U.S. patent number 3,604,269 [Application Number 04/835,081] was granted by the patent office on 1971-09-14 for automatic gas chromatographic sample injection device.
This patent grant is currently assigned to The Upjohn Company. Invention is credited to Ernest J. Kubiak, Jr., Edwin W. Smith.
United States Patent |
3,604,269 |
Smith , et al. |
September 14, 1971 |
AUTOMATIC GAS CHROMATOGRAPHIC SAMPLE INJECTION DEVICE
Abstract
An apparatus for periodically injecting samples of fluid into a
receptacle. The apparatus includes a movable frame which supports a
syringe having a passageway adapted to be moved through an opening
in the receptacle. The syringe controls the collection of a
predetermined fluid sample and it is flushed after each use. The
syringe is moved by the apparatus to inject the predetermined
sample through the passageway into the receptacle.
Inventors: |
Smith; Edwin W. (Climax
Township, Kalamazoo County, MI), Kubiak, Jr.; Ernest J.
(Kalamazoo, MI) |
Assignee: |
The Upjohn Company (Kalamazoo,
MI)
|
Family
ID: |
25268522 |
Appl.
No.: |
04/835,081 |
Filed: |
June 20, 1969 |
Current U.S.
Class: |
73/864.87 |
Current CPC
Class: |
G01N
30/24 (20130101); G01N 35/1095 (20130101) |
Current International
Class: |
G01N
1/00 (20060101); G01N 30/00 (20060101); G01N
30/24 (20060101); G01n 001/02 () |
Field of
Search: |
;73/421,423A,422GC
;128/218R ;141/130 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Swisher; S. Clement
Claims
We claim:
1. An apparatus for injecting a sample of liquid into an opening in
a receptacle, comprising:
base means;
a mounting member supported by said base means for reciprocable
movement relative to said base means;
first actuating means connected to said base means for effecting
said movement of said mounting member;
syringe means supported on said mounting member and having outlet
means arranged for insertion into said opening in said receptacle,
said syringe means having a chamber and a plunger slideably
disposed in said chamber for discharging liquid from said chamber
through said outlet means;
a source of liquid;
means adapted to provide a driving force for said liquid;
conduit means communicating between said chamber and said driving
force means;
second actuating means supported by said mounting member and
connected to said plunger for moving same relative to said syringe
means, including a position blocking said communication; and
control means for effecting operation of said first and second
actuating means to permit said liquid to move through said outlet
means and said chamber for a selected period of time after which
said plunger blocks said communication to limit the liquid in said
chamber to a selected amount and said syringe means is thereafter
caused to inject said selected amount of said liquid into said
receptacle.
2. An apparatus for injecting a sample of liquid into an opening in
a receptacle, comprising:
base means;
a mounting member supported by said base means for reciprocable
movement relative to said base means;
first actuating means connected to said base means for effecting
said movement of said mounting member;
syringe means supported on said mounting member and having outlet
means arranged for insertion into said opening in said receptacle,
said syringe means having a chamber and a plunger slideably
disposed in said chamber for discharging liquid from said chamber
through said outlet means;
a source of liquid under pressure;
conduit means communicating between said source and said
chamber;
second actuating means supported by said mounting member and
connected to said syringe means for effecting relative movement
between said outlet means and said plunger; and
control means for effecting operation of said first and second
actuating means to permit said liquid to discharge through said
outlet means for a selected period of time after which said syringe
means is caused to inject a selected amount of a liquid into said
receptacle.
3. An apparatus according to claim 2, including exhaust means
supported on said base means and having inlet means near said
outlet means, said exhaust means being moved intermittently by said
control means into and out of a position aligned with the discharge
end of said outlet means to collect said liquid discharging from
said outlet means during said selected period of time.
4. An apparatus according to claim 3, wherein said second actuating
means comprises:
support means slideably mounted upon said mounting member for
movement in a direction parallel with the movement of said mounting
member;
a first pressure fluid-operated cylinder connected between said
mounting member and said support means for effecting said movement
of said support means; and
a second pressure fluid-operated cylinder connected between said
support means and said plunger, whereby said first cylinder urges
said plunger into a position blocking said conduit means and said
second cylinder causes said plunger to discharge said selected
amount of liquid.
