U.S. patent number 3,595,386 [Application Number 04/794,103] was granted by the patent office on 1971-07-27 for process for beneficiation of nonmagnetic material.
Invention is credited to Joseph R. Hradel.
United States Patent |
3,595,386 |
Hradel |
July 27, 1971 |
**Please see images for:
( Certificate of Correction ) ** |
PROCESS FOR BENEFICIATION OF NONMAGNETIC MATERIAL
Abstract
A novel process for beneficiating nonmagnetic ores and other
source materials, particularly lean iron ores, wherein paramagnetic
material in such ores is given a temporary positive magnetic
susceptibility, passed within the field of a moving permanent
magnet system before the material decays to its natural state, and
the so activated paramagnetic substance separated by deflection
toward the magnet system and recovered from nondeflected
diamagnetic material in admixture therewith.
Inventors: |
Hradel; Joseph R. (Mount
Pleasant, MI) |
Family
ID: |
25161721 |
Appl.
No.: |
04/794,103 |
Filed: |
January 27, 1969 |
Current U.S.
Class: |
209/8; 209/39;
209/214; 209/232 |
Current CPC
Class: |
B03C
1/025 (20130101); B03C 1/12 (20130101); B03C
1/005 (20130101); B03C 1/26 (20130101); B03C
1/002 (20130101); B03C 2201/20 (20130101) |
Current International
Class: |
B03C
1/00 (20060101); B03c 001/00 () |
Field of
Search: |
;209/39,40,219,214,215,212,213,232,220,218,478,216,227,131.1,314,8,8.1
;210/222,223 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lutter; Frank W.
Assistant Examiner: Halper; Robert
Claims
I claim:
1. A process for separating nonmagnetic paramagnetic material from
diamagnetic material which comprises:
a. providing a finely divided mixture of paramagnetic and
diamagnetic material, said mixture being further characterized as
being not naturally magnetic,
b. passing said mixture within the effective range of an
electrically energized upset coil thereby upsetting said mixture
and imparting a temporary positive magnetic susceptibility to said
paramagnetic material of said mixture and a negative magnetic
susceptibility to said diamagnetic material of said mixture, said
temporary positive and negative magnetic susceptibilities existing
in said materials for a period of time of from less than 1 second
up to about several minutes
c. bringing the so upset mixture within the field of a moving
permanent magnet system within the time interval that the
paramagnetic material retains its temporary positive magnetic
susceptibility and is attracted and deflected towards said magnet
system, and
d. recovering the so deflected paramagnetic material.
2. The process as defined in claim 1 wherein the upset material is
passed through said electrically energized upset coil.
3. The process as defined in claim 2 wherein the upset mixture is
passed adjacent to a rotating system of a plurality of permanent
magnets.
4. The process as defined in claim 3 wherein the mixture comprises
nonmagnetic iron source material and the time interval between
upset and passage within the field of said moving magnet system
ranges from less than one second to about one minute.
5. The process as defined in claim 4 wherein the iron source
material is a lean iron ore or tailings resulting from conventional
ore processing operations, said material being substantially free
from naturally magnetic substances and said material ranging from
about 60 to about 325 mesh U.S. Standard Sieve.
6. The process as defined in claim 5 wherein the iron source
material is provided as an aqueous slurry and including the step of
pumping said slurry through said energized coil and adjacent said
rotating system of permanent magnets.
Description
The present invention relates to a novel process for separating
paramagnetic material from diamagnetic material and more
particularly is concerned with a novel process for beneficiating
ores which are not naturally magnetic such as, for example, lean
nonmagnetic iron ores including tailings from conventional ore
processing, to recover the bulk of the useful and desired metal
values therefrom.
Current ore beneficiating employing electromagnetic and magnetic
separatory techniques as exemplified by U.S. Patents Nos.
2,954,122, 2,325,149 and 2,558,635 are applicable only in
separating and recovering from ore bodies the naturally magnetic
portions of the ore or those metal values which can be given a
prolonged magnetism from an induced electromagnetic force and which
retain this magnetism until the material is demagnetized by passage
through an opposing electric coil or other demagnetizing means.
Many lean ores, particularly ferrous ores, which are abundantly and
widely distributed throughout the world are not presently mined
because they are not susceptible to beneficiation by such known
techniques. Additionally, nonmagnetic tailings resulting from
beneficiation of magnetic ores contain a large percentage of iron
values which at present are discarded because these values are
unresponsive to separation by magnetic beneficiation techniques now
practiced.
