U.S. patent number 3,595,486 [Application Number 04/879,322] was granted by the patent office on 1971-07-27 for treatment of granular solids by fluid energy mills.
This patent grant is currently assigned to Fluid Energy Processing & Equipment Company. Invention is credited to Nicholas N. Stephanoff.
United States Patent |
3,595,486 |
Stephanoff |
July 27, 1971 |
TREATMENT OF GRANULAR SOLIDS BY FLUID ENERGY MILLS
Abstract
A method of treating solid particles by propelling jets of
elastic fluid, such as gas or vapor, in selected lateral directions
against a circulating vortex of particles entrained in similar
elastic fluid to selectively propel a larger proportion of the
particles toward or away from an outlet positioned adjacent the
inner peripheral portion of the vortex.
Inventors: |
Stephanoff; Nicholas N.
(Haverford, PA) |
Assignee: |
Fluid Energy Processing &
Equipment Company (Hatfield, PA)
|
Family
ID: |
25373902 |
Appl.
No.: |
04/879,322 |
Filed: |
November 24, 1969 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
607974 |
Jan 9, 1969 |
3491953 |
Jan 27, 1970 |
|
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Current U.S.
Class: |
241/24.1;
241/5 |
Current CPC
Class: |
B02C
19/063 (20130101) |
Current International
Class: |
B02C
19/06 (20060101); B02c 019/06 () |
Field of
Search: |
;241/5,39 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Kelly; Donald G.
Parent Case Text
This is a division of copending application Ser. No. 607,974, filed
Jan. 9, 1967 now issued as U.S. Pat. No. 3,491,953, dated Jan. 27,
1970.
Claims
The invention I claim is:
1. In a method of treating solid particles whereby the particles
are subjected to the turbulent action of elastic fluid under
pressure and are thereafter propelled in a circulating vortex
through a classification area where the lighter particles in the
inner peripheral portion of the vortex are separated from the
heavier particles in the outer peripheral portion of the vortex and
pass through an outlet adjacent said inner peripheral portion, the
step of propelling jets of elastic fluid in selected lateral
directions against said vortex to selectively propel a larger
proportion of said particles toward and away from said outlet.
2. In the method of claim 1, the step of secondarily separating
lighter from heavier particles in the product passing through said
outlet.
3. In the method of claim 2, the step of recycling the secondarily
separated heavier particles back to be resubjected to the turbulent
action of said elastic fluid.
4. In the method of claim 2, the step of applying an additional
material for selective chemical and physical interaction with the
secondarily separated particles.
5. In the method of claim 1, the step of applying an additional
material for selective chemical and physical interaction with said
particles prior to their initial subjection to the turbulent action
of said elastic field.
Description
This invention relates to the treatment of solid granular materials
by subjecting them to the action of moving gases or vapors in an
enclosed mill, referred to generally as a fluid energy mill, and it
particularly relates to the control of such gases or vapors to
selectively vary the size, shape and other characteristics of the
particles of such materials.
The so-called fluid energy mills have various inherent
characteristics. For example, they have no moving parts in the
actual treating zones. Therefore, when they are used for grinding
or pulverizing, only the material is in motion and the grinding is
effected by impacts between the particles themselves and between
the particles and the walls of the mill. There is, therefore, no
overheating due to the friction of moving parts. In fact, the
finished product is often cooler than the material fed into the
mill, or than the gas or vapor (hereafter referred to as the
elastic fluid) used as the energizing medium. One reason is that
the elastic fluid expands as it is expelled from the expanding gas
nozzle, there is an exothermic Joule-Thompson effect, and the
impacts between the particles generate less heat than the cooling
due to the fluid expansion. This is the usual effect with most
elastic fluids such as air, oxygen, nitrogen, steam and water
vapor, carbon dioxide, etc. Hydrogen appears to be an exception to
the rule because the inversion of the Joule-Thompson effect occurs
at -112.degree. F., and any flow through the nozzle at temperatures
above this point produces heating. The treatment, whether it be
grinding, chemical reaction, coating or merely dispersing of
adherent particles, can be carefully controlled by using different
fluids, or combinations of fluids, to effect a desired degree of
cooling or heating. Inert gases are preferably used to prevent
chemical reactions, coating deposits, etc., during grinding or
dispersing of the particles. Selected fluids are, on the other
hand, utilized at controlled temperatures to obtain hydration,
dehydration, oxidation, mixing, blending, coating, or any other
desired chemical or physical reaction.
