U.S. patent number 3,599,679 [Application Number 04/769,678] was granted by the patent office on 1971-08-17 for inextensible filamentary structure and fabrics woven therefrom.
This patent grant is currently assigned to Monsanto Company. Invention is credited to Ernest P. Carter.
United States Patent |
3,599,679 |
Carter |
August 17, 1971 |
INEXTENSIBLE FILAMENTARY STRUCTURE AND FABRICS WOVEN THEREFROM
Abstract
Strands of brittle, highly inextensible filamentary material are
collimated into a bundle and spot bonded at regular intervals with
an epoxy resin or the like, to form a composite yarn structure
having sufficient flexibility and mechanical stability to permit
the yarn to be woven as the warp of a fabric, the fill yarn being
any conventional fibrous material. The inextensible filamentary
materials include, among others, boron, boron carbide, silicon,
silicon carbide, carbon, quartz, and similar inorganic refractory
fibers which are characterized by high strength and modulus,
brittleness, and inextensibility.
Inventors: |
Carter; Ernest P. (Durham,
NC) |
Assignee: |
Monsanto Company (Saint Louis,
MO)
|
Family
ID: |
25086207 |
Appl.
No.: |
04/769,678 |
Filed: |
October 22, 1968 |
Current U.S.
Class: |
139/420R;
385/115; 428/373; 57/251; 428/198; 428/375 |
Current CPC
Class: |
D03D
15/00 (20130101); D03D 15/513 (20210101); D02G
3/40 (20130101); D03D 15/593 (20210101); D03D
15/47 (20210101); D10B 2211/02 (20130101); Y10T
428/24826 (20150115); D10B 2101/20 (20130101); D10B
2401/062 (20130101); D10B 2401/063 (20130101); Y10T
428/2929 (20150115); Y10T 428/2933 (20150115); D10B
2101/06 (20130101); D10B 2201/02 (20130101) |
Current International
Class: |
D03D
15/12 (20060101); D03D 15/00 (20060101); D03d
015/00 (); D02g 003/12 (); D02g 003/36 () |
Field of
Search: |
;139/420,42C,426
;57/140,14C,14B,139,153 ;161/142,143,175,179,172 ;28/75 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
Business Week Production-Weaving Tough Fabric with a New Dimension,
Aug. 31, 1968 pgs. 84 & 86 copy in GR 352.
|
Primary Examiner: Kee Chi; James
Claims
I claim:
1. A method of preparing a composite multifilament structure of
inorganic inextensible fibers characterized by high strength
modulus, brittleness, limited flexibility and essentially zero
elongation suitable for use as the warp yarn in weaving
inextensible fabrics which comprises:
a. collimating a plurality of inextensible filaments into a compact
bundle in a parallel and substantially untwisted relationship to
form a continuous filamentary structure, said filaments having a
tensile strength of at least 50 thousand p.s.i. and an elastic
modulus of at least 4 million p.s.i., said filaments being a
composite filament comprised of tungsten wire core and a sheath
selected from the group consisting of boron and boron carbide,
b. applying a bonding agent to the surface of the filaments in
spots at regular intervals along the longitudinal axis of the
continuous filamentary structure, said bonding agent being a member
selected from the group consisting of acetate, polyester,
polyamide, polyimide, phenolic alkyd acrylic and epoxy resins,
and
c. maintaining the compact bundle of inextensible filaments in a
fixed position until the bonding agent is hardened and the
integrity of the filament bundle is assured.
2. The method of claim 1 wherein the bonding agent is applied at
intervals of from about 0.5 to about 12 inches along the
longitudinal axis of the continuous filamentary structure.
3. The method of claim 1 wherein the number of inextensible
filaments comprising the bundle is from three to about seven.
4. A composite filamentary structure comprised of a plurality of
substantially parallel, substantially untwisted and closely
compacted highly inextensible monofilaments bonded in spots at
regular intervals along the length thereof with an adhesive
material, said filaments having a tensile strength of at least 50
thousand p.s.i. and an elastic modulus of at least 4 million
p.s.i., said filaments being a composite filament comprised of
tungsten wire core and a sheath selected from the group consisting
of boron and boron carbide; said adhesive material being a member
selected from the group consisting of acetate, polyester,
polyamide, polyimide, phenolic alkyd and epoxy resins.