5. Apparatus for injecting a sample liquid into an upwardly facing
opening of a gas chromatograph, comprising:
base means;
a mounting member supported by said base means for vertical
movement relative to said base means;
first actuating means connected between said base means and said
mounting member for effecting said vertical movement of said
mounting member;
a syringe secured to said mounting member and having outlet means
vertically aligned with said opening in said chromatograph, said
syringe having a chamber and a plunger slideably disposed in said
chamber for discharging liquid from said chamber through said
outlet means;
a source of liquid under pressure;
conduit means communicating between said source and said
chamber;
second actuating means supported by said mounting member and
connected to said plunger for moving said plunger vertically
relative to said syringe;
exhaust means having inlet means supported on said base means for
movement into and out of a position between said opening in said
chromatograph and said outlet means; and
control means for effecting operation of said first and second
actuating means to permit said liquid to discharge through said
outlet means into said inlet means for a selected period of time
after which said syringe is caused to inject a selected amount of
said liquid into said chromatograph.
6. An apparatus according to claim 5, wherein said first actuating
means is a first pressure fluid-operated cylinder having a piston
connected to said mounting member;
wherein said second actuating means comprises a second pressure
fluid-operated cylinder secured to said mounting member and having
an upright piston connected to a frame and adapted to move said
frame relative to said mounting member, and a third pressure
fluid-operated cylinder carried by said frame and having a
downwardly extending piston connected to said plunger.
7. An apparatus according to claim 6, wherein said outlet means of
said syringe is a needle;
wherein said first pressure cylinder moves said needle from a
position above said inlet means through said opening in said
chromatograph;
wherein said second pressure cylinder moves said plunger into a
position blocking said conduit means; and
wherein said third pressure cylinder causes said plunger to
discharge said selected amount of liquid into said
chromatograph.
8. An apparatus according to claim 5, wherein said exhaust means
includes a source of reduced pressure and first tubular means
communicating between said inlet means and said source of reduced
pressure; and
said inlet means comprises a second, rigid tubular means supported
upon said base means and having an end portion with an inlet
opening therein aligned with said outlet means when said end
portion is in said position between said outlet means and said
opening in said chromatograph.
9. An apparatus according to claim 5, wherein said actuating means
comprise fluid-operated cylinders and a source of fluid connected
to said cylinders;
wherein said control means comprises a plurality of cam-actuated
valves connected between said cylinders and said source of fluid,
and a plurality of cams mounted upon shaft means supported by said
base means, said cams being operably connected with said valve
means for controlling the flow of fluid to said cylinders; and
drive means for rotating said shaft means.
10. An apparatus for injecting a sample of fluid into an opening in
a receptacle, comprising:
syringe means having outlet means and means supporting same for
alignment with and insertion into said opening in said receptacle,
said syringe means having a chamber and a plunger slideably
disposed in said chamber for discharging liquid from said chamber
through said outlet means;
a source of liquid;
means adapted to provide a driving force for said liquid;
conduit means communicating between said chamber and said driving
force means;
actuating means drivingly interconnected to said plunger for moving
same between a plurality of positions, including a position
blocking the communication between said conduit means and said
chamber; and
control means for effecting operation of said actuating means (1)
to permit said liquid to move through said outlet means and said
chamber for a selected period of time, (2) to thereafter move said
plunger to block said communication to limit the liquid in said
chamber to a selected amount, and (3) to thereafter cause said
syringe means to inject said selected amount of said liquid into
said receptacle.
11. An apparatus according to claim 10, wherein said actuating
means includes:
first drive means connected to said plunger for causing linear
movement thereof in a first direction;
second drive means connected in series with said first drive means
for causing linear movement thereof in a second direction parallel
to said first direction; and
third drive means connected to said supporting means for causing
linear movement of said supporting means and said syringe means in
a third direction parallel to said first direction.
Description
BACKGROUND OF THE INVENTION
A need has long existed for an automated device to accurately
collect a predetermined amount of sample fluid and then inject same
into a sample fluid-analyzing system, such as a gas chromatograph.
In the past, such injection has been performed manually or by
devices which have not been entirely satisfactory. Tests involving
the use of a gas chromatograph may extend over several hours during
which it has previously been necessary to provide continuous
skilled supervision. Usually, the ambient temperature in the region
of these tests is elevated so that the operator is uncomfortably
warm during the injection procedure. Moreover, the work performed
by the operator is tediously repetitious, even through it must be
skillfully performed.
Thus, it is a primary object of this invention to provide a sample
fluid injection apparatus which is capable of automatically,
accurately and repeatedly collecting predetermined amounts of
sample fluid and then injecting said amounts into a sample
fluid-analyzing system.
