U.S. patent number 3,611,939 [Application Number 05/004,960] was granted by the patent office on 1971-10-12 for primer.
Invention is credited to Hellmut Bendler, Heinz Gawlick, Hans Stadler.
United States Patent |
3,611,939 |
Stadler , et al. |
October 12, 1971 |
**Please see images for:
( Certificate of Correction ) ** |
PRIMER
Abstract
A primer comprising a body of priming composition composed of a
thermal mixture and an initial detonating agent, and a body of
booster material composed of thermal mixture substantially free of
initial detonating agent. The booster material and the priming
composition are in direct contact.
Inventors: |
Stadler; Hans (85 Nurnberg,
DT), Gawlick; Heinz (851 Furth i.B, DT),
Bendler; Hellmut (85 Nurnberg, Furth/Bay, DT) |
Family
ID: |
25971540 |
Appl.
No.: |
05/004,960 |
Filed: |
January 22, 1970 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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691647 |
Dec 18, 1967 |
3499386 |
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612049 |
Jan 26, 1967 |
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326457 |
Nov 27, 1963 |
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Foreign Application Priority Data
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Nov 29, 1962 [DT] |
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D 40 379 |
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Current U.S.
Class: |
102/204;
102/202.9; 102/202.8 |
Current CPC
Class: |
F42C
19/0803 (20130101); F42C 19/0815 (20130101); F42C
19/12 (20130101); F42C 19/0807 (20130101); C06C
7/00 (20130101); F42C 19/10 (20130101) |
Current International
Class: |
C06C
7/00 (20060101); F42C 19/08 (20060101); F42C
19/00 (20060101); F42C 19/10 (20060101); F42C
19/12 (20060101); F42b 009/08 () |
Field of
Search: |
;102/46,28,70.2,86.5 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Stahl; Robert F.
Parent Case Text
This application is a division of application Ser. No. 691,647,
filed Dec. 18, 1967, now U.S. Pat. No. 3,499,386, which is a
continuation of Ser. No. 612,049, filed Jan. 26, 1967, now
abandoned, which in turn is a continuation of Ser. No. 326,457,
filed Nov. 27, 1963 abandoned.
Claims
What is claimed is:
1. A primer comprising a container, a body of priming composition
within the container, a body of booster material within the
container, said bodies being in communication with each other for
igniting of the booster material in response to detonation of the
priming composition, and means for effecting detonation of the
priming composition, the booster material comprising a thermal
mixture substantially free of initial detonation agent, the priming
composition consisting essentially of a thermal mixture and initial
detonation agent, the thermal mixtures comprising an oxidizer
selected from the group consisting of the oxides of lead, copper,
manganese, iron, and a reducer selected from the group consisting
of aluminum, calcium, silicon, boron, zirconium, magnesium, the
proportion of primer composition to booster material being in the
range of about 1:1 to 1:500, the booster material and the priming
composition being in direct contact.
2. Primer according to claim 1, the cross-sectional area of the
booster material being about 9 times that of the priming
composition where the booster material and the priming composition
are in direct contact.
Description
For the ignition of powder in gun cartridges, shotgun shells, etc.
etc., are used which contain a limited amount of primer composition
which suffices to ignite the relatively small amount of powder in
these cartridges. The powder is usually smokeless powder, in a
charge amounting to between 1 and 8 grams, in which case quantities
of 20 to 40 mg. of priming composition suffice.
Larger cartridges with a caliber of 15 or 20 mm., in which the
amount of powder runs as high as about 50 grams, require
correspondingly larger amounts of priming composition to ignite the
powder. Percussion and electrical primers are made for this purpose
which contain a charge of up to 200 mg. of priming composition. The
handling of these heavily charged primers is not always without
danger, and special precautions must be taken in the shipment and
in the installation of these primers to prevent unintentional
explosions. An amount of 200 mg. of primer composition is, in
general, not exceeded for reasons of safety because otherwise it
would act as an explosive detonator.
Consequently, in the case of still larger charges, i.e. larger than
50 grams, threaded percussion primers have long been used. These
threaded primers have only small percussion caps containing
approximately the same amount of priming composition as a gun
cartridge primer and in addition contain a charge of black powder.
The priming composition serves to ignite the black powder. This
black powder, the charge and arrangement of which may vary
considerably according to requirements, serves in turn to ignite
the smokeless powder.
Herein the term "primer" is used to designate the thing inserted in
a shell or the like, and which receives an initial impulse to
effect firing of the shell. The term "primer composition" is a
composition within the shell responsive to the initial impulse. In
addition to the primer composition, the primer may contain a
"booster charge." In the case of shells containing a charge in
excess of 50 grams, described above, the primer contains a primer
composition and in addition a booster charge (which can be black
powder), and the primer composition initiates the booster charge
and the booster charge in turn initiates the shell charge.