5. A woven fabric having fill yarns and warp yarns, said fill yarns
being a flexible textile material, said fill yarns being selected
from the group consisting of glass, cotton, wool and organic
manmade fibers, and each of said warp yarns being a composite
filamentary structure comprised of a plurality of substantially
parallel, substantially untwisted and closely compacted highly
inextensible monofilaments bonded in spots at regular intervals
along the length thereof with an adhesive material, said filaments
having a tensile strength of at least 50 thousand p.s.i. and an
elastic modulus of at least 4 million p.s.i., said filaments being
a composite filament comprised of tungsten wire core and a sheath
selected from the group consisting of boron and boron carbide, said
adhesive material being a member selected from the group consisting
of acetate, polyester, polyamide, polyimide, phenolic alkyd,
acrylic and epoxy resins.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to a method of weaving fabrics from brittle
and highly inextensible filamentary materials. More particularly,
this invention relates to a method for forming a composite yarn
structure from inorganic refractory fibers and utilizing this
composite as the warp yarn in weaving a fabric.
2. Description of Prior Art
Recent developments in the field of high strength, temperature
resistant materials have included the use of inorganic refractory
fibers such as boron, boron nitride, boron carbide, silicon,
silicon carbide, alumina, alumina-silica, carbon, glass, and quartz
to fabricate reinforced composite structures having outstanding
stiffness and strength-to-weight ratios. These inorganic refractory
fibers are characterized by high strength modulus, brittleness,
limited flexibility, and by essentially zero elongation as defined
by the term "inextensible."
Although many of these refractory fibers are presently available
only in short lengths or as whiskers, efforts are being made to
produce the materials in continuous filament form. Continuous
filament boron formed by the vapor deposition of boron on a fine
wire tungsten substrate is now commercially available.
High-strength reinforced structures are generally fabricated either
by filament winding or by sheet layup. In filament winding, strands
of reinforcement are oriented directly onto surfaces which control
their form. In sheet layup, the strands are first formed into
sheets, and the sheets are laid up and laminated to provide the
desired form and orientation. While these methods are useful,
composites made by these processes do not possess the
cross-reinforcement provided by a woven structure. For this reason
it is desirable to prepare woven fabrics of the inextensible
materials as reinforcement for composite structures.
Although the art of weaving is ancient, the inextensible and
brittle nature of the inorganic refractory fibers makes it
extremely difficult to weave these materials in a conventional
manner. Conventional textile yarns have a reasonable amount of
elongation due to the intrinsic properties of the fibers used and
due to the generally twisted yarn structure. Consequently, such
yarns are capable of absorbing energy to fairly high strain levels,
without breaking. They may also be bent to very short radii of
curvature without damage.
Filaments of the inorganic refractory fibers presently available
conform to none of these conditions. The high filament modulus, in
combination with a relatively large filament diameter, results in a
gross stiffness and consequent fabrication difficulties. Since the
bending moment of a circular rod is proportional to the fourth
power of the radius of the rod, it is apparent that the intrinsic
stiffness of the material is augmented by its geometry. Attempts at
weaving individual monofilaments into the warp of a fabric have
resulted in frequent breakage of the brittle filaments. A method
for handling and weaving these materials was clearly needed if the
advantages of the woven fabric in reinforced composited structures
were to be obtained.
SUMMARY OF THE INVENTION
It has been discovered that a multiplicity of high modulus, high
strength, brittle, and highly inextensible filaments may be
collimated into a bundle and spot bonded at regularly spaced
intervals to hold the bundle as a unit for further processing. The
preferred bonding agent is an epoxy adhesive or cement, although
any of several suitable resins may be employed.
The inextensible filaments which may be used in the practice of
this invention are the inorganic refractory fibers which have a
tensile strength of at least 50,000 p.s.i. (pounds per square inch)
and an elastic modulus of at least 4 million p.s.i. Included among
others are boron, boron nitride, boron carbide, silicon, silicon
carbide, alumina, alumina-silica, carbon, and quartz. The filament
may also be a composite structure consisting for example of a
tungsten wire core with a sheath of boron, boron carbide, or
titanium diboride.
The bonded bundles can be handled with relative ease and can be
woven into tapes, ribbons, or fabrics using the bundles as warp
ends. The advantage of the bundle structure arises from the freedom
of the component filaments to move with respect to the others,
particularly in bending, and to assume a position of minimum
strain. Furthermore, should one or more individual filaments be
broken, the unity of the bundle is maintained by the points of
bonding.
The frequency of the spot bonding intervals can be varied to suit
filament length. Thus, for bonding long continuous strands of
filamentary material, the spot may be spaced several inches apart,
while for bonding shorter lengths, the spots may be only one inch
or less apart.
As stated above, epoxy resins are preferred as the bonding agent
because of their high strength and ability to dry and cure into a
hard, smooth, nontacky bond. Other bonding agents in the form of
cements, adhesives, etc. which can be used with good results
include, for example, acetate, polyester, polyamide, polyimide,
phenolic alkyd, and acrylic resins. Generally, it is preferred to
select the bonding agent to be compatible with the intended end use
of the final inextensible fabric. In other words, if the final
fabric is to be used to form an epoxy bonded laminate structure,
where several layers of the fabric are impregnated with an epoxy
resin and cured while held in a desired structural configuration,
then it would be logical and desirable to use the same or similar
epoxy resin as the spot bonding agent in forming the original
composite yarn structure.
