U.S. patent number 3,608,638 [Application Number 04/887,613] was granted by the patent office on 1971-09-28 for heavy oil recovery method.
This patent grant is currently assigned to Gulf Research & Development Company. Invention is credited to Paul L. Terwilliger.
United States Patent |
3,608,638 |
Terwilliger |
September 28, 1971 |
**Please see images for:
( Certificate of Correction ) ** |
HEAVY OIL RECOVERY METHOD
Abstract
A hydrocarbon solvent such as benzene, platformate, or kerosene
at a temperature in the range of 300.degree. to 700.degree. F. is
injected into the top of tar sands at an injection well and forced
through the formation to an adjacent production well. Injection of
the solvent and production of oil are continued to maintain a
gaseous phase across the top of the formation. The tar sand oil is
made more mobile as a result of heating and dissolution of the
solvent into the oil whereby the oil drains into the production
well and is lifted to the surface.
Inventors: |
Terwilliger; Paul L. (Fox
Chapel Borough, PA) |
Assignee: |
Gulf Research & Development
Company (Pittsburgh, PA)
|
Family
ID: |
25391509 |
Appl.
No.: |
04/887,613 |
Filed: |
December 23, 1969 |
Current U.S.
Class: |
166/272.1 |
Current CPC
Class: |
E21B
43/24 (20130101) |
Current International
Class: |
E21B
43/24 (20060101); E21B 43/16 (20060101); E21b
043/24 () |
Field of
Search: |
;166/272,302,303 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Novosad; Stephen J.
Claims
I claim:
1. A method of producing heavy asphaltic oil from a tar sand
comprising injecting into the upper portion of the tar sand at an
injection well penetrating the tars and a hot fluid consisting
essentially of a hydrocarbon solvent selected from the group
consisting of at least one aromatic hydrocarbon selected from the
group consisting of benzene, toluene and xylene, mixtures
containing a high concentration of such aromatic hydrocarbons with
nonaromatic hydrocarbons of of substantially the same boiling
point, and kerosene; the temperature of the hot solvent injected
into the formation being in the range of 300.degree. to 700.degree.
F. such that the temperature exceeds the initial boiling point of
the solvent at the tar sand formation pressure to form a vapor zone
extending substantially horizontally across the tar sad near the
lower boundary thereof at a production well production well spaced
from the injection well; and continuing the injection of the hot
solvent to extend the vapor zone in the tar sand to the vicinity of
the production well and heat oil in the tar sand below the vapor
zone whereby said heated oil whereby said heated oil drains to the
production well.
Description
This invention relates to the production of oil and more
particularly relates to the production of heavy, highly viscous
oils from tar sands.
Enormous quantities of hydrocarbons exist in known deposits of
high-density, high-viscosity oil in essentially unconsolidated
formations referred to as tar sands. Examples of such formations
are the Athabasca and Peace River tar sands in Canada Oil in such
formations frequently includes substantial amounts of asphaltic
materials that are insoluble in petroleum-naphthas. The oil may be
highly viscous or even of a semisolid bituminous nature, or may
have a high pour point. Any one of the properties alone may
preclude recovery of oil from the tar sands by primary production
methods.
Although the permeability of some of the tar sands is sometimes
relatively high, because of the low mobility of the oil and the
shallow depth of many tar sands which preclude applying high
pressures to the tar sands without breaking through the overburden,
effective production procedures have not been developed. The
unconsolidated nature of the deposits prevents effective fracturing
and propping of a fracture to form flow channels of high flow
capacity and controlled location through the tar sand to production
wells.
In-situ combustion has been attempted as a method of producing the
tar sands, but has not been successful because the permeability of
the tar sands to flow is sharply reduced by the three phases of
gas, water, and oil ahead of the combustion front. Furthermore, the
oil ahead of the combustion front remains cold and immobile.
Attempts have been made to produce heavy oils from tar sand by by
creating a permeable channel through tar sands from an injection
well to a production well, and thereafter injecting air into the
channel. It was believed that oil from the formation would diffuse
into the channel burn and thereby heat the oil in the tar sands the
increase its mobility. Such procedures have not been successful
because the air injected largely bypasses the oil in the formation,
flows into the production well, and ignites oil in the production
well. As a result of all of these difficulties, some have gone to
an expensive mining and surface treating of the tar sands to
recover the hydrocarbons.
