U.S. patent number 3,619,280 [Application Number 04/843,223] was granted by the patent office on 1971-11-09 for treated paper and nonwoven material for wiping surfaces and method therefor.
This patent grant is currently assigned to Dustikin Products, Inc.. Invention is credited to Fred F. Scheuer.
United States Patent |
3,619,280 |
Scheuer |
November 9, 1971 |
TREATED PAPER AND NONWOVEN MATERIAL FOR WIPING SURFACES AND METHOD
THEREFOR
Abstract
Tissue-type paper and nonwoven material are uniformly
impregnated with a nonaqueous liquid carrier selected from liquid
hydrocarbons, glycols and pine oils containing an agent uniformly
distributed therein automatically, by applying a predetermined
quantity of treating fluid to any portion of the nontreated
material. The agent is selected from waxes, silicones and materials
producing a predetermined odor. The agent does not separate from
the carrier until at least the treated material is substantially
impregnated, and the carrier and agent remain in the material
substantially as when it was impregnated and are deposited in the
same proportions as a thin film on a surface wiped by the
material.
Inventors: |
Scheuer; Fred F. (Bronx,
NY) |
Assignee: |
Dustikin Products, Inc. (Bronx,
NY)
|
Family
ID: |
25289376 |
Appl.
No.: |
04/843,223 |
Filed: |
July 18, 1969 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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475234 |
Jul 27, 1965 |
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Current U.S.
Class: |
15/210.1;
424/443; 427/391; 15/104.93; 427/387; 427/395 |
Current CPC
Class: |
A61Q
19/00 (20130101); A61K 8/0208 (20130101); A61Q
19/005 (20130101); A61K 2800/75 (20130101) |
Current International
Class: |
A61K
8/02 (20060101); D21h 001/40 (); D21h 005/22 () |
Field of
Search: |
;15/209,210,506,104.93
;106/287C ;117/154,158,155R ;424/28 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Martin; William D.
Assistant Examiner: Lusignan; M. R.
Parent Case Text
This application is a continuation of my copending application for
"Treated Paper and Tissue," filed July 27, 1965, Ser. No. 475,234,
now abandoned.
Claims
What I claim is:
1. A medicated tissue for depositing a thin film on the skin of the
user which emits a medical odor comprising tissue paper uniformly
impregnated with a nonaqueous treating fluid consisting essentially
of a liquid hydrocarbon oil containing an agent uniformly
distributed therein, said agent being selected from menthol, a
homologue of menthol, thymol, a homologue of thymol, camphor, and a
homologue of camphor, said agent being not less than 0.1% by weight
of the treated tissue and the treating fluid being at least about
71/2 to 70% of the weight of the impregnated tissue with the
proportion of the liquid hydrocarbon oil being greater than that of
the agent, there being no separation of the liquid hydrocarbon oil
and agent until at least the tissue is substantially impregnated,
said liquid hydrocarbon oil and said agent releasably remaining
uniformly distributed in said tissue during the normal life of the
tissue in the state substantially as when the tissue was
impregnated and capable of being deposited as a film on the skin of
the user wiped by the tissue wherein the agent and an oil are
homogeneously mixed on the skin of the user to provide a slow
continuous release of the odor of the agent.
2. A tissue in accordance with claim 1, wherein said agent further
has the characteristic odor of a selected animal, plant, flower,
tree or medicine, and a silicone, said agent not exceeding 2% of
the treated tissue.
3. A tissue according to claim 1, wherein the weight of liquid
hydrocarbon and said agent is at least about 10% to 70% by weight
of the impregnated paper.
4. A tissue according to claim 2, wherein said agent includes about
1% of menthol, 1% of lavender and about 1% to 8% of a silicone, all
percentages being based on total weight of the treating fluid, and
said carrier being a white mineral oil.
Description
This invention relates to a disposable treated tissue and nonwoven
material. More particularly, it relates to a treated tissue or
nonwoven material, which may be used as is, to wipe a predetermined
surface and deposit a thin, invisible film on such surface, and
which material is then discarded; and a process for treating the
tissue and material. The treated tissue and material may be used
for a variety of personal and cleaning purposes, such as toilet
tissue, facial tissue, and dusting and polishing cloths, and
wipers.