The expansion effect of the elastic fluids in fluid energy mills
also makes them extremely well adapted for injection mold
processes. In this respect, many natural and synthetic plastics and
resins are extremely hydroscopic even at room temperature. In the
usual injection molding process, the materials must, therefore, be
preheated to expel the moisture prior to introducing them into the
injection feeder. This not only necessitates an extra step
involving additional apparatus, time and labor, but may sometimes
deleteriously affect the materials themselves. However, when fluid
energy mills are used to prepare the materials for injection
molding, most of the moisture is expelled due to the low relative
humidity of the expanded gases and to the fact that the finely
ground particles have so much of their surfaces exposed that the
adherent moisture usually found in the interstices between the
particles is open to the action of the expanding gases. For
example, if air is compressed on a warm summer day at 80.degree.
F., and 90 percent relative humidity, a pound of this air will
contain about 140 grains of water. But if this air is compressed to
100 p.s.i.g. pressure, and cooled to 70.degree. F., then one pound
of the air can hold only 14 grains of water, while 126 grains, or
90 percent of the moisture, appears as water and can be removed
before entering the mill. Now, when the air is expanded in the mill
to approximately atmospheric pressure, it will still have only 14
grains of water per pound, but at atmospheric pressure it will have
only 13.5 percent relative humidity. This extremely dry air will
not deposit any moisture unless it is cooled below 20.degree. F. As
a result, the resin or other material will be quite dry and will
not produce any blistering such as so often occurs in injection
molding processes where too much moisture is present in the
material. It is to be noted that since the mill is an enclosed
system, no outside moisture or dirt can contaminate the finished
product.
An important consideration in ground or pulverized particles is the
shape and size of the particles. Both the shape and size of the
particles depend on the inherent characteristics of the fluid
energy mills and are a function of the type of material used, the
type of elastic fluid used, the directional velocity of the fluid,
the accelerative motion of the fluid, the temperature in the mill,
etc.
When the direction of the elastic fluid stream from the nozzle is
at an angle of about 40.degree. relative to the direction of flow
in the mill, there is a balance between the highest induced flow of
the circulating stream in the mill and the most efficient grind,
thereby obtaining the most satisfactory separation at the outlet
from the mill, which generally extends in a reverse direction from
the direction of flow in the mill. Under these conditions, the
particle-loaded nozzle streams impact the circulating load at a
fairly sharp angle, and the resulting cracked particles appear to
roll in the manner of pebbles in a fast-flowing stream. This
results in relatively round, smooth, discrete particles. This is an
important characteristic for such polymeric materials as "Teflon"
(tetrafluoroethylene), "Nylon" (polyamides), polystyrene, etc. The
smooth, somewhat flattened particles, without an excess of extreme
fines, gives the smoothest finish after molding.
In grinding very tough, resilient plastics such as "Teflon" and
"Nylon," which do not fracture easily, it has, in accordance with
the present invention, now been bound preferable to use a separator
or secondary classifier in stream with the primary mill, whereby
the secondary classifier is selectively controlled to reject
particles over a predetermined size but to pass those under such
size to a collector. The oversized particles are automatically
returned to the primary mill for further grinding. Those particles
that do pass into the secondary classifier are whirled in
stratified layers, causing them to be further rounded and polished.
This has been found to be particularly effective with such
materials as Ceylon flake graphite and artificial graphite.
If it is desired to produce products having sharper edges and less
roundness, the nozzle angles are increased accordingly, as, for
example, to 50.degree. or 60.degree.. With such angles of impact,
the collisions are more direct and the particles shatter rather
than abrade. It is, furthermore, possible to obtain a combination
of particle types, i.e., some shattered and some abraded, by using
a plurality of fluid nozzles and reversing one or more of them up
to 180.degree. against the main circulatory stream in the mill.
This may also be utilized to vary the size of the particles from
close to 0 microns to about 100--150 microns or more. This is
desireable in some cases, as, for example, in the grinding of
cement or fillers, because the smaller particles fill the voids
between the larger particles.
It is, therefore, one object of the present invention to provide a
method which is highly effective in treating solid particles to
obtain any desired shape and size of finished particle size and any
desired chemical or physical reaction or interaction.