Now, unexpectedly I have discovered a novel process for separating
and recovering nonmagnetic but paramagnetic metal values,
particularly nonmagnetic iron values, form ores and other source
materials including tailings from gangues resulting from
conventional iron separatory techniques.
It is a principal object of the present invention to provide a
novel process for separating and recovering paramagnetic materials
which are nonmagnetic, i.e. are not naturally magnetic or will not
hold any induced magnetism for a prolonged period of time, from
diamagnetic materials.
It is also an object of the present invention to provide a novel
process for beneficiating and recovering iron values from source
materials which do not respond to and cannot be used in
conventional magnetic beneficiating techniques.
These and other objects and advantages readily will become apparent
from the detailed description presented hereinafter when read in
accordance with the FIGURE of the appended drawing which shows a
schematic flow diagram of one embodiment of the process of the
present invention.
In general the process of the present invention comprises providing
a particulate nonmagnetic source material which cannot be rendered
permanently magnetic but which contains at least one paramagnetic
substance to be separated and recovered. This source material is
passed through or within the effective range of an electric coil
thereby upsetting said material and imparting a temporary positive
magnetic susceptibility to said paramagnetic material and a
negative magnetic susceptibility to any diamagnetic material
present therein. The so upset material is brought within the field
of a moving permanent magnet system before the positive magnetic
susceptibility in the paramagnetic material decays to a state where
said paramagnetic material is not attracted by said magnetic system
thereby deflecting and separating said paramagnetic material from
diamagnetic materials present which received a negative magnetic
susceptibility from exposure to said coil. The term "upset" for the
purpose of this specification is defined as the act of disturbing
the electromagnetic equilibrium of a paramagnetic or diamagnetic
material form its natural state by electromagnetic means.
This method is particularly adapted for use in separating and
recovering iron values from nonmagnetic ore bodies and other source
materials as has been pointed out hereinbefore. Representative
examples of such iron source materials are iron ores containing
such paramagnetic materials as the spicular and cherty hematites
consisting largely of Fe.sub.2 O.sub.3 embedded in diamagnetic
gangues of the nature of silica as are found in the upper central
United States. These materials, although lean, represent an
economically beneficiable reserve beyond that which is currently
being recovered if consideration is given to the fact that
differences in magnetic susceptibility values constitute a basis
for separation of iron compounds form their gangues. Other iron
bearing compounds are contained in lean ores such as mascarite, the
nonmagnetic fraction of pyritic magnetite, pyrite, siderite,
limonite, and the green potassium iron silicate as well as the
tailings from previous beneficiations of these ores. All of these
are available in abundant quantities in various parts of the United
States as well as throughout the world. Hereinafter the term "ore"
as used in the specification will mean and include both naturally
occurring nonmagnetic ores such as the lean ores exemplified
hereinbefore as well as tailings and other source materials
resulting from prior beneficiation or separatory processes.
Ordinarily in carrying out the practice of the present invention,
an ore is crushed or ground to break it down and effect separation
of the paramagnetic metal values from diamagnetic gangue materials.
Usually the ore is crushed to pass a number 60 U.S. Standard Sieve,
and particulate materials ranging from 60 to 325 mesh or finer have
been found to be particularly suited to the practice of the present
invention. Coarser particles can be employed, if desired, provided
that effective physical separation from gangue material is
realized.
The crushed ore is subjected to the influence of an energized
electric coil of sufficient energy and for a period of time to
establish a temporary positive magnetic susceptibility in the
paramagnetic materials present therein and a negative magnetic
susceptibility in any diamagnetic substances which may be in
admixture therewith. The resulting positive and negative magnetic
susceptibilities in the upset material are not permanent or even
prolonged in duration but are of short duration, i.e. exist from
less than a second to a minute or more and ordinarily have a
maximum of about several minutes.
The so upset ore is passed within the field of at least one
rotating permanent magnet, usually a plurality of such magnets,
before the positive magnetic susceptibility given to the
paramagnetic material in the ore decays to a state where the
material becomes unresponsive to the permanent magnet system. One
particularly effective system employs a plurality of magnets
mounted on a moving frame, for example, a rotating drum. This
system has been found to be of a high utility since the rotation of
the magnets serves to substantially eliminate undesirable buildup
of the paramagnetic material, even for a short period of time, on
the magnets or clogging of the deflection chamber, adjacent thereto
if such is employed in the apparatus for carrying out the
process.
