U.S. patent number 3,608,044 [Application Number 04/816,136] was granted by the patent office on 1971-09-21 for process for melt spinning polyaxymethylene filaments having elastic recovery.
This patent grant is currently assigned to Celanese Corporation. Invention is credited to Myron J. Coplan, Howard I. Freeman, Joseph S. Panto.
United States Patent |
3,608,044 |
Coplan , et al. |
September 21, 1971 |
PROCESS FOR MELT SPINNING POLYAXYMETHYLENE FILAMENTS HAVING ELASTIC
RECOVERY
Abstract
A process for producing filamentary material of an oxymethylene
polymer having an elastic recovery at 70.degree. F. of at least
about 70 percent when subjected to a strain of up to 50
percent.
Inventors: |
Coplan; Myron J. (Dedham,
MA), Freeman; Howard I. (Sharon, MA), Panto; Joseph
S. (Dedham, MA) |
Assignee: |
Celanese Corporation (New York,
NY)
|
Family
ID: |
26735068 |
Appl.
No.: |
04/816,136 |
Filed: |
January 28, 1969 |
Related U.S. Patent Documents
|
|
|
|
|
|
|
Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
341725 |
Jan 31, 1964 |
|
|
|
|
Current U.S.
Class: |
264/210.7;
264/231; 264/289.6; 264/290.7; 264/346; 264/211.14; 264/235;
264/290.5 |
Current CPC
Class: |
D01F
6/66 (20130101) |
Current International
Class: |
D01F
6/58 (20060101); D01F 6/66 (20060101); D01d
005/12 (); D01f 003/10 () |
Field of
Search: |
;264/176,210,168,231,235,290,346 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
|
|
|
|
|
|
|
37-12,719 |
|
Sep 1962 |
|
JA |
|
38-2,021 |
|
Mar 1963 |
|
JA |
|
Primary Examiner: Frome; Julius
Assistant Examiner: Woo; Jay H.
Parent Case Text
This is a continuation-in-part of Ser. No. 341,725, filed Jan. 31,
1964, and now abandoned.
Claims
The embodiments of the invention in which an exclusive property or
privilege is claimed are defined as follows:
1. A process comprising the steps of melt spinning a random
oxymethylene copolymer comprising a copolymer of trioxane with from
about 0.5 to 25 mole percent of a cyclic ether having adjacent
carbon atoms at a temperature of from about 380.degree. F. to
420.degree. F. at a sheer rate of from about 250 to 2,500
reciprocal seconds, taking up the resulting filamentary material at
a drawdown ratio of from about 25:1 to 350:1, subjecting said
random oxymethylene polymer filamentary material to an
after-stretching operation at a temperature of from about
50.degree. F. to 250.degree. F. and a draw ratio of from about
1.2:1 to 2.3:1, enhancing the elastic recovery and tenacity and
rendering said filamentary material uniformly opaque by subjecting
said filamentary material to a second after-stretching operation
which comprises contacting said filamentary material with hot
H.sub.2 0 at a temperature of from about 190.degree. F. to
250.degree. F. for at least 1 minute at a draw ratio of from about
1.2:1 to 2.3:1 and forming said filamentary material, which has an
elastic recovery at 70.degree. F. of at least about 70 percent from
an extension up to 50 percent, into a yarn package.
2. The process of claim 1 comprising subjecting the random
oxymethylene copolymer filamentary material to a quench temperature
up to about 285.degree. F., a first after-stretching operation at a
draw ratio of from about 1.3 to 1.5 and a second after-stretching
operation at a draw ratio of from about 1.3 to 1.5.
3. The process of claim 1 comprising initially taking up the random
oxymethylene copolymer filamentary material at a drawdown ratio of
from about 25 to 350, continuously advancing said material at a
point beyond the point of initial takeup at a rate greater than
that of said takeup such that said fully solidified material is
drawn at a temperature of from about 50.degree. F. to 250.degree.
F. and a draw ratio of from about 1.2 to 2.3
4. The process of claim 1 comprising taking up the filamentary
material just subsequent to extrusion at an overall drawdown ratio
of from about 25 to 350, subjecting said material to frictional
contact with a solid surface at a point intermediate the points of
extrusion and takeup such that the tension exerted on said material
at the takeup point is not translated back to the point of
extrusion, subjecting said taken-up material to an after-stretching
operation at a temperature of from about 50.degree. F. to
250.degree. F. and a draw ratio of from about 1.2:1 to 2.3:1,
enhancing the elastic recovery and tenacity and rendering said
filamentary material uniformly opaque by subjecting said
filamentary material to a second after-stretching operation which
comprises contacting said filamentary material with hot H.sub.2 0
at a temperature of from about 190.degree. F. to 250.degree. F. for
at least 1 minute at a draw ratio of from about 1.2:1 to 2.3:1 and
forming said filamentary material, which has an elastic recovery at
70.degree. F. of at least about 75 percent from an extension of 50
percent, into a yarn package.
Description
This invention relates to the preparation of relatively elastic
filaments of an oxymethylene polymer.
It has been proposed to prepare filaments from oxymethylene
polymers, e.g., by melt spinning. Such filaments, especially those
prepared from oxymethylene copolymers such as the copolymers
described in U.S. Pat. No. 3,027,352 issued to Walling et al., have
many outstanding properties such as high strength, stiffness and
stability. We have now discovered an entirely new type of
oxymethylene polymer filamentary material which, unlike the
filaments of the prior art, possess a high degree of elasticity
after being subjected to a relatively large amount of stretch,
e.g., 50 percent or more at 70.degree. F. These new filaments are
particularly useful in the preparation of elastic yarns for stretch
garments, either alone or in a blend with a nonelastic material.
The new filamentary materials have been found to be superior to
known elastic fibers, such as spandex fibers, in such properties as
breaking tenacity and stiffness as indicated, for example, by
initial modulus.
In the past, of all high polymer solids, only elastomers have been
established as a class of the materials that exhibits high
"elasticity" (i.e., the ability to retract rapidly from a large
extension). On the molecular scale, the deformation of elastomers
is controlled by a network of cross-linked flexible polymer chains,
where the cross-linking results from either primary chemical bonds
or secondary bonding between the chains. Thermodynamically, the
deformation has its basis in an entropy effect involving the
distortion of polymer chains from their most probable
configurations in the unstretched state.
Within the class of crystalline or semicrystalline polymers, some
with a low degree of crystallinity (e.g., less than perhaps 15
percent) can manifest rubberlike elasticity, where the crystallites
act as the cross-links. However, polymers with an intermediate or
high degree of crystallinity usually undergo yielding and "necking"
at large extensions, and this tendency is more marked in unoriented
specimens. Some rearrangements of both crystallites and disordered
chains as well as disruption of the crystallites occur at large
strains. The resulting macroscopic deformation of the material is
largely irreversible due to permanent changes in the structure on
extension.
Elastic "hard" (nonelastomeric) polyoxymethylene fibers represent a
new class of elastic polymeric solids of high crystallinity which
are capable of undergoing large elastic deformations due to a
specific morphology present in the material. These materials are
prepared in the form of extruded fibers under specific conditions
of crystallization from the melt (i.e., crystallization under
stress).