It is a further object of this invention to provide an automatic
sample fluid injection device which can be easily operated by
persons capable of operating the test system with which it is used,
which can be manufactured and maintained inexpensively, , and which
can be easily adapted to use with existing types of gas
chromatographs.
Other objects and purposes of this invention will be apparent to
persons acquainted with apparatus of this general type upon reading
the following specification and inspecting the accompanying
drawings, in which:
FIG. 1 is a front elevational view, partially broken away, of a
fluid sample injecting apparatus embodying the invention and
showing the starting position of the power cylinders for
controlling the syringe;
FIG. 2 is a top plan view of the apparatus;
FIG. 3 is a side elevational view as seen from the left side of the
apparatus illustrated in FIG. 1;
FIG. 4 is a sectional view taken along the line IV--IV of FIG.
3;
FIG. 5 is a sectional view taken along the line V--V of FIG. 1 and
excluding cylinder 26;
FIG. 6 is a fragmentary, rear elevational view of the
apparatus;
FIG. 7 is a fragment of FIG. 1 showing a second position of the
power cylinders for controlling the syringe;
FIG. 8 is a fragment of FIG. 1 showing a third position of the
power cylinders controlling the syringe;
FIG. 9 is a fragment of FIG. 1 showing a fourth position of the
power cylinders controlling the syringe;
FIG. 10 is a sectional view taken along the line X--X of FIG.
1;
FIG. 11 is a sectional view taken along the line XI--XI of FIG.
1;
FIG. 12 is a sectional view taken along the line XII--XII of FIG.
1;
FIG. 13 is a sectional view taken along the line XIII--XIII of FIG.
1;
FIG. 14 is a sectional view taken along the line XIV--XIV of FIG.
1;
FIG. 15 is a sectional view taken along the line XV--XV of FIG.
3;
FIG. 16 is a sectional view taken along the line XVI--XVI of FIG.
1;
FIG. 17 is a sectional view taken along the line XVII--XVII of FIG.
1; and
FIG. 18 is a schematic of an electrical circuit utilized in
controlling the operation of the drive motor.
Certain terminology will be used in the following description for
convenience in reference only and will not be limiting. The words
"up," , "down," "right" and "left" will have reference to the
apparatus of the invention as appearing in FIG. 1. The words
"front" and "rear" will refer to the front and rear of the
apparatus, respectively, the front of the apparatus being
illustrated in FIG. 1. The words "in" and "out" will refer to
directions toward and away from, respectively, the geometric center
of the device and designated parts thereof. Such terminology will
include derivatives and words of similar import.
SUMMARY OF THE INVENTION
The objects and purposes of the invention are met by providing an
apparatus for collecting and injecting a sample fluid into a system
and comprises a vertically movable frame having a syringe mounted
thereon and movable therewith. The syringe has a needle which is
movable through the entrance to the system. The syringe is flushed
and then accurately collects a predetermined amount of sample fluid
after which the needle is inserted through the entrance of the
system and the predetermined amount of sample fluid is thereafter
injected into the system.
DETAILED DESCRIPTION
A sample fluid injection apparatus 10 is illustrated in FIG. 1 and
comprises a base 11 and a vertical plate 12 (FIG. 3) mounted on the
upper surface of the base 11 near the front edge thereof, said
plate 12 being braced by a pair of gussets 13 and 14 (FIG. 2). A
vertically oriented guide rail 16 (FIGS. 3 and 4) is mounted on the
front side of the plate 12 by any convenient means such as screws
(not illustrated).
A mounting member 17 has a guide channel 18 (FIGS. 3 and 4) secured
thereto and slideably connected to the guide rail 16 by means of
the ball bearings 15 which permit vertical movement of the channel
relative to the plate 12. A pair of gussets 21 and 22 (FIGS. 2 and
3) are secured to the rear side of the mounting member 17 near its
upper end and extend rearwardly therefrom. The upper edges of the
gussets 21 and 22 are horizontally aligned and support a plate 23
which is secured thereto by a plurality of countersunk screws 24
(FIG. 2).
A power cylinder 26 (FIGS. 2 and 3), operable by either air or
hydraulic fluid, is mounted on the base 11 between the gussets 13
and 14, as shown in FIG. 2. The piston rod 27 of the cylinder 26 is
secured to the plate 23 between the supporting gussets 21 and 22 so
that operation of the power cylinder 26 causes the rod 27 to move
the mounting member 17 vertically relative to the base 11 and plate
12. The control for the power cylinder 26 will be described in more
detail hereinafter.
