U.S. patent number 3,608,821 [Application Number 04/571,243] was granted by the patent office on 1971-09-28 for electrostatic atomization of liquids.
This patent grant is currently assigned to Agfa-Gevaert Aktiengesellschaft. Invention is credited to Otto Koch, Walter Simm.
United States Patent |
3,608,821 |
Simm , et al. |
September 28, 1971 |
**Please see images for:
( Certificate of Correction ) ** |
ELECTROSTATIC ATOMIZATION OF LIQUIDS
Abstract
The process of atomizing liquids having conductivity in
10.sup.-.sup.6 to 10.sup.-.sup.3 ohms - centimeters range using
either a negative or a positive electrostatic charge for the
purpose of producing the aerosol which is deposited. In this
process an ambient atmosphere is placed around the atomizing
electrodes of an electric field with gases and vapors having a
higher breakdown that air which vapors include short chained
aliphatic compounds containing halogens and inorganic halogens. As
a result, both negative and positive charges can be used in
atomizing with liquids in the indicated conductivity range.
Inventors: |
Simm; Walter (Leverkusen,
DT), Koch; Otto (Leverkusen, DT) |
Assignee: |
Agfa-Gevaert Aktiengesellschaft
(Leverkusen, DT)
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Family
ID: |
6937440 |
Appl.
No.: |
04/571,243 |
Filed: |
August 9, 1966 |
Foreign Application Priority Data
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Oct 15, 1965 [DT] |
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A 50511 VIb/75c |
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Current U.S.
Class: |
239/3; 361/227;
427/486; 427/483 |
Current CPC
Class: |
B05B
5/087 (20130101); G03G 9/16 (20130101) |
Current International
Class: |
B05B
5/08 (20060101); G03G 9/00 (20060101); G03G
9/16 (20060101); G03g 013/16 (); B05b 005/02 () |
Field of
Search: |
;117/37LX,17,93.4-93.44,17.5 ;239/3,15 ;317/3 ;174/127 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
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901,449 |
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Jul 1962 |
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GB |
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975,717 |
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Nov 1964 |
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GB |
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994,645 |
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Jun 1965 |
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GB |
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Other References
Rodine, M. T. and R. G. Herb, "Effect of CC1.sub.4 Vapor on the
Dielectric Strength of Air" Physical Review, Vol. 51, Mar. 15, 1937
pages 508-511. .
Corbine, James Dillon, "Gaseous Conductors - Theory and Engineering
Applications" McGraw-Hill Book Co. Inc. New York 1941 pages 173-177
and 181-184..
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Primary Examiner: Martin; William D.
Assistant Examiner: Cabic; Edward J.
Claims
We claim:
1. In the process of electrostatically atomizing coloring liquids
having an electrical conductivity in the range of 10.sup..sup.- 5
Ohm.sup. 1 cm..sup..sup.- 1 to 10.sup..sup.-3 ohm.sup..sup.- 1
cm..sup..sup.- 1 by an electrostatic voltage, the improvement
according to which the coloring liquid having an electrical
conductivity in said range is atomized by the field of an
electrostatic charge by applying a negative or a positive charge
For atomization of the liquid in an atmosphere between electrodes
with the atmosphere within at least 5 cm. of the atomizing
electrodes being of a vapor or of a gas selected from the group
consisting of sulfur hexafluoride, dichlorodifluoromethane,
trichlorofluoromethane, chlorotrifluoromethane,
trichlorotrifluoroethane and dichlorotetrafluoroethane, in an
amount of 5 to 50 percent by volume, whereby the atomization is
effectuatable by either sign of the potential of the electrostatic
atomizing electrodes.
Description
The electrostatic atomization of liquids is already known in
connection with various lacquer spraying techniques. Among others
there are those in which lacquers are sprayed, without the use of
compressed air, simply by means of the atomizing effect of powerful
inhomogeneous electric fields, and are deposited on conductive
surfaces. In electrostatic lacquer spraying on a commercial scale,
one wishes to accomplish the atomization and deposition of large
quantities of lacquer economically. The ranges of sizes of the
droplets and the sign of their electric charge are of secondary
importance. It is noteworthy that not all combinations of pigments
and solvents can be sprayed electrically and certain conditions
have to be fulfilled in respect of the electrical properties of the
lacquer. These include primarily the range of electrical
conductivity which generally has an upper limit of 10.sup. .sup.-6
Ohm.sup..sup.-1 cm..sup. .sup.-1.