The polymers that can be used for formation of such elastic
materials are oxymethylene polymers, preferably "random"
oxymethylene copolymers as hereinafter defined. After melt
spinning, the material is subjected to a hot-wet treatment to
improve tenacity and elastic recovery and render the material
uniformly opaque. The essential morphological feature of the
hot-wet-treated elastic materials as revealed by X-ray and light
scattering and electron microscopy is the presence of stacked
crystalline lamellae with their normals primarily aligned along the
fiber and film extrusion direction. The mechanism of elasticity is
based on a splaying-apart of these lamellae, involving their
reversible bending and torsional deformation during macroscopic
deformation of the material. Thus, in contrast to rubber
elasticity, where the kinetic units are flexible chain segments,
the kinetic units for the elasticity of an elastic "hard" material
are the lamellar crystals. Due to the orientation of the lamellae
along the fiber and film extrusion direction, the elasticity is
exhibited almost exclusively in that direction.
Although subsequent hot-wet treatment increases the elastic
recovery of elastic materials, the conditions of the initial
crystallization process are important with the respect to the route
by which a high degree of elastic recovery is achieved.
Inappropriate spinning conditions may lead to fibers which exhibit
not only a relatively low level of elastic recovery, but also
require comparatively more stringent hot-wet conditions to reach a
good degree of elastic recovery.
It is accordingly an object of this invention to prepare a new
elastic filamentary material.
It is a further object of this invention to provide an elastic,
random, oxymethylene copolymer filamentary material having
properties superior to those of known elastic materials.
It is a still further object to provide a process for the
production of the above-described elastic filamentary material.
Other objects will be apparent from the following detailed
description and claims.
FIGS. 1 to 3 show typical stress-strain curves for filamentary
materials of this invention as more fully described hereinafter at
up to 50 percent strain (curve A) as compared with the
stress-strain curve of one of the stiffest commercially available
spandex yarns (curve B).
In accordance with one aspect of the invention, there is provided
filamentary material of an oxymethylene polymer having an elastic
recovery at zero recovery time (hereinafter defined) at 70.degree.
F. of at least about 70 percent when subjected to a strain, for
example, of up to 50 percent, and preferably an elastic recovery at
zero recovery time of at least about 75 percent when subjected to a
strain of 35 to 50 percent. More specifically, the material has at
70.degree. F. an elastic recovery at zero recovery time of at least
about 70 percent, preferably at least about 75 percent when
subjected to a strain (or extension) of 50 percent. In particular,
filamentary materials having at 70.degree. F. an elastic recovery
at zero recovery time of at least about 80 percent or 90 percent
after being subjected to an extension of 50 percent are
contemplated under the invention.
In general, the elastic recovery after 2 minutes recovery time of
the above-described filamentary material is at least 10 percent
greater than the values of elastic recovery at zero recovery time.
Thus, filamentary materials are contemplated under the invention
which have an elastic recovery at 70.degree. F. after 2 minutes
recovery time (as hereinafter defined) of at least about 80 percent
when subjected to a strain of up to 50 percent and preferably an
elastic recovery at 70.degree. F. after 2 minutes recovery time of
at least about 85 percent when subjected to a strain of about 35 to
50 percent. More specifically, material is contemplated which has
an elastic recovery at 70.degree. F. after 2 minutes recovery time
of at least about 80 or 85 percent, e.g., about 85 to 98 percent,
when subjected to a strain of 50 percent. In particular,
filamentary material having at 70.degree. F. an elastic recovery
after 2 minutes recovery time of about 90 to 100 percent is
included within the invention.
The filamentary material of this invention also has comparatively
high elastic recoveries when stretched to extensions substantially
higher than 50 percent. Thus, material is contemplated having at
70.degree. F. an elastic recovery after 2 minutes recovery time of
at least about 70 percent, e.g., about 72 to 95 percent from a 100
percent strain, and at least about 60 percent, e.g., about 60 to 85
percent from a 150 percent strain.
The filamentary material maintains a substantial degree of its
elasticity at elevated temperatures. Thus, the filaments may, when
subjected to a strain of 50 percent, have elastic recoveries after
2 minutes recovery time of at least about 70 percent, e.g., about
75 to 97 percent, at a temperature of 130.degree. F.; at least
about 70 percent, e.g., about 72 to 96 percent at a temperature of
190.degree. F.; and at least about 60 percent, e.g., about 62 to 82
percent at 250.degree. F.
The values for elastic recovery given above are for the first cycle
of strain and recovery, using the procedure described hereinafter.
It has been found in addition that the elastic recovery of the
filamentary material between consecutive cycles changes little,
after the material has been subjected to several cycles of strain
and recovery. Thus, material is contemplated which, when subjected
to seven cycles of 50 percent strain and recovery, has an elastic
recovery at 70.degree. F. with zero recovery time which decreases
less than 1.5, and generally less than 1.0 percentage units between
the start of the sixth and the start of the seventh cycle.
While various values are given above for elastic recovery after
zero and 2 minutes recovery time, it should be understood that the
material of the invention is capable of recovering an additional
amount, i.e., may have a still higher elastic recovery, when the
recovery time is substantially greater than 2 minutes.
In addition to these elastic properties the filaments generally
have, e.g., at 70.degree. F., a breaking tenacity of at least about
1.0, preferably at least about 1.3, e.g., about 1.3 to 2.5
grams/denier, a breaking elongation of at least about 55 percent,
preferably at least about 75 percent, e.g., about 75 to 200
percent, and an initial modulus of at least about 2 grams/denier,
preferably about 5 to 30 grams/denier. Thus the filaments produced
under this invention have other good mechanical properties as well
as elasticity, e.g., stiffness and strength.
The tensile properties of the preferred polyoxymethylene copolymer
fibers essentially remain constant on going from room temperature
to -190.degree. C., including the absence of necking behavior. On
the other hand, the corresponding nonelastic fibers become brittle
at the low temperature, reflecting the glassy state of the polymer.
The observed superiority of the elastic fibers over the spandex
fibers at the low temperature is unexpected.
Thus the tensile properties, including elastic recovery, of elastic
"hard" fibers of a polyoxymethylene random copolymer undergo a
small change over the temperature range -190.degree. C. to
23.degree. C., compared with "nonelastic" polyoxymethylene and
spandex fibers. The tensile properties of the elastic "hard"
materials are relatively free from the embrittling effects of low
temperatures, which is commonly observed at temperatures below the
glass transition of amorphous and semicrystalline polymers. In
particular, a relatively high value of break elongation of the
elastic materials at very low temperatures is remarkable. These
observations indicate that tensile deformation of the elastic
materials is accommodated largely by a reversible deformation of
lamellar crystals.
In addition to the above mechanical properties, the filamentary
material of the invention generally has a birefringence of at least
about 0.03, e.g., from about 0.04 to 0.08, and most often from
about 0.05 to 0.07.
A "random" oxymethylene copolymer, as the term is used above,
contains recurring oxymethylene, i.e., --CH.sub.2 O--, units
interspersed with --OR-- groups in the main polymer chain where R
is a divalent radical containing at least two carbon atoms directly
linked to each other and positioned in the chain between the two
valences, with very substituents on said R radical being inert,
that is, those which do not include interfering functional groups
and which will not induce undesirable reactions, and wherein a
major amount of the --OR-- units exist as single units attached to
oxymethylene groups on each side. A random copolymer may thus be
distinguished over a block copolymer wherein repeating units of
each monomer make up block segments containing little or no units
of any other monomer. Thus, in block copolymers containing
oxymethylene and other units, substantially all of the other units
are attached to like units rather than oxymethylene units on each
side. Particularly preferred are random copolymers which contain
from 60 to 99.6 mol percent of recurring oxymethylene groups. In a
preferred embodiment R may be, for example, an alkylene or
substituted alkylene group containing at least two carbon atoms.
