U.S. patent number 3,616,436 [Application Number 04/736,051] was granted by the patent office on 1971-10-26 for oxygen stream dispenser.
Invention is credited to Georg Haas.
United States Patent |
3,616,436 |
Haas |
October 26, 1971 |
OXYGEN STREAM DISPENSER
Abstract
A unitary device for providing oxygen, from water, for breathing
as a small stream or a breathing mixture when desired. The oxygen
is provided in measured amounts by the opening and closing of
valves in the inlet and exit lines of a storage chamber fed by an
oxygen-producing electrolytic cell. Electrolysis by the cell is
controlled according to the pressure of gas within the cell.
Inventors: |
Haas; Georg (7737 Bad Durrheim,
DT) |
Family
ID: |
27180809 |
Appl.
No.: |
04/736,051 |
Filed: |
June 11, 1968 |
Foreign Application Priority Data
|
|
|
|
|
Jun 13, 1967 [DT] |
|
|
P 15 66 611.2 |
Jan 30, 1968 [DT] |
|
|
P 16 16 196.9 |
Feb 2, 1968 [DT] |
|
|
P 16 16 197.0 |
|
Current U.S.
Class: |
204/228.2;
204/278; 204/228.5; 222/3 |
Current CPC
Class: |
C25B
15/02 (20130101); C25B 9/17 (20210101) |
Current International
Class: |
C25B
9/06 (20060101); C25B 15/00 (20060101); C25B
15/02 (20060101); C01b 013/06 () |
Field of
Search: |
;204/129,229-231,266,275,278 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Tung; T.
Claims
I claim:
1. A device for supplying oxygen to a coin-in-the-slot oxygen
dispenser for inhalation, said device comprising a wet electrolytic
cell for producing oxygen and hydrogen and having a partitioning
wall forming a substantially gastight anode compartment and a
cathode compartment and a common electrolytic fluid therefor, an
oxygen tank having a discharge valve and connected to the anode
compartment, an inlet valve interposed between the anode
compartment and the oxygen tank, and means for imposing
superatmospheric pressure on the oxygen in the anode compartment
when said inlet valve is closed during electrolysis and for holding
the pressure after electrolysis stops, spaces above the electrolyte
serving as intermediate gasholders for oxygen and hydrogen
respectively, said cell having an electrolyte storage compartment
therein divided by said wall into anode and cathode regions, one
region having twice the volume of the other, the said spaces
including spaces above the electrolyte in the said anode and
cathode regions of the storage compartment as well as spaces above
the anode and the cathode compartment, and a pressure-equalizing
passageway near the top of the cell so that all gas in the cell is
under substantially equal pressure, and lower passage means near
the bottom of the cell and below the electrodes for the flow of
electrolyte from both regions to and from the anode and cathode to
make the level of the electrolyte in the cell compartments
dependent on the oxygen and hydrogen pressures thereabove.
2. A device as claimed in claim 1 further comprising a source of
electric current to the anode and cathode, and a pressure switch
responsive to the gas pressure in the cell for controlling the
current.
3. A device as claimed in claim 1 further comprising a hydrogen
tank having a discharge valve and connected to said cathode
compartment, a hydrogen inlet valve interposed between the cathode
compartment and the hydrogen tank and ganging means for said valves
for opening the inlet valves when the discharge valves are closed
and closing the inlet valves when the discharge valves are
opened.
4. A device as claimed in claim 1 wherein said cathode compartment
is substantially gastight and is provided with a hydrogen duct for
discharge against atmospheric pressure and a pressure-regulating
valve is provided in the hydrogen duct for bleeding off hydrogen so
that oxygen may accumulate in the anode compartment and cause the
level of the electrolyte in the cathode compartment to rise above
the level of the anode compartment until a predetermined
differential in gas pressure exists in the two compartments.
5. A device as claimed in claim 4 further comprising a limit switch
for controlling current to the cell, said switch being adapted to
open when said predetermined differential is reached.
6. A device as claimed in claim 1 further comprising a hollow
open-bottomed cathode member provided with an inner axially
vertical metal lining as the active surface and a vertical hydrogen
duct connected to the lining as an extension thereof for collecting
and conducting away all hydrogen evolved in the cell, whereby the
height of the electrolyte in said cathode compartment is a measure
of the pressure on the oxygen in the anode compartment, said
cathode compartment and the duct being substantially open to
atmosphere pressure.
7. A device as claimed in claim 1 wherein said cathode compartment
is provided with a switch for interrupting electrolysis when the
electrolyte rises to a predetermined level in the cathode
compartment.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
A unitary device for supplying inhalation oxygen and an
electrolytic cell.
