U.S. patent number 3,621,464 [Application Number 04/878,315] was granted by the patent office on 1971-11-16 for amplitude modulated rf generator for quadrupole mass analyzer.
This patent grant is currently assigned to Electronic Associates. Invention is credited to Fonger Wiersma, Robert M. Bryndza.
United States Patent |
3,621,464 |
|
November 16, 1971 |
AMPLITUDE MODULATED RF GENERATOR FOR QUADRUPOLE MASS ANALYZER
Abstract
An improved radio frequency (RF) generator for use with a
quadrupole mass analyzer is disclosed wherein a ramp of RF at
constant frequency is provided by developing a difference signal
between the output of the circuit and a control ramp input. The
error signal is modulated by the desired frequency supplied from an
oscillator and amplified by a push-pull arrangement. The amplified
signal is applied to a series resonant tuned circuit which directly
supplies the quadrupole rods.
Inventors: |
Robert M. Bryndza (San Jose,
CA), Fonger Wiersma (Palo Alto, CA) |
Assignee: |
Electronic Associates (Inc.,
Long Branch)
|
Family
ID: |
25371783 |
Appl.
No.: |
04/878,315 |
Filed: |
November 20, 1969 |
Current U.S.
Class: |
331/106; 250/292;
331/183; 331/109 |
Current CPC
Class: |
H01J
49/022 (20130101); H01J 49/421 (20130101); H03L
5/00 (20130101) |
Current International
Class: |
H01J
49/42 (20060101); H01J 49/34 (20060101); H03L
5/00 (20060101); H03b 003/02 () |
Field of
Search: |
;331/106,109,182,183
;250/41.9DS |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Roy Lake
Assistant Examiner: Siegfried H. Grimm
Attorney, Agent or Firm: Edward A. Petko Robert M.
Skolnik
Claims
1. A radiofrequency generator for supplying a variable amplitude
radiofrequency electrical energy comprising: an oscillator for
producing a constant frequency output signal; switch means
connected to said oscillator and responsive to said output signal,
said switch means being rendered alternately conductive and
nonconductive at said frequency; first amplifier means connected to
said switch means, a series resonant circuit connected to said
amplifier for producing an output voltage having a magnitude
dependent upon the output of said first amplifier, detector means
connected to said tuned circuit for producing an electrical signal
representing said output voltage; means for producing a ramp
voltage; differential amplifier means having a first input
connected to receive said ramp voltage and a second input connected
to said detector means for producing an output signal representing
the amplitude difference between said ramp and said output voltage;
means including second amplifier means connected to said
differential amplifier and to said switch means for applying said
difference signal to said switch means and said first amplifier
means whereby the magnitude of said resonant circuit output voltage
is a function of said difference
2. A radiofrequency generator comprising: means for producing a
control signal having a predetermined frequency, a resonant circuit
for supplying a constant frequency output voltage having variable
amplitude, means for producing a voltage having a predetermined
amplitude change; means connected to said voltage producing means
and to said resonant circuit for producing a difference signal
representing the difference in amplitude between said variable
amplitude radiofrequency voltage and said source; means including
switch means connected to said control signal producing means; to
said resonant circuit; and to said difference signal producing
means for selectively applying said difference signal to said
resonant circuit at said predetermined frequency; whereby the
frequency of said output voltage is said predetermined frequency
and the amplitude of said output voltage tracks said predetermined
amplitude change.
Description
This invention relates to a radiofrequency generator for use in a
quadrupole mass analyzer.
Quadrupole mass analyzers have been described in the prior art,
particularly in U.S. Pat. No. 2,939,952 to Wolfgang Paul et al. In
that patent, a controlled varying voltage is used in conjunction
with a fixed frequency signal to perform a mass spectrum analysis.
Such analyzers may be used in measuring the composition of chemical
substances and are primarily comprised of an ionizer, a quadrupole
section, and an ion detector. Generally, the substance to be
analyzed is introduced into the ionizer as a vapor at low pressure.
A portion of the atoms or molecules which make up the chemical
substance are ionized by electron bombardment or other means, and
these ions are then accelerated and focused into the quadrupole
section as an ion beam. The ion beam is filtered by permitting only
those ions having specific values of charge-to-mass ratio to pass
through the quadrupole section. Those ions which are able to pass
through the quadrupole section are then collected by the ion
detector which may be an electron multiplier or a Faraday Cup.