Examples of preferred polymers include copolymers of trioxane and
cyclic ethers containing at least two adjacent carbon atoms such as
the copolymers disclosed in U.S. Pat. No. 3,027,352 of Walling et
al.
The preferred random oxymethylene copolymers which are treated in
accordance with this invention are thermoplastic materials having a
melting point of at least 150.degree. C. and are normally millable
at a temperature of 200.degree. C. They have a number average
molecular weight of at least 10,000. These preferred polymers have
a high thermal stability. For example, if the stabilized
oxymethylene polymer used in a preferred embodiment of this
invention is placed in an open vessel in a circulating-air oven at
a temperature of 230.degree. C. and its weight loss is measured
without removal of the sample from the oven, it will have a thermal
degradation rate of less than 1.0 wt. percent/min. for the first 45
minutes and, in preferred instances, less than 0.1 wt. percent/min.
for the same period of time.
The preferred random oxymethylene copolymers which are treated in
this invention have an inherent viscosity of at least one (measured
at 60.degree. C. in a 0.1 weight percent solution in p-chlorophenol
containing 2 weight percent of .alpha.-pinene). The preferred
copolymers of this invention exhibit remarkable alkaline stability.
For example, if the preferred copolymers are refluxed at a
temperature of about 142.degree. -145.degree. C. in a 50 percent
solution of sodium hydroxide in water for a period of 45 minutes,
the weight of the copolymer will be reduced by less than 1
percent.
As used in the specification and claims of this application, the
term "copolymer" means polymers having two or more types of
monomeric units, including terpolymers and higher polymers.
Suitable oxymethylene terpolymers are those having more than two
different kinds of monomeric units such as those disclosed in U.S.
Pat. application Ser. No. 229,715, filed Oct. 10, 1962 by Walter E.
Heinz and Francis B. McAndrew, which application is assigned to the
same assignee as the subject application.
In accordance with another aspect of the invention, the filamentary
material of this invention is formed by melt spinning a
fiber-forming oxymethylene polymer, i.e., extruding the polymer in
the form of a melt through the orifices of a spinneret at a shear
rate of about 250 to 2,500 reciprocal seconds to form filaments
which are taken up at a "drawndown" or "spin draw" ratio of at
least about 25, e.g., up to about 350, preferably about 90 to 235
when the quench temperature is 70.degree. F. The product as spun
may have elastic properties as described above, and may be formed
into a yarn package, or may be subjected to further treatment as
described hereinafter before packaging. In any case, the yarn which
is packaged for ultimate use will have the elastic properties
described above.
The "shear rate" of extrusion is defined by the expression
4q/.pi.r.sup.3, where q is the volume rate of extrusion of the
molten polymer through each orifice in cc./sec., and r is the
radius of the orifice in centimeters. The shear rate is an
indication of the shearing force exerted between the molten polymer
of the orifice wall as the polymer is being extruded.
The "spin draw" or "drawndown" ratio is the ratio of the velocity
of initial yarn takeup to the linear velocity of extrusion of the
molten polymer.
In one embodiment of this process, the polymer is melt spun by
extrusion through orifices having a diameter for example in the
range of about 5 to 25, preferably about 10 to 20 mils, at a linear
speed, for example of up to about 15, preferably about 6 to 12
feet/min. at a shear rate within the range set out above, to form
filaments which are taken up initially at a speed, for example, in
the range of about 150 to 1,500, preferably about 450 to 1,050 feet
per minute, at a drawdown ratio within the ranges set out above.
The "quench" temperature, i.e., the temperature of air or other
inert gas such as stream, nitrogen or argon, at the outlet side of
the spinneret, is suitably up to about 285.degree. F. A stack or
column must be employed downstream of the spinneret if the desired
quench temperature is substantially above or below the ambient
temperature of air, and may also be useful for better control when
air at ambient temperature is used as the quench. However, in the
latter case, the polymer may also be extruded directly into
air.
In accordance with another aspect of the invention, the as-spun
filaments are afterdrawn or stretched at a temperature up to about
250.degree. F., e.g., 50.degree. to 250.degree. F., at a draw ratio
within the range of about 1.2 to 2.3, preferably about 1.3 to 1.5.
The stretching may be carried out by first taking up the yarn on
godet rolls from which it is wound on a package and stretching in a
separate operation, or in a combined operation, wherein the yarn is
initially taken up by one set of godet rolls from which it travels
to a second set of godet rolls traveling at a speed faster than the
first set so that the cold-drawing step is accomplished between the
two sets of rolls.
In another embodiment of the process, the freshly spun filaments
are passed around a frictional device in the spinning cabinet,
e.g., a snubbing pin or pigtail guide which prevents all the
tension exerted on the filaments downstream of the frictional
device from being translated back to the face of the spinneret, and
the filaments downstream of the frictional device are cold-drawn,
e.g., by taking up the filaments on godet rolls at a speed greater
than that at which they pass around the frictional device. The
overall draw ratio between spinneret face and takeup rolls may be
for example within the ranges given for drawdown ratio.
While the yarn so produced possesses a considerable degree of
elasticity, it is preferable to subject such yarn to a second
afterdrawing step in amount sufficient to render the fibers
uniformly opaque, e.g., at a draw ratio within the ranges given
above for the afterdrawing step. As is the case when no frictional
device is used, the subsequent afterdrawing step may be carried out
in a separate operation wherein the yarn from the freshly spun yarn
is taken up on godet rolls from which it is wound on a package and
is subsequently drawn by conventional means, or as part of a
combined operation wherein the yarn from the first takeup godet
rolls travels directly to a second set of rolls rotating at a speed
greater than that of the first set, with the afterdrawing taking
place between the rolls.
The initial spinning operation is carried out in a unit which melts
the solid polymer and pumps it at a constant rate and under fairly
high pressure through the small holes of a spinneret. It is
generally desirable to melt spin a polymer having incorporated
therein one or more thermal stabilizers. Suitable combinations of
stabilizers are shown, for example, in French Pat. No.
1,273,219.
Melt spinning temperatures, i.e., of the molten polymer being
extruded from the orifices of a spinneret, may range from about
380.degree. to 420.degree. F. for the preferred random oxymethylene
copolymers.
The polymer is generally melted by subjecting chips of the polymer
to the action of a heated screw extruder. The chips are suitably
between about 200 and 2 mesh. The melt is forced through the
spinneret orifices by a metering pump. Generally, a filter or sand
pack is maintained upstream of the orifices to remove particles or
gels which might block them. Preferably, the polymer is maintained
as a melt for not more than 20 minutes.
The spinneret may contain, for example, from one to about 500
orifices. Elastic monofilaments, for special uses such as tow rope,
may be extruded through orifices up to 100 mils in diameter. The
liquid streams emerge from the orifices, generally downwardly, into
a gaseous medium, which may be air or an inert gas and
solidify.
Filamentary material having the indicated physical properties and
also a denier/filament of up to about 20 and even as low as about 1
is contemplated within the invention.
The following examples further illustrate the invention. All
properties were measured at 70.degree. F. unless otherwise
stated.
EXAMPLE I
A copolymer of trioxane and 2 weight percent based on the
polymerizable mixture of ethylene oxide was prepared as described
in U.S. Pat. No. 3,027,352 and aftertreated to remove unstable
groups as described in application Ser. No. 102,096, filed Apr. 11,
1961. The copolymer was then further stabilized by blending with
0.5 weight percent of 2,2'-methylene bis (4-methyl 6-tertiary butyl
phenol) and 0.1 weight percent of cyanoguanidine based on the
weight of the polymer.
