U.S. patent number 3,615,915 [Application Number 04/871,893] was granted by the patent office on 1971-10-26 for method of densifying magnetically anisotropic powders.
This patent grant is currently assigned to U.S. Philips Corporation. Invention is credited to Gijsbertus Maria Arnoldus Josephus DE Kort, Willem Luiten, Frans Frederik Westendorp.
United States Patent |
3,615,915 |
Luiten , et al. |
October 26, 1971 |
**Please see images for:
( Certificate of Correction ) ** |
METHOD OF DENSIFYING MAGNETICALLY ANISOTROPIC POWDERS
Abstract
A method of densifying magnetically anisotropic powders under a
magnetic field by the use of isostatic pressures of at least 10
kb.
Inventors: |
Luiten; Willem (Emmasingel,
Eindhoven, NL), Westendorp; Frans Frederik
(Emmasingel, Eindhoven, NL), DE Kort; Gijsbertus Maria
Arnoldus Josephus (Emmasingel, Eindhoven, NL) |
Assignee: |
U.S. Philips Corporation (New
York, NY)
|
Family
ID: |
19805046 |
Appl.
No.: |
04/871,893 |
Filed: |
October 28, 1969 |
Foreign Application Priority Data
|
|
|
|
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Oct 31, 1968 [NL] |
|
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6815510 |
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Current U.S.
Class: |
419/62; 148/105;
264/427; 148/103; 148/301 |
Current CPC
Class: |
H01F
1/06 (20130101); H01F 41/0273 (20130101); B22F
3/04 (20130101) |
Current International
Class: |
H01F
1/06 (20060101); H01F 41/02 (20060101); H01F
1/032 (20060101); B22F 3/04 (20060101); H01f
001/11 (); H01f 001/08 () |
Field of
Search: |
;148/100,101,102,103,108,31.57,104,105 ;264/24,111 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rutledge; L. Dewayne
Assistant Examiner: White; G. K.
Claims
What is claimed is:
1. A method of densifying magnetically anisotropic powders of
ferromagnetic metals, metal alloys or ceramic materials to solid
magnetic bodies, comprising the steps of subjecting a powdery mass
to an external magnetic field which orients the powder particles,
and compressing said mass under an isostatic pressure of at least
10 kb. to slightly deform said mass anisotropically and
plastically.
Description
The invention relates to a method of densifying magnetically
anisotropic powders, for example, powders of ferromagnetic metals,
metal alloys or ceramic materials into solid magnetic bodies, in
which method a powdery mass is subjected to an external magnetic
field which orientates the powder particles, said mass being
densified by compression.
It is common practice to subject the previously orientated powder,
as the case may be, subsequent to preliminary densification at low
pressure, to a high pressure in a mould by one die or one lower and
one upper die. It has to be endeavored to maintain the orientation
of the particles in order to obtain satisfactory permanent magnetic
properties.
Such a densifying method has various disadvantages. In the first
place the orientated powder is not densified homogeneously so that
the relative orientation of the powder particles (alignment) is
changed and hence the magnetization in the direction of
magnetization is adversely affected. During compression the powder
mass is locally deformed to a great extent mainly due to friction
along the wall. This has an unfavorable influence on the
orientation of the particles and hence on the magnetization in the
direction of magnetization. It has, moreover, been found that in
the known compression method the attainable density and hence the
attainable magnetization of the compressed powder are limited.
There appears a strange phenomenon in that however high the
pressure is raised the density of the compressed powder does not
exceed a given value. For example, in compression barium
hexaferrite it has not been possible to attain a density exceeding
60 percent of the theoretical density.
This phenomenon has not yet been satisfactorily accounted for. A
fact is, however, that the attempts to increase magnetization by
increasing the density by compression have so far failed due
thereto.
The present invention has for its object to obviate said
disadvantage and to overcome the barrier to the increase in
magnetization by an increased density obtained by compression.
For this purpose the method according to the invention is
characterized in that the powdery mass is compressed by an
isostatic pressure of at least 10 kb., and that it is slightly
deformed anisotropically plactically, the said isostatic pressure
being maintained.
It has been found that by isostatic compression a homogeneous
densification of the powdery mass is obtained, while the
orientation of the particles is maintained. During the subsequent
slight anisotropic, plastic deformation, while the isostatic
pressure is maintained, a surprisingly considerable increase in
density is obtained, whereas the orientation of the particles is
hardly affected by this deformation. These two measures provide a
magnet having a considerably higher energy product (BH).sub.max
than could hitherto be obtained.
The invention furthermore relates to a permanent magnet
manufactured of magnetically anisotropic powder by the method
described above. The permanent magnet is characterized in that the
density is at least 85 percent of the theoretic density and the
magnetization in the direction of magnetization is at least 90
percent of the saturation magnetization.
