U.S. patent number 3,603,471 [Application Number 04/879,232] was granted by the patent office on 1971-09-07 for septum valves.
This patent grant is currently assigned to Precision Sampling Corporation. Invention is credited to Rano J. Harris, Jr., Rano J. Harris, Sr..
United States Patent |
3,603,471 |
Harris, Sr. , et
al. |
September 7, 1971 |
SEPTUM VALVES
Abstract
Apparatus for containing fluids, i.e., liquids or gases, within
a confined space. In one embodiment, the apparatus comprises a
valve structure including a tubular member (with axial opening)
which leads into an enclosed space which can contain fluid. A
septum, and a stem, provided with a lateral opening therethrough,
are integrally mounted or mounted in series. The stem is rotatably
mounted within the wall of the tubular member for exposure of the
septum to the valve exterior. Exposure of the septum in such manner
permits injection or withdrawal of fluid from the enclosed space.
In preferred embodiments, the septum is located within an axial
opening through the valve stem and lies across the lateral opening
of the stem to provide an effective leakproof seal. In other
embodiments, the septum is contained within the tubular member in
series with the stem. The valve, in all embodiment, is adaptable
for use with containers of various types or for use in sample inlet
systems, as conventionally used in modern analytical
instruments.
Inventors: |
Harris, Sr.; Rano J. (Baton
Rouge, LA), Harris, Jr.; Rano J. (Baton Rouge, LA) |
Assignee: |
Precision Sampling Corporation
(N/A)
|
Family
ID: |
25373694 |
Appl.
No.: |
04/879,232 |
Filed: |
November 24, 1969 |
Current U.S.
Class: |
215/247; 215/313;
604/236; 604/415; 422/913; 215/DIG.3; 604/86; 604/244; 422/940 |
Current CPC
Class: |
A61M
5/31 (20130101); B01L 3/5082 (20130101); F16K
13/00 (20130101); B01L 3/508 (20130101); Y10S
215/03 (20130101) |
Current International
Class: |
A61M
5/31 (20060101); F16K 13/00 (20060101); B01L
3/14 (20060101); B01L 3/00 (20060101); B65d
051/00 () |
Field of
Search: |
;215/37,38,76,DIG.3
;128/214,214.4,215,218NV,272,DIG.5 ;73/425.6 |
References Cited
[Referenced By]
U.S. Patent Documents
|
|
|
3198368 |
August 1965 |
Kirkland et al. |
|
Foreign Patent Documents
Primary Examiner: Reeves; Robert B.
Assistant Examiner: Shannon, Jr.; John P.
Claims
Having described the invention, what is claimed is:
1. A valve for containing fluids within a confined space
comprising, in combination,
a tubular member formed by an enclosing wall providing an axial
opening therethrough, the wall of said member also containing a
lateral opening,
a septum which lies across, covers and seals the axial opening
through the said tubular member,
a stem provided with a lateral opening therethrough rotatably
mounted within the lateral opening in the wall of said tubular
member
whereby rotation of said stem to align the lateral opening of the
stem and the axial tubular opening provides access for withdrawal
and injection of fluids by penetration of the septum, after which
time misalignment of said openings closes the valve and limits such
exposure for maximum confinement of the fluids within the confined
space.
2. The apparatus of claim 1 wherein the septum is contained within
an axial opening provided in the rotatable stem.
3. The apparatus of claim 1 wherein the septum and stem are in
series.
4. The apparatus of claim 3 wherein the septum constitutes the
outer member of the series.
5. The apparatus of claim 1 wherein the lower portion of the valve
is flanged, the outer peripheral edge of the flange is recessed and
contains an O-ring.
6. The apparatus of claim 5 wherein the O-ring is constructed of
rubber.
7. The apparatus of claim 5 wherein a container is secured to the
valve via an open-centered cap, the tubular portion of the valve
being extended through the opening in the center of the cap, while
the flanged portion is held in place atop the contained via
threadable engagement between the cap and the top of the container,
and whereby the downward pressure exerted by the cap causes
extrusion of the O-ring against the internal surfaces of the cap
and upon the lower portion of the flange to press the latter
downwardly to seal the container.
8. The apparatus of claim 1 wherein the valve is provided within a
sample inlet system.
9. The apparatus of claim 1 wherein the valve is constructed of a
self-lubricating type of rigid plastic, with the exception of the
septum which is of rubber.
10. The apparatus of claim 9 wherein the rigid plastic is Teflon.
Description
This invention relates to apparatus for containing fluids, i.e.,
liquids and gases, or both, within a confined space. In all
combinations, the apparatus includes valves, with seal features,
adapted especially for use in confining fluids until such time as
it is desired to withdraw fluid from or inject other fluid into the
confined space, e.g., a container or sample inlet system such as is
widely used in modern analytical instruments.