The above-described polymeric composition was melt spun at
400.degree. F. by means of a gear pump, downward through a 22-hole
spinneret having hole diameters of 15 mils and 15 mils in length at
a shear rate of about 1,140 reciprocal seconds. The resulting 22
filament yarn was taken up by godet rolls at a speed of 1,000 feet
per minute after passing directly through a pigtail guide located
in a column 10 feet long containing air at about
80.degree.-90.degree. F. A total of 8.17 cc./minute of polymer was
extruded through the spinneret, corresponding to a linear speed of
10.68 feet per minute. The drawdown ratio was thus 1,000 divided by
10.68 or 93.6.
The yarn obtained by this process was uniformly lustrous but turned
opaque on stretching to yield.
The as-spun yarn was lubricated with 50 percent aqueous
polyalkylene glycol-based "Ucon H-6N" textile finish and was
afterstretched in air at room temperature 70.degree. F., using a
draw ratio of 2.3 to 1.
The properties of yarn obtained, as spun and afterstretched at room
temperature, are shown in table 1.
---------------------------------------------------------------------------
TABLE
1 As Spun Afterstretched
__________________________________________________________________________
Denier 293 188 Initial modulus, grams/denier 18.7 5.1 Tenacity,
grams/denier 1.17 1.46 Breaking Elongation, % 200 114 Elastic
Recovery from 50% Extension at Zero Recovery Time, % 81.2 77.6
Birefringence, .DELTA.n 0.0581 0.0380
__________________________________________________________________________
EXAMPLE II
The procedure of example I was carried out except that the
extrusion temperature was 415.degree. F., the spinneret contained
34 holes each, 12 mils in diameter and 18 mils in length, the gear
pump was operated so as to obtain an extrusion rate of 4.90
cc./min. corresponding to a linear extrusion speed of 6.48
feet/min., at a shear rate of about 860, the yarn passed over a
kiss-roll where it was lubricated with 25 percent aqueous fatty
ester-based "Nopocostat 2152-P" textile finish, and was then passed
through a pigtail guide with one wrap taken around the guide stem.
The yarn was then taken up by godet rolls at a speed of 500
feet/min. with an overall drawdown ratio of 77.
The resulting yarn had alternating patches of opaque and lustrous
zones with the opaque zones exhibiting a relatively high degree of
recoverable stretch.
The patchy yarn was drawn at room temperature (70.degree. F.) at a
draw ratio of 2 to 1. The resulting yarn was completely opaque, had
a total denier of 250, a breaking tenacity of 1.2 grams/denier, a
breaking elongation of 160 percent, and an elastic recovery from 50
percent extension at zero recovery time of about 80 percent.
The elastic properties of the as-spun or after-stretched
filamentary material of this invention may be improved by a heat
treatment. Preferably the treatment is a hot-wet treatment, e.g.,
contact with hot water or wet steam at a temperature of at least
190.degree. F., e.g. up to about 285.degree. F. for a period of at
least 1 minute.
The following examples illustrate the effect of a hot-wet treatment
of the product.
EXAMPLE III-VI
The procedure of example II was carried out except that no textile
finish was applied, the yarn was passed directly through the
pigtail guide rather than being wrapped around the guide stem and
yarn was taken up at different speeds, 250, 500, 750 and 1,000
feet/minute (examples III to VI respectively) corresponding to
drawdown ratios of 38.6, 77.2, 115.8 and 154.3 respectively. The
yarn was not subsequently drawn. Various mechanical properties,
other than elastic recovery, of three of the yarns obtained, all of
which are lustrous, are given in table 2.
---------------------------------------------------------------------------
TABLE
2 Ex.V Ex.III Ex.VI 250 750 1000 ft./min. ft./min. ft./min.
__________________________________________________________________________
Denier 726 219 157 Initial modulus,grams/denier 20.9 17.5 23.2
Tenacity, grams/denier 0.8 1.39 1.74 Breaking Elongation, % 372 195
146 Birefringence, .DELTA.n 0.0532 0.0617 0.0626
__________________________________________________________________________
Some values of elastic recovery after 2 minutes recovery time of
the four samples of yarn as spun and after a hot-wet treatment or
"boiloff" i.e., immersion in water under about 15 p.s.i.g. pressure
at a temperature of about 250.degree. F. for 30 minutes, were
determined after extensions of 50 percent, 100 percent, 150
percent, 200 percent and 250 percent at temperatures of 70.degree.
F., 130.degree. F., 190.degree. F. and 250.degree. F. The results
are given in table 3. ##SPC1##
The data in tables 2 and 3 show that filaments may be obtained in
accordance with this invention which have very desirable elastic
properties, even at elevated temperatures while at the same time
having adequate mechanical properties such as breaking tenacity,
breaking elongation and initial modulus, and that the elastic
properties of the yarn as spun, using a relatively high drawdown
ratio, are significantly improved by heat treating the yarn, e.g.,
by contacting it for a short period with hot water.
EXAMPLE VII
The procedure of example I was followed except that the amount of
molten polymer extruded through the spinneret was 4.73 cc./min. at
a shear rate of about 660 reciprocal seconds, and the resulting
yarn was taken up a speed of 1,250 feet/min. resulting in a
drawdown ratio of 201. Samples of the yarn were afterstretched at
70.degree. F. in air at draw ratios of 1.2, 1.3, 1.4 and 1.5, and
at 170.degree. F. while in contact with a water-wet cloth covering
a hot metal plate, at draw ratios of 1.2 and 1.4. The physical
properties of the yarns obtained are shown in table 4. ##SPC2##
FIGS. 1, 2 and 3 show stress-strain curves (curve A) obtained up to
50 percent extension, for the yarns of this example as spun (FIG.
1), afterstretched at 70.degree. F. using a draw ratio of 1.5 (FIG.
2), and afterstretched wet at 170.degree. F. using a draw ratio of
1.4 (FIG. 3). In each case, curve B represents a similar
stress-strain curve obtained for the stiffest commercial spandex.
It can be seen that the yarn included within the invention is in
each case considerably stiffer than the spandex, regardless of the
aftertreatment. However, the aftertreatment, e.g., afterstretching
whether dry or wet and using any of various draw ratios, results in
yarns having different stress-strain characteristics which may be
utilized in various applications. Thus, the slope of the
stress-strain curve of the as spun yarn tapers off rather sharply
after a certain stress has been applied (see FIG. 1), whereas this
effect is considerably modified by a dry after-stretching treatment
(see FIG. 2). Moreover, a hot-wet after-stretching treatment
results in a considerable change in the shape of the stress-strain
curve, which, after this type of treatment has two points of
inflection (see FIG. 3).
The heat treatment, e.g., hot wet treatment described above may be
used to improve properties such as elastic recovery of dry
afterstretched as well as the as spun yarn. Thus, when the yarn of
this example which was dry afterstretched at 70.degree. F. using a
draw ratio of 1.5, was subsequently immersed in hot water at
250.degree. F. and 15 p.s.i.g. for a period of 30 minutes, it had
the following properties: denier--126; initial modulus--29
grams/denier; tenacity--1.7 grams/denier; breaking elongation--94
percent; elastic recovery at zero recovery time after 50 percent
extension--92 percent. It can be seen therefore that a hot-wet
treatment of after-stretched yarn resulted in a substantial
increase in initial modulus and elastic recovery.