Treated paper is old. However, all of the treatments to these
materials are directed solely to affecting the paper or material.
Hence, paper has been treated with ingredients that inhibit mold
growth, bacteria growth, sticking of candy and the like on or to
the treated paper. These treated materials are incapable of
transmitting that treatment to another surface, since the treating
material is dried or hardened after application. Further, the
manner of treatment for paper on one hand, and tissue or nonwoven
material on the other hand, is entirely different. Heretofore,
paper, cloth or the like was treated with the desired ingredients
by coating the surface by rollers or other mechanical means, or the
paper or cloth was pulled through the treating liquid. While this
method is feasible for strong papers and cloths, it is not
practical, or is too expensive, for thin materials or multiple
tissue paper. Similarly, for certain purposes an agent, such as a
water-repellant, was distributed over the surface of cloth by
dissolving the agent in a solvent, spreading the solution on the
surface, and evaporating the solvent, thereby leaving the agent
attached to the surface. This treatment also was with respect to
the cloth itself, i.e., waterproofing it.
The present invention is directed to treating relatively weak paper
materials, such as tissue papers and nonwoven materials. These
materials are inexpensive and are intended to be disposable. The
paper and nonwoven materials are treated not for affecting the
properties of the paper and material, but to apply the treating
fluid in the same proportions as originally applied to the paper,
to another surface that is wiped with the treated paper or
material, in a thin layer, in which the agent is uniformly
distributed. In effect, the treated tissue or material acts as an
applicator for the treating fluid, even while performing its
primary function as a facial tissue or wiper or toilet tissue or
duster.
The different end uses of the material treated in accordance with
the present invention require different agents, all of which are
completely dispersed in a nonaqueous carrier. The total quantity of
treating fluid is applied to any portion of the tissue paper and
distributes itself throughout the paper uniformly, in the same
proportion of agent to carrier, as originally applied, so that a
surface wiped with one portion of the treated paper will have the
same quantity of agent remaining on it as another surface wiped
with a different portion of the treated paper.
It is an object of the present invention to provide a disposable
treated tissue or nonwoven material, which is useful for many
purposes, including personal, toilet, and dusting and polishing of
furniture and glass surfaces, and which is simple and convenient to
use.
It is another object of the present invention to provide a treated
paper, which is disposable, economical and effective in polishing
delicate surfaces, such as furniture, cars, metal, plastic and
glass, when wiped with any part of this treated paper. The treated
paper applies a nondrying film in a thin layer, so as to provide a
maximum polish and high gloss without leaving any smearing
film.
It is a further object of the present invention to provide a
treated tissue, which is dry to the touch and having an emollient
feel, which is usable as toilet tissue by sufferers of piles and
other irritations of the anus.
It is still a further object of the present invention to provide a
treated tissue having an emollient feel and a long shelf life,
which can be applied to the nose by sufferers of colds and other
respiratory afflictions, which provides a desired characteristic
odor to relieve the distress caused by these ailments, as well as
applying a soothing film for preventing chapping and irritation of
the skin.
It is another object of the present invention to provide a method
for preparing such treated paper in a simple manner.
Treated paper and nonwoven material prepared in accordance with the
present invention is useful for many purposes, such as cleaning,
polishing and dusting various types of surfaces, including
furniture, automobiles, glass, mirrors and the like. The treated
paper besides polishing collects and retains the dust in the air
with resulting respiratory dangers, as well as the resettling of
the dust on the surfaces cleaned. The treated tissue made in
accordance with the present invention is emollient and can be used
dry on the most delicate and fine wood finishes, and deposits an
invisible thin film on the surface wiped without the need of
further additional material, liquid, or additional polishing or
rubbing. The present treated paper is easy to use and provides a
high gloss on the wiped surface.
Additionally, tissue paper may be treated in accordance with the
present invention with a nonaqueous liquid carrier vehicle and a
chemical which produces an odor, which alleviates the distress
occasioned by nasal, throat or bronchial ailments. One such
chemical is menthol, represented by the formula C.sub.10 H.sub.19
OH and its homologues. Other chemicals are thymol, represented by
the formula CH.sub.3 (C.sub.3 H.sub.7)C.sub.6 H.sub.3 OH and its
homologues, and camphor, represented by the formula C.sub.10
H.sub.16 O and its homologues. Menthol and thymol and their
homologues have properties in common and may be classified under
the broad group of phenols and their corresponding carbocyclic
products of varying degrees of saturation. The chemical
homogenously mixed with the carrier retains its odor-forming
properties, even for a long period of shelf life, and produces a
slow, continuous release of the odor for a relatively long period
of time, much longer than if the chemical were applied directly,
and the present invention not used.