Among the objects of this invention are:
To provide a valve which makes the confinement of even highly
volatile fluids feasible, without adverse effect or change caused
by the external environment.
To provide a valve not only effective for preventing such adverse
effect or change, or loss of fluid from a confined space when
closed, but yet effective even when the valve is opened, or used
repeatedly, to permit withdrawal or injection of fluid into the
space within which it is confined.
To provide unique valve container combinations by virtue of which
even highly volatile fluids can be contained without adverse
effect, change or loss of contents from the container, even after
repeated usage, and wherein the fluid withdrawn therefrom is truly
representative of that originally supplied to the container.
To provide unique valve sample inlet system combinations by virtue
of which fluid specimens can be injected therein conveniently,
easily and without loss of fluid.
To provide such valve container, and valve sample inlet
combinations which are readily adapted for reuse by virtue of
easily changeable septum portions.
To provide valves and valve combinations, the valve portions of
which contain stems readily freely rotatable or movable without
side thrust within the tubular portion of the valve, or body, and a
valve which is compact and readily operated, without
lubrication.
These and other objects will be apparent in view of the present
invention which, in all embodiments, includes a valve structure
comprising a body, or tubular member, which leads into a space
wherein fluids can be confined, and which contains a septum and
stem integrally mounted, or mounted in series. The stem, provided
with a lateral opening therethrough, is rotatably mounted within
the wall of the tubular member to provide a means for exposure of
the septum to permit injection or withdrawal of fluid from the
confined space. The valve, but for the presence of the septum, is
thus opened and closed by alignment and misalignment of the lateral
opening of the stem with the axial opening through the tubular
member to expose the septum located adjacent the stem, or
preferably within the stem itself. In either instance, the septum
acts as a fluid impervious seal to maximize closure of the tubular
member, even when the valve is open for fluid withdrawal or
injection.
These and other features and advantages will be better understood
by reference to the following detailed description and to the
accompanying drawings to which reference is made in the
description.
Referring to the drawings:
FIG. 1 is a side elevation view, in section, showing a preferred
valve, and valve-container combination. The valve, shown in open
position, is provided within a stem within which an easily changed
septum is integrally mounted;
FIG. 2, a fragmentary view, is also a sectional side elevation view
identical to the preceding figure except that the valve is shown in
closed position; and
FIG. 3, also a fragmentary sectional side elevation view, is the
same as FIG. 1 except that the septum has been punctured by the
needle of a syringe for withdrawal of liquid contents from the
container;
FIG. 4 depicts a valve generally similar, at least in part, to that
described by reference to the preceding figures except that, in
this instance, the valve is employed as a portion of a sample inlet
system, e.g., as used on a G.C. column or mass spectrometer;
FIGS. 5 and 6 depict the sequence of simple steps involved in
changing a septum as employed in the several apparatus combinations
described in the foregoing figures;
FIGS. 7 and 8 depict valve portions wherein the septum is located
adjacent, separate from, and in series with the stem.
Referring to the sequence represented by FIGS. 1-3, there is shown
generally a preferred type of flanged valve 10 in combination with
a container or bottle 26, filled to a level 25 with a volatile
liquid composition.
The valve 10 is constructed of a body or tubular member formed by
the enclosing wall 11, providing an axial opening 12 which leads
into the vapor space above the liquid level 25. A stem 14, provided
with a handle 17 and a lateral opening 15, is rotatably mounted
within the transverse opening 13 of wall 11. The stem 14, in this
embodiment, is also provided with an axial opening 18 within which
is contained a plug septum 16 which lies across, seals off, blocks,
or closes the transverse opening 15.
For use in valve-container combinations, the lower portion of the
tubular member 11 is also provided with a flanged end portion
containing a peripheral groove 23 within which rests a packing or
O-ring 21. The O-ring 21 is pressed between the upper side 19 and
the lower thin member 22, and pressure is maintained on the O-ring
21 by tightening down on the open centered cap or cover 24 which is
threadably engaged to the top of the bottle 26. Thus, it is to be
observed that the upper side 19 of the flanged member is pressed
downward by the cap 24, and the O-ring 21 is compressed between
member 19 and member 22, shown as an integral construction in this
instance, which rests atop the upper rim 27 of bottle 26. In this
fashion, the O-ring 21 is extruded or thrust outwardly and
downwardly against the inside of the cap 24 and thin member 22, so
that the latter presses against the rim 27 of bottle 26 to form an
effective leakproof seal.
In the closed position of the valve 10 as shown by reference to the
first figure, the fluid contents of the bottle 26 are maintained
completely isolated from the external environment. Highly volatile
fluids, and mixtures of such fluid components, will retain their
original composition and condition without significant change as
would be expected even when such fluids are loaded and contained in
ordinary bottles or containers. Such high degree of isolation can
even be maintained in accordance with the present invention,
however, even after the bottles have been once opened, or
repeatedly opened.