A gusset 28 (FIG. 1) is secured to the front side of the mounting
member 17 approximately in the center thereof and supports a plate
29. A power cylinder 30 is mounted on the plate 29 and has a piston
rod 38 which extends upwardly therefrom to support the plate 37 of
a frame 31 for vertical movement. The frame 31 comprises a plate 32
secured to the plate 37 and having a guide rail 33 secured to one
side thereof and provided with bearing ball races 34 (FIG. 4). A
gusset 36 (FIGS. 1 and 3) is secured between the plate 37 and one
side of the plate 32 to brace the latter. The power cylinder 30
drives the frame 31 vertically relative to the mounting member
17.
A vertical plate 39 is secured to the front surface of the mounting
member 17 and projects frontwardly therefrom, as illustrated in
FIG. 4. A guide channel 41 (FIG. 4), similar to the guide channel
18, is secured to the plate 39 by any convenient means, such as a
plurality of screws (not illustrated). The guide channel 41 has a
pair of oppositely facing bearing ball races 43 and 44 which oppose
the races 34 and 35, respectively. A plurality of bearing balls 46
are received in the respective races 34, 43 and 35, 44 to guide the
vertical movement of the support frame 31 relative to the mounting
member 17. An abutment flange 47 (FIG. 1) is secured to the upper
edge of the plate 39 and an adjustable screw 48 projects through
the abutment flange 47 to engage the upper surface of the guide
rail 33 on the plate 32 to limit the upward movement of the frame
31 relative to the mounting member 17.
A power cylinder 49 (FIG. 1) is secured to the underside of the
support plate 37 and extends downwardly therefrom. A plate 54 is
secured to the lower end of the power cylinder 49 and has an
opening 56 therein. The piston rod 50 of the power cylinder 49 is
connected to the plunger 51 of a syringe 52 through a coupling 53.
A bracket 57 is secured to the coupling 53 of the power cylinder 49
and extends sidewardly where it supports a vertical rod 59 which
projects upwardly through the opening 56 in plate 54. The upper end
61 of the rod 59 is threaded to receive adjustable locknuts 62.
Thus, upon an extension of the rod 50 of the power cylinder 49, the
locknuts 62 will engage the upper surface of the plate 54 to limit
downward movement of the plunger 51 relative to the syringe 52.
The syringe 52 is secured to the mounting member 17 by a pair of
spaced clamps 63 and 64. In this particular embodiment, each clamp
releasably engages the mounting member 17 to permit removal of the
syringe 52, by loosening the screws 66 which secure the clamps 63
and 64 to the mounting member 17.
In this particular embodiment, the syringe 52 has a narrow chamber
67 therethrough (FIG. 10) and a passageway 68 communicating
therewith. The passageway is connected to a source of liguid S
supplied by a pump P schematically illustrated in FIGS. 3 and 10. A
needle 69 is connected to the lower end of the syringe barrel 70
and communicates with the chamber 67. Sample liquid can be
introduced into the chamber 67 through the passageway 68 and thence
through the needle or cannula 69 in a predetermined manner. The
plunger 51 is vertically movable in the chamber to eject a
predetermined amount of the sample fluid from the syringe through
the needle 69. Alternatively, the liquid can be drawn into the
syringe barrel 70 through the needle 69 by applying vacuum to the
passageway 68.
A support plate 71 (FIGS. 2 and 5) is secured upon the base 11
transversely thereof and extends upwardly therefrom. A frame 72 is
mounted on the base 11 and comprises a pair of vertical side
members 73 and 74 and an interconnecting cross member 76 (FIG. 1)
secured to the upper ends of the vertical side members 73 and
74.
A drive motor 77 is secured to the right side (FIG. 1) of the
support plate 71 and has a shaft 78 extending therethrough and
secured to a drive sprocket 79. A shaft 81 is rotatably supported
by bearings (not shown) located in the vertical side members 73 and
74 of the frame 72. The left end (FIG. 1) of the shaft 81 projects
through the side member 73 and the support plate 71 and has a cam
82 secured upon the left end thereof. A sprocket 83 is secured to
the shaft 81 between the cam 82 and the support plate 71. Said
sprocket 83 and the sprocket 79 on the shaft 78 have radii rotating
in a common plane. An endless chain 84 interconnects the sprockets
79 and 83 so that the shaft 81 is rotated by the drive motor
77.
