strip on the inner side
only ignite at comparatively high ambient temperatures. On the
other hand lamps having a tin oxide layer have a satisfactory
ignition behavior over the entire temperature range which is
covered by the two ignition strip types combined. The use of a tin
oxide layer has, however, a great drawback, for it has been found
that after some time, sometimes already after 50 operating hours,
black stains having a diameter of up to several mms are formed on
the inner side of the discharge tube. In these areas the tin oxide
layer and the luminescent layer are damaged. As a result the
emitted luminous flux decreases, while in addition the appearance
of the lamp is detrimentally influenced in an aesthetical respect.
An object of the present invention is to prevent this drawback as
much as possible.
According to the invention a low-pressure mercury vapor discharge
lamp comprises a glass envelope whose inner side is provided with a
layer of luminescent material and with a light-transmitting layer
of conducting tin oxide located between the luminescent layer and
the glass envelope and is characterized in that the tin oxide layer
on the side remote from the glass envelope is provided with a
light-transmitting protective layer of one or more of the colorless
oxides of the elements from the secondary groups in the columns 4
and 5 of the periodical system of the elements and that the
protective layer has a thickness of from 0.02-1/.mu. m.
Experiments have shown that protective layers having a thickness of
from 0.02-1/.mu. m. are sufficiently light-transmitting for all
radiation to be passed. However, the protective layer preferably
has a thickness of from 0.05-0.15/.mu. m., because at this
thickness a satisfactory adhesion of the layer is ensured and there
is no risk of cracks occurring. Furthermore, interference effects
are avoided as much as possible at the preferred thicknesses.
Particularly the oxides of titanium, zirconium, hafnium, niobium
and tantalum are suitable for the protective layer, because these
oxides do not absorb the useful radiation to be emitted by the
lamp. A layer of titanium dioxide is preferably used, because this
material is not expensive and can be easily provided in the form of
a homogeneous layer on the tin oxide layer by means of a method
explained with reference to the following examples.
In certain cases, namely when greater layer thicknesses are used,
zirconium oxide is preferably used for the protective layer, for
zirconium oxide has a lower refractive index than titanium dioxide.
Thus the layers may be made thicker without the interference
effects being increased.
The oxides to be used for the protective layer are substantially
insulating and constitute a dielectric layer. As experiments have
shown, the protective layers influence the conductivity of the tin
oxide layer only to a very slight extent. It has been found that
the adhesion of the luminescent materials to the protective layer
is satisfactory.
A low-pressure mercury vapor discharge lamp according to the
invention is preferably manufactured by means of a method in which
both the tin oxide layer and the protective layer are provided on
the inner side of the glass envelope by means of identical spray
processes. Due to the uniformity of the two coating processes, this
method is very economic and renders the formation of very uniform
layers possible.
In order that the invention may be readily carried into effect, it
will now be described in detail by way of example with reference to
the accompanying diagrammatic drawings.
In the drawing the reference numeral 1 denotes the glass envelope
of a low-pressure mercury vapor discharge lamp the ends of which
are provided with electrodes 2 and 3. The inner side of the
envelope 1 has a layer of conducting tin oxide 4, a protective
layer 5 of one or more of the colorless oxides of the elements from
the secondary groups in the columns 4 and 5 of the periodical
system of the elements and a layer 6 of luminescent material. The
thicknesses of the tin oxide layer 4 and the light-transmitting
layer 5 are indicated greatly exaggerated as compared with the
thickness of the glass envelope 1.
The two examples below describe the manufacture of a lamp shown in
the drawing with reference to the application of the tin oxide
layer 4 and the protective layer 5. The other manufacturing stages
of the lamp do not at all deviate from those of the known
lamps.
EXAMPLE I
The glass envelope to be coated of a low-pressure mercury vapor
discharge lamp was heated in an electric tube furnace to a
temperature of approximately 450.degree.-500.degree. C., preferably
480.degree. C. A solution of 20 percent of SnC1.sub.4 in butanol to
which a few percents of HF were added was sprayed with the aid of a
spray nozzle and passed in vapor form through the envelope.
A similar method was used for the formation of the protective
layer. The spray mixture was a 20 vol. percent solution of
tetrabutyl titanate in butanol. The spray gas supplied to the spray
nozzle must in this case be dry in order that the tetrabutyl
titanate which is sensitive to hydrolysis is not hydrolized before
the drops fall on the hot glass of the tube. Consequently, dry air
or dry oxygen was used. Also the air transported from the ambience,
which air is essential for the formation of a fine spray must be as
dry as possible. To this end the spray nozzle was provided in the
rear wall of a metal pot which was connected through an aperture to
a plastic bag. During spraying enough dry air or dry oxygen was
present in the plastic bag to maintain the supply to the nozzle.
The layer was sprayed on in an intermittent process so that during
the spraying intervals the initial temperature of approximately
480.degree. C. on the glass wall was reached again. The tetrabutyl
titanate was decomposed pyrolytically on the hot glass of the tube
while forming a titanium dioxide layer, the organic radicals
burning completely. It was found that the flow rate of the spray
could best be chosen in the boundary range where laminar flow
changes into a turbulent flow.
EXAMPLE II
A glass tube for a low-pressure mercury vapor discharge lamp was
provided with a tin oxide layer in a similar manner as described in
example I. This tin oxide layer was coated with a protective layer
of zirconium oxide by means of the method described with reference
to example I. To this end a 20 percent solution of
tetrapropylzirconate in propanol was used during spraying.
It was found that the use of alcoholates of alcohols having
comparatively long chains is more favorable as regards the
sensitivity to hydrolysis. Bright layers of titanium dioxide were
manufactured with the aid of a solution of tetrapentyl titanate in
butanol or pentanol without special steps being taken with
reference to the dryness of the spray gas.
Experiments showed that for the formation of the protective layer
alternatively chlorides, for example, titanium chloride or
zirconium chloride dissolved, for example, in butanol may be used.
The spray process may then be performed in exactly the same manner
as for the formation of the tin oxide layer.
Low-pressure mercury vapor discharge lamps were made from the glass
tubes coated in accordance with example I. It was found that the
ignition behavior of these lamps as compared with the known lamps
having a tin oxide layer was not influenced. The lamps according to
the invention had no black stains after 2,500 operating hours.
* * * * *