U.S. patent number 3,603,954 [Application Number 05/010,848] was granted by the patent office on 1971-09-07 for gas alarm device.
This patent grant is currently assigned to New Cosmos Electric Company Limited. Invention is credited to Tutaharu Takeuchi.
United States Patent |
3,603,954 |
Takeuchi |
September 7, 1971 |
**Please see images for:
( Certificate of Correction ) ** |
GAS ALARM DEVICE
Abstract
A detecting element for inflammable gases which includes a pair
of electrodes formed of a relatively nonoxidizable material which
are supported in spaced relationship by an intervening member
having parallel grooves for receiving the coils and to which the
coils are fixed at least in part and a metal oxide semiconductor
covering said electrodes and intervening member.
Inventors: |
Takeuchi; Tutaharu (Osaka-fu,
JA) |
Assignee: |
New Cosmos Electric Company
Limited (Osaka-shi, JA)
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Family
ID: |
11899907 |
Appl.
No.: |
05/010,848 |
Filed: |
February 12, 1970 |
Foreign Application Priority Data
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|
|
|
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Feb 22, 1969 [JA] |
|
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44/15836 |
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Current U.S.
Class: |
340/634;
73/31.06; 338/34; 324/71.5; 422/98 |
Current CPC
Class: |
G01N
27/12 (20130101); G08B 17/117 (20130101) |
Current International
Class: |
G01N
27/12 (20060101); G08B 17/10 (20060101); G08B
17/117 (20060101); G08b 021/00 (); H01c
013/00 () |
Field of
Search: |
;340/237 ;338/34
;23/232E,254E ;73/23,25-27 ;324/71SN |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
T Seiyama et al.; Analytical Chemistry; Vol. 38, No. 8; Pages
1069-1073; July, 1966 copy in Art Unit 171.
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Primary Examiner: Caldwell; John W.
Assistant Examiner: Myer; Daniel
Claims
What is claimed is:
1. An inflammable gas detector comprising a pair of coiled
electrodes formed of a metal that is relatively stable at high
temperatures, a body of heatproof electrically insulating material
having a pair of opposing edges thereon, means securing a portion
of the periphery of each electrode to one of said opposing edges
and a metal oxide semiconductor enclosing said body and electrodes
with the ends of said electrodes extending therefrom, the
resistance of said semiconductor when at a high temperature
changing in value in the presence of an inflammable gas.
2. An inflammable gas detector according to claim 1 wherein said
opposing edges of said body having cylindrical concave grooves and
portions of the peripheries of said electrodes are secured in said
grooves by a high melting point bonding agent.
3. An inflammable gas detector according to claim 3 including a
stem of insulating material and supports carried by said stem, and
wherein the ends of said electrodes are secured to said
support.
4. An inflammable gas detector according to claim 3 including a
metal mesh surrounding at least part of said element and secured to
said stem.
5. An inflammable gas detector according to claim 1 including a
transformer having at least one winding with terminals at the ends
thereof and a voltage tap, means connecting one electrode to one
terminal and the tap to energize said electrode and means including
a buzzer connecting the other electrode to the other terminal of
said winding.
6. An inflammable gas detector according to claim 5 wherein said
buzzer comprises a pole piece, a coil surrounding said pole piece,
a yoke of magnetic material magnetically coupled to one end of said
pole piece, a diaphragm secured at one end to said yoke and
extending in spaced overlying relationship to the other end of said
pole piece and means engaging said diaphragm to modify the spacing
between it and said pole piece.
7. An inflammable gas detector according to claim 5 including a
housing enclosing said element, transformer and buzzer, said
housing including an opening for admission of air to said metal
oxide semiconductor enclosing said electrodes and a skirtlike wall
surrounding said housing and in spaced relationship thereto, said
wall forming with said housing a resonant chamber for increasing
the level of sound produced by said buzzer.
Description
This invention relates to a device for the detection of gases and
generating an alarm in response thereto. More specifically the
device is particularly useful for the detection of inflammable
gases as well as the detection of carbon monoxide which may be
produced at the time of a fire.
It has been found that a particular form of metal oxide
semiconductor when heated exhibits a variation in electrical
resistance when in contact with an inflammable gas. For example a
gas detecting element may be arranged with two electrodes in the
form of helical coils wound in spaced relationship on a helical
bobbin of a heatproof insulating material. The two coils and the
surface of the bobbin are then coated with a metal oxide conductor.
With this structure, however, the characteristics of the finished
product may not be uniform because of the displacement of the wires
which occurs during assembly. In some cases the wires may contact
one another or may slide off the bobbin. To overcome these
difficulties extreme care must be exercised during assembly. In
order to avoid displacement of the wires a glass like bonding
material may be used to fix the wires to the surface of the bobbin,
but the bonding agent tends to adhere to the wires covering them
wholly or in part with the result that a good electrical connection
between the wires and the metal oxide conductor cannot be
obtained.