A spacing block 86 (FIG. 1) is secured to the support member 71 on
the left side thereof by any convenient means (not shown). The
spacer block 86 projects frontwardly from the front edge of the
support member 71 as is illustrated in dotted lined in FIG. 5 and
has an opening 85 (FIG. 1). A lever 87 is pivotally mounted upon
the spacer block 86 by the bolt 88 received in the opening 85. The
lever 87 is pivotable between the position illustrated in solid
lines and the position illustrated in dotted lines in FIG. 5. A cam
follower 89 is rotatably mounted on the rear end (FIG. 5) of the
lever 87 and is peripherally engaged with the cam surface of the
cam 82 so that rotation of the cam 82 will effect a periodic
vertical movement of the cam follower 89, hence the lever 87, about
the axis of the bolt 88.
A tubular element 91 is gripped by a clamp member 92 which is
secured to the lever 87 by screws 93 (FIG. 1). In this particular
embodiment, the tubular element 91 extends sidewardly and
downwardly from the lever 87 and has a horizontal end portion 97
disposed below, and in line with, the needle 69 of the syringe 52.
An opening 98 is provided in the upper surface of the tubular end
portion 97 so that the needle 69 can discharge liquid into the end
portion across the gap 99 therebetween. A vacuum source VS is
connected to the right end of the tubular element 91, as
schematically illustrated in FIG. 1.
A mounting block 101 (FIG. 5) is secured to the support plate 71 by
any convenient means, not shown. A spring-biased power cylinder 102
is secured to the mounting block 101 and has a rod 103 extending
through an opening 104 in the mounting block 101. A piston 106 is
secured in the usual manner to the rod 103 and is slideable
internally of the cylinder 102. A spring 107 is positioned between
the end of the cylinder 102 and the piston 106 to urge the rod 103
rightwardly (FIG. 5) to the position illustrated in solid lines. A
block 108 is secured to the rear side of the mounting member 17 and
has a recess 109 in the rear face thereof which is alignable with
the front end of the rod 103 for reception of said rod 103 when the
mounting member 17 is in the raised condition. The right end of the
rod 103 is urged into the recess 109 to prevent downward movement
of the mounting plate 17 when there is a failure in the supply of
fluid pressure to the power cylinders of the sample fluid injection
apparatus.
A plurality of cams 111 through 118 (FIG. 1) are secured upon the
shaft 81 and are rotatable therewith. The cams 116 and 118, acting
through valves not illustrated, control the performance of
components of the gas chromatograph and associated devices not
illustrated herein. A plurality of valves 119 through 122 and
switches 123 and 124 are mounted on the upper surface of the cross
member 76 of the frame 72 in line with the cams 111 through 115 and
117, respectively. These valves and switches have roller elements
125 through 130, respectively, which engage the peripheries of the
cams 11 through 115 and 117, respectively. Rotation of the shaft 81
and cams 111 through 115 and 117 will cause movement of the roller
elements 125 through 130 between the positions illustrated in solid
lines and the positions illustrated in dotted lines in FIGS. 11
through 14, 16 and 17. The degree of arc shown on or adjacent each
of the cams 82 and 111 through 115 and 117 represent the angular
distances from the starting position of a cycle of operation
through which the cams must rotate to reach a rise or fall in the
cam surfaces which will effect a movement of the roller elements 89
and 125 through 130. These angles are shown for illustrative
purposes only and are not to be taken as limiting.
The valve 119 (FIG. 1) is connected by a pair of lines 131 and 132
(schematically illustrated by dotted lines) to the power cylinder
30 to supply or return pressure fluid for driving same. The valve
120 is connected through a line 133 (schematically illustrated by
dotted lines) to the safety cylinder 102 (FIGS. 2 and 5). The valve
121 (FIG. 1) is connected through lines 134 and 135 (schematically
illustrated by dotted lines) to the power cylinder 26 (FIG. 2) for
supplying or returning pressure fluid. The valve 122 is connected
through lines 136 and 137 (schematically illustrated by dotted
lines) to opposite ends of the power cylinder 49 to supply or
return pressure fluid. The valves 119, 120, 121 and 122 are all
connected to a source F of pressure fluid by the line 138.
A normally open switch 123 is connected to conventional means (not
shown) to effect a braking of the drive motor 77 whenever the
switch is changed from the open to the closed condition. A normally
open switch 124 is electrically connected to a motor driving the
pump P for controlling the supply of fluid to the chamber 67 from
the source of liquid S.