The use of a black powder booster charge is accompanied by the
disadvantage of requiring much space, this being due to the
relatively small caloric yield developed by black powder. Due to
black powder's high sensitivity to moisture, special measures must
be taken to seal it. It is furthermore necessary to pack the black
powder loosely, so that it will burn fairly rapidly to achieve the
short ignition time required for the shot. It is not possible to
concentrate the black powder into a small space by great
compression, because this causes it to burn slowly and with a great
delay.
Attempts have been made to replace black powder with a brisant
smokeless powder. The igniting capacity of this powder, however, is
lower than that of black powder, and hence the brisant smokeless
powder is not a satisfactory replacement.
All these primers develop relatively a relatively amount of gas,
which results in a high pressure in the primer body and also in the
cartridge, and hence the bottom of the cartridge is placed under a
severe stress, necessitating a special design that provides a very
strong wall between the charge and the firing pin or electrode.
This is especially disadvantageous in the case of percussion-type
threaded primers since it greatly reduces their percussion
sensitivity.
In all cartridges in which the expansion of the area of combustion
is very rapid, a gas-rich booster charge will drive the smokeless
powder propellant out of the cartridge before it can be ignited.
This is particularly true of cartridges having naught but light
wadding (instead of a projectile), as for example in the case of
blank cartridges or cartridges used to propel mortar shells, and
cartridges in which the sidewall of the casing is perforated.
The problem thus develops of creating a primer with a booster
charge which will work with a relatively small amount of primer
composition, ignites very easily, requires little space, and is
better as regards gas development than the previously known primers
which contain a booster charge.
A common primer composition is made up of an admixture of a thermal
material or mixture, and an initial detonating agent. The thermal
mixture can be composed of oxygen carrier, oxidizer and reducer;
the initial detonating agent can be such as tricinate, tetracene,
lead azide or mercury fulminate. Without the initial detonating
agent, the thermal mixture reacts but poorly. Consequently (as is
known), the content of initial detonating agent cannot be reduced
below a certain percentage without risking the loss of the igniting
power of the priming composition. Now the surprising discovery has
been made that the reactivity of the thermal mixture containing no
initial detonating agent is excellent if the reaction is initiated
by igniting it with a thermal mixture that does contain an initial
detonating agent. This characteristic of the reaction of the
explosive-free thermal mixture is utilized according to the
invention by providing a booster charge composed of a thermal
mixture of oxidizer and reducer, but containing no initial
detonating agent. In this manner a rapidly acting primer is
obtained which, with a very small amount of initial detonating
agent, is capable of igniting even relatively large amounts of
smokeless powder.
The invention, however, is especially valuable because the booster
charge, on account of its high calorie content, requires
substantially less space than
prior art charges, and also especially because of the fact that it
can be very highly compressed, e.g. up to 1,000 kg. per sq. cm.,
desirably 500- 1,000 kg. per sq. cm. A booster charge 2.5 cm. along
according to the invention is equivalent to a prior art booster
charge approximately 10 cm. long.
The following are particularly good examples of thermal mixtures
suitable as the booster charge:
1. 75% barium nitrate 9% lead dioxide 18% calcium silicide 2. 62%
barium nitrate 8% lead dioxide 30% aluminum silicide 3. 65% barium
nitrate 7% copper oxide 28% silicon
Generally speaking the nitrates of the groups Ia and IIa of the
Periodical System of the Elements may be used oxygen carriers.
Other nitrates can also be used as oxygen carriers, such as basic
lead nitrates. The oxides and dioxides, respectively, as cited
above are also oxygen carriers, but their main purpose is to
accelerate the reaction of the nitrates. They are oxidizers. Also,
instead of lead or copper oxides, manganese and iron oxides; and,
as reducer components, instead of aluminum calcium or silicon,
zirconium, boron magnesium etc. and their alloys. However,
chlorates and perchlorates are to be avoided, since they give the
thermal mixture an excessively high reactivity and would thus bring
it dangerously close to constituting a detonating composition.
Accordingly, the thermal mixture, i.e. the booster, should be free
of or the tantially free of chlorates and perchlorates.
A mixture of thermal components and initial detonating agents which
would be suitable as the primer composition, is, for example:
3% tetracene [1 - (5' tetrazolyl)-4- guanyl-tetrazene-hydrate] 42%
tricinate [leadstythnate] 40% barium nitrate 5% lead dioxide 10%
calcium silicide
The thermal mixture component in the priming composition does not
have to be identical to the booster composition, but preferably has
the same character.