In use the treated tissue is used in the conventional manner in
wiping the nose. The odors of the chemical used provides relief to
the user and the pliable treated tissue deposits a thin film of oil
and odor-producing chemical on the sensitive skin about the nose
and lips of the user, which oil prevents irritation and chapping of
the skin, and the odor remains for a relatively long period. After
use the tissue is discarded.
Also, other chemicals can be used to provide desired odors to the
impregnated paper, including "essential oils" and artificial
scents, which produce animal, tree, plant, flower, astringent and
medicinal odors, which are well known in the cosmetic and perfumery
field. "Essential oils" are volatile oils derived from the selected
plants and flowers carrying the characteristic odor or flavor of
the plant or flower used. (See "The Condensed Chemical
Dictionary"--7th Edition, Reinhold Publishing Corp. 1961,
1966.)
Similarly, toilet tissue may be impregnated with a liquid
hydrocarbon and a silicone, in accordance with the present
invention, which will sooth the irritated skin by depositing a thin
layer of oil on the skin of the user without any greasy
feeling.
Heretofore, in the manufacture of treated facial and toilet tissues
and polishing and dust cloths made of paper, cotton and the like,
it has been customary to impregnate the material with an aqueous
solution containing the treating ingredients by spraying, soaking
and the like, which ingredients were then air dried on the
material. Because of the nature of the structure of the cloth or
special types of paper, these could be subjected to treatment with
an aqueous solution for long periods of time without deleterious
effect. In attempting to apply these aqueous processes to the
treatment of conventional paper, such as tissue paper, it was found
that the results were not satisfactory. It was found that paper
treated with an aqueous solution could not absorb more than one
percent of water without altering its structure. The absorption of
this small amount of water would not result in the deposition of
adequate amounts of the treating material, such as polishing agents
on the paper. It was thus necessary to devise a method to deposit
an adequate amount of the treating material on the paper without
altering the structure of the paper. Also, the dried paper required
wetting in some manner from an outside source before using, in
order to be effective.
In accordance with the present invention, the paper being treated
will absorb sufficient treating material, such as a polishing
agent, menthol or other ingredients, to render the paper useful for
the purpose intended, such as polishing and dusting, a toilet
tissue or a facial type of tissue, without altering the structure
of the paper if the paper is treated with a nonaqueous liquid
vehicle, in which the treating material is substantially uniformly
distributed. The treating liquid is self-spreading throughout the
entire sheet and is spread evenly over the entire surface of the
paper. No separate drying operation is required, as was necessary
previously.
A variety of nonaqueous liquid vehicles are known, which are useful
for the purpose of the present invention. Among these may be
mentioned liquid hydrocarbons, glycols and pine oils. The preferred
liquid vehicles are the normally liquid hydrocarbons, e.g.,
normally light liquid hydrocarbon oils, aliphatic naphthas,
Stoddard solvents, kerosenes (refined), paraffinic hydrocarbons,
natural mineral oil and white mineral oil.
Since the products of the present invention generally come in
contact with the skin, the nonaqueous liquid vehicles generally
employed are those that are nontoxic or nonirritating when the
paper contacts the skin.
All of the ingredients are preferably completely dispersible in the
nonaqueous vehicle, and remain so, so that subsequent agitation is
not needed to redisperse the ingredients in the vehicle before use.
By using the proper percentage of liquid vehicle, a total all-side
surface treatment is assured. This is especially important when
tissue paper is being used, which comes in one-, two-, three-,
four-ply, or more.
For some purposes, certain agents should be incorporated in the
paper. Thus, for example, there may be added to the liquid vehicle
a silicone, wax or menthol, scent, perfume or other agent or
combination of these, which will be absorbed by the paper when the
paper is processed in accordance with this invention.
With the present invention, waxes, scents, pine alcohols, essential
oils and/or silicones can be added to the required degree and the
resulting admixture remains clear indefinitely without separation.