The output current produced by the ion detector is a measure of the
number of atoms or molecules in the ion beam which have a
particular charge-to-mass ratio. The specific detected
charge-to-mass ratio is determined by the values of the scanned or
controlled varying RF voltage and the related DC voltage which
voltages are applied to the electrodes of the quadrupole section.
The RF and DC voltages applied to the rods at any given time
determine the mass number of the ions being passed by the filter
and the ion detector current indicates the ion abundance at that
mass number. A display of the quantitative abundance of such
detected ions as a function of atomic mass may be conveniently
presented on conventional display instruments such as
oscilloscopes, X-Y recorders, or strip chart recorders.
It will be appreciated that precise voltage and frequency control
of the radiofrequency applied to the mass analyzer is required to
obtain maximum resolution. The present invention provides an
electronic circuit for providing a fixed frequency ramp of
radiofrequency voltage for the filter of a quadrupole mass
analyzer.
In brief, the invention provides a series resonant tuned circuit
connected to the quadrupole rods supplying opposite phase
radiofrequency ramps. The output of the tuned circuit is
continuously detected and compared with a control ramp voltage. An
error signal is generated which is amplified and utilized to
control the amplitude of the signal applied to the tuned circuit.
The feedback loop described provides precise amplitude control of
the radiofrequency applied to the quadrupole rods.
It is an object of the present invention to provide a simplified
radiofrequency generator for a quadrupole mass analyzer.
A further object of the present invention is the provision of a
radiofrequency generator having a series resonant tuned circuit
which enables the required high voltage to be applied to the rods
of the quadrupole filter section.
Another object of the present invention is the provision of a
radiofrequency generator for a quadrupole mass analyzer having
precise radiofrequency amplitude control throughout the range of
radiofrequency amplitudes required.
These as well as further objects and advantages of the present
invention will become apparent to those skilled in the art from a
reading of the specification with reference to the accompanying
drawings in which:
the single FIGURE is a schematic diagram of the preferred
embodiment of the radiofrequency generator in accordance with the
invention.
In the FIGURE, numeral 1 denotes an oscillator which may be a
crystal oscillator producing a square wave output at a frequency of
2.8 MHz. The output of oscillator 1 is connected to the input of an
amplifier A304 which provides current amplification.
Voltage supply for the oscillator is provided from bias source 2
via resistor R312. Resistor R312, capacitor C312 and zener diode
CR303 provide bias voltage regulation for the oscillator as well as
for amplifier A304.
The output of amplifier A304, developed across load resistor R313,
is connected to the base of transistor Q305 via resistor R10.
Resistor R10 develops base current for transistor Q305. Shunt
resistor R11 stabilizes the base voltage for transistor Q305
ensuring that the transistor will be rendered nonconductive when
the output of A304 switches to 0 volts.
Transistor Q305 is thus rendered alternately conductive and
nonconductive at the oscillator output frequency. The amplitude of
the output of transistor Q305 is established by the voltage at
point V. More particularly, the collector of transistor Q305 is
connected to point V via the series connection of R12 and R13. The
primary winding of transformer T302 and capacitor C307 are
connected across R13. The configuration just described presents a
low impedance drive for the transformer. When transistor Q305 is
nonconductive, the impedance seen by transformer T302 is R13. When
transistor Q305 is conductive, the impedance seen by transformer
T302 is R12 in parallel with R13. Transistor Q305 thus functions as
an electronic switch. Resistor R13 also serves to dissipate the
energy stored in the primary of transformer T302 when transistor
Q305 is nonconductive.
In the preferred embodiment, the primary winding of transformer
T302 has 20 turns while each of the portions of the center tapped
secondary winding has five turns. This results in one-eighth of the
voltage at point V being developed across each portion of the
center tapped secondary winding. The secondary winding is connected
to the bases of push-pull amplifier transistors Q306 and Q307 via
current limiting resistors R14 and R15. The push-pull output at the
collectors of transistors Q306 and Q307 is connected across the
center tapped primary winding of transformer T303. In the preferred
embodiment, each portion of this center tapped primary winding
consists of 12 turns while the secondary winding has eight turns.
Capacitor C308 is connected between the center tap of the primary
winding of transformer T303 and ground to provide RF bypass. It
will be noted that the potential of point V is also applied to the
center tap of the primary winding of transformer T303 via lead
30.
It has been found that the push-pull stage must be effectively
bypassed for low amplitude radiofrequency voltage. At low
radiofrequency amplitude, the difference signal at point V is, of
course, at a very low amplitude. Distortions in the push-pull
amplifier at crossover degrade the small amplitude error signal.