The electrostatic atomization of dye solutions and color pigment
dispersions for developing latent electrical images by the
electrophotographic process is described in German Pat.
Specifications Nos. 1,164,829, and 1,172,955. When electrically
charged dye aerosols are used for the development of images in this
way, the size of the droplets and nature of charge of the droplets
are of decisive importance. It is thus necessary to provide special
electrode arrangements, predetermined conductivity regions for
relatively high electrical conductivity of the liquids, and
predetermined electrical field distributions and field densities.
This process operates within a critical field of atomizability in
that the coloring liquid used in the negatively charged aerosols
must have a conductivity above 10.sup..sup.- 5 Ohm.sup..sup.-1
cm..sup. .sup.-1. Positive atomization also becomes difficult in
this conductive region because interfering corona discharges then
easily occur at the atomization electrodes, and may severely
inhibit or even prevent the atomization.
The object of this invention is to provide a means for atomizing
liquids which have electrical conductivity higher than 10.sup.
.sup.-5 Ohm.sup..sup.-1 cm..sup..sup.-1, by the use of both
negative and positive electrostatic charges. Another object of the
invention is the improvement of the operational safety of
electrostatic atomization apparatuses.
A process has now been found in which liquids having conductivities
of up to 10.sup..sup.-3 Ohm.sup. .sup.-1 cm..sup. .sup.-1 or more
and preferably conductivities between 10.sup.6 and 10.sup..sup.-3
Ohm.sup..sup.-1 cm..sup..sup.-1 , can be negatively or positively
atomized using simple electrodes at normal pressure, and which
moreover has high operational safety. The process according to the
invention is characterized in that the liquids are
electrostatically sprayed by atomizing electrodes which are
surrounded by an atmosphere of a gas which has a higher electric
breakdown voltage than air at an atmospheric pressure of 760 mm.
Hg. The breakdown voltage measured with plane electrodes at a
distance of 1 cm. should preferably be at least 35 kv./cm.
Reference is made to Handbook, Landolt-Bornstein, Vol. IV, part 3,
p. 107 stating the breakdown value at 760 torr, 20.degree. C. and
11g. H.sub.2 0 per cubic meter of air between plane electrodes at a
distance of 1 cm. is 31.0 kv./cm.
According to a preferred embodiment of the invention, the process
comprises supplying to the air surrounding the atomization
electrodes, gases or vapors which have a higher electric breakdown
potential than air. Such gases preferably contain halogen atoms in
their molecules, in particular chlorine or fluorine, and are
short-chained aliphatic compounds having preferably not more than
three C-atoms, in particular the so-called refrigerants which are
used as spray propellants namely CC1.sub.3 F, C.sub.2 C1.sub.2
F.sub.4, C.sub.2 C1.sub.3 F.sub.3, CC1.sub.2 F.sub.2, CC1F.sub.3 ,
etc. Low boiling inorganic halogen compounds are also especially
suitable in particular fluorine compounds such as SF.sub.6. An
example of a suitable vapor with high electric breakdown potential
is CC1.sub.4. The formation of a corona discharge at the
atomization electrodes is largely prevented in the presence of such
gases of vapor so that a powerful electric field which does not
vary with time can develop for use in the atomization of the
liquid.
The concentration of the additional gas or vapor in the atmospheric
air surrounding the atomization electrodes may vary within wide
limits. It is determined by the desired breakdown potential of the
gas atmosphere surrounding the atomization electrode. The required
breakdown potential may depend on the electrical properties of the
liquid which is to be atomized. The concentration of the gas added
further depends, within certain limits, on the degree of moisture
in the air of course, and on the breakdown potential of the gas or
vapor itself. Depending on the conditions, it is usually sufficient
to add quantities of about 5 to 50 percent in order to achieve the
breakdown potentials stated above. In general, the desired
conditions are achieved by concentrations of about 20 to 50
percent. There is no upper limit to the concentrations added since
the process can, of course, be carried out particularly well in an
atmosphere of the pure gas or vapor of high breakdown potential. On
the other hand the concentrations may be limited by economic
considerations. The average expert will find no difficulty in
determining the optimum proportion by volume of gas to add for any
particular atomization process.
In order to carry out the process according to the invention, it is
only necessary that the immediate surroundings of the atomization
electrode should have a breakdown potential within the range
indicated above. The atmosphere of high breakdown potential need
only be maintained up to a distance of not more than about 5 cm.
from the atomization electrode. This makes it relatively easy to
construct suitable apparatus for the process of the invention since
the usual additional apparatuses which are required for
electrostatic atomization, in particular electrostatic atomization
with the use of counterelectrodes or receiver electrodes for the
development of latent electrostatic images by means of dye aerosols
can be chosen just as freely as in the case of normal electrostatic
atomization in air.