When the hot-wet-treated yarn described in the previous paragraph
was subjected to seven cycles of 50 percent extension at 70.degree.
F., the elastic recovery of the yarn at the end of the sixth cycle
was 82 percent.
EXAMPLE VIII
The procedure of example I was followed except that the amount of
polymer extruded was 3.26 cc./min. at a shear rate of about 450
reciprocal seconds, the temperature of polymer being extruded was
405.degree. F. and the yarn was taken up at a speed of 1,000
meters/min. and a drawdown ratio of 234. Samples of the yarn were
afterstretched in air at 70.degree. F. using various draw ratios.
Properties of the resulting yarn samples are given in table 5. In
determining the elastic recovery of the yarn, each sample was
subjected to seven cycles of 50 percent extension at 70.degree. F.
and the elastic recovery at zero recovery time was measured at the
end of the first cycle and the end of the sixth cycle. ##SPC3##
The yarn sample of this example which was afterstretched at a draw
ratio of 1.5 as described above, was subsequently subjected to a
hot-wet treatment by immersing it in water at 250.degree. F. and 15
p.s.i.g. for 30 minutes. The resulting yarn had a denier of 96, an
initial modulus of 20 grams/denier, a tenacity of 1.6 grams/denier,
a breaking elongation of 53 percent, an elastic recovery after the
first cycle as described above, of 91 percent and an elastic
recovery after the sixth cycle of 50 percent extension as described
above, of 82 percent.
EXAMPLES IX and X
The procedure of example VIII was followed except that the
spinneret contained 13 holes, each of which was 12 mils in diameter
by 18 mils in length resulting in a shear rate of 1,600 reciprocal
seconds, and the resulting yarn was taken up at a speed of 1,000
feet/minute with a drawdown ratio of about 90 (example IX) or at a
speed of 1,250 feet/min. with a drawdown ratio of 110. Properties
of the resulting as spun yarns are shown in table 6.
TABLE
6 Property Example IX Example X
__________________________________________________________________________
Denier 93 75 Initial Modulus, grams/denier 19.4 26.7 Tenacity,
grams/denier 1.06 1.36 Breaking Elongation, % 105 110 Elastic
Recovery from 50% Extension at Zero Recovery Time, % 78
75.2Birefringence, .DELTA.n 0.070117
__________________________________________________________________________
The following examples illustrate the use of quench temperatures,
i.e. temperatures of circulating air in the spinning column
downstream of the spinneret, of other than room temperature.
EXAMPLES XI and XII
The procedure of example VIII was followed except that different
conditions of quench temperature, takeup speed and drawdown ratio
were used. These variations in the conditions of the process as
well as the properties of the resulting as spun yarns are shown in
table 7.
---------------------------------------------------------------------------
TABLE 7Condition or
Property Example XI Example XII
__________________________________________________________________________
Quench Temperature, .degree.F 221 280 Takeup Speed, feet/min. 750
1500 Drawndown Ratio 172 343 Denier 209 76 Initial Modulus,
grams/denier 22.8 17.5 Tenacity, grams/denier 1.12 1.03 Breaking
Elongation, % 203 174 Elastic Recovery from 50% Extension at Two
Minutes Recovery Time, % 91.2 88.4 Birefringence, .DELTA.h 0.0644
0.0588
__________________________________________________________________________
The data in the above table illustrates that as spun yarn having
relatively high elastic recovery may be produced using an elevated
quench temperature.
The values of tenacity, breaking elongation, modulus, stress and
strain given above were determined in a conventional manner with
the use of an Instron Tensile Tester operating at a strain rate of
100 percent/minute. The "initial" modulus as the term is used above
was determined by measuring the slope of the stress-strain curve at
the point indicated by 1 percent strain.
The values of elastic recovery given above were also determined
with the Instron at a strain rate of 100 percent/minute. After the
yarn was extended to the desired strain value, the jaws of the
Instron were reversed at the same speed until the distance between
them was the same as at the start of the test, i.e. the original
gauge length. The jaws were again reversed, i.e., immediately for
values of elastic recovery at zero recovery time, or after 2
minutes for values obtained at 2 minutes recovery time, and were
stopped as soon as the stress began to increase from the zero
point. The elastic recovery is then calculated as follows:
Measurements with the Instron at room temperature were carried out
in air at 65 percent relative humidity. Determinations at elevated
temperatures were determined in air at 70.degree. F. and 65 percent
relative humidity which was heated to the desired temperature.
Values of birefringence were determined with a polarizing
microscope equipped with a Berek compensation, in accordance with
procedures well known in the fiber arts. The value of birefringence
is a measure of the degree of molecular anisotropy of the filament
which in turn is indicative of the degree of molecular orientation
produced as a result of spinning and drawing procedures.
Although the product and process of this invention have their most
desirable embodiments in conjunction with random oxymethylene
copolymers as pointed out above, oxymethylene homopolymers are also
contemplated, e.g. as prepared by the polymerization of anhydrous
formaldehyde or by the polymerization of trioxane which is a cyclic
trimer of formaldehyde. High molecular weight oxymethylene
homopolymers as well as random copolymers may be prepared in high
yields and at rapid reaction rates by the use of acidic boron
fluoride-catalysts such as boron fluoride itself, and boron
fluoride coordinate complexes with organic compounds, as described
in U.S. Pats. Nos. 2,989,585; 2,989,506; 2,989,507; and 2.989,509
of Hudgin and Berardinelli, 2,989,510 of Bruni; and 2,989,511 of
Schnizer, as well as in the above-cited U.S. Pat. No. 3.027,352 of
Walling et al.
In addition to the methods disclosed in the above-cited patents,
other methods may be used to prepare oxymethylene copolymers and
homopolymers contemplated under this invention, including those
taught by Kern et al. in Angewandt Chemie 73 (6), pages 177 to 186
(Mar. 21, 1961), e.g. homopolymers in which the end groups have
been reacted with an alkanoic acid such as acetic acid or an ether
such as dimethyl ether. These reactants cause stable ester or ether
end groups, e.g., acetyl or methoxy groups, to form at the ends of
the polymer molecules.
The elastic filamentary materials of this invention are useful in a
wide variety of applications. Because of the importance of these
applications, they will be described in some detail below, under
separate headings.
REPLACEMENT FOR WRAPPED-CORE ELASTIC YARNS
In many applications, rubber or so-called spandex fibers are
employed as the core in a wrapped-core yarn construction, the
wrapping being comprised generally of staple or filament yarns made
of conventional high modulus low-stretch fibers such as cotton,
rayon, nylon, etc. The process of wrapping is costly and frequently
difficult to control. The properties of the wrapped yarn are
somewhat unpredictable and often represent only a compromise
between what is desired and what can be achieved by the combination
of two or more yarns assembled and held together under radically
different levels of strain.
For example, a typical double-wrapped spandex core, cotton wrapped
yarn may be produced with the core prestretched 300-400 percent
when the wrapping is twisted around it. In the "at rest" state, the
core retracts to some strain lower than that at which it was
wrapped, thereby causing the wrapper yarns to be compressed into a
jammed helix configuration.
Subsequent stretching of such a yarn, then, represents the combined
effect of reextending the core from some already partially
stretched state and the opening of the jammed helix configuration
of the wrapper. The stretch modulus of such a complex combination
of material properties and geometric structure is easily disturbed
by a number of transient variables in original manufacture and
subsequent processing as well as during use of such yarns and
fabrics made therefrom. Moreover, the ultimate stretch of such
yarns cannot be varied independently of the stretch modulus.
