U.S. patent number 3,607,761 [Application Number 04/782,416] was granted by the patent office on 1971-09-21 for soap bars containing salts of fatty acids derived from the guerbet reaction.
This patent grant is currently assigned to Continental Oil Company. Invention is credited to George C. Feighner, William L. Groves, Jr..
United States Patent |
3,607,761 |
Feighner , et al. |
September 21, 1971 |
SOAP BARS CONTAINING SALTS OF FATTY ACIDS DERIVED FROM THE GUERBET
REACTION
Abstract
A detergent bar comprising an alkali metal salt or a blended
magnesium-alkali metal salt of blends of C.sub.12 to C.sub.16 acids
derived from the oxidation of alcohols produced by the Guerbet
reaction and an alkali metal soap or a blended magnesium-alkali
metal soap of a C.sub.16 -C.sub.18 fatty acid.
Inventors: |
Feighner; George C. (Franklin
Lakes, NJ), Groves, Jr.; William L. (Ponca City, OK) |
Assignee: |
Continental Oil Company (Ponca
City, OK)
|
Family
ID: |
25125987 |
Appl.
No.: |
04/782,416 |
Filed: |
December 9, 1968 |
Current U.S.
Class: |
510/152; 510/491;
554/71 |
Current CPC
Class: |
C11D
9/007 (20130101); C11D 9/005 (20130101) |
Current International
Class: |
C11D
9/00 (20060101); C11d 009/00 (); C11d 009/18 ();
C11d 017/00 () |
Field of
Search: |
;252/110,108,367,368,369,370 ;260/413,417,418 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
"The Merck Index," 8th Edition, Apr., 1968, Pg. 1173..
|
Primary Examiner: Rosdol; Leon D.
Assistant Examiner: Albrecht; Dennis L.
Claims
Having thus described the invention, we claim:
1. A toilet detergent bar consisting essentially of about 10 to 15
weight percent of salts of blends of C.sub.12, C.sub.14 and
C.sub.16 acids derived from the oxidation of alcohols produced by
the Guerbet reaction having the general formula:
where p is an integer from 4 to 6; n is an integer from 6 to 8 and
N+p is always equal to an even number, said blends consisting of
about 30 to 70 percent of the C.sub.12 acids, from about 40 to 15
weight percent of the C.sub.14 acids and from about 40 to 15 weight
percent of the C.sub.16 acids wherein said salts of said blends are
selected from the group consisting of the sodium salts of said
acids and blends of sodium and magnesium salts of said acids and
from about 90 to 85 weight percent of a salt of a C.sub.16 to
C.sub.18 straight chain fatty acid wherein said salt of said
C.sub.16 to C.sub.18 straight chain fatty acid is selected from the
group consisting of the sodium salts of said acids and blends of
the sodium and magnesium salts of said acids.
2. The toilet detergent bar of claim 1 wherein said salts of blends
of said C.sub.12, C.sub.14 and C.sub.16 acids and said salts of
said C.sub.16 to C.sub.18 straight chain fatty acids are the sodium
salt or a blended magnesium-sodium salt of said acids containing
from about 25 to 40 weight percent magnesium salt.
3. The toilet detergent bar of claim 2 wherein said magnesium salt
is present in an amount of about 36 weight percent.
4. The toilet detergent bar of claim 1 wherein said blend of
C.sub.12, C.sub.14 and C.sub.16 acids contains about 65 weight
percent C.sub.12 acids, about 17.5 weight percent C.sub.14 acids
and about 17.5 weight percent C.sub.16 acids and said salt of said
acid is a sodium salt.
5. The toilet detergent bar of claim 1 wherein said blend of said
C.sub.12, C.sub.14 and C.sub.16 carbon acids contains about 25
weight percent C.sub.12 acid, about 37.5 weight percent C.sub.14
acid and about 37.5 weight percent C.sub.16 acid and said salt of
said acid is a sodium salt.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to am improved detergent bar composition. In
another aspect this invention relates to a detergent bar
composition which has excellent washing property characteristics in
both hard and soft water and which can be milled, plodded, and
pressed on soapmaking equipment and possesses many of the more
desirable products characteristics of soap. More particularly, this
invention relates to a detergent bar comprising a major portion of
an alkali metal soap or a blended magnesium-alkali metal soap of a
C.sub.16 to C.sub.18 fatty acid, and a minor portion of an alkali
metal salt or a blended magnesium-alkali metal salt of a blend of
C.sub.12 to C.sub.16 acids derived from the oxidation of alcohols
produced by the Guerbet reaction.
