U.S. patent number 3,601,471 [Application Number 04/803,918] was granted by the patent office on 1971-08-24 for durable first surface silver high reflector.
This patent grant is currently assigned to Optical Coating Laboratory. Invention is credited to Richard Ian Seddon.
United States Patent |
3,601,471 |
Seddon |
August 24, 1971 |
DURABLE FIRST SURFACE SILVER HIGH REFLECTOR
Abstract
Durable first surface silver reflector having a layer of silver
which is undercoated and overcoated in such a manner as to give the
layer excellent adhesion to the substrate and which is also
provided with a multilayer dielectric coating to give the coating
an ability to withstand high humidity salt spray and the like.
Inventors: |
Seddon; Richard Ian (N/A,
CA) |
Assignee: |
Laboratory; Optical Coating
(CA)
|
Family
ID: |
25187753 |
Appl.
No.: |
04/803,918 |
Filed: |
March 3, 1969 |
Current U.S.
Class: |
359/584; 428/333;
428/450; 156/325; 428/336 |
Current CPC
Class: |
C03C
17/3649 (20130101); C03C 17/3615 (20130101); C03C
17/3621 (20130101); C03C 17/3644 (20130101); G02B
5/0858 (20130101); C03C 17/36 (20130101); C03C
17/3657 (20130101); C03C 17/3652 (20130101); Y10T
428/265 (20150115); C03C 2217/78 (20130101); Y10T
428/261 (20150115) |
Current International
Class: |
G02B
5/08 (20060101); C03C 17/36 (20060101); G02B
005/28 () |
Field of
Search: |
;350/163-166 ;156/325
;161/4,196,207 ;117/35V |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
2Baumeister, F. W.; "Multilayer Filters," Volume 7, Notes for
summer Course at the Institute of Optics, University of Rochester,
Mil-HDBK-140; Rec'd. 4-1964, Copy in Gp. 259, pp.-Cover Sheets
20-69, 70, 71, 81, 82 and 83..
|
Primary Examiner: Schonberg; David
Assistant Examiner: Sherman; Robert L.
Claims
I claim:
1. In a durable first surface silver high reflector, a substrate
having a first surface, a layer of silver of sufficient thickness
so that it is substantially opaque to visible light, an adhesion
layer deposited on said surface of said substrate and serving as an
undercoat for said layer of silver to secure said layer of silver
to said substrate, a multilayer dielectric coating carried by the
substrate and overlying the silver layer and a substantially
transparent bonding layer serving as an overcoat on said silver
layer and serving to bond said multilayer dielectric coating to
said silver layer.
2. A reflector as in claim 1 wherein said multilayer dielectric
coating is formed of a plurality of layers, certain of said layers
being formed of materials which exert compressive forces after they
have been evaporated onto a surface and certain of the other layers
being formed of a material which exerts tensile forces after it is
evaporated onto a surface.
3. A reflector as in claim 3 wherein said multilayer dielectric
coating has a thickness ranging from 0.2 to 0.6 microns.
4. A reflector as in claim 2 wherein said multilayer dielectric
coating is formed of a plurality of layers arranged as LHLHHL in
which the letter L represents a low index material and H represents
a high index material, each of said layers having an optical
thickness of approximately one-fourth of the design wavelength.
5. A reflector as in claim 2 wherein said multilayer dielectric
coating is formed of a plurality of layer arranged as LH in which
the letter L represents a low index material and H represents a
high index material, each of the layers having an optical thickness
approximately one-fourth of the design wavelength.
6. A reflector as in claim 2 wherein said multilayer dielectric
coating consists of a plurality of layers designated as LHL in
which the letter L represents a low index material and H represents
a high index material, each of the layers having an optical
thickness of approximately one-fourth of the design wavelength.
7. A reflector as in claim 1 wherein said adhesion layer is formed
of a chromium nickel alloy.
8. A reflector as in claim 1 wherein said bonding layer is formed
of a metal oxide.
9. A reflector as in claim 4 wherein said low index material is
magnesium fluoride and said high index material is fused
silica.
10. A reflector as in claim 1 wherein a multilayer dielectric
coating is formed of at least two different materials in which one
of the materials exerts compressive forces after evaporation and
the other of said materials exerts tensile forces after evaporation
and in which the layers are arranged so that the net stress is
relatively low.
