U.S. patent number 3,616,138 [Application Number 04/871,757] was granted by the patent office on 1971-10-26 for carpet structure with foamed secondary backing.
This patent grant is currently assigned to Monsanto Chemicals Limited. Invention is credited to Victor Harold Wentworth.
United States Patent |
3,616,138 |
Wentworth |
October 26, 1971 |
CARPET STRUCTURE WITH FOAMED SECONDARY BACKING
Abstract
Carpets, particularly tufted carpets having a primary backing of
hessian or jute, having a secondary backing which comprises an
extruded foamed aliphatic thermoplastic resin having a glass
transition temperature below ordinary room temperature. Preferably,
the resin is an olefin polymer or copolymer, e.g., polyethylene,
and the foamed resin has a predominantly closed cell structure, the
majority of the cells having a diameter of 0.002-0.1 inch. The
foamed resin can be up to 0.5-inch thick; can be in the form of a
continuous sheet, a woven fabric or net, or a plurality of adjacent
sheets; and, if desired, can be perforated, corrugated, or
embossed. It can be fastened to the back of the carpet in any
convenient manner, e.g., by sewing it in place or by adhering it by
means of a suitable adhesive such as a pressure-sensitive adhesive,
a latex adhesive, or a heat-sensitive adhesive.
Inventors: |
Wentworth; Victor Harold
(Uxbridge, EN) |
Assignee: |
Monsanto Chemicals Limited
(London, EN)
|
Family
ID: |
10445319 |
Appl.
No.: |
04/871,757 |
Filed: |
August 12, 1969 |
Foreign Application Priority Data
|
|
|
|
|
Nov 23, 1964 [GB] |
|
|
47,533/64 |
|
Current U.S.
Class: |
428/96; 428/97;
428/317.7; 428/314.8 |
Current CPC
Class: |
D06N
7/0073 (20130101); D06N 7/0076 (20130101); B32B
27/00 (20130101); D05C 17/023 (20130101); Y10T
428/249977 (20150401); Y10T 428/23986 (20150401); D06N
2203/045 (20130101); Y10T 428/23993 (20150401); D06N
2203/042 (20130101); Y10T 428/249985 (20150401); D06N
2205/04 (20130101) |
Current International
Class: |
B32B
27/00 (20060101); D06N 7/00 (20060101); D05C
17/02 (20060101); D05C 17/00 (20060101); D05c
017/02 () |
Field of
Search: |
;161/62-67,109,112,113,159-161 ;156/72 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Burnett; Robert F.
Assistant Examiner: Carlin; Linda M.
Parent Case Text
This application is a continuation of copending application Ser.
No. 506,400, filed Nov. 4, 1965 and now abandoned.
Claims
What is claimed is:
1. In combination with a carpet having a primary backing, the
improvement which comprises a secondary backing sheet adhered
thereto; said secondary backing sheet comprising an extruded foamed
aliphatic thermoplastic resin; said resin having a glass-transition
temperature below ordinary room temperature; said secondary backing
sheet having a multiplicity of voids extending therethrough from
one face of the sheet to the other and being a woven fabric
comprising strands of the extruded foamed aliphatic thermoplastic
resin, said voids being formed by the interstices of the weave.
2. The improved carpet of claim 1 wherein the carpet is a tufted
carpet comprising individual tufts of pile yarn pulled through a
primary backing fabric.
3. The improved carpet of claim 1 wherein the extruded foamed
aliphatic thermoplastic resin is polyethylene.
4. The improved carpet of claim 1 wherein adhesion of the secondary
backing sheet to the primary carpet backing is accomplished by
means of a pressure-sensitive adhesive.
5. The improved carpet of claim 1 wherein adhesion of the secondary
backing sheet to the primary carpet backing is accomplished by
means of a heat-sensitive polyvinyl acetate adhesive.
Description
This invention relates to carpets, and particularly to carpets
having a secondary backing.
It has been proposed to apply to carpets, particularly those of the
tufted type, a secondary backing consisting of hessian fabric in
order to improve the appearance and provide additional stiffness
for the carpet as a whole. A secondary backing of hessian has been
found to have some disadvantages, however, including the serious
one that it can make the carpet more likely to slip on polished
floors.
It is therefore an object of this invention to provide an improved
backing for carpets and the like.
It is a further object of this invention to provide an improved
carpet having a secondary backing comprising an extruded foamed
aliphatic thermoplastic resin having a glass-transition temperature
below ordinary room temperature.
Each of the above objects has been realized through the development
of a new type of secondary backing that not only improves the
appearance and handle of the carpet, but also increases its
resilience, resistance to wear and apparent depth and is moreover
less likely than hessian to slip on floor surfaces.