This invention resides in a process for producing low gravity,
highly viscous oils from tar sands in which a hot hydrocarbon
solvent such as benzene, platformate, and kerosene is injected into
the top of the tar sands at an injection well and forced through
the formation to an adjacent production well. The temperature of
the injected hydrocarbons is high enough to maintain a gaseous
phase to establish a permeable vapor-filled channel across the top
of the formation. Oil flowing into the production well is lifted
through the production at a rate maintaining a pressure not
substantially greater than atmospheric pressure in the production
well. As production continues, the upper portion of the tar sands
is left filled with hydrocarbon vapors, or liquid of low viscosity
formed by the condensation of hydrocarbon vapors, that can readily
be recovered by a subsequent production step.
The single FIGURE of the drawings is a diagrammatic vertical
sectional view through injection and production wells extending
downwardly through a tar sand.
Referring to the drawing, a tar sand 10 is shown penetrated by an
injection well indicated generally by reference numeral 12 and a
production well spaced from the injection well and indicated
generally by reference numeral 14. Both wells 12 and 14 are shown
extending through an overburden 16 across the top of the tar sand
10, through the tar sand, and into an underlying formation 18.
The tar sand 10 is an incompetent or partially consolidated
formation which can be parted by the injection of fluid at a high
rate but cannot be fractured in the sense of creating a
well-defined channel which can be propped open. This invention can
be used when the permeability of the tar sand is relatively high,
preferably exceeding 100 millidarcies, to permit flow at
significant rates through the formation at low pressure
differentials from the injection well to the production well. The
mobility of the oil in tar sand 10 is low enough to prevent
economically feasible production by primary production methods or
by simple fluid drive processes. This invention is particularly
advantageous in the recovery from tar sands of oil that includes
substantial quantities of asphaltic materials that are insoluble in
highly paraffinic hydrocarbons such as propane, butane or even
light naphthas or condensate. This invention is particularly
valuable when tar sand 10 is relatively shallow and cannot be
subjected to high pressures, and, therefore, the pressure available
for driving oil through the formation is limited.
Injection well 12 has casing 20 extending downwardly into the
underlying formation 18. Casing 20 is cemented in place by
conventional cementing procedures, after which perforations 22
through the casing and surrounding cement sheath are formed by any
suitable method such as by use of shaped charges in the interval of
the tar sand near its upper boundary. It is preferred that the
perforations 22 be in the upper eighth of the tar sand 10. Casing
20 is capped at 24 and a tubing 26 run into the casing through a
packer 28.
Production well 14 is spaced from the injection well 12 at a
desirable distance, depending on the characteristics of the tar
sand and the well pattern, to give suitable production rates. It is
preferred that well 14 be at a distance less than about 600 feet
from well 12 to give 5 to 10 acre spacing. Production well 14 has
casing 30 extending downwardly through tar sand 10 into the
underlying formation 18. Casing 30 is cemented in accordance with
the conventional cementing procedures. After perforations 32 are
formed in casing 30 and the surrounding cement sheath in the
interval of tar sand 10 near its lower boundary, tubing 34 is run
into well 14 and held in place at its lower end by a packer 36 set
in casing 30 above the perforations. Tubing 34 extends through a
cap 38 closing the upper end of the well 14. A pump 40 is anchored
in the lower end of the tubing 34 for lifting oil through the
production well.
In the method of this invention, a hot solvent is pumped down
through tubing 26 and injected through the perforations 22 into the
upper part of tar sand 10. The solvents should include hydrocarbons
of low enough boiling point to result in a vapor-filled zone
extending across the tar sands in the area that has been swept free
of reservoir oil. The gaseous solvent will condense and dissolve in
oil remaining in the vapor-filled zone and reduce its viscosity
beyond the reduction resulting from heating alone. Any liquid of
low viscosity that is capable of being vaporized at temperatures
that will not cause cracking of the solvent or the tar sand oil and
is miscible in the tar sand oil without precipitating constitutes
in the oil can be used as the solvent. Preferred solvents because
of their relatively low cost and good solvent properties are
aromatic hydrocarbons or mixtures of hydrocarbons containing
substantial amounts of aromatic hydrocarbons. Examples of such
hydrocarbons are benzene, toluene, xylene, and highly aromatic
mixtures of hydrocarbons having a boiling point range substantially
the same as gasoline. Kerosene can also be used. Highly paraffinic
hydrocarbons such as LPG, light naphthas or condensate are not
suitable because of their inability to dissolve asphaltic
constituents of the tar sand oil. Condensate composed principally
of paraffinic hydrocarbons has been found to cause precipitation of
asphalt from Athabasca or Peace River tar sands even though the
condensate was approximately 70 percent C.sub.6 + and contained
only about 7 percent C.sub.3 and C.sub.4.