One object of the invention resides in the provision of an improved
gas detecting element structure which will afford uniform
characteristics and at the same time simplify manufacture. The
improved detecting element in accordance with the invention
includes two helically wound coil electrodes formed of a metal
which is relatively nonoxidizable at a high temperature, and a
block of heatproof electrical insulating inorganic material having
concave grooves on two side faces with the radius of the grooves
conforming with the peripheral surfaces of the electrodes. An
inorganic high melting point bonding agent is used to fix the
electrodes to the concave grooves of the block. The structure is
then embedded in a metal oxide semiconductor to form in effect a
unitary structure. In this way the electrodes are permanently fixed
to the insulating block by a bonding agent, even though the bonding
agent may cover part of the electrodes, a major portion of the
electrodes are in good electrical contact with the semiconductor.
Furthermore, the spacing between the electrodes is maintained
constant and accordingly, the characteristics of the finished
products are uniform.
With the invention as described above, the coiled electrodes are
permanently fixed to the insulating block during assembly and
accordingly cannot move one relative to the other during the
manufacturing process with the result that the manufacture is
greatly facilitated. Furthermore, the bonding agent for bonding the
coiled electrodes to the insulating block and baking of the
semiconductor can be performed very simply by passing an electric
current through the electrodes of the assembled structure so that
complicated heating furnaces generally required are not
necessary.
A still further object of the invention resides in the provision of
an improved mount for the detecting element. As previously
mentioned, the detecting element does not have to be heated in a
furnace and accordingly, does not require the utilization of a
heatproof stem. With this invention an inexpensive synthetic resin
stem can be employed and further a normal organic bonding agent can
be utilized for sealing the envelope and the stem. This results in
a still further reduction in manufacturing costs. In a preferred
embodiment of a gas alarm circuit for use with the detecting
element in accordance with this invention, heater current is
supplied from a tap on the autotransformer to one of the coiled
electrodes in order to heat the electrode to a proper operating
temperature which is generally lower than the treating temperature
at the time of manufacture. Normal operating temperatures are
within the range of 50.degree. C. to 300.degree. C. The primary
voltage of the transformer is applied between the heated electrode
and the unheated electrode through a buzzer or other suitable
device for generating an alarm. If an inflammable gas is not
present in material quantities in the air, the current traversing
the semiconductor of the element is insufficient to cause operation
of the buzzer. When the quantity of inflammable gas exceeds a
predetermined limit, the current flowing through the semiconductor
increases and causes the buzzer to operate. The buzzer may
preferably be of a structure wherein the spacing between the
magnetic pole piece and the vibrating element is adjustable in
order to fix the minimum threshold current for operation of the
buzzer. Because of some irregularities of the detection
characteristics of the detecting element and because of variations
in the secondary voltage of the autotransformer, some variation in
sensitivity of the assembled circuit will be experienced. However,
by adjusting the buzzer as mentioned above the alarm circuits can
be arranged to have uniform resultant sensitivity.
A preferred embodiment of a container for the gas alarm device
utilizing a detecting element in accordance with the invention
includes a main body for containing the alarm circuit and a
skirtlike resonator extending from the side face of the main body.
An opening is formed in the body for the admission of air to the
detecting element housed within the body. By utilizing the
skirtlike resonator, a relatively weak sound produced by the buzzer
which is directly driven by the detecting element can be greatly
enhanced. Furthermore, the resonator can be used as a container for
the power cord for supplying power to the alarm circuit.
The above and other objects of the invention will become more
apparent from the following description and accompanying drawings
forming part of this application.
In the drawings:
FIG. 1 is a perspective view of a detecting element in accordance
with the invention;
FIG. 2 is a cross-sectional view of the structure shown in FIG.
1;
FIG. 3 is a side elevational view in partial section of a detector
mount in accordance with the invention;
FIG. 4 is a circuit diagram of an alarm system utilizing the
invention;
FIG. 5 is a plan view of the base plate of the alarm structure
showing the positioning of the various components;
FIG. 6 is a side elevational view of an adjustable buzzer utilized
with the invention;
FIG. 7 is a plan view of a housing for the structure shown in FIG.
5;
FIG. 8 is a perspective view of the housing shown in FIG. 7;
FIG. 9 is a bottom view of the housing with the structure of FIG. 5
removed; and
FIG. 10 is a cross-sectional view taken along the line 10--10 of
FIG. 7.