How effective the new primer is can be seen from the fact that it
has been possible to bring 4 grams of booster charge to reaction
with a priming composition charge of only 30 mg. within 1 to 3
milliseconds, i.e., in a ratio of 200:1. The upper limit of the
ratio of priming composition charge to booster charge can be set at
about 1 to 500.
This wide range of sensitivity of the combination of a booster
charge containing no detonating agent with a priming composition
charge that does, is of especial importance in production for it is
no longer necessary to match the two charges to one another in each
case; instead, the same priming composition charge (which contains
initial detonating agent) can always be used over a range of weight
ratios of primer composition charge to booster charge of about 1:1
to about 1:500 (parts of booster).
Mention has already been made of the possibility of highly
compressing the booster charge. This is also very favorable from
the mechanical viewpoint, since such compression gives the primer
considerable strength in itself, and thus it becomes very
insensitive to mechanical stresses, e.g. shock.
Thus, the invention provides a primer comprising a container, a
body of priming composition within the container, and a body of
booster material within the container. These bodies are in
communication with each other for igniting of the booster material
in response to detonation of the priming composition. The primer
further includes means for effecting the detonation, such as a
plate for transmitting impact to the priming composition or for
transmitting an electrical igniting impulse thereto. The booster
material comprises a thermal mixture which is substantially free of
initial detonation agent, and the priming composition consists
essentially of a thermal mixture and initial detonation agent.
Desirably the thermal mixture of the booster and the thermal
mixture of the priming composition consist essentially of the same
components.
The invention is further described in reference to the accompanying
drawing, wherein:
FIG. 1 and FIG. 2 are of primers according to the invention;
and
FIG. 3 shows a portion of a shell outfitted with a primer according
to the invention.
The primer body consists of the shell 1, the threaded collar 2 and
the bottom plate 3, which is held tightly against shell 1 by the
threaded collar 2. The compressed priming charge 6 is inserted into
a recess 4 in the bottom plate 3 in a cup 5, the said priming
charge consisting of a thermal mixture and an initial detonating
agent. Above the priming charge 6 is the anvil 7 with holes 7a. The
booster charge 8, which contains no initial detonating agent, is
pressed into the funnel-shaped hole 9 in shell 1, and is covered by
a thin lid 10. Between the recess 4 containing the priming charge 6
2-6 the booster charge there is a relatively narrow passage 18
whose diameter is to be expediently between one-half to 4-36 the
booster charge chamber 9. The transition from passage 18 to chamber
9 is not abrupt, but passes through a conically flared portion 11
with walls at an angle of about 30.degree. to 60.degree.. The ratio
of booster charge to priming composition is 500.
In the embodiment shown in FIG. 1 the booster material is contained
within a chamber provided in the container, and this chamber has an
axially extending portion of relatively large cross-sectional area
and an axially extending portion of relatively small
cross-sectional area. The axially extending portion of small cross
section is disposed to transmit initiation of the booster material
from the primer composition to the portion of relatively large
cross-sectional area. The diameter of the large portion can be 2-6
times the diameter of the small portion (or the area of the large
portion can be about 4-36 times the area of the small portion). The
booster material and priming composition can be in direct contact,
and, desirably, the diameter of the body of booster material is
about 3 times the diameter of the body of priming composition at
the locus of direct contact (the cross-sectional area of the
booster material about 9 times that of the priming
composition).
In the embodiment in FIG. 2, an electrically operated primer is
shown. 12 represents the outer shell, 13 a supporting shell, 14 a
plug for the one pole of the electrical igniting system including
contact 14a, and 15 is an insulator. The priming charge is
designated as 16, and the booster charge containing no initial
detonating agent is designated as 17. This embodiment differs from
the one in FIG. 1, in that the booster charge 17 is pressed
directly upon the priming charge 16. However, it is not necessary
that both charges have the same diameter when pressed together. The
diameter of the booster charge can also be greater than that of the
priming charge by as much as a factor of three. The design of FIG.
2 is desirable when it is desired to have the priming flash cover
the entire charge chamber.
The arrangement shown in FIG. 2 can furthermore also be used for
percussion fuses.
In FIG. 3, a shell 20 containing a charge of smokeless powder 21 is
outfitted with a primer 22.
The primer of the invention is well suited for shells having a
projectile piece as well as blanks, cartridges for use to propel
mortar shells, cartridges with wadding, etc.
While the invention has been described with reference to particular
embodiments thereof, these are merely representative and do not
serve to set forth the limits of the invention.
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