The solvent is injected preferably in the vapor phase at a
temperature in the range of 300.degree. to 700.degree. F. It is
preferred that the temperature of the injected solvent be as high
as possible without causing substantial cracking of the solvent as
it passes down tubing 26 and into the tar sand 10. In any event,
the temperature of the solvent should exceed its initial boiling
point at the formation pressure in the tar sand. On entering the
tar sand 10, solvent will remain in the vapor phase in the upper
part of the tar sands where the reservoir has been flushed out.
Where the solvent vapor contacts reservoir oil, the solvent will
condense and dissolve in the oil in the tar sands. The raising of
the temperature of the oil in the tar sands and the dilution of the
oil by the hot solvent greatly increase the mobility of the oil in
the tar sand 10. Continued injection of the hot solvent results in
extension of a vapor-filled zone 42 across the top of the tar sand
from well 12 to well 14. The single phase in the zone greatly
increases the permeability of the formation to the injected solvent
and allows circulation from the injection well to the production
well at a low pressure differential.
During the injection of hot solvent at the injection well, oil is
pumped from the production well by pump 40. Injection and
production are continued after the solvent breaks through at the
production well to heat the tar sands adjacent the production well
and reduce the production well and reduce the pressure in the tar
sands adjacent the production well to less than the vapor pressure
of the solvent at the prevailing temperature. The maximum pressure
which can be maintained in the reservoir adjacent the production
well will, therefore, depend on the particular solvent used and the
temperature of the solvent. If benzene is the solvent used and the
temperature adjacent the production well is 400.degree. F., for
example the pressure at the production well may be as high as 200
p.s.i. Higher pressures can be maintained if the temperature is
increased. A low pressure, for example less than 100 p.s.i. and
even as low as atmospheric pressure can be attained, adjacent the
production well and is advantageous in increasing the volumes of
the hot vapors and thereby increasing their effectiveness in
driving oil from the formation.
Injection of hot solvent at well 12 and production of oil at well
14 is continued at a rate to extend a vapor phase zone 42 all of
the way across the tar sand from the injection well to the
production well. The vapors cone downwardly at the production well
toward the perforations 32 and thereby cause the lower boundary of
the vapor zone to slope downwardly. Oil adjacent well 14 drains by
gravity drainage into the well through perforations 32. Oil in the
tar sand 10 directly below zone 42 is heated and diluted by the hot
solvent. The resultant mixture has a high mobility and flows along
the lower boundary of zone 42, particularly along the downwardly
sloping boundary of the production well 14, and drains into
production well 14 through perforations 32. If part of the oil in
the tar sand is vaporized it flows into zone 42 and is swept by the
hot vaporized solvents to well 14. The downwardly flowing vapors
mix with the heated oil near the production well and further reduce
the viscosity of the oil flowing into the well.
The oil entering well 14 is lifted by pump 40 to the surface.
Continued injection of hot solvent through well 12 and production
of oil through well 14 cause zone 42 to be gradually enlarged
downwardly. When the lower boundary of zone 42 approaches the lower
boundary of the tar sand 10, or the viscosity of the remaining tar
sand oil has been reduce by heating or dilution with solvent, the
hot solvent injection is stopped. The solvent and low viscosity oil
remaining in the tar sand can be readily displaced through the tar
sand to the production well by a tertiary recovery process such as
water or insert gas flooding. Forward combustion can also be used
to displace the remaining oil.
It is essential to this invention that the hot solvent be injected
into the formation near its upper boundary. If hot solvent is
injected into a lower part of the tar sand, oil above the level of
injection made fluid by the hot solvent drains downwardly into the
vapor zone, condenses the hot solvent, and prevents the rapid
establishment of a well-to-well vapor zone.
This invention has been described for a production well having
perforations 32 near the lower boundary of the tars and 10 from the
beginning of the operation. Perforations could initially be made
near the upper boundary of the tar zone and then, as the zone 42 is
enlarged, new perforations made at successively lower positions, in
each instance below the lower boundary of the zone 42, and the
packer 36 successively resets just above the lowest perforations.
Oil made mobile or fluid by heat and dilution will still flow into
the production well by gravity drainage, but will not have as far
to drain.
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