The gas detecting element in accordance with this invention and
illustrated in FIGS. 1 and 2 includes a pair of coils 1 and 2 made
of a metal wire such as platinum, palladium, or platinum-iridium
alloy which does not oxidize readily at high temperatures. These
coils are contained within cylindrical concave grooves 4 and 5 on
opposite faces of the block 3, the latter being made of a heatproof
electrically insulating inorganic oxide such as Al.sub.2 O.sub.3,
SiO.sub.2, or BeO. These coils are fixed in part to the faces of
the grooves 4 and 5 by an inorganic high melting point bonding
material 6 and 7 of a glassy substance consisting of a solid
solution of Na.sub.2 O and one or more elements selected from the
group consisting of K.sub.2 O, CaF.sub.2, Al.sub.2 O.sub.3, Ba.sub.
2 O.sub.3, and SiO.sub.2. In so doing the coils are maintained in
precise parallel relationship. It will also be observed that the
coils 1 and 2 are embedded in the bonding agents 6 and 7 only in
the portions contained within the respective grooves so that the
major portions of the coils remain exposed. The block 3 and the
coils 1 and 2 are then embedded in a metal oxide semiconductor
material 8 which is sensitive to inflammable gas at a high
temperature and the resultant assembly is in the form of a
blocklike structure. The ends of the coils 1 and 2 extend from
opposite faces of the block 8 and are denoted by the numerals 9,
10, 11 and 12.
The metal oxide semiconductor material 8 may be SnO.sub.2, ZnO,
Nb.sub.2 O.sub.5, Ta.sub.2 O.sub.5, TiO.sub.2, or Fe.sub.2 O.sub.3.
When the semiconductor material heated to a temperature of
50.degree. C. to 300.degree. C. contacts an inflammable gas, the
gas removes oxygen ions from the semiconductor material and thus
oxidizes the semiconductor material. Thus the balance between the
cations and the anions within the semiconductor material is upset
and the resistance of the material will therefore be changed.
The detecting element is preferably formed in the following matter.
The lead wires 9, 10, 11 and 12 of the coils 1 and 2 are fixedly
connected to four posts 13, 14, 15 and 16 which are secured to and
extend through a stem 17 of plastic or other good insulating
material. This procedure positions the coils in a predetermined
spaced parallel relationship. The insulating block 3 having grooves
4 and 5 coated with the high melting point bonding agents 6 and 7
is then placed between the coils 1 and 2 with a portion of a
periphery of the coils being seated within the grooves 4 and 5. A
current is then passed through the supports 13 and 14 and the
supports 15 and 16 to heat the coils and in turn melt the bonding
agents so that the coils 1 and 2 will become fixed within the
grooves of the block 3. The coils 1 and 2 and the block 3 are then
coated by a nonsintered material consisting of a gas sensitive
oxide. A current is then passed through the coils to sinter the gas
sensitive oxide and thus complete the fabrication of the element.
As the heater current of the element during normal use is
materially below the current required for heat treatment during
manufacture, neither the bonding agent nor the oxide material will
be affected during actual use.
FIG. 3 illustrates a method particularly useful for supporting the
gas sensitive element. As pointed out above, the stem 17 is formed
of a suitable plastic and the supports 13, 14, 15, and 16 extend
through the stem. The portions of the supports protruding from the
lower face of the stem are utilized for making external
connections. A cylindrical container 18 is formed of a metal mesh
and the upper end is closed by a metal cap 19. The stem includes an
upper portion 20 of reduced diameter and a lower portion 21 of an
enlarged diameter. An annular groove 22 is formed in the lower
portion 21 and the metal mesh container 18 extends over the stem
portion 20 and is suitably bonded in the annular groove 22.
Referring now to FIG. 4, which illustrates a circuit embodying the
gas detecting element described above, the numeral 23 denotes a
pair of power source terminals to which the power cord 24 as shown
in FIG. 5 is attached. Alternating current energy of the order of
100 volts to 200 volts is applied to the cord for operation of the
circuit. One of the terminals 23 is connected through a fuse 25 to
the terminal 35 of an autotransformer 26 while the other terminal
23 is connected to the other terminal 31 of the autotransformer. A
pilot light 27 in the form of a neon discharge tube is connected in
series with the resistor 28 and in parallel with the terminals 31
and 35 of the autotransformer. One of the coils 30 of the detecting
element generally denoted by the numeral 29 is connected between
the terminals 31 and 32 of the autotransformer, the latter terminal
being a tap to provide the desired low voltage to the coil 30. The
ends of the second coil 33 of the detecting element 29 are
connected one to the other and to the terminal 35 of the
autotransformer through the buzzer or other suitable alarm 34. If
the voltage applied to the autotransformer is relatively high as
for example approximately 200 volts, the autotransformer may be
provided with a second tap for attachment of the buzzer 34 in order
to apply the proper voltage to the buzzer. The components of the
circuit of FIG. 4 are assembled on a printed circuit base plate 36
as illustrated in FIG. 5, and the wiring of FIG. 4 is printed on
the back surface of the base plate. Holes 37 and 38 are used for
mounting the base plate in the gas detector.