11. A reflector as in claim 10 wherein one of the materials is
fused silica and the other material is magnesium fluoride and
wherein the layers have a thickness so that the multilayer
dielectric coating is formed of more fused silica than magnesium
fluoride.
12. A reflector as in claim 11 where the reflectivity is over 90
percent from 400 millimicrons to 21/2 microns.
13. A reflector as in claim 1 wherein said bonding layer is as thin
as possible so that it absorbs substantially no energy consistent
with the requirement that it be a continuous layer.
14. A reflector as in claim 8 wherein said metal oxide is an oxide
of titanium which is as thin as possible so that it absorbs
substantially no energy consistent with the requirement that it be
a continuous layer.
Description
BACKGROUND OF THE INVENTION
Heretofore silver has been utilized as a reflector but it has
suffered from severe environmental limitations. For example, the
adhesion to the substrate has been very poor and the silver coating
was easily scratched so that it was virtually uncleanable. In
addition, in a humid atmosphere, such a coating was found to
oxidize with a consequent loss in reflectivity. The use of
overcoatings in such situations has not been satisfactory because
such overcoatings, when thick, have had a tendency to give rise to
poor adhesion and when relatively thin, serving to give little
protection to oxidation in a humid atmosphere. There is, therefore,
a need for a new and improved silver reflector.
SUMMARY OF THE INVENTION AND OBJECTS
The durable first surface silver high reflector consists of a
substrate which has a first surface. An adhesion layer is deposited
on the first surface. A layer of silver is deposited on the
adhesion layer and is of a sufficient thickness so that it is
opaque to visible light. A multilayer dielectric coating is
deposited over the silver layer and serves as a protective
layer.
In general, it is an object of the present invention to provide a
durable first surface silver high reflector which has excellent
adhesion to the substrate and which has the ability to withstand
abrasion, salt, fog and the like.
Another object of the invention is to provide a silver high
reflector of the above character in which the silver layer has
excellent adhesion to the substrate and wherein the dielectric
overcoating has excellent adhesion to the silver layer.
Another object of the invention is to provide a silver high
reflector of the above character in which crazing or poor adhesion
are not present.
Additional objects and features of the invention will appear from
the following description in which the preferred embodiment is set
forth in detail in conjunction with the accompanying drawing.
BRIEF DESCRIPTION OF THE DRAWING
FIG. 1 is a cross-sectional view of a silver high reflector
incorporating the present invention.
FIG. 2 is a curve showing the reflectivity of a silver high
reflector incorporating the present invention.
BRIEF DESCRIPTION OF THE PREFERRED EMBODIMENT
As shown in FIG. 1, the silver high reflector 11 consists of a
substrate 12. The substrate 12 can be formed of suitable material
such as metal, glass and the like. It is preferably formed of a
rigid material. The substrate 12 is provided with a first surface
13. An adhesion layer 14 is deposited on the surface 13 in a
conventional manner such as by evaporating the material in a
vacuum. One material found to be particularly satisfactory is
"Inconel" which is a chromium nickel alloy. Alternatively, it can
be a material such as chromium. The principal characteristic for
the adhesion layer 14 is that it be one to which silver will
readily adhere. The thickness of the layer 14 is not critical and
therefore, any desired thickness can be utilized. For example, it
has been found that a physical thickness in the order of 50
millimicrons is adequate.
A layer 16 of silver is then deposited upon the adhesion layer 14
in a suitable manner such as by evaporating silver in a vacuum
chamber. It has been found to obtain the best adhesion to the layer
14, that is is desirable to bond or deposit the silver layer on the
layer 14 while the layer 14 is still "fresh." By "fresh" is meant
within a period of a few seconds after the coating has been
deposited. In fact, it has been found that it is desirable to
commence the evaporation of the layer 16 just prior to completion
of the layer 14. Thus, in practice, it has been found that it is
best to commence evaporation of the silver layer 16 immediately
before or immediately upon conclusion of the evaporation of the
material for making the layer 14. The silver layer 16 is evaporated
to a thickness which is just sufficient to be opaque to visible
light. The silver layer is quite soft and, therefore, it is
desirable to keep the silver layer as thin as possible and still
obtain the desired reflectivity.