2. Description of the Prior Art
Oxygen-supplying devices are known by which a person may inhale the
oxygen as a small jetstream or "spray" when he senses the ambient
air as overladen with pollution. These devices are frequently
coin-in-the-slot controlled and supply a measured amount of oxygen.
The devices up to the present time have been supplied by cylinders
of oxygen under pressure and require constant attention. Moreover,
they are quite expensive if the discharge pressure is to be held
constant as by a good pressure-reducing valve. Otherwise the
discharge pressure varies excessively with the pressure of the gas
within the cylinder.
Since the present invention utilizes essentially only water as its
raw material its maintenance is quite simple, and one volume of
water produces about 600 volumes of oxygen.
SUMMARY OF THE INVENTION
The unitary device is made up of a generally closed electrolytic
cell which may discharge oxygen into a storage tank whose inlet and
outlet valves are operated so as to enable the building up of
predetermined pressure in the storage chamber to permit a measured
amount of oxygen to be emitted. The cell is divided into anode and
cathode compartments with latter about twice the volume of the
former, and the gas space above the electrolyte in the anode
compartment serves as an intermediate gas storage chamber.
Electrolysis is controlled by a switch responsive to the level of
electrolyte in the cathode compartment or simple lowering of the
electrolyte in the anode compartment below the level of the anode
due to oxygen accumulation above the electrolyte. The partitioning
of the cell into the two compartments is by an essentially gastight
wall member essentially reaching to near the bottom of the
electrolyte container.
DESCRIPTION OF THE DRAWING
FIG. 1 shows schematically, the invention in a form in which the
electrolyte is maintained at about the same level throughout the
cell,
FIG. 2 shows a form of the invention in which the oxygen pressure
normally exceeds the hydrogen pressure; and
FIG. 3 shows a modified form of the cathode compartment.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The invention as shown in FIG. 1 is made up of a generally known
type of electrolytic cell. The shape of the cell is not critical
and may even be of round cross section. The electrolyte container
may be of plastic if inert toward oxygen and the electrolyte which
may be acid or alkaline.
The apparatus of FIG. 1 includes a closed electrolytic cell C in
which oxygen is produced at the anode 1 while hydrogen is produced
at the cathode 2 and the oxygen collects in the upper portion 3 of
the anode compartment or tube which serves as an intermediate
container for oxygen. In similar manner hydrogen collects in the
upper portion 4 of the cathode compartment or tube. The volumes of
the containers 3 and 4 must be maintained at a 1:2 ratio. It is
advantageous to use the electrolyte fluid storage vessel as
intermediate gasholders and the same pressure relationship must be
obtained in the storage vessel as in the electrode tubes. This
condition is obtained by having a pressure-equalizing duct. As
shown the liquid storage vessel is divided into two chambers 7 and
8 by a partition wall 9 with a resulting chamber volume ratio
1:2.
Thus there are formed above the liquid in the container
correspondingly large spaces 5 and 6 having the same ratio as the
intermediate chambers 3 and 4 with which they communicate by their
passages 10 for the pressure equalization. The intermediate
containers are thus made up of chambers 3 and 5 or 4 and 6
respectively.
Each of the intermediate containers or holders 5 and 6 is provided
with vent valves at 20 and 21, respectively, which can be opened
and closed simultaneously. Upon opening of the valves 20 and 21 the
electrolytic fluid can be added through valve 22 into chamber 8 and
it passes thence through lower openings 12 and 11 into the
electrode tubes. During this operation the vented gases from valves
20 and 21 must not come into contact with each other.
When the gas pressure falls below a predetermined minimum pressure
in the intermediate containers the electrical line switch 13 for
supplying current to the electrodes closes and electrolysis begins.
Upon the formation of gases at the anode 1 and the cathode 2, the
pressure then rises in the intermediate chambers 3, 5, and 4,
6--the former pair being connected to an oxygen storage tank 16 via
a filling valve 14 and the latter to a hydrogen tank 17 twice as
large via filling valve 15. Thus the pressure in the storage tanks
may vary directly with the pressures in the intermediate
containers. The tanks 16 and 17 are provided with discharge valves
18 and 19 respectively. For the taking off of oxygen from the
storage tank 16 and supplying it to an inhalation mixture (through
means not shown) the valve 14 is closed first and then the
discharge valve 18 is opened, so that the oxygen under pressure, is
thus led off for supplying the inhalation mixture. In some uses it
is preferable that the oxygen be inhaled directly from a jet as
issued from the valve 18 without special mixing.