Another object of the present invention is to provide a method
which is adapted to selectively obtain any desired shape and size
of particles and any desired chemical or physical reaction or
interaction.
Other objects and many of the attendant advantages of this
invention will be readily appreciated as the same becomes better
understood by reference to the following description when read in
conjunction with the accompanying drawing wherein the single FIGURE
of drawing is a somewhat diagrammatic side elevational view of an
apparatus embodying the present invention.
In accordance with the present method, jets of elastic fluid, such
as gas or vapor, are propelled against a circulating vortex of
particles entrained in similar elastic fluid, to selectively propel
a larger proportion of the particles toward or away from an outlet
positioned adjacent the inner peripheral portion of the vortex.
Referring in greater detail to the drawing wherein similar
reference characters refer to similar parts, there is shown a fluid
energy mill, generally designated 10, having a curved lower inlet
or treating section 12 integral with an upstack 14 that is, in
turn, integral with a curved upper classifier section 16. The
classifier section 16 is integral with a return duct or downstack
18 that leads back into the inlet section 12. An outlet duct or
primary classifier 20 leads from the lower end of the classifier
section to a conduit 22 which is, in turn, tangentially connected
to a chamber 24 comprising the upper section of a secondary
separator or classifier, generally designated 26.
Adjacent to, but in opposed relation to the entrance of the duct 20
are a pair of flow-diverting nozzles 28 and 30 extending from a
common manifold 32 having a manually operable valve 34. The nozzles
28 and 30 direct fluid toward the top and bottom of the entrance to
duct 20. The valve 34 is connected to a source of elastic fluid
under pressure (not shown). Another flow-diverting nozzle 36 is
provided at the upper bend between the section 16 and duct 20. This
nozzle 36 is positioned to direct fluid to bypass the duct 20 and
direct it toward the downstack 18. The nozzle 36 is connected to a
manual valve 38 connected to the source of elastic fluid (not
shown). A two-way valve (not shown) is provided at the source to
direct the flow either toward nozzles 28 and 30 or toward nozzle
36. There may also be provided a valve means of standard design
(not shown) to vary the pressure or velocity of the fluid from the
source, or the pressure or velocity may be varied in any other
manner known to the art.
By selectively directing jets of fluid through either nozzles 28
and 30 or nozzle 36, and by selectively varying the pressure or
velocity of these jets, more of the larger particles on the outer
periphery of the circulating flow can be directed toward the outlet
duct 20 by nozzles 28 and 30 or more of the finer lighter particles
on the inner periphery of the circulating flow can be bypassed away
from the outlet duct into the downstack 18 by nozzle 36. The
nozzles 28, 30 and 36 can also be made inoperative merely by
closing off their respective valves 34 and 38 to permit normal
circulatory flow. If the nozzles 28 and 30 are in use, there will
be a larger proportion of larger particles removed from the mill
through duct 20, whereas if the nozzle 36 is in use, there will be
a larger proportion of smaller particles since substantially all
the larger particles will be recycled through the downstack 18 for
further grinding. An increased velocity of the jets from the
diverting nozzle 36 also increases the velocity of the circulating
particles through the downstack and adds to the kinetic energy of
these particles as they impact each other and entering new
particles in the inlet or grinding chamber 12, thereby causing a
greater grinding effect. The nozzles 28 and 30, on the other hand,
when the velocity of their jets is increased, increase the velocity
of the stream flowing into the chamber 24 of the secondary
classifier 26.
A feed inlet 40 (illustrated as a simple chute, but which may be
any desired form of feed means) is provided between the lower end
of the downstack 18 and the inlet chamber 12. Just below the feed
inlet 40 is a bridging conduit 42 leasing form the upper end of the
inlet chamber 12 to the lower or nozzle portion 44 of a cone-shaped
lower chamber 46 of the secondary separator-classifier 26. This
conduit 42 is provided with a Venturi passage 48 and is positioned
in opposed relation to a nozzle 50 connected to a source of elastic
fluid under pressure (not shown).