The invention, which comprises a carpet having a secondary backing
comprising an extruded foamed aliphatic thermoplastic resin that
has a glass-transition temperature below ordinary room temperature,
is particularly applicable to tufted carpets which are not woven in
the traditional way but comprise individual tufts of pile yarn
pulled through a primary backing fabric, normally of jute or
hessian, and anchored in place by means of a binding composition.
Binding compositions can for example be those described in British
Patent specifications Nos. 903,009 and 969,368. However, more
conventional carpets, for example Wilton or Axminster, can usefully
have applied to them a secondary backing according to the
invention.
The aliphatic thermoplastic resin is one derived by polymerization
or copolymerization of an ethylenically unsaturated monomer. The
monomer is preferably an ethylenically unsaturated hydrocarbon, and
more specifically an olefin, but it may for instance be a nitrile,
such as acrylonitrile; vinyl or vinylidene chloride, vinyl acetate;
or an acrylate, such as ethyl acrylate or methyl methacrylate. The
most suitable hydrocarbon monomers are ethylene, propylene, and the
butylenes. For instance, the polymer may be polyethylene
(low-density or high-density material) or polypropylene. Moreover,
copolymers of at least 50 percent by weight of the ethylenically
unsaturated monomers mentioned above, with up to 50 percent by
weight of other ethylenically unsaturated monomers copolymerizable
therewith, such as maleates, fumarates, divinyl benzene, divinyl
phthalate, diallyl maleate, etc., may be employed in the practice
of this invention. Preferably, a copolymer of one of the
hydrocarbon monomers (such as ethylene) with another ethylenically
unsaturated monomer, such as one of those given above is employed.
Thus, the copolymer can, for example, be an ethylene-vinyl acetate
copolymer.
The resin has a glass-transition temperature below ordinary room
temperature. The glass-transition temperature of a resin, sometimes
known as its second-order transition temperature, is defined as the
temperature below which the resin is hard and rigid but above which
it possesses elastic properties. The glass-transition temperature
is thus normally below about 20.degree. C., and preferably below
0.degree. C. Many of the resins derived by polymerization or
copolymerization of the monomers mentioned above, for example
polyethylene, intrinsically possess glass-transition temperatures
below room temperature, but others, for example, polyvinyl
chloride, may require the addition of a plasticizer in order to
achieve a sufficiently low glass-transition temperature. Suitable
plasticizers include, for example, dioctyl phthalate and
chlorinated diphenyl.
The resin is in the form of an extruded foam, which can be made by
extruding a foamable resin composition containing a blowing agent.
The blowing agent is preferably a normally gaseous substance but it
can be a volatile liquid. In many cases the blowing agent is one
that is normally gaseous but which while under pressure before
extrusion is present in the liquid state. Examples of volatile
substances that can be used include lower aliphatic hydrocarbons,
such as ethane, propane, a butane or butene, or a pentane or
pentene; lower alkyl halides, such as methyl chloride,
trichloromethane or 1,2-dichlorotetrafluoroethane; and inorganic
gases such as carbon dioxide or nitrogen. The lower aliphatic
hydrocarbons, especially a butane, or mixture of butanes, are
preferred. The blowing agent can also be a chemical blowing agent,
which can for example be a bicarbonate such as for example sodium
bicarbonate or ammonium bicarbonate, or an organic nitrogen
compound that yields nitrogen on heating, such as for example
dinitrosopentamethylenediamine or barium azodicarboxylate. From 3
to 30 percent, especially 7 to 20 percent, by weight based on the
weight of the resin is generally a suitable proportion of blowing
agent. For example, the use of from 7to 15percent by weight of
butane in conjunction with polyethylene has given excellent
results.
Preferably the foamable resin contains a nucleating agent, which
assists in the formation of a large number of small cells. A wide
range of nucleating agents can be employed, including finely
divided inert solids such as for example silica or alumina,
preferably in conjunction with zinc stearate, or small quantities
of a substance that decomposes at the extrusion temperature to give
a gas. An example of the latter class of nucleating agents is
sodium bicarbonate, used if desired in conjunction with a weak acid
such as tartaric acid or citric acid. A small proportion of the
nucleating agent, for example up to 5 percent by weight of the
resin, is usually effective.
Extrusion of the resin takes place through a die, which is normally
of the slit type so that a sheet of resin is produced. Slit dies
that have been modified so as to produce a more uniform product, as
described in British Patent specifications 1,034,120 and 1,089,561
can often be advantageously used.