2. Brief Description of the Prior Art
Toilet bars are conventionally of tallow and coconut oil fatty acid
soaps. The ratio of the tallow and coconut oil fatty acid soaps
present in the toilet bars are usually about 80 percent tallow to
20 percent coconut oil fatty acid soaps in order to form a toilet
bar having desirable lathering characteristics in both warm and
cold water. The cost of the coconut oil fatty acid soap is usually
much greater than that of the tallow fatty acid soap because of the
nature of its source and limited supply. Therefore, it is desirable
to reduce or eliminate the quantity of the higher priced coconut
oil fatty acid soap component in the milled toilet soap for
economical reasons. However, problems have occurred in providing
detergent bar compositions from synthetic detergents which produce
the same desirable characteristics as the soap bar formed from the
tallow and coconut oil fatty acid soap blends.
In recent years much time and money have been expended in an effort
to produce bar and cake detergents based on synthetic organic
detersive materials, or bar or cake detergents containing a
synthetic organic detersive material as one of the components.
However, in the manufacture of detergent bars, problems have
occurred in that the final shape, appearance, cohesiveness and
solubility properties of the products produced wherein synthetic
organic detergents employed in the detergent blend are not
comparable to those obtained with soap. Further, the use of
synthetic organic detersive materials as one of the components in
the detergent bar has often resulted in that the finished bar is
very tacky and, consequently, unattractive for use. Further, the
prior art synthetic organic detergent bars are not of the same
character as the toilet bars formed from the conventional
coconut-tallow fatty acid soap blends. Thus, the above-mentioned
defects in the final shape, appearance, cohesiveness, and
solubility properties of the detergent bars wherein a synthetic
organic detersive material is employed as one of the components
have had a substantial effect on the marketability of such
detergent bars.
Therefore, in order to produce an acceptable toilet bar composition
containing a synthetic organic detersive material as one of the
components, the detergent bar composition must be capable of being
milled, plodded, and pressed so as to obtain a bar of satisfactory
appearance and suitable structure. Also, it is necessary that the
compositions employed to produce the detergent bar be capable of
being worked and readily shaped. In the consideration of the
acceptability of a detergent bar composition designed for personal
use on the hands, face, and body of the user, it is also necessary
to consider objective factors, such as scum, dispersion, and soil
removal with a multitude of subjective considerations such as the
many personal considerations of feel, effect on the skin, and the
like. Thus, new and novel detergent bar compositions are constantly
being sought which are equal to or superior to the washing
properties of the conventional coconut-tallow fatty acid soap blend
and, at the same time, are equivalent or better than such soap in
their physical characteristics, such as hardness, plasticity under
pressure, workability, extrusion, film formation, solubility rate,
reduced curd formation, rehardening after moisture, and the
like.
OBJECTS OF THE INVENTION
An object of the invention is to provide a detergent bar which
possesses desirable physical characteristics. Another object of the
invention is to provide a detergent bar which exhibits the
excellent washing property characteristics of detergents while
still possessing favorable appearance and processing properties of
soap. Another object of the invention is to provide a detergent bar
which functions equally well in hard water and soft water and which
can be manufactured in suitable milled and plodded form. Other
objects and advantages of the invention will become apparent to
those skilled in the art from a study of the following detailed
description and appended claims.
SUMMARY OF THE INVENTION
A novel, satisfactory detergent bar is prepared from a mixture of
about 10 to 15 weight percent of an alkali metal salt or a blended
magnesium-alkali metal salt of a blend of a C.sub.12 to C.sub.16
acids derived from the oxidation of alcohols produced by the
Guerbet reaction and from about 90 to 85 weight percent of an
alkali metal soap or a blended magnesium-alkali metal soap of a
C.sub.16 to C.sub.18 fatty acid. More specifically, the alkali
metal soap of the detergent bar is a sodium soap of a C.sub.16
-C.sub.18 fatty acid, or a blended magnesium-sodium soap of a
C.sub.16 to C.sub.18 carbon fatty acid containing from about 25 to
40 weight percent magnesium soap constituent, and the alkali metal
salt of the blend of C.sub.12 to C.sub.16 acids is the sodium salt
or a blended magnesium-sodium salt. The detergent bar of the
invention forms a plastic, cohesive mass from which a bar having a
low slough loss, good lathering characteristics, and low wear can
be produced. Moreover, the aforesaid mixtures can be shaped or
pressed into a bar that has a pleasant feel on contact with the
skin, is harmless to the human body, and is nonsticky.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The preparation of a detergent bar containing a mixture of a metal
soap of a C.sub.16 to C.sub.18 fatty acid wherein the metal
constituent of the soap is an alkali metal, magnesium, and mixtures
thereof, and a blend of C.sub.12 to C.sub.16 metal salts of acids
derived from the oxidation of alcohols produced by the delayed
reaction wherein the metal constituent of the salt is an alkali
metal, magnesium, and mixtures thereof, produces a detergent bar
having the desirable features of a toilet bar formed from the
conventional blends of tallow and coconut oil fatty acids.