Optimum in separation of the active paramagnetic material from
diamagnetic material in admixture therewith is realized by
utilizing a minimum period of time between upset and subjection to
the magnetic field. The sooner the material is brought under the
influence of the permanent magnet the more positive and greater
will be the deflection and consequent separation of the desired
paramagnetic product. As indicated hereinbefore, at a maximum about
one minute is employed and preferably this time is from less than a
second up to several seconds.
The deflected paramagnetic product after it is passed beyond the
magnetic field is collected separately from the nondeflected
diamagnetic byproduct. In some instances it is to be understood
that the nondeflected diamagnetic material may be the desired
product or both materials may be of interest.
Conveniently, the starting material is passed by gravity flow
through an energizing coil past the magnet system and the separated
materials further passed into a collection system. Alternatively, a
liquid pumping system for handling an ore in aqueous suspension can
be employed. This latter procedure assures that the throughput
rates of the ore can be controlled by the pumping rates thus
reducing to a minimum, e.g. a fraction of a second, the time
required to transport the ore between the energized upset coil and
the permanent magnet system. This provides the added advantage that
the flow rate through the coil can be adjusted and maintained to be
the same as the flow rate past the moving permanent magnets thereby
serving to further control the product distribution and eliminate
congestion in the vicinity of the magnets and/or the
collectors.
The collected paramagnetic product can be recovered and used
directly, or, in the case of iron ores, can be further processed
concentrated and otherwise converted, for use in particular
situations.
Alternating current in the upset coil is preferred over direct
current in that the former offers the further advantage that
minimum clogging or buildup in the core is found. This is
particularly true when utilizing silicate and sulfur based iron
ores, e.g. marcasite, pyrite, and pyritic hematite. Oxide and
hydroxide ores are less prone to clogging and a direct current
source is just as effective as an alternating current for these
latter materials.
One embodiment of a hydraulic system for carrying out the present
process is shown schematically in the FIGURE of the drawing. In
this embodiment, a mixing-holding-feed hopper 10, usually fitted
with a valve near its bottom, is provided. This hopper 10 is
connected at its bottom to the top of a flow through electrically
powered upset coil 12. The bottom of the hopper 10 is connected to
the top of a deflection chamber 14. This chamber 14 is curved along
one side of its length s so as to coincide generally with the
contour of a cylindrical frame 16 holding a plurality of permanent
magnets 18. Preferably the wall of the chamber adjacent the magnet
system is in close proximity to this system. The bottom of chamber
14 is fitted with a divider 20 which serves to direct diamagnetic
byproduct to a gangue thickener collecting vessel 22 and
paramagnetic product to a product collector 24. Conveniently the
intake at the top of the deflection chamber has a cross-sectional
area about equal to that of the two discharge outlets of the bottom
of this chamber. Ordinarily, the cross-sectional area of each of
the discharge outlets is slightly smaller than 0.5 that of the
intake. This, in turn, provides for a slight back pressure in the
system thereby providing during operation cleaner cuts in a more
rapid manner with less recycle. Each of the containers 22 and 24 is
fitted respectively with a conduit 26 and 28 which fed to a common
transport conduit 30. Conduit 30 in turn is connected through pump
32 to hopper 10. The hopper 10 is fitted with an ore supply conduit
34 which extends to an ore supply reservoir 36. Conduit 30 can be
fitted with a makeup conduit 38 connected to a fluid supply source
(not shown).
In operation of this system, in one embodiment a ground ore and a
liquid carrier, usually water, with or without additional agents
such as, for example surfactants, are blended in the hopper 10 to
provide a slurry of predetermined consistency. This slurry is
controllably fed through the coil 12 where the ore is upset and the
paramagnetic material of the ore is given a temporary positive
magnetic susceptibility. The so upset ore containing slurry is
directed to the inlet of the deflecting chamber 14. As the slurry
passes through this chamber 14 and past the revolving magnets 18
the paramagnetic material is deflected towards and attracted by the
magnets. This material follows the contour of the chamber adjacent
the magnets 18 and drops form outlets at the bottom of the
collection chamber 14 into the collector 24. The nondeflected
diamagnetic material falls directly into the gangue collector
22.