In this particular embodiment, the apparatus 10 (FIG. 1) has been
designed for use with a gas chromatograph having a vertical column
141 (FIG. 1) with an upwardly facing septum 142 in the upper end
thereof through which the cannula 69 is received.
If desired, a timing mechanism 143 (FIGS. 1 and 2) may be connected
into the circuit of the motor 77 for controlling the time between
cycles of the apparatus during which time the motor 77 remains in
the "off" condition so that the chromatograph will be given the
proper time to complete its analysis of the sample fluid injected
into the column 141 thereof.
The electrical circuit 146 for the apparatus 10 is illustrated in
FIG. 18. Electrical power is supplied to the electrical circuit 146
from lines L1 and L2, which circuit is protected by a fuse 147
connected in series with line L1. The circuit 146 is controlled by
the switch S1.
The components of the timer 143 are enclosed in broken lines and
are positioned for a timing sequence. More particularly, the clutch
solenoid C of the timer 143 is connected in series with the
normally open switch 123, shown closed by the cam follower 129
(FIG. 16), between the lines L1 and L2. A delayed contact switch
148 has an armature 149 movably connected to the terminal 151,
which is connected between the clutch solenoid C and the switch
123. The armature 149 is positioned, in FIG. 18, to connect the
terminal 151 to the terminal 152. Thus, the clock motor M is
connected in parallel with the clutch solenoid C.
One side of the drive motor 77 is connected by line 154 to the line
L1. The other side of the drive motor 77 is conventionally
connected through a conductor 156 to the terminal 153 of the
delayed contact switch 148. A delayed contact switch 157 is
connected in series with a capacitor C1, rectifier CR and load
resistor R between the lines L1 and L2. In the position shown, the
delayed contact switch 157 is in the closed position. A junction
point 158, located between the capacitor C1 and the relay CR, is
connected to terminal 159 of an instantaneous contact switch 161.
The armature 162 of the switch 161 is connected through a conductor
to the terminal 153 of the delayed contact switch 148. In the
condition illustrated for the timer 143, the junction point 158 is
connected through the armature 162 to the conductor 156 of the
drive motor 77 and the terminal 153. A terminal 163 of the
instantaneous contact switch 161 is connected to line L2.
The normally open switch 124, shown closed by the cam follower 130
(FIG. 17), is connected in series with the pump motor P for driving
the pump to supply fluid to the cylinder barrel 70 and chamber 67
therein. While 143 is in the timing sequence, the switch 124 is
closed so that the drive motor for the pump P is energized to
supply a quantity of fluid to the chamber 67.
OPERATION
Although the operation of the above-described apparatus will be
apparent to skilled persons from reading the foregoing description
and examining the accompanying drawings, such operation will now be
briefly summarized. The column 141 (FIG. 1) is part of the
conventional gas chromatograph having a rubber septum 142 which is
penetrated by the needle 69 of the syringe 52.
The rod 103 (FIG. 5) of the cylinder 102 will initially extend into
the pocket 109 before fluid pressure is supplied to the valve 119
through 122 and to the cylinders 26, 30, 49 and 102. That is, the
spring 107 will urge the piston 106 and rod 103 rightwardly to lock
the mounting member 17 in the raised position.
When operating pressure is initially supplied to the system, the
valves 119, 121 and 122 will direct pressure fluid to the power
cylinders 26, 30 and 49, respectively, whereby their rods 27, 38
and 50, respectively, will assume the positions illustrated in
FIGS. 1 and 3. That is, the power cylinder 26 is energized to
maintain the rod 27 (FIG. 3) fully extended so that the mounting
member 17 is maintained in an elevated position to space the needle
69 of the syringe 52 above the septum 142 of the chromatograph
column 141. At this point, however, no pressure is yet applied to
the cylinder 102 from source F, so that the spring 107 is holding
the rod 103 of the cylinder 102 in an extended position to lock the
mounting member 117 in its raised position.
With fluid pressure applied to the system, the rod 38 of the power
cylinder 30 is in the extended position whereby the support plate
37 and the power cylinder 49 are held in a raised position relative
to the mounting member 17. The rod 50 of the power cylinder 49 is
in the retracted position so that the lower end of the plunger 51
is in its highest position "X" (FIG. 10). Thus, the plunger 51
permits communication between the passageway 68 and the chamber
67.