The core wrapper structure attempts to combine the virtues of high
elastic recovery from high strain of the core with the relative
rigidity of the wrapper. The principal object of such a combination
is to achieve relatively high "power" of recovery from fairly high
extensions.
The elastic yarns of this invention are very suitable for the
replacement of such wrapped-core yarns for many applications. With
a relatively high modulus obtained with the yarn of this invention,
e.g., in the range of 2-15 grams/den., compared to spandex yarns
with a modulus in the order of 0.2-0.5 grams/den., the yarn of the
invention need not be prestrained and wrapped in order to exhibit
high stretch "power." Used alone (i.e. without a wrapper) the yarn
of the invention can provide substantial reduction in weight and
bulk at the same level of stretch "power," extensibility, and
recovery. Thus, many fabrics may be markedly reduced in weight and
bulk, made more sheer, by their use. On the other hand, at the same
weight of yarn, density of weave, etc., fabrics produced from the
yarn of the invention exhibit substantially more "power" than
wrapped-core fabrics.
Used as a single-component yarn, therefore, the yarn of this
invention may be substituted directly for wrapped-core yarns at
considerable saving in cost and improvement in performance. A
typical useful construction is a 3-ply yarn having a total denier
of 750 comprised of 75 filaments. Each single yarn is twisted up to
15 t.p.i. and the ply construction back twisted to yield a balanced
yarn. One familiar with the art will recognize many variations of
yarn denier, twist, ply construction, and denier per filament
suitable for individual applications.
REPLACEMENT FOR BARE SPANDEX OR FINE-DENIER STRETCH YARNS
Fine-denier continuous filament yarns (30 up to 100 denier, for
example) comprised of a thermosettable polymer (especially nylon)
have found considerable application in lingerie and "intimate"
garments. While those yarns have customarily been knitted
(generally tricot) or woven for such fabrics as standard yarns,
increasing interest is displayed in the use of stretch yarns made
therefrom.
Stretch yarns of such thermosettable materials are produced by a
number of techniques such as stuffer-box crimping,
twist-set-untwist, edge-crimping, etc. The stretch characteristic
is imparted by building geometric distortability into the
individual filaments of said yarns.
An alternative approach to the use of stretch nylon yarns has been
dependent on the application of bare or lightly wrapped spandex
yarns. Here the stretch and conformability, of course, depends upon
the material extensibility of the fiber. Knitted or woven fabrics
from such yarns, however, are generally rather limp and suffer from
the relatively low degree of thermal stability of the typical
spandex materials and their sensitivity to discoloration and fading
in storage and use.
The desirable virtues of either the geometrically stretchy nylon
stretch yarns, or the bare or lightly wrapped spandex yarns for
lingerie where stretch and conformability are desired, may be
achieved by the use of light-denier yarns of this invention. A
typical application of such yarns is 70- or 100 -denier stretch
tricot fabric for ladies' slips.
VARIABLE POROSITY PARACHUTE CANOPY FABRIC
Multifilament yarns of this invention which exhibit high elastic
recovery from loads approaching 90 percent of ultimate rupture are
eminently suitable for the fabrication of variable porosity
fabrics. A fabric of this type possessing approximately the
following properties may be made from the yarn of this
invention:
Weight 1-2 ounces per square yard
Permeability of 50-90 cubic feet per minute per square foot at 0.5
inches of water pressure differential
Ultimate tensile strength of 20 pounds per inch of fabric width in
both warp and filling directions
An exceptionally large permeability at a pressure differential that
imposes a fabric tensile load of 15 pounds per inch of fabric
width.
A typical fabric construction having these properties is as
follows:
---------------------------------------------------------------------------
Fabric Specifications
__________________________________________________________________________
Weight 2 ounces per square yd. Ends per inch 130 End denier 60
Picks per inch 130 Pick Denier 60 No. of fils per yarn 21 % Crimp
filling 6 Strip tensile warp 20 lbs./inch of width Strip tensile
filling 20 lbs./inch of width Ultimate Elongation Warp 75 %
Ultimate Elongation Filling 75%
__________________________________________________________________________
Yarn Properties
__________________________________________________________________________
Yarn Denier 130 No. of filaments 21 T.P.I. 0.5 Ultimate Stress
1.5-2.0 Ultimate Elongation 75% Stress at 20% 1.0 g.p.d. Elastic
Recovery at 20% Strain 99% Elastic Recovery at 50% Strain 85-90%
__________________________________________________________________________
Fabric Performance
__________________________________________________________________________
Porosity at low strains: 50-90 cubic feet per minute per square
foot at 0.5 inches of water pressure differential Porosity at a
stress of 5 pounds per inch of fabric width: 1000 cubic feet per
minute per square foot at 4.0 inches of water.
__________________________________________________________________________
WOVEN FOUNDATION GARMENTS, ELASTIC BANDAGES, AND LIKE PRODUCTS
Candidate fabrics for woven foundation garments, elastic bandages
and similar products comprise anywhere from 5 to 90 percent elastic
fiber content in fabric weights from 2 to 15 ounces per square
yard. Highly recoverable stretch with presently available materials
is possible from strain levels of 20 to 40 percent.
By employing the filamentary material of this invention, it is
possible to obtain durable elastic recovery from higher strain
levels than presently available with spandex and rubber materials
and greater range of available power at given strain levels.
A typical woven batiste foundation fabric is as follows:
---------------------------------------------------------------------------
Fabric Weight 4 ounces per sq. yd. Warp-- Acetate 140 denier Ends
per inch 65 Filling-- yarn of this invention 200 denier Picks per
inch 60 Elastic recovery at 60% strain 95% Stretch level 50%
Rupture tenacity warp 45 lbs. per inch of width Rupture tenacity
filling 40 lbs. per inch of width Modulus in pounds at 40% strain
10 lbs. per inch of width
__________________________________________________________________________
Other stretch fabrics also rely upon the incorporation of
bulked/stretch yarns or spandex-type yarns in combination with
other less extensible yarns. The elastically recoverable yarns in
some of these fabrics comprises, for example, from 5 to 65 percent
of the fabric which performs elastically up to strain levels of 100
percent in the elastic direction.
A typical ski pant fabric utilizing the material of this invention
contains 150 ends per inch of 70 -denier, 21-filament yarn of this
invention and 42 picks per inch of 700-denier, 2-fold worsted yarn,
and has a plain weave stretched. This abrupt large change in
modulus is often undesirable, and can be avoided by using the
filamentary material of this invention as the covering yarn. By
varying the angle of wrap of such yarn, modulus values, extending
over a range of extension of significantly more than 100 percent,
can be varied from those typical of spandex up to those typical of
the yarns of this invention and the magnitude of any changes in
modulus with extension can be reduced greatly from those resulting
from the use of conventional fibers in the wrapping yarn.
BLENDS WITH OTHER FIBERS
Spun stretch yarns composed predominantly of conventional fibers
such as cotton, wool, nylon, polyester, or other commonly used
materials, can be produced by blending such fibers with 5 to 45
percent of staple fiber of this invention. Such blending is carried
out in a card, pill box, pin drafter, Pacific Converter, or other
normally used blending procedure prior to spinning the yarn. The
relatively high modulus of the fiber of this invention makes these
blending operations much easier to control than when other elastic
fibers having a much lower modulus are used, and drafting and
spinning are accomplished with only minor adjustments of normal
machine settings. The final product can be used to produce fabrics
having usable stretches in the range of 10 to 30 percent, and the
high recoverability and high recovery energy provided by the
filamentary material of this invention ensures excellent elastic
characteristics in the stretch fabric, and minimizes or eliminates
the problem of pilling encountered with low-modulus fibers.