This process can be applied to all electrostatic atomization but is
particularly advantageous in the case of atomization of dye liquids
for electrophotographic image development. By using suitable dye
solutions and dispersions of high conductivity, it is possible to
use both negative and positive development processes on the
photoconductive layers which normally consist of a mixture of zinc
oxide and binder. Since the size of the droplets from the
electrostatic dye aerosol decreases with increasing conductivity of
the liquid, it is possible to achieve by these means higher optical
resolution in the development of the image.
Compounds which have a low chlorine content and high fluorine
content, such as CC1.sub.2 F.sub.2, are particularly suitable for
use as aliphatic chlorine-fluorine compounds, owing to their low
toxity and general noninflammability. The use of sulfur
hexafluoride which is also nontoxic is particularly advantageous
owing to its particularly high breakdown potential.
A suitable atomization electrode for lacquering any metal articles
by means of electrostatic atomization is illustrated
diagrammatically in FIG. 1 of the accompanying drawings. The tube 1
constitutes the electrode and preferably has sharp edges at the top
and from which the liquid is atomized. This rim may be
funnel-shaped, for example, and arranged as a surface of revolution
about the longitudinal axis of the tube. The electrode tube 1 is
surrounded by a tube 2, made for example of plastic, through which
the additional high-breakdown gas is introduced. Outer tube 2 has
an open annular orifice 3, at the spraying end of the electrode,
through which the gas of higher breakdown voltage escapes and
circulates in the immediate vicinity of the electrode rim.
A preferred means of application of the process of the invention
for the development of electrostatic images is illustrated
diagrammatically in the FIG. 2 of the attached drawings. The
electrophotographic layer 4 which carries the electrical image is
attached by a support to a grounded metal plate 5. A wire sieve 7,
stretched in a metal frame 6 and connected to a source of voltage
is arranged in front of the photoconductive layer. The frame is
attached to a plastic casing 8 which contains the additional gas of
high electric breakdown potential. The desired concentration of
additional gas in the electrode chamber is controlled by the influx
rate of the gas entering the plastic casing through the aperture 9.
Excess gas can escape through the aperture 10. The atomization
electrode 11, which is fed from outside with colored developer
liquid in known manner enters the plastic casing through this
aperture. The nature of the electrode itself is not important and
can be of any known design.
Example 1
A metal article is coated electrostatically with a dye pigment from
a dispersion which has an electrical conductivity of a 5
.times.10.sup..sup.-5 Ohm.sup..sup.-1 cm..sup..sup.- 1. The metal
article is connected, for this purpose, to ground. Lacquering is
carried out by means of an atomization electrode of the type shown
in FIG. 1. In order to carry out the operation, the atomization
electrode 1 has a potential of -50 kv. (with respect to ground)
applied to it from a high-voltage source. Sulfur hexafluoride is
used as the additional gas and is introduced through the plastic
tube 2 which surrounds the electrode. Atomization is
extraordinarily uniform, and safe in operation even at high
voltages. This makes it possible to atomize relatively large
quantities of liquid per unit time.
Example 2
A photoconductive layer consisting of zinc oxide as the
photoconductive substance, and an insulating silicone resin (e.g. a
polyphenylmethyl resin) as binder is applied to a conductive
support. The photoconductive layer is negatively charged in the
usual manner and exposed through a negative original to form an
image. An electrostatic charge image is obtained. Development is
carried out by means of liquid aerosol using an apparatus of the
type shown in FIG. 2. A potential of -200 v. is applied to the wire
sieve 7. The atomization electrode 11 is connected to a
high-voltage source and receives a potential of -35 k.
Dichlorodifluoromethane is used as the additional gas and is
introduced through the aperture 6. The supply of this gas is
controlled in such a manner that its concentration is about 20 to
50 percent. The development liquid has the following composition:
30 percent concentrated Astra-new fuchsine
(Schultz-Farbstofftabellen, 7 th Edition No. 782) 70 percent benzyl
alcohol.
The conductivity of the dye carrying liquid is 3
.times.10.sup..sup.-4 Ohm.sup..sup.- 1 cm..sup..sup.-1. The
spraying time is about 10 seconds. A positive image of the negative
original is obtained.
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