The drive motor 77 is initially deenergized. However, when the
timer 143 reaches a predetermined time in the operating cycle, the
armatures of switches 148 and 157 will be moved by the timer to the
dotted line positions to deenergize the clock motor M. Movement of
the armature 149 from the terminal 152 to the terminal 153 in the
switch 148 will cause the drive motor 77 to become energized
through the closed switch 123, which switch is maintained in the
closed position by the roller element 129 (FIG. 16). Energization
of the motor 77 (FIG. 1) will effect a rotation of the sprocket 79
and endless chain 84 to rotate the sprocket 83 and the shaft 81, as
well as the cams 82 and 111 through 118. Since the switch 123
remains in the closed position for a short period of time, power is
still applied to the clutch solenoid C in the timer 143 thereby
preventing the timer from resetting.
During this stage of the operation, the pump P is in the "on"
condition and is maintained in the on condition by the roller 130
(FIG. 17) engaging the high lobe on the cam 117. After 10 degrees
of rotation of the shaft 81 (FIG. 11) in a clockwise direction, the
cam 111 will permit the cam follower 125 to move to the broken line
position and shift the valve 119 and operate the power cylinder 30
to retract the rod 38 from the position illustrated in FIG. 1 to
the lowered position illustrated in FIG. 7. This will move the
plunger 51 of the syringe 52 to the intermediate position "Y" (FIG.
10) whereby the inlet passageway 68 is blocked from communication
with chamber 67.
Continued rotation of cam 117 for another 5.degree. (or a total of
15.degree.) causes the cam 117 (FIG. 17) to permit a lowering of
the cam follower 130 to the broken line position to open the switch
124 which deenergize the pump motor P. Although the liquid is
restricted from flowing into the chamber 67 while the pump P is
still operating, the pump is shut off before there is any
sufficient pressure developed to rupture the line. The delay in
shutting off the pump also prevents air bubbles from developing in
the liquid.
Continued rotation of the shaft 81 through 20.degree. (a total of
35.degree.) will cause the cam 115 (FIG. 16) to lower the cam
follower 129 to the broken line position (FIG. 16) to effect an
opening of the switch 123 (FIG. 18). The opening of the switch 123
effectively deenergizes the clutch solenoid to reset the timer 143.
Simultaneously therewith, the resetting of the timer 143 causes the
switches 148 and 157 to return to their solid line positions
illustrated in FIG. 18 and the armature 162 of the switch 161 to
move to the dotted line position. Thus, power is still applied to
the drive motor 77 through the terminal 163, armature 162 and line
156 to maintain a continued rotation of the shaft 81. The closing
of the switch 157 completes the circuit so that current will flow
through the rectifier CR to charge the capacitor C1. The purpose of
this will become apparent hereinbelow.
Further rotation of the shaft 81 through 20.degree. (a total of
55.degree.) will cause the cam 82 (FIG. 5) to raise the cam
follower 89 to the broken line position and thereby displace the
tubular end portion 97 (FIG. 15) from beneath the needle 69 of the
syringe 52. The shaft 81 then rotates another 5.degree. (a total of
60.degree.) and thereby causes the cam 112 (FIG. 12) to move the
cam follower 126 to the broken line position to shift the valve 120
to supply pressure fluid to the cylinder 102 to urge the piston 106
leftwardly against the force of the spring 107 to retract the rod
103 from the pocket 109 and thereby unlock the mounting member
17.
Continued rotation of the shaft 81 through 15.degree. (a total of
75.degree.) will cause the cam 113 (FIG. 13) to permit lowering of
the cam follower 127 to the broken line position to shift the valve
121 to operate the power cylinder 26 to retract the rod 27 and
lower the mounting member 17, syringe 52 and needle 69 into their
positions illustrated in FIG. 8, wherein the needle 69 penetrates
the rubber septum 142 of the column 141.
Further rotation of the shaft 81 through 25.degree. (to the
100.degree. position) will cause the cam 114 (FIG. 14) to effect a
lowering of the cam follower 128 to the broken line position
wherein the valve 122 will be shifted to energize the power
cylinder 49 and extend the rod 50 to the position illustrated in
FIG. 9. This will move the plunger 51 from the position "Y" (FIG.
10) to the position "Z" whereby a measured quantity of sample
liquid contained within the syringe will be injected into the
column 141 of the chromatograph.
Additional rotation of the shaft 81 through 30.degree. (to the
130.degree. position) will effect a movement of the cam follower
127 (FIG. 13) back to the sold line position to shift the valve 121
and energize the power cylinder 26 to extend the rod 27 to the
position illustrated in FIGS. 1 and 3. This will raise the mounting
member 17, syringe 52 and needle 69 to disengage the needle 69 from
the rubber septum 142.