With the closure of oxygen valve 14 the hydrogen valve 15 also
becomes closed so that neither of the evolved gases reaches its
storage tank. Similarly discharge valves 18 and 19 open at the same
time. The hydrogen issuing from valve 19 and tank 17 is led away so
as not to be mixed with the oxygen for inhalation. Preferably the
hydrogen is burned. As soon as the oxygen has ceased flowing from
its storage tank 16, discharge valves 18 and 19 are closed and
subsequently valves 14 and 15 are reopened. When a predetermined
maximum gas pressure is attained in the system, the switch 13 is
opened and electrolysis is stopped. Of course the pressure-operated
switch 13 can be in the DC electrode circuit instead of the line
circuit as shown. As a further safety precaution each intermediate
chamber may be provided with a relief valve.
It is possible that the oxygen from valve 18 be partially converted
to ozone. This can be done either by radiation from a quartz
ultraviolet lamp or a capacitor ozonizer operating on high
voltage.
The apparatus as shown in FIG. 2 is made up of a suitable round
container 25 which is divided into two chambers 3 and 4 by a wall
28, the anode 1 being in the chamber 3 and the cathode 2 in chamber
4. The anode chamber 3 is closed off from the atmosphere by a valve
26 which is opened only during the taking off of oxygen.
The level 29 of the electrolyte stands at the same height in the
two chambers before closing the electrolyzing circuit. As soon as
the circuit is closed oxygen is evolved at the anode 1, and is
confined in the chamber 3 when valve 26 is closed, while on the
other hand, the hydrogen produced at the cathode can evolve against
only the free atmosphere if valve 27 is open. The fluid level in
the anode chamber 3 therefore becomes depressed and the level in
the cathode chamber rises. The difference in height of levels 30
and 31 is therefore an indication of the pressure in the anode
chamber 3. The oxygen can therefore be held stored in the chamber 3
under pressure.
Cutting off the current is preferably done by a cathode compartment
limit switch 13' which opens as soon as the liquid level in the
cathode chamber reaches its upper position 31. In this manner the
lower end 23 of the anode may still remain immersed in the
electrolyte.
It is also possible that as the fluid level 29 falls to level 30
the anode not be in the electrolyte. Also if the anode end 23 of
the anode is about at level 24 then it is above lower level 30 of
the fluid and electrolysis is stopped. Hence the switch 13' may be
eliminated and the electrolysis be automatically controlled as the
fluid level rises and falls, with respect to the anode, under the
influence of the oxygen pressure.
However if the limit switch 31 is used, the switch closes the
electric circuit as soon as fluid level 31 falls. The rise in level
30 or the fall of level 31 follows from the outward flow of oxygen
when the valve 26 is opened.
It is also possible within the scope of the invention to make the
valve 27 in the hydrogen exit tube 32 a pressure-opening valve.
This valve then first opens when a predetermined pressure is built
up in the chamber 4 and always allows so much hydrogen to flow that
this amount of pressure is maintained. The maximum pressure in the
chamber 3 corresponds then to the opening pressure of the valve 27
plus the pressure due to the water column between the levels 30 and
31.
The embodiment of the invention having a discharge valve such as 27
is preferable because during the lowering of the liquid level 31
the hydrogen present in chamber 4 expands. Without any valve 27 for
the tube 32, air would enter the chamber 4 when the level 31
falls.
In order to avoid the entrance of air, the cathode chamber may be
as partially shown in FIG. 3, that is, for the cathode side of the
embodiment in FIG. 2, and the anode side remaining as in FIG. 2.
Upon opening the oxygen valve 26, the electrolyte level adjusts
itself to a height shown at 29 in both chambers. A hollow electrode
member 33 is provided with an inner metal covering 34 as the active
surface and is situated in the cathode chamber 4. This hollow
electrode discharges above the liquid level 29 into a hydrogen
takeoff duct 32'. In this arrangement the entry of hydrogen into
the general space above the liquid level is avoided. The passageway
between the hollow electrode and the hydrogen duct is shown at 35.
When oxygen collects in the anode chamber 3, due to closure of the
oxygen valve 26, the liquid level in that chamber is depressed and
the level rises in the cathode chamber 4. When the level for switch
13' is reached electrolysis is interrupted. When oxygen is
withdrawn from the anode chamber the liquid level 29 can adjust
itself to the height 31 again. The upper part of the cathode
chamber can be open since it is separated from the anode chamber by
the partitioning wall 28.
Ganging of valves is shown schematically generally in the drawing,
especially in FIG. 1, as is the means for operating electrical
switches. The details of controllers to carry out the respective
operations are well known to those skilled in the art. For
instance, the switch 13' may have a float operative at level
31.
It is contemplated that the valve 18 may be controlled by a
coin-in-the-slot device so that the device may be installed in
public as well as other places owing to its unitary and simple
structure.
* * * * *