The density of the foamed resin may vary between fairly wide
limits. Foamed resins having a density between 1 pound per cubic
foot or slightly less and 10 pound per cubic foot or more are
suitable. Resins having a density between 1 and 7 pounds per cubic
foot, and preferably between 2 and 4 pounds per cubic foot, are
generally most useful, particularly in the case of a foamed
polyethylene.
Preferably the foamed resin has a predominantly closed cell
structure, the majority of the cells may for example have a
diameter of from 0.002 to 0.1 inch. Preferably the majority of the
cells have a diameter of from 0.003 to 0.01 inch.
The foamed resin may be in the form of a continuous sheet,
perforated by a number of holes about 0.1 inch in diameter and
spaced about 0.25 inch apart, or it can be a woven fabric or net
comprising strands of the extruded foamed resin. Alternatively, a
number of strips of foamed resin can be used side by side, and the
resin can be corrugated or embossed.
A very suitable form of foamed resin is that described in British
Patent specification No. 1,089,561.
The foamed resin may be up to 0.5-inch thick. Usually however, it
will be in the range of about 0.05 inch to 0.3-inch thick.
Preferably, the thickness is from 0.1 inch to 0.25 inch.
The foamed resin may be fastened to the carpet in any convenient
way. For example, it may be sewn in place or stuck to the back of
the carpet by means of a suitable adhesive, for instance an
"impact" or pressure-sensitive adhesive, or one that comprises a
polymer latex, especially a latex of a natural or synthetic rubber
such as a styrene/butadiene rubber or a nitrile rubber. A mineral
filler such as barytes, china clay, whiting or titanium dioxide may
also be present. Excellent results can often be obtained using as
adhesive a composition comprising a latex and a filler of the kind
that are commonly applied as a binding composition to a primary
backing of tufted carpets. Where the carpet is tufted, the foamed
resin secondary backing can conveniently be applied to the
partially dried binding composition on the primary backing, thus
eliminating the need for additional adhesive. After the foamed
resin is applied to the carpet the adhesive or binding composition
is dried out. Drying is facilitated if the foamed resin is
perforated as mentioned above. Good results are obtainable by
applying a heat-sensitive adhesive such as polyvinyl acetate to the
foamed resin and then placing the treated resin against the back of
the carpet while the latter is hot, for example from a drying
operation.
The invention is illustrated by the following Examples.
EXAMPLE I
This example describes the production of carpets having a secondary
backing according to the invention.
The first carpet was a tufted one comprising tufts of rayon pulled
through a hessian primary backing fabric and anchored in place by a
binding composition comprising a styrenebutadiene copolymer
containing 60 percent by weight of combined styrene together with
whiting as a filler.
The secondary backing consisted of strips of foamed polyethylene
having a density of 2 pounds per cubic foot, containing
predominantly closed cells of diameter about 0.040 inch. The strips
were 0.125 inch thick and 8 inches wide and were made by extruding
a foamable polyethylene composition containing 3 percent by weight
of finely divided silica, 1 percent by weight of zinc stearate and
10 percent by weight of butane through a slit orifice of length 2
inches, a width 0.040 inches and a land 0.75 inch.
The secondary backing was stuck to the back of the carpet by means
of a commercial adhesive of the "impact" type, a thin layer of
adhesive being spread on the back of the carpet and on the
secondary backing and allowed to dry for 15 minutes, and the two
surfaces then being pressed firmly together.
A good bond was obtained and the carpet as a whole had an excellent
handle and resilience. When laid on a floor the apparent depth and
the resistance to wear and slipping were improved compared with
those of a similar carpet having a secondary backing of
hessian.
EXAMPLE II
The same foamed resin secondary backing was applied in the same way
to an Axminster woven carpet, and the same advantages were
obtained.
EXAMPLE III
Example I was repeated using strips of foamed ethylene vinyl
acetate copolymer wherein the copolymer had a vinyl acetate content
of 35 percent.
EXAMPLE IV
Example I was repeated using foamed polyvinyl chloride resin having
incorporated therein 50 parts of dioctyl phthalate.
EXAMPLE V
Example I was repeated using foamed polyisobutylene in place of
foamed polyethylene.
EXAMPLE VI
Example I was repeated using a foamed ethyl acrylate copolymer.
EXAMPLE VII
Examples I and II were repeated except that the polyethylene was
applied to the primary backing in the form of a perforated
continuous sheet.
The above description and particularly the examples are set forth
for purposes of illustration only. Many modifications and
variations will be apparent to those skilled in the art and can be
made without departing from the scope of the invention herein
described.
* * * * *