The structure which permits removal of contents from the bottle 26
without exposure to the atmosphere is further described by
reference to FIGS. 2 and 3. Stem 14 is first rotated through a
90.degree. angle, by action on handle 17 as shown by specific
reference to FIG. 1. The contents of the bottle 26 nonetheless
remain protected from exposure to the atmosphere because of the
presence of the septum 16. In this position of the valve stem,
however, a needle syringe 20 can be passed through the septum 16
and into the liquid for withdrawal of a fluid specimen as shown in
the third figure. The needle 20 can be withdrawn back through the
septum which in itself tends to return to its original unstretched,
unruptured position to minimize or prevent leakage of fluid from
the bottle 26. Immediately after the withdrawal of fluid, the valve
is again closed as again shown by reference to FIG. 2 to protect
the fluid contents. This process can be repeated ad infinitum until
the bottle 26 has been emptied. The elimination of changes brought
about by entry of air into such containers, escape of highly
volatile components as by diffusion and pressure increases,
particularly as occurs after such bottles or containers are once
opened, is striking. This is particularly important with regard to
standard fluids used in highly accurate modern analytical
instruments.
Valves of generally the same type can also be directly used in
sample inlet systems of modern analytical instruments. This is
shown by reference to FIG. 4 wherein a valve 30 is mounted upon a
sample inlet system, represented by the enclosing wall 28. The
sample inlet system is, in turn, provided with an optional carrier
gas inlet formed by the enclosing wall 29. Rotation of the stem 34,
to the position shown, via action upon handle 37 aligns the lateral
opening 35 with the opening 32, formed by the enclosing section of
wall 31, of the sample inlet system. The needle portion of a
syringe (not shown), containing a measured fluid specimen, can be
passed through the septum 36 and sample injected into the
passageway where it is picked up by carrier gas fed into the inlet
system via conduit 29. Escape of fluid is minimized, and
essentially completely eliminated upon closure of valve 30. A
unique feature of this embodiment for application to sample inlet
systems is that the septum can be readily changed without
disassembly of the sample inlet.
The simple technique by which septums can be changed in the
embodiments represented by FIGS. 1 through 4, inclusively, is shown
and described by reference to FIGS. 5 and 6. The plug septum 36 is
thus pushed out of the opening 38 by action of the new replacement
plug septum 36.sub.1 and cylindrical rod 9. When the septum 36 is
extended from the opening 38, it is easily removed with the fingers
and the cylindrical rod 9 is withdrawn, leaving the new septum
36.sub.1 in position.
The septum, if desired, can also be mounted in series separate and
apart from the rotatable stem itself as shown, e.g., by reference
to FIGS. 7 and 8. In these figures are thus shown rotatable stems
44, 54 mounted in tubular members 41, 51 such as may constitute the
valve portion of a valve container or valve inlet system
combination. In the former, the septum 46 is seated and held in
place by an open centered extremely threaded member 45 which is
engaged with an internally threaded counterbore contained within
the top of member 41. In the latter the septum 56 is seated and
held in place within a space provided in an internally threaded
member 55, the threads of which mate with external threads on the
member 51. In these embodiments it is apparent that the order of
the stem and septum can be reversed, but preferably the septum
components are located outwardly from the stem in the series. In
passage of the needle through the septums, the stem is rotated to
open the valve, and at all other times, as in changing the septums,
the valves are closed.
The apparatus of the present invention can be constructed of
essentially any material substantially inert to chemical or
corrosive action by the fluid, or contained elements. The valve can
be conveniently constructed of various metals, e.g., ferrous metals
such as iron, iron alloys, steel, stainless steels, and the like;
or e.g., glass, brass, copper, bronze, chrome, and the like. The
materials can be solid or of laminar construction, and can be
provided with a protective film, coated, plated, or the like,
particularly those films known to be unreactive or impervious to
known chemicals. Rigid and semirigid forms of plastics and
plasticlike materials can also be employed, these materials being
particularly desirable. The self-lubricated plastics are especially
preferred in this capacity, and are also suitable for application
in the form of protective films. The polyfluorinated ethylene
polymers, notable among which is polytetrafluoroethylene (Teflon),
are particularly outstanding.
The septums are constructed of conventional septum materials,
resilient or elasticlike materials such as natural or synthetic
rubber, gasket materials and the like.
It is apparent that various changes, such as in absolute or
relative dimensions of the parts, materials used, and the like, as
well as the suggested mode of withdrawing or delivering fluids, can
be made without departing the spirit and scope of the invention, as
will be apparent to those skilled in this art.
* * * * *