In the circuit as described above, when the terminals 23 are
connected to a source of alternating current power, the neon tube
27 will be illuminated and at the same time a low voltage will be
supplied to the coil 30 of the detecting element 29 in order to
heat the element to a temperature of 50.degree. C. to 300.degree.
C. Although at this time a relatively high alternating current
voltage is also applied through the buzzer 34 to the coils 30 and
33, and if the air surrounding the detector 29 does not contain an
inflammable gas, the current flowing between the coils 30 and 33
will be too small to actuate the buzzer. When an inflammable gas
does contact the detector 29, it will cause a relatively large
current to flow between the coils 30 and 33 which in turn causes
the buzzer to operate.
The buzzer, as will be explained, is adjustable to compensate for
slightly varying characteristics of detecting elements 29 and
slight variations of the voltage produced by the autotransformer.
In this way, sensitivity of the device can be adjusted.
FIG. 6 illustrates a buzzer 34 which comprises an iron pole piece
41 having a magnetizing coil 39 mounted thereon. The pole piece 41
is secured at one end to the yoke 40 and is positioned at one end
of the yoke. The other end of the yoke 40 carries a diaphragm 42
made of thin iron which is secured to the yoke by screws 43 and 44.
The free end of the diaphragm 42 extends over the pole piece 40 and
forms a narrow gap between the end of the pole piece. An adjusting
screw 45 extends through the diaphragm at a point near the
supported end and the lower edge of the screw 45 abuts the bottom
of the yoke 40. With this arrangement, rotation of the adjusting
screw will modify the spacing between the diaphragm 42 and the pole
piece 41 and thereby modify the sensitivity of the buzzer to the
magnetizing current applied to the coil 39. In this way, adjustment
of the sensitivity of the buzzer will compensate for irregularities
in the characteristics of the detecting element 29 as well as the
variations in the secondary voltage of the autotransformer. Thus
substantially the same sensitivity can be obtained for all alarm
devices. Moreover, the adjustment is relatively simple and is
accomplished by means of a single screw 45.
FIGS. 7 through 10 show the case or housing for the alarm circuit
as described above. The case includes a main body portion 46 which
is provided with a bottom closure 47. The top surface of the body
46 has an opening carrying a red transparent material 48. A
peripheral flange 49 extends outwardly from a point approximately
midway of the side walls of the main body 46 and the flange carries
a downwardly and outwardly extending skirt 50 which skirt
terminates generally in the same plane as the bottom cover 47 as
will be observed more clearly in FIG. 10. An elongated slot 51 is
formed in one corner of the body 46 and at a point adjoining the
top side of the flange 49. Within the main body 46 a detecting
chamber 53 is formed by a partition wall 52 and this chamber is
positioned at the corner of the body 46 containing the gap 51. The
bottom end of the partition wall 52 terminates below the bottom
edge of the main body 46. The corner of the main body opposite the
corner enclosed by the partition 52 has a shoulder disposed in
substantially the same plane as the bottom edge of the partition
52, and the enclosed corner is also provided with a similar
shoulder. The shoulders are threaded to receive screws 59 and 60.
In addition, the bottom edge of the main body 46 is also provided
with a slot 56. It is preferable that the main body 46, the flange
49 and skirt 50 are formed integrally of a strong resistant
material such as acrylobutadiene-styrol resin (ABS resin). The
cover 47 is formed of similar material and is provided with a ridge
adjoining the peripheral edge portion of its inner surface. It also
includes a pressure sensitive bonding agent 58 on the back surface
and at opposing corners which include holes through which the
screws 59 and 60 will extend.
The structure shown in FIG. 5 is then inserted in the main body 46
as shown in FIG. 10 with the detector 29 entering the compartment
formed by the partition wall 52. The cover 47 is then placed in
overlying relationship and the assembly is secured in place by
screws 59 and 60 as shown in FIG. 9. The neon tube 27 is positioned
adjoining the indicating window 48 and the circuit base plate 36 is
supported by the partition wall 52 as well as the shoulders 54 and
55. The ridges 57 of the cover hold the base plate in position and
the cord 24 extends outwardly through the cutout 56.
While only one embodiment of the invention has been illustrated and
described, it is apparent that alterations, modifications and
changes may be made without departing from the true scope and
spirit thereof as defined by the appended claims.
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