BULK STRETCH YARNS
Bulked yarns as presently being produced are characterized by being
lofty, but not having unusual stretch characteristics. Stretch
yarns, on the other hand, may be bulky, but they achieve their
stretchiness at the expense of reducing this bulk; that is, by
removal of the crimp which causes it. A true bulk stretch yarn
would be one in which the bulk is retained when the yarn is
stretched. This could be accomplished if the fibers from which the
yarn was made had a low enough modulus to ensure that the yarn
could stretch by virtue of the fibers themselves stretching, and
not primarily or exclusively by a crimp removal mechanism.
Yarns made from the fibers of this invention can be made bulky by
drawing them under slight tension over a sharp, unheated edge,
followed by stretching and relaxing. This causes the filaments to
kink extensively, and results in a very bulky yarn having 50 to 100
percent of highly recoverable stretch. Such bulky stretch yarns are
useful for producing light, lofty fabrics, in the range of 3 to 10
ounces per square yard, having excellent cover and the ability to
recover their original dimensions after being stretched 50 percent
or more. Moreover, much of this bulk is retained over wide ranges
of stretch, and thus the fabric cover is not seriously reduced by
stretching, making it ideal for applications like bathing suits,
formfitting blouses, leotards or other formfitting garments,
etc.
Fabrics for these applications can be made somewhat more open from
the yarns of this invention than from other types of stretch yarns,
thus providing the possibility of constructing lighter, more porous
and, therefore, more comfortable fabrics.
STRETCH SEWING THREADS
One of the current problems in the production of garments made from
stretch fabrics is to retain that stretch in the seam of these
garments. This can easily be accomplished by using a sewing thread
which is capable of stretching with the fabric. The sewing thread,
on the other hand, must be capable of withstanding the normal
stresses imposed by the sewing operation without undue stretch, or
seam puckers will result. Sewing threads having the desired
characteristic of good sewability and capable of providing the
stretch needed in the seams of garments made from stretch fabrics
can be made from fiber of this invention in a number of ways. One
such thread can be produced in normal sewing thread constructions
using the filaments of this invention in place of those made from
other fibers. A gradation of stretchability can be provided by
producing yarns from blends of staple fiber made from the filaments
of this invention in varying amounts with cotton, nylon, or other
textile fiber, and using such yarns in conventional sewing thread
constructions. Still another suitable yarn for the production of
stretchable sewing threads is one in which normal textile fibers
are either spun or wrapped around a yarn of this invention as core,
in any one of a number of normal core-yarn-manufacturing
techniques.
BULK FILLING MATERIAL
Pillows and cushions are generally filled with synthetic or natural
fibers to produce a resilient end product. Certain fibrous
materials, due to poor elastic recovery from bending and a tendency
to cluster or clump, demonstrate poor durability as pillow or
cushion fillers. A cut staple fiber such as that made from the
filamentary material of this invention, crimped and/or bulked, has
very desirable properties as a filling material. A typical blend
for filling pillows made completely from filamentary material of
this invention, is as follows:
---------------------------------------------------------------------------
50% low modulus 6 denier material 50% medium modulus 3 denier
material Staple length 3 inches Crimps per inch of fiber length 10
__________________________________________________________________________
STRETCH NONWOVENS
Nonwoven fabrics are relatively stiff materials which do not drape
or conform to bodily contours as do normally woven fabrics. A
method of improving the quality of a nonwoven fabric in terms of
drapeability and recoverability from imposed strains is to
construct the nonwoven in part or entirely from fibers of this
invention. The highly elastic nature of relatively low modulus
fibers of this invention in low deniers can make them desirable
materials for stretch nonwovens.
A typical nonwoven is composed of 11/2 inch cut staple, low modulus
fibers made from 3-denier filaments of this invention and having a
web weight of 2.0 ounces per square yard and a 30 percent by weight
low modulus high-strength adhesive binder.
TUFTED CARPETS
A typical application, taking advantage of the recovery properties
of the material of this invention is in a rug backing (either in
total or as a component) for tufted carpets. A tightly woven fabric
of suitable construction and weight passes through the tufting
machines under fillingwise extension and tension (approximately 25
percent extension). The base fabric is tufted in this form after
which the filling tension is allowed to relax. The fabric then
contracts, which causes the pile to condense producing a heavier
and denser pile than can currently be obtained by the present
rug-backing fabrics (jute, cotton, polypropylene). This procedure
produces carpets with a denser pile, and therefore with a more
enhanced and more luxurious-looking pile than can currently be
produced by prior art methods. Besides the advantage of appearance,
the more compact pile has better resistance to crushing, better
abrasion properties, and longer wear, etc.
A typical construction of such a rug-backing fabric is a plain
woven fabric weighing about 9 ounces per square yard constructed
from 3,100-denier yarns having a yarn count of 12.5 ends per inch
of 13 picks per inch. These yarns can be either continuous filament
or spun staple yarns.
WOVEN CARPETS
The filamentary material of this invention has applications in the
woven carpet industry as binding yarns in carpets. The high
recovery forces of the yarn and fiber imparts higher--and therefore
more desirable--binding forces to the pile than can be obtained
from current binding yarns. The higher binding forces also prevent
pile "pullout" and produce a more stable pile and carpet.
The additional ease of extension of the yarn, with high recovery,
also aids in the formfitting and stability of rugs on stairs, over
angles, and around objects. In this application it applies to both
the binding yarns and to the rug pads used underneath rugs.
The fiber is used in both spun staple yarns or continuous filament
yarns in yarn number and construction currently used by the rug
industry.
FORM-FIT FABRICS: BEDSHEETS, SHIRT COLLARS AND LIKE PRODUCTS
A typical application of the filamentary material of this invention
which takes advantage of the high recovery force of the fiber is in
the area of form-fit fabrics such as bedsheets and shirt collars.
The advantage of such material in form-fit bedsheets over
conventional form-fit sheets is that the higher retractive forces
cause the form-fit sheets to adhere more closely to the mattress
producing a neater appearance and a more stable sheet than
currently available form-fit sheets.
A typical woven sheeting construction utilizing the material of
this invention in either continuous filament or staple spun yarns
has a fabric width of 40 inches, a fabric weight of 4 yards/lb.
(3.3 oz./sq. yd.) and a yarn count of 48 warp ends per inch and 48
filling ends per inch.
The same advantages hold true for other form-fit applications such
as shirt collars. These applications utilize either woven or
nonwoven fabrics containing the material.
GLOVE FABRICS
Another typical application for the material of this invention,
taking advantage of its high recovery and bulking ability
properties, is in glove wear fabrics--including woven, knitted, and
nonwoven. The advantages of using such material are better bulking
characteristics and better extensibility and recovery performance,
and the resulting fabrics produce better warmth, better comfort,
and more efficient use. The ease of extensibility with high
recovery results in more efficient and comfortable gloves than
currently in use.
The material may be used in the production of a wide range of glove
products, from work gloves to women's fashion gloves.