An advantageous permanent magnet embodying the invention is
characterized in that the essential constituent of the powder is a
compound of hexagonal structure, the existence range of which is
integral with the existence range of the compound in the system
M--R that is M.sub.5 R, wherein M is Co or a combination of Co with
one or more of the elements Fe, Ni and Cu and R designates one or
more of the elements of the rare earth metals and/or Th and/or
Y.
Such powders are known from Dutch Pat. application No. 6,608,335
and are particularly suitable for providing in conjunction with the
method according to the invention permanent magnets having very
high (BH).sub.max values.
In a further advantageous permanent magnet embodying the invention
M is Co and R is Sm, while the energy product (BH).sub.max has a
value of at least 14.10.sup.6 Gauss Oersted. The energy product
(BH).sub.max of this magnet is considerably higher than that of the
SmCo.sub.5 magnets hitherto known. From the review "Journal of
Applied Physics", Vol. 39, No. 3, 1968, pages 1,719-1,720 is known,
for example, an SmCo.sub.5 magnet on which a (BH).sub.max value of
8.1.times.10.sup.6 Gauss Oersted has been measured, whereas the
present magnet attains values of 15.times.10.sup.6 Gauss Oersted
and higher.
By way of example the invention will be described more fully with
reference to the drawing.
Magnetically anisotropic powder is put into a rubber bag and
disposed in a magnetic field so that the powder particles are
orientated. While the magnetic field is maintained, the powder is
compressed until a coherent block of particles is obtained.
Then the rubber bag with its contents is evacuated and sealed in an
airtight manner. The block is then isostatically predensified (for
example at a pressure of 8 kb.) and after the compression the
rubber bag is removed.
The isostatic predensification may be carried out by hydrostatic
means.
The block is then introduced in a container of ductile material.
The container is sealed by a covering plate, which may be soldered
to the container. Then the container is compressed at a high
isostatic pressure of, for example, 20 kb. and while this high
pressure is maintained it is slightly deformed anisotropically and
plastically. This compression may be carried out hydrostatically in
a press having, in addition, the means for performing said plastic
deformation. Such a press may be constructed as is shown
schematically in the FIGURE.
Reference numeral 1 designates a compression vessel having a
shoulder 2 on the inner side. The vessel has a space 3 filled with
liquid. In order to prevent the liquid from changing into the solid
state at the high pressures of the order of 7 kb., petrol is used
as a pressure transmitting medium. Other appropriate liquids may be
chosen for this purpose.
The space 3 is bounded on the lower side by a plunger 4, which is
adapted to reciprocate in the compression vessel by means of a
hydraulic worm 5, connected therewith, and on the upper side by a
plunger 6, which is connected with a hydraulic worm 7 and is also
adapted to reciprocate in the compression vessel. The hydraulic
worms 5 and 7 can be driven independently of each other.
In the space 3 between the shoulder 2 and the plunger 6 two loose
dies 8 and 9 are provided, between which is arranged the aforesaid,
hermetically closed container 10 containing the block of
magnetically orientated material. The container may be introduced
into the vessel by removing the plunger 6. The assembly of the
compression vessel, the dies and the hydraulic worms is arranged in
a frame 11.
The press operates as follows:
By actuating the worms 5 and 7 each of the plungers 4 and 6 exert
equal high pressures on the liquid in the space 3. The hydrostatic
pressure is exerted on the container 10, which is thus compressed,
the orientated powder contained therein being homogeneously
densified. Then the pressure exerted by the plunger 6 is slightly
raised, whereas the pressure exerted by the plunger 4 is kept
constant. The assembly of plungers 4 and 6 and the liquid column
thus move slowly downwards. At a given instant the plunger 6
touches the die 8 and the container 10 is slightly deformed. By
means of the die 8 an anisotropic plastic deformation is obtained.
It has, of course, to be ensured that liquid can always flow along
the dies 8 and 9, for example, by providing holes therein.
After the hydrostatic compression of the container 10 and the
slight anisotropic, plastic deformation, the pressure of the
plungers is obviated and the container can be removed from the
compression vessel and be opened.
Although only one form of the method according to the invention is
described herein, presses of different constructions may of course
also be employed.
EXAMPLE
Powder of SmCo.sub.5 having an average particle size of less than
10 .mu.m. was orientated in a magnetic field of 30,000 Oersted and
then hydrostatically predensified to 70 percent of the theoretic
density. The resultant material was hermetically enclosed in a lead
container then hydrostatically compressed and slightly deformed
anisotropically and plastically in the manner described above. The
hydrostatic pressure was 20 kb. The result was an SmCo.sub.5 magnet
having a density amounting to 93 percent of the theoretic density.
The energy product (BH).sub.max was 18.5.times.10.sup.6 Gauss
Oersted.
* * * * *