In some instances, where the presence of a foreign substance may be
undesirable in the final fabric, the bonded yarn may be woven into
the fabric and the bonding material subsequently removed by washing
with a solvent.
Collimated bundle fabrics made from high modulus, high strength,
brittle, and highly inextensible filaments may be incorporated in
resin matrices to produce high performance composite. The
reinforcing filaments are present in high density, and their
intrinsic filament properties are unimpaired by the geometry of the
fabric. Therefore, the composite has a high strength to weight
ratio, high modulus, and high stiffness.
Filling yarns for weaving the collimated bundle warp fabric may be
selected from a wide variety of available materials including
glass, cotton, wool, and organic manmade fibers. If the transverse
properties of the fabric reinforcement in the ultimate composite
are not critical, it is convenient to use synthetic organic fiber
yarns such as nylon, polyester, the acrylics, or polyolefin. If,
however, the transverse properties are of consequence, high
performance synthetic organic fibers, glass, quartz and other
available materials may be used.
DESCRIPTION OF THE DRAWING
FIGS. 1, 2 and 3 show three typical cross-sectional views of the
spot bonded composite yarn structure. The inextensible filaments
are designated by the numeral 10, while the bonding material is
designated by numeral 12.
FIG. 4 shows a representative side view of a spot bonded composite
yarn structure produced in accordance with the instant
invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
In the practice of the present invention, a plurality of the
inextensible inorganic refractory fibers are collimated into a
bundle and bonded together in a parallel and substantially
untwisted relationship by spot bonding the bundle with an adhesive
material at regular intervals to maintain its integrity. Generally,
the bundle will be comprised of from three to seven essentially
continuous inextensible monofilaments of 100 yards or greater
length. The bundle may also be comprised of an arrangement of an
inextensible filaments having shorter lengths of from about 2 to
about 8 inches or longer. Generally, 2 inches is the practical
minimum length which can be used in accordance with this
invention.
For ease of handling, and for superior product characteristics, the
continuous monofilaments are preferred. Excellent results are
obtained using the commercially available filaments produced by
vapor deposition of boron on the very fine tungsten wire substrate.
These filaments have a tensile strength of about 400,000 p.s.i., an
elastic modulus of about 60 .times. 10.sup.6 p.s.i., and an upper
temperature limit of about 2000.degree. C. in an inert atmosphere.
Three to seven of these composite monofilaments bonded at regular
intervals of about 6 to 12 inches or so are easily handled and can
be used as warp ends to weave a fabric having in the warp direction
the same high strength and modulus as the boron-tungsten
filaments.
The bonding material may be applied to the filaments by hand or
automatically by machine. It is only required that provision be
made to first of all collimate the filaments into a compact bundle,
and second, to hold the bundle in a fixed relationship while the
adhesive is applied and cured.
The bonded composite yarns can be handled with relative ease and
with little danger of breaking any of the inextensible filaments if
reasonable precautions are taken to avoid folding or bending the
yarn about a very small radius. Although the composite yarns are
generally used as warp ends in constructing the fabric, they may
also be used as fill if it is preferred. In this case, the
inextensible filaments are most conveniently cut to a length
corresponding to the width of the fabric, and individually placed
through the warp shed during the weaving process. When using the
inextensible filaments as fill, it is generally advisable to use a
flexible textile yarn as the warp.
The following examples will serve to further illustrate the
invention.
EXAMPLE 1
Three ends of continuous boron-tungsten sheath-core composite
monofilament 8 mils in diameter were collimated into a bundle and
spot bonded with drops of epoxy cement applied at 12 inch
intervals. The epoxy bonds were dried and cured by heating with a
stream of hot air. A woven fabric was prepared by using 80 bundles
of the bonded composite yarn per inch of width as warp ends and a
single 189 denier fiberglass yarn as the fill. The resulting fabric
was completely flexible in the fill direction and sufficiently
flexible in the warp direction to bend around a 2-inch radius
material with no fracture of boron filaments.
EXAMPLE 11
Seven boron-tungsten monofilaments were spot bonded at 6 inch
intervals with an epoxy resin according to the procedure of Example
I. The composite was very flexible and easily woven into a fabric
having 40 braid covered bundles per inch as warp ends with a single
189 denier fiberglass yarn as fill. The lightweight fabric had
excellent flexibility.
It will be apparent from the foregoing description and examples
that this invention provides a novel method for preparing yarns and
fabrics from highly inextensible filamentary materials. As many
widely different embodiments of this invention may be made without
departing from the spirit and scope thereof, it is to be understood
that this invention is not to be limited to the specific
embodiments thereof except as defined in the appended claims.
* * * * *