The materials are settled in their respective collectors, and
recovered by conventional means. The supernatant liquid is removed
form the collectors 22 and 24 by conduits 26 and 28 being pumped
into conduit 30 and returned to hopper 10 for reuse. Such reuse of
the carrier liquid provides for the maximum of product recovery as
any useful values retained in the liquid will be again passed
through the beneficiation process. The diamagnetic gangue can be
recycled for further beneficiation if desired.
Alternatively, the hydraulic conduit and pumping system can be
eliminated and dry material by gravity or force fed from the hopper
through the energizing coil, passed through the field of the moving
permanent magnet system and on into the collection bins.
Other modifications can be employed. Also electrical assemblies,
mechanical and hydraulic systems suitable for use in the practice
of the invention for any particular applications are within the
knowledge of one skilled in the art to which this process
pertains.
The following examples will serve to further illustrate the present
invention but are not meant to limit it thereto.
EXAMPLE 1.
Nonmagnetic cherty hematite tailings or spicular hematite having
various amounts of iron (expressed as percent Fe.sub.2 0.sub.3 )
and ground to pass a 60 mesh U.S. Standard Sieve but be retained on
a 325 mesh sieve were passed dry through a 2,500 ohm upset coil
energized by an alternating current circuit and operating at 16
volts. These tailings were discard nonmagnetic gangue products
resulting from conventional magnetic ore beneficiation
processes.
Each of the upset materials was retained for a predetermined period
of time and then passed within the field of a revolving permanent
magnet system. The amount of sample attraction, i.e. beneficiation
of the iron source, by the permanent magnets was determined.
The results of this study which was designed to illustrate the
operability of the present process for beneficiating paramagnetic,
but not permanently magnetic, materials from diamagnetic substances
admixed therewith are summarized in table I. These results also
show the criticality of passing the upset material within the field
of the permanent magnet system within a short period after being
activated by the upset coil to achieve optimum in beneficiation.
##SPC1##
EXAMPLE 2.
Using a separatory apparatus of general construction similar as
that shown in the FIGURE of the drawing, an aqueous slurry of a
cherty hematite tailing (one kilogram of iron source material) and
having a known iron content (expressed as percent Fe.sub.2 0.sub.3)
and ground to a predetermined particle size range was pumped
through an alternating current (16 volts) energized upset coil
(2,500 ohms). The resulting upset iron source material was pumped
into a deflection chamber which was adjacent a plurality of
permanent magnets mounted on a revolving drum. The time between
upset and passing of a given particle of the iron source material
in the field of the magnets was a fraction of a second at a
maximum. The product materials were collected in separate bins, the
gangue material being recycled for a total treating time of five
minutes. After this period of time, the beneficiated iron product
was recovered and the iron content determined by conventional
analytical techniques.
The results of this study are summarized in table II which follows.
##SPC2##
EXAMPLE 3.
Dry iron source materials of particle size ranging from about 60 to
325 mesh and which had been freed of all naturally magnetic
materials were passed by gravity feed through an upset coil of
7,500 ohms and activated by alternating current at a potential of
16 volts. The upset material was passed through a deflection
chamber adjacent a revolving magnet system in a single pass, the
time period between the time of upset and contact with the field of
the magnet being about 15 seconds. The diamagnetic materials, i.e.
tailings, which were not attracted by the magnet system were
collected separately from the paramagnetic iron product, i.e.
beneficiate, that had received a temporary positive magnetic
susceptibility and was deflected towards the magnet. This latter
material was separated from the magnetic field and recovered. The
iron contents of the recovered fractions were determined by
conventional analytical techniques.
The results of a number of runs with various iron source materials
are summarized in table III. ##SPC3##
EXAMPLE 4.
A number of studies were run to determine the current consumption
for various diamagnetic and paramagnetic substances in an upset
coil. For these studies, a coil of 2,500 ohms at a predetermined
temperature was energized by alternating current of 16 volts
potential and a core of a predetermined material placed within the
coil. The time for consumption of a watt-hour of energy was
measured. The results of these runs are summarized in table IV. The
marked differences in power consumption rates for the various
materials as shown in the table indicates the coil influences a
given material in a specific manner, i.e. gives it a temporary
positive or negative susceptibility, and thus provides the basis
for the present process for recovering useful paramagnetic
materials from nonmagnetic source materials. ##SPC4##
Various modifications can be made in the present invention without
departing from the spirit or scope thereof for it is understood
that I limit myself only as defined in the appended claims.
* * * * *