The alkali metal salts of the C.sub.16 to C.sub.18 fatty acids
employed in the detergent bar of the present invention may be
derived from any convenient source. The only criteria is that the
C.sub.16 to C.sub.18 fatty acids be straight chain fatty acids.
However, it is preferred ordinarily to use the alkali metal salts
of C.sub.16 to C.sub.18 fatty acids derived from tallow. Desirable
results have been obtained wherein the sodium salts or a mixture of
sodium salt and magnesium slat of the C.sub.16 to C.sub.18 fatty
acids derived from tallow are employed as one of the constituents
of the composition employed to produce the detergent bar of the
present invention.
The alkali metal salts or the blends of alkali metal salt and
magnesium of C.sub.12 to C.sub.16 acids which are employed as the
other constituent of the detergent bar composition of the present
invention are derived from the oxidation of alcohols produced by
the Guerbet reaction and the subsequent neutralization of the
resulting acids. The process of neutralization of the acid
components of both the C.sub.16 to C.sub.18 fatty acids and the
blends of C.sub.12 to C.sub.16 acids produced by the oxidation of
the product resulting from the Guerbet reaction are well known in
the art and, in view of such, further detail is believed
unnecessary.
The Guerbet reaction involves the dimerization of straight chain
alcohols in the presence of an alkali or metallic catalyst to form
a single molecule containing 1-hydroxyl group. The resulting
molecule has twice the number of carbon atoms as the original
straight chain alcohol. The oxidation of the resulting alcohol thus
produces the desired acids. The number of carbon atoms present in
the resulting acid can be readily controlled by employing the
proper straight chain alcohol or alcohols which are to be
dimerized. However, we have found that the amount and type of acids
derived from the oxidation of alcohols produced by the Guerbet
reaction must be closely controlled in order to provide a detergent
bar containing same which possesses satisfactory characteristics.
For example, we have found that blends of alkali metal salt of
magnesium alkali metal salts of C.sub.12 to C.sub.16 carbon acids
derived from alcohols which are produced by the Guerbet reaction
when incorporated into the alkali metal or magnesium alkali metal
salt of tallow acid, commonly referred to as tallow soap, that the
resulting composition can be readily plodded, milled, and shaped
into a desirable detergent bar which has good lathering, and the
advantages of conventional soap formed from the tallow-coconut oil
fatty acid soaps. Further, we have found that it is necessary to
restrict the chain lengths of the acids produced by the oxidation
of the alcohols produced by the Guerbet reaction because branched
C.sub.16 carbon acids and higher are not satisfactory for
introduction into the composition due to the poor lathering
properties of the resulting detergent bar.
We have unexpectedly found, however, that by employing a blend of
n-hexanol and n-octanol as the straight chain alcohol to undergo
dimerization and subsequent oxidation and neutralization a salt of
a blend of C.sub.12, C.sub.14, and C.sub.16 salts was produced,
which, when employed in the composition produces a very desirable
detergent bar. It is preferred that the blend contains from about
25 to 65 weight percent of the C.sub.12 constituent, from about
37.5 to 17.5 weight percent of the C.sub.14 constituent, and from
about 37.5 to 17.5 weight percent of the C.sub.16 constituent.
Further, we have found that it is desirable to employ from about 10
to 15 weight percent of the blend described above with from about
85 to 90 weight percent of the salt of the tallow acid in order to
produce a detergent bar having the required characteristics to
produce good lathering, and appearance which is required of all
toilet bars.