At the lower end of the mill 10 is provided a plurality of fluid
nozzles 52. These nozzles 52 are each in the form of an individual
ball positioned in a ball socket. The ball nozzles 52 each have a
handle 53 that can be used to rotate the ball through angles of
about 120.degree. to direct the nozzles individually in all
increments of angular direction from about 30.degree. in the
direction of flow through the chamber 12 to about 30.degree. in the
opposite direction. The nozzles 52 receive their fluid from a
manifold 54 that has an access door 55 to permit entry to
manipulate the ball nozzles. The manifold 54 is provided with
high-pressure elastic fluid from a conduit 56 that is controlled by
a valve 58. The conduit 56 is connected to a source of fluid (not
shown). The valve 58 as well as the valves 34 and 38, although
shown as being manually operable, may be controlled an any other
feasible manner, as by remotely controlled solenoid systems,
hydraulic or pneumatic pressure systems, or the like. This may also
be true of the ball nozzles 52.
The nozzles 52 are illustrated as being of the standard
convergent-divergent type to obtain high fluid velocities, this
being preferred for grinding processes and the like. However,
abrupt-type nozzles or any other desired nozzle types may be used
in accordance with the treatment being practiced and the materials
being processed. Furthermore, although high-pressure fluid is
illustrated as being passed through the nozzles 52, it may
sometimes be preferred to use low-pressure fluid in accordance with
the particular process and materials.
A separate feed means 60 is positioned just above the inlet section
12 and is controlled by a valve 62. This inlet 60 is provided as an
optional feature for the insertion of a liquid spray when such is
desired for the coating of particles or for chemical reaction
therewith.
An exhaust duct 64 leads upwardly from the chamber 24 of
separator-classifier 26 to a manifold 66 connected to a collector
(not shown). The lower nozzle portion 44 leads into the top of a
conical after-blender chamber 68 from the lower end of which
extends a conduit 70. The conduit 70 curves upwardly to connect
with the manifold 66, and is provided with a nozzle 72 at its lower
bend. The nozzle 72 is connected to a source of elastic fluid under
pressure (not shown) to provide a propellant for the flow from the
chamber 68 upwardly to the manifold 66.
A feed means 74 extends tangentially into the chamber 24 and is
provided with a valve-controlled nozzle 76 connected to a source of
fluid pressure (not shown) to act as a propellant means. A similar
feed means 78 provided with a similar nozzle 80 tangentially
extends into the after-blender chamber 68. Both of these feed means
are optionally used to feed additives of any desired type into the
respective chambers.
In the operation of the above-described apparatus, when used as a
grinding mill, the solid particles are fed through inlet 40 and are
ground or pulverized by impacts between themselves and the chamber
walls as they pass through the inlet chamber 12 where high-pressure
fluid from the nozzles 52 acts as the energy medium in the standard
manner of fluid energy mills. The degree of pulverization and the
size and shape of the pulverized particles are controlled by the
angles of the various nozzles 52 and the velocity of the fluid. In
this respect, if the nozzles are directed in the direction of flow
through the chamber 12, there will be a minimum of violent impacts
and the result will be more of a separation of particles from each
other rather than a pulverization. When the nozzles are directed
against the flow, there will be a maximum amount of impacts and
maximum pulverization. These effects can be varied between extremes
by selectively varying one or more of the nozzle angles and by
varying the velocities of the fluids passing through the different
nozzles.
As the particles pass around the mill to the classifier section 16,
in the normal operation, the finer, lighter particles on the inner
periphery of the circulating vortex would pass out through the
outlet duct 20, while the larger, heavier particles on the outer
periphery would pass through the downstack 18 for further grinding.
However, if it is desired that the distribution of the particles in
the final product include more intermediate or larger size
particles, the diverting nozzles 28 and 30 are actuated. The
jetstreams from these nozzles propel more of the larger particles
toward the entrance into duct 20, the size of such particles being
determined by the velocity of the jets, whereby higher velocities,
with greater kinetic energy, will propel larger, heavier particles
toward the duct 20. In this manner, only such particles as are too
large and heave to be sufficiently propelled by the jets will
continue to fall through the downstack 18 for further grinding. On
the other hand, when it is desired to obtain a particle
distribution in the final product that includes only relatively
small, light particles, the nozzle 36 is actuated to propel the
heavier particles in a direction to bypass the entrance to duct
20.