This will permit the production of the treated paper for the many
different purposes intended in the invention.
Some waxes, which are suitable for use, are carnauba, beeswax,
candelilla, paraffin, ceresin, esparto, ouricuri, rezo-wax and
other known waxes.
A feature of the present invention is the fact that no separation
of the essential constituents of the treating composition occurs.
This is true of the treating liquid before it is applied to the
nonwoven material or tissue, as well as the treating composition
disposed on the paper or tissue. Since the treatment of the paper
in accordance with the present invention may involve contacting the
paper with a treating solution for several days, it is very
important that the components of the treating liquid do not
separate out during this period. Furthermore, since it may take
several days for the treating fluid to reach the deeper plies of
paper, it is essential for the proper treatment of these deeper
plies that the constituents of the treating fluid do not separate
out.
The relative proportions of the ingredients contained in the
impregnating liquid may be varied considerably without departing
from the spirit of this invention. In the preferred practice of the
invention, the ratio of the treating liquid to the weight of
treated paper will vary in the range of from about 10 to 70 parts
by weight of the treated paper. For example, a multiple of paper
sheets, size 12 inches .times.24 inches, requires for end use a 25
percent treatment. The weight of the paper unit untreated is 10
grams; therefore, 2.5 grams of the solution is applied to any part
of this paper unit, which distributes itself throughout the paper
evenly in a relatively short time.
The range of wax or combination of waxes added can vary from 1
percent to 40 percent of the impregnating liquid, with about 7
percent to 15 percent being preferred; the silicone added should
not be less than one-tenth of a percent and the range of the
odor-producing chemical can vary from about fifteen-hundredth of a
percent to about seven-tenths of a percent, all percentages being
by weight of the impregnated sheet.
The following examples are further illustrative of the present
invention. It is to be understood, however, that this invention is
not limited thereto.
EXAMPLE 1
The percentages of the materials indicated below in this example,
are based on the total weight of the treating liquid made in
accordance with the present invention.
Seven percent of carnauba wax and three percent paraffin wax was
mixed with a solution containing 87 % hydrocarbon
distillate.sup.(1)
Example 2
A solution was prepared by mixing 1% menthol and 1% lavender with
97 % of hydrocarbon distillate.sup.(1) and 1% cosmetic
silicones.sup.(3).
The above solutions were affixed onto two test samples of paper.
The treating solutions were free-flowing and a predetermined amount
was applied locally to one spot or part of the surface of the paper
to be treated. Within a few days, the solution penetrated every
part of its corresponding paper to provide a uniform distribution
of the treating solution throughout the paper and over the entire
surface. For the purpose of this invention, a permanently dispersed
and uniform distribution of the vehicle throughout the paper is
necessary.
In preparing the treated sheet constituting the product of this
invention, the sheet is treated in any convenient manner with a
predetermined quantity of the nonaqueous treating solution from
about 71/2% to about 70% of the weight of the treated paper product
applied locally to any spot or part of the surface thereof. The
entire quantity of treating liquid applied to the paper is absorbed
and retained by the paper. Advantageously, the treated paper or
tissue is packaged in the normal manner, and within a relatively
short time, i.e., several hours to a few days, the treating
solution spreads by itself to penetrate every part of the paper
without any further act being necessary to provide a uniform and
homogeneous distribution of the treating solution throughout the
paper. The treated paper feels dry to the touch.
An impregnated paper sheet made in accordance with the present
invention is soft and clothlike, so that it covers all of the areas
or surfaces to be wiped or contacted. The treated paper is pliable
and soft, so that the most sensitive skin surface or furniture
surface rubbed with it will not be irritated, marred or scratched.
Dust or loose dirt on the furniture adheres to the surface of the
treated sheet when the furniture is wiped by the sheet used as a
polishing or dusting cloth. In view of the large surfaces of the
sheet, a large amount of dust can be collected. If smearing or
transferring a heavy layer of oil to the surface wiped is to be
avoided, care should be taken as to how much treating liquid is
applied to the paper. Further, the added agents, especially the
odor-producing compounds, such as menthol, are retained on the
sheets and on the surface wiped, for long periods of time, with
little or insignificant loss of effective power. Thus, the present
invention provides long shelf life for the treated paper.
* * * * *