The application of the error signal via lead 30 thus ensures a
driving signal for the tuned circuit throughout the amplitude range
of the ramp of radiofrequency.
The secondary winding of transformer T303 is connected to two
series resonant tuned circuits. The desired voltage output for the
quadrupole mass analyzer is 2,400 volts peak-to-peak. The tuned
circuits are employed to increase the voltage at the secondary
winding of transformer T303 to the desired level.
The first tuned circuit includes inductor L11, adjustable capacitor
C207, fixed capacitor C201 and the inherent capacitance of one pair
of quadrupole rods themselves. The second tuned circuit includes
inductor L12, adjustable capacitor C208, fixed capacitor C202 and
the inherent capacitance of the other pair of quadrupole rods. The
output of each of the tuned circuits is connected to the rods of
the quadrupole mass analyzer via respective DC blocking capacitors
C205 and C206 (numeral 17 denotes the lead from C205 to the
quadrupole rods).
The amplitude of the output thus generated is detected and fed back
to a comparator circuit which sweeps the amplitude of the voltage
output supplied to the rods through the desired amplitude range.
More particularly, capacitors C201 and C203 constitute a capacitive
voltage divider. Diode CR201 clamps the voltage developed by the
divider to ground. Resistor R201 and voltage source 20 provide
forward bias for diode CR201 to improve performance of the detector
at low RF voltages. The out-of-phase voltages developed by the
detectors are summed at the juncture of resistors R202 and R203 and
filtered by capacitor C209.
Each of the diodes CR201 and CR202 are heated for temperature
stability as is shown schematically by the resistors within the
dotted circle surrounding each diode. Voltage source 19 supplies
power for the heating elements.
Capacitor C204 cooperates with capacitor C202 to form a capacitive
voltage divider. Diode CR202 clamps the voltage output of the
divider to ground. The output of the detector on conductor 21 is a
full wave rectified DC level which is connected as one input to
differential amplifier A301.
More particularly, resistors R301, R302, R303 and R304 with voltage
source 22 comprise an adjustable voltage divider. Adjustable
resistor R303 with fixed resistor R304 sets the maximum slope or
amplitude change of the RF frequency. Adjustable resistor R302
provides a zero adjustment to set the divider to a voltage level
above the ambient noise while resistor R301 sets the range of
resistor R302. Capacitor C301 is connected between the juncture of
resistors R303 and R304 and ground to provide filtering of any AC
ripple on the detected DC level. Input terminal 23 is connected to
a ramp voltage source (not shown) which produces the waveform shown
in the drawing. This ramp voltage is fed to an input of the
differential amplifier A301 via input resistor R305. The output of
amplifier A301 is prevented from going positive by clamping diode
CR301. Capacitor C302 connected across amplifier A301 provides
frequency compensation and stabilization for the amplifier.
The negative polarity output of amplifier A301 representing the
difference between the magnitude of the ramp voltage and the DC
level at the output of resistor R303, is amplified by transistor
Q301. More particularly, the base of transistor Q301 is connected
to the output of amplifier A301 via the base resistor R306. A
regulated bias supply for this amplification stage is provided by
voltage source 24, resistors R307 and R308, zener diode CR302 and
capacitor C310. This regulator provides a reference voltage of 12
volts.
The amplified error signal output of amplifier A301 at the
collector of Q301 is developed across load resistor R309 and is
coupled to a current amplifier which consists of transistors Q302
and Q303 with resistor R316. This connection constitutes the well
known Darlington configuration. A battery 25 is connected to the
circuit by way of the resistor 317 which leads to the juncture of a
capacitor 309 and the resistor 309. The emitter of transistor Q303
is grounded by way of a capacitor C307.
It will be recalled that the RF voltages to be supplied must be
equal in magnitude and opposite in phase. This is achieved in the
present invention by the switching of the power transistor Q305
having the inductive load T302. At the moment when the transistor
switches off, the collector voltage of transistor Q305 increases
rapidly to a relative high value determined by:
E.sub.i =-L di/dt
Further amplification of this collector voltage output is provided
by the push-pull amplifier. In addition, it will be recognized
that, because of the series resonant effect provided by the tuned
circuits, only that component of the signal having the fundamental
frequency of the oscillator will be amplified: other frequencies
will be filtered out. This results in a pure sine wave output. The
output voltage is proportional to the Q of the tuned circuit and
the higher the Q, the less will be the distortion in the output
voltage.
The RF voltage is modulated with a ramp at the point V. The error
amplifier A301 forces the output voltage supplied to the quadrupole
rods to follow the ramp input at terminal 23.
* * * * *