The particles that pass out of the mill through duct 20 flow
through conduit 22 and pass into the upper portion of the secondary
classifier chamber 24 in a tangential direction. The tangency of
the conduit 22 creates a horizontal, downwardly moving vortex in
chamber 24. From this vortex, the finer particles, on the inner
periphery of the vortex, pass upwardly through duct 64 and manifold
66 to the collector (not shown) while the heavier particles on the
outer periphery pass down with the circulating vortex into the
conical chamber 46 from where they pass, by gravity, through the
nozzle 44 into the chamber 68 from where they are propelled through
conduit 70, by the fluid jet from nozzle 72, into the manifold
66.
If it is desired to return some, or all of the particles falling
through chamber 46 to the mill chamber 12 for further grinding, the
nozzle 50 is actuated to propel such particles into the bridging
conduit 42, the amount and size of the returned particles being
determined by the velocity or force of the fluid jet from the
nozzle 50.
If it is desired to coat the particles with a particular material
or to obtain a chemical or physical reaction therewith, such
material may be inserted through the inlet 60. If additional
reaction with the same or other material is desired, such
additional material may be inserted through either or both of the
inlets 74 and 78, depending upon what stage of the processing and
which particles are to be reacted. Alternatively, the inlet 60 may
be deactivated and only one or both of the inlets 74 and 78 may be
used.
Although the process described above relates to grinding or
pulverization, the apparatus may be used for drying, mixing,
chemical or physical reaction, without grinding, merely by passing
low-pressure fluid through the nozzles 52 or by using
high-temperature, low-pressure fluid. Drying and grinding is
effected by using high temperature, high pressure fluid.
Fluid energy mills are adapted to grind, mix, blend, combine or
chemically or physically react any type of solid particles
including foods, cosmetics, pharmaceuticals, metals, minerals and
natural and synthetic plastics. Among such materials are
polyesters, polyethers including polymers of acrylonitrile,
butadiene, styrene, acrylates and methacrylates, acetal resins and
fibers, allyl resins, amino resins such as melamine and urea
formaldehyde. Also cellulose and cellulose/resin fibers such as
cellulose triacetate, cellulose acetate butyrate, cellulose
propionate, cellulose nitrate, ethyl cellulose, etc. Also
haloplastics such as paraffinic hydrocarbon polymers in which all
or part of the hydrogen atoms are replaced with a halogen such as
chlorine, bromine and fluorine. Particularly important among these
are polytetrafluoroethylene, fluorinated ethylene propylene,
chlorotrifluoroethylene, etc. Also haloginated polyvinylidene,
epoxy resins, furane resins, ionomers, isocynates, parylene
polymers, polyamides such as nylon, phenolics, phenol-furfural and
resorcinal formaldihyde. Also phenoxy resins, polyallomers,
polycarbonates, polyimides, polyethylene both low and high
molecular weight as well as cross-linked. Also unsaturated
polyesters, polyphenylene oxides, silicones and silicon. Also
polypropylene, propylene copolymer and polysulfane. Vinyl polymers
and copolymers such as polyvinylchloride and polyvinyl acetate, are
effectively processed by these mills. They are also effective in
the treatment of inorganic polymers such as glass, fiberglass and
Wollastonite, as well as asbestos, carbon black, silica gel, etc.
They are also very effective in the treatment of polyparaxylenes
which are formed of linear, highly crystalline molecules, as well
as the polybenzimidazoles, polyphenylene oxides and fiber glass
reinforced thermoplastics.
Fluid energy mills may also be effectively used to provide a
so-called "matt finish" or "satinizing" of the particle surfaces.
This type of finish is nothing more than a slight roughness on the
surface and has, heretofore, generally been obtained by chemical
treatment.
This apparatus can also be used to accomplish chemical reaction
under increased pressure by merely restricting the exhaust from the
mill, thereby building up pressure in the treating chamber 12. For
example, coarse silicon metal may be abraded and reacted with
high-pressure methyl chloride at about 500.degree. to 800.degree.
F., or above, while the pressure in the mill is increased to
between about 30 to 80 p.s.i.g.
The above-listed materials are merely illustrative of the type of
materials effectively processed by fluid energy mills and are not
intended as a limitation since any solid or semisolid material of
whatever kind or type can be treated. Any of these materials can be
made of any desired size and shape by merely regulating the
functioning of the mill and are, therefor, to be considered
inherent in the functioning of the mill.
* * * * *