As previously stated, the toilet detergent bar of the present
invention comprises from about 10 to 15 weight percent of salts of
blends of C.sub.12 to C.sub.16 acids derived from the oxidation of
alcohols produced by the Guerbet reaction wherein the salts of the
blends are selected from the group consisting of alkali metal
salts, and blends of alkali metal salts and magnesium salts, and
from about 90 to 85 weight percent of a salt of a C.sub.16 to
C.sub.18 fatty acid wherein the salts of the C.sub.16 to C.sub.18
fatty acids are also selected from the group consisting of alkali
metal salts, and mixtures of alkali metal salts and magnesium
salts. Desirable results, however, have been obtained wherein the
salt for both constituents described above is the sodium salt of
the blends of the C.sub.12 to C.sub.16 carbon acids and the sodium
salt of the C.sub.16 to C.sub.18 fatty acids. The amounts of
magnesium salt incorporated when the salt constituents are a
mixture of magnesium and sodium salt must be carefully controlled
in order to provide a resulting product which is not tacky and
possesses the desirable foaming properties of the detergent bar. We
have thus found that when employing a salt mixture of an alkali
metal salt, such as sodium, and a magnesium salt it is necessary
that the mixture contain about 25 to 40 weight percent magnesium
salt in order to provide a composition which is not tacky and
possesses the desirable foam characteristics, while at the same
time preventing the problem of extreme brittleness in the resulting
bar. However, if the amount of the magnesium constituent exceeds
about 25 to 40 weight percent, one is faced with the problem of
extreme brittleness of the resulting bar.
In order to further illustrate the detergent bar of the present
invention the following specific examples are given. These examples
are presented primarily for the purpose of illustration and any
enumeration or details contained therein are not to be interpreted
as a limitation on the invention except as indicated in the
appended claims. All parts and percentages of constituents referred
to in the following examples are by weight unless otherwise
indicated.
Example 1
Detergents bars were formed from blends of 12 to 16 carbon acids
derived from the oxidation of the alcohol resulting from the
dimerization of normal hexanol and normal octanol by the reaction
known as the Guerbet reaction. The resulting blends contained the
carbon atom distribution shown as follows:
Blend 1 Blend 2
__________________________________________________________________________
C.sub.12 acids 65 25 C.sub.14 acids 17.5 37.5 C.sub.16 acids 17.5
37.5
__________________________________________________________________________
Each of blend 1 and blend 2 was then converted to the sodium soaps
and the resulting soaps were added at both a 10 weight percent and
15 weight percent level to the sodium soap of tallow acid so as to
form compositions which could be stamped into toilet bars. The
toilet bars so produced were not tacky, stamped without mold
release, and lathered as well as the conventional soap made from
the slats of natural coconut oil acids and tallow acids. Further,
the slough, i.e., the weight loss after removing soap softened from
soaking in water, was essentially the same for the detergent bar of
the present invention as for toilet bars employing the conventional
blends of tallow and coconut oil fatty acid soaps. Thus, it is
clearly evident that the sodium salts of the two blends described
can be satisfactorily substituted for the costly coconut oil
derived acids, while, at the same time, producing a detergent bar
from a blend of tallow soap and the salts of blends of C.sub.12 to
C.sub.16 acids which can be processed with ease, are not tacky and
which possesses the desirable characteristics of the conventional
toilet bars made from conventional coconut oil-tallow fatty acid
soaps.
EXAMPLE 2
A number of detergent bars were made wherein the sodium soap of the
tallow acid and the sodium soap of the blends of C.sub.12 to
C.sub.16 acids were partially converted to a magnesium soap by
blending in magnesium sulfate immediately after neutralization.
Having a level of 20 weight percent magnesium-80 weight percent
sodium soap the product was tacky and had unusually poor foaming
characteristics. However, at 36 percent magnesium soap, the product
was hard, more soaplike, and exhibited improved foaming
characteristics. The bars made containing the mixed sodium and
magnesium salts were harder than the 100 percent sodium-containing
detergent toilet bars. However, when controlling the amount of
magnesium constituent present in the magnesium-sodium salt soaps
within the range of about 25 to 40 weight percent magnesium soap
produced a harder bar, while at the same time did not result in a
brittle bar. Further, the resulting bar was more soaplike.
Therefore, it is clearly evident from the above description that
detergent bars can be formed wherein the coconut oil fatty acids
soaps are replaced by salts of blends of C.sub.12 to C.sub.16 acids
derived by the oxidation of the reaction product formed by the
Guerbet reaction without sacrificing the desirable properties of
the toilet bars prepared from the conventional blends of tallow and
coconut oil fatty acid soaps.
* * * * *