UMBRELLA FABRIC
A more compact folded umbrella may be made using fabric made from
the yarn of this invention, having the ability to stretch 25
percent or more when the umbrella is opened, without serious loss
of cover. This can be accomplished by using a high bulk yarn, so
that even after the fabric is stretched, the yarn still retains
sufficient bulk to fill the fabric interstices and retain the
required water repellency. The amount of bulk required varies with
the amount of stretch desired, and the construction is adjusted to
provide the prime requirement of high cover to provide good water
repellency when the umbrella is open (i.e., when the fabric is
stretched).
NOVELTY PUCKERED FABRIC
The material of this invention is suitable for a seersucker-type
fabric in which bands of puckers run lengthwise in the fabric, and
are of a size and frequency controlled by the fabric construction.
These are produced by setting up a warp containing alternating
bands of yarns made of any normal textile fiber and of the elastic
yarns of the invention.
The latter yarns are wound onto the warp beam under tension
sufficient to stretch them 5 or more percent, and this stretch is
maintained in the loom by adequate warp tensioning. After weaving,
the fabric is permitted to relax, and the high energy of recovery
provided by the yarns of the invention causes the whole fabric to
contract, and in turn causes the surface to pucker in those bands
which contain normal warp yarns. The advantage of yarns of the
invention in such applications results from its high recovery
energy. This permits both very light and very heavy fabrics to be
produced more successfully than is possible by currently used
procedures.
CAMP COT FABRIC
The filamentary material of the invention is suitable for use in
"camp cot" fabric for both military and civilian applications. The
purpose of such material is to provide a small amount of
recoverable stretch and thereby provide more comfort in use than is
currently obtained from present camp cots. The material is suitable
for use in all current camp cot fabrics, in plain weave, twills and
other constructions.
A typical construction for this fabric contains 96 ends per inch by
64 picks per inch in a 40-inch width producing a fabric weighing
about 2.5 yards per pound (5.8 ounces per square yard).
UPHOLSTERY FABRICS: OUTDOOR AND INDOOR
The filamentary material of the invention is suitable for use in
both outdoor and indoor upholstery fabrics. Such material imparts
better drape, elastic, and formability properties to these fabrics
than they currently exhibit. The ease of extensibility with high
recoverability enables easier, more efficient fabrication of the
fabric to the furniture as well as producing a neater appearance
after fabrication caused by the high recovery giving a tight or
snug fit on the padding and structure of the upholstery.
Current upholstery fabrics come in a wide range of types, weights,
and construction. The material of the invention may be used,
without restrictions, in all types of such fabric either as part of
a blend or alone. The material may be in either staple form or in
continuous filament form depending upon the desired end
characteristics.
SHOE APPLICATIONS: FABRIC AND LININGS
The filamentary material of the invention finds many applications
in the shoe industry in both outer shoe and sneaker fabrics as well
as inner shoe linings. In use, many shoe fabrics fail in the area
of fabrication to the leather. Because of the relative ease of
extensibility of the material of the invention, associated with
high recoverability, the shoe fabric containing such material can
be fabricated to the shoe with less internal stress. Also, during
walking--applicable to both shoes and sneakers--the fabric extends
easier and recovers more completely thereby producing a more
comfortable and longer lasting shoe or sneaker. The lower stresses
on the elastic material where the fabric covers the toes results in
more comfortable and longer lasting sneakers.
The ease with which fabrics comprising the filamentary material of
the invention can be formed and coated or impregnated make it very
desirable for shoe linings. Such fabrics adhere to the shape of the
shoe easily, without wrinkles, and lend themselves easily to
stitching and fabrication of the shoe.
The material is utilized in all presently used shoe fabric and shoe
lining fabric constructions. It can be used in the form of spun
staple yarns or continuous filament yarns and may comprise 100
percent of the fabric or a component part of the fabric.
COATED FABRICS
The material of this invention is useful in the manufacture of
highly elastic coated structures. As is well known to coaters,
soft, drapey, elastic-coated fabrics can be made utilizing cotton
knit goods as contrasted with typical woven cotton sheetings and
twills due to the stretchability of knit fabrics. This
stretchability is translated to the coated structure and is useful
in formable furniture and automatic upholstery, headlining or for
leatherette, as it is known, which is also used for luggage,
etc.
In coating knitted fabrics with vinyl compositions or other plastic
films by coating or lamination, it is generally noted that knit
fabrics require more coating materials to fill the interstices and
to obtain level, smooth coatings as compared to those same coatings
on flat woven structures.
Woven fabrics containing the material of the invention exhibit
stretch characteristics of the knit fabrics while enjoying the
benefits of coating virtues of flat woven structures. Better
overall reinforcement of plastic films also results from compatible
characteristics of stretch of both the yarn and the plastic film to
make better performing products.
Fabrics containing the elastic material of the invention can be
constructed of either filament or spun yarns as desired and made in
roughly comparable weight and strength with typical constructions
of other fibers now used, as for example the woven sheeting of
cotton such as the 80.times.80 print cloth of 4 sq. yds. per pound
or heavier sheeting of coarse yarns as a typical 48.times.48
construction of 2.6 sq. yds. per pound. Weights and weaves like
typical canvas or special weaves as twills and drills are likewise
of use.
To gain extreme extensibility for special uses the material may be
knit into fabrics of structure similar in weight and strength to
cotton knit goods. The stretch of the yarns of the invention added
to that already available from the knit structure yields coated
structures of unusual softness, pliability, and elasticity. This
enables the coater to produce structures that can be made to
conform to odd shapes and around corners without producing
unsightly folds or damage to the base fabric.
Coated fabrics using heavy fabrics comprising the elastic material
of the invention are highly desirable in coated inflatable or
air-supported fabrics. The easy extensibility and high
recoverability of this fiber make it easy to fabricate and give a
neater appearance at the seams while under air pressure. The fabric
adjusts itself easier to changes in air pressure under use because
of the extensibility and recovery properties.
NETS
Nets are extremely open structures formed by knotting together the
component yarns at the intersections. They are extremely deformable
structures because of the relative infrequency of the points of
restriction created by the knots. They have little if any tendency
to recover from any deformation. A significant amount of recovery
could be provided by making the nets out of yarns of this
invention, which, because of their ability to stretch and high
energy of recovery, make it possible to produce nets with a
characteristic not provided by normal net constructions. Thus,
formfitting hairnets, useful over a wide range of head sizes, are
contemplated from yarns of the invention of 100 denier or less.
Expandable containers (e.g. laundry bags) and carrying bags are
easily produced from heavier yarns, in the range of 100 to 1,000
denier or more. Also, gill nets are contemplated which are designed
to catch a wider range of fish size than do those made from from
conventional fibers, in which the larger fish are lost because they
cannot get their heads through the mesh. These contain cords or
more than 1,000 denier.
SUPPORT HOSIERY
Whereas the majority of support hose utilize relatively coarse yarn
constructions to create the necessary amount of support stress at a
worn strain (anywhere from 0 to 2 pounds per inch of fabric width
depending upon leg size, position on the leg and amount of support
required) it is possible to utilize yarns of this invention to
produce, in combination with other materials, a much shearer
support hose.
One technique whereby elastic filaments are utilized is by laying
in continuous filament elastic yarn within the knit loops of the
stocking. Using the filament yarn of the invention, a typical
construction for a support stocking is as follows:
---------------------------------------------------------------------------
Wales per inch 30 to 60 Courses per inch 30 to 65 Knit structure 30
denier nylon monofilament with 35 denier filament of the invention
laid into the knitted mesh
__________________________________________________________________________
It is to be understood that the foregoing detailed description is
given merely by way of illustration and that many variations may be
made therein without departing from the spirit of our
invention.
* * * * *