A continued rotation of the shaft 81 through 85.degree. (a total of
215.degree.) will cause the cam 82 to move the follower 89 (FIG. 5)
back to the solid line position and thereby place the tubular end
portion 97 (FIG. 15) beneath the needle 69 of the syringe 52.
Simultaneously therewith, the cam follower 126 (FIG. 12) will move
back to the solid line position to cause the valve 120 to cut off
the supply of pressure fluid to the cylinder 102 whereby the spring
107 urges the end of the rod 103 into the pocket 109 to lock the
mounting member 17 against vertical movement.
Continued rotation of the shaft 81 through 20.degree. (a total of
235.degree.) will cause the cam 114 (FIG. 14) to raise the cam
follower 128 to the solid line position thus operating the valve
122 and thereby activating the power cylinder 49 which moves the
rod 50 to the position illustrated in FIG. 1 and thereby rotates
the plunger 51 to the position "Y" of FIG. 10.
Further rotation of the shaft 81 through 15 degrees (a total of
250.degree.) will cause the cam 111 (FIG. 11) to raise the cam
follower 125 to the solid line position to shift the value 119 and
operate the power cylinder 30 to extend the rod 38 to the FIG. 1
position. This will move the plunger 51 of the syringe 52 to its
highest position "X" illustrated in FIG. 10 whereby the inlet
passageway 68 again communicates with the chamber 67.
Simultaneously therewith, the cam follower 130 (FIG. 17) will move
back to the solid line position to close the switch 124 (FIG. 18)
to energize the pump motor P to move liquid through the inlet
passageway 68, the chamber 67 and the needle 69. The discharge
liquid will be directed into the opening 98 in the portion 97 of
the tubular element 91 and exhausted therefrom by the vacuum
VS.
Continued rotation of the shaft 81 through 100.degree. (a total of
350.degree.) will cause the follower 129 (FIG. 16) to move back to
the solid line position to close the switch 123 (FIG. 18) to start
the timer 143. Simultaneously with the starting of the timer 143,
the armature 162 of the switch 161 will be moved by the timer to
terminal 159 so that power is discontinued to the drive motor 77
and the capacitor C1 is discharged into the drive motor 77 to
dynamically brake same in a well-known manner.
The gas chromatograph will continue to perform its analyzing
function on the sample liquid injected therein in a conventional
manner. This analyzing process and the operation of the apparatus
10 can vary in time depending upon the type and quantity of sample
liquid injected into the column, as well as the type of tests that
are being conducted on the sample liquid. The timing mechanism 143
can be adjusted accordingly to provide ample time to permit a
complete test to be conducted on the sample liquid injected into
the column. At the completion of the predetermined test time set
into the timer 143, the above-described operation can be repeated
on a new sample liquid sequentially.
The foregoing description and operation have been directed to an
apparatus 10 designed for use with an upright column 141 having a
septum 142 at the upper end. Thus, it is at least advantageous to
provide an apparatus for moving the syringe vertically. However,
some chromatographs have sidewardly opening septums. In such case,
the apparatus 10 can be positioned on its side and, with minor
modifications, adapted to move the needle 69 sidewardly.
The apparatus 10 can be adapted to obtain liquid samples,
intermittently, from a plurality of containers presented
sequentially and periodically to a position below the needle 69. In
such case, the needle 69 would, at least intermittently, be
connected by the passageway 68 to a source of reduced pressure so
as to withdraw a sample from a container presented to it.
Thereafter, the sample would be discharged into the column 141, as
discussed above. In order to clean the syringe between samples, the
syringe would be connected by the passageway 68, acting through
valve means (not shown), to a pressurized source of cleaning liquid
which would be discharged through the needle and into the end
portion 97 of the tube 91, as described above.
It may be advantageous to use a vacuum system to both purge the
syringe with a cleaning solution and thereafter draw a sample
liquid into the syringe because the quantity of sample required
will be only enough to fill the chamber 67 and needle 69. However,
in the case of the pressure system the amount of sample required is
several times the volume of the chamber 67 in order to effectively
purge the previous sample from the chamber and needle.
Although a particular preferred embodiment of the invention has
been disclosed in detail for illustrative purposes, it will be
recognized that variations or modifications of the disclosed
apparatus, including the rearrangement of parts, lie within the
scope of the present invention.
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