It can be seen that the layer 14 serves as an undercoating for the
silver layer 16 to secure firm adhesion of the silver layer to the
substrate 12. An overcoating in the form of a layer 17 is deposited
on the top side of the silver layer 16 and serves to bond a
multilayer dielectric coating 18 to the silver layer 16. The layer
17 is preferably formed of a very thin layer of a metal oxide. One
material found to be particularly satisfactory is titanium monoxide
evaporated in an oxygen atmosphere. However, other materials can be
utilized such as zirconium oxide, cerium oxide, aluminum oxide and
magnesium oxide, etc., or mixtures of these oxides. The layer 17
should be as thin as possible consistent with the requirement that
it be a continuous layer. When this layer 17 becomes too thick, it
absorbs energy and, therefore, causes a loss in reflectivity of the
silver layer 16. The layer 17, in addition to serving as a bonding
layer, serves as a moisture-resistant layer and, therefore,
provides humidity protection to prevent oxidation of the silver
layer.
The layer 18 is a multilayer dielectric coating which has been
designed to provide a low residual stress. In order to provide such
a coating, it has been found desirable to provide a plurality of
layers which have a combined physical thickness ranging from 0.2 to
0.15 microns. By way of example, one such multilayer dielectric
coating had the following design:
LHLHHL
in which the letter L stands for a layer formed of a low index
material, and H stands for a layer formed of a high index material.
Magnesium fluoride having an index of refraction of 1.38 was used
for the low index material, and fused silica having an index of
refraction of 1.46 was used for the high index material. These
layers were deposited in a conventional manner in a vacuum chamber.
Under normal deposition conditions, the magnesium fluoride layers
assume internal tensile stresses and the fused silica layers assume
internal compressive stresses. The net stresses of the combined
layers which form the multilayer dielectric coating 18 are
sufficiently low so that the multilayer dielectric coating can be
supported by the relatively weak silver layer 16.
The particular multilayer dielectric coating set forth above is
also advantageous because it provides interference reinforcement of
the silver reflectivity in the blue spectrum region (400-450
millimicron region).
It should be pointed out that use of high and low index materials
for the multilayer dielectric coating is not particularly
significant in and of itself. The principle characteristic for the
two materials is that one material counterbalances the stresses in
the other so that there is relatively little net stress placed on
the silver coating 16. When the tensile and compressive forces of
the two materials equalize each other, there is provided a strong
multilayer coating. Each of the layers of the multilayer dielectric
coating 18 has an optical thickness which is one-fourth of the
design wavelength, or, in other words, has a thickness of
approximately 0.4 microns quarter-wave optical thickness.
In making the multilayer dielectric coating 18, it is desirable
that the total physical thickness of the fused silica be equal to
or greater than that of the magnesium fluoride. This is desirable
because the tensile stresses in vacuum evaporated magnesium
fluoride tend to be greater than the compressive stresses in fused
silica and, therefore, in order to prevent crazing or poor adhesion
it is desirable there be at least as much fused silica as magnesium
fluoride.
A curve showing the results which can be obtained with a silver
high reflector incorporating the present invention is shown in FIG.
2. Curve 21 shows the percent of reflectance for a silver high
reflector made in accordance with the present invention in
comparison to a curve 22 for a conventional aluminum reflector with
a silicon monoxide overcoat. As can be seen, the reflectivity of
the silver high reflector is over 90 percent and consistently
higher than the aluminum reflector throughout the entire wavelength
range (400 millimicrons to 21/2 microns) considered and at certain
wavelengths by as much as 20 percent higher. The design wavelength
for the silver high reflector shown in FIG. 2 was 400
millimicrons.
Although magnesium fluoride and fused silica have been disclosed as
being useful for making the multilayer dielectric coating 18, other
materials not quite as satisfactory may be utilized. For example,
other forms of silicon dioxide can be used in place of the fused
silica. In place of the magnesium fluoride, sapphire and possibly
zirconium oxide can be utilized.
Another alternative arrangement for the multilayer dielectric
coating 18 is to utilize a layer of magnesium fluoride followed by
a thicker layer of silicon dioxide which is followed by another
thin layer of magnesium fluoride. Such a coating had a design
wavelength of 450 millimicrons and because it was reduced to three
layers is of lower cost.
It can be seen that such a silver high reflector has many
advantages. It has excellent reflectivity. In addition, it has
substantial abrasion resistance. Also, it is capable of
withstanding salt, fog and humidity tests without oxidizing the
silver layer. The silver high reflector has excellent reflectivity
in all regions of the spectrum. The coating is also one which can
be produced relatively simply and inexpensively.
* * * * *