U.S. patent number 3,593,721 [Application Number 04/876,084] was granted by the patent office on 1971-07-20 for process for the production of tobacco foils and products thereof.
This patent grant is currently assigned to Henkel & Cie GmbH. Invention is credited to Franz-Bernhard Knop, Werner Scherff.
United States Patent |
3,593,721 |
Knop , et al. |
July 20, 1971 |
**Please see images for:
( Certificate of Correction ) ** |
PROCESS FOR THE PRODUCTION OF TOBACCO FOILS AND PRODUCTS
THEREOF
Abstract
In the process of producing tobacco foils comprising the steps
of mixing a slurry of tobacco dust with a water-soluble binder to
form a moldable slurry, forming a tobacco foil or film and drying
said tobacco foil or film, the improvement which consists of using
as said water-soluble binder, a water-soluble methylcellulose
containing from 0.05 to 0.25 carboxymethyl groups and also
containing from 1.4 to 2.1 methoxy groups per anhydro glucose unit
in said methylcellulose.
Inventors: |
Knop; Franz-Bernhard (Monheim
Rhineland, DT), Scherff; Werner (Hilden Rhineland,
DT) |
Assignee: |
Henkel & Cie GmbH
(Dusseldorf-Holthausen, DT)
|
Family
ID: |
5715197 |
Appl.
No.: |
04/876,084 |
Filed: |
November 12, 1969 |
Foreign Application Priority Data
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Dec 4, 1968 [DT] |
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P 18 12 601.7 |
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Current U.S.
Class: |
131/355 |
Current CPC
Class: |
A24B
15/12 (20130101) |
Current International
Class: |
A24B
15/00 (20060101); A24B 15/12 (20060101); A24b
003/14 () |
Field of
Search: |
;131/15,17,140--144 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
ENCYCLOPEDIA OF POLYMER SCIENCE AND TECHNOLOGY Vol. 3 pub. by
Interscience Publishers Uy 1965 p. 495 cited.
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Primary Examiner: Rein; Melvin D.
Claims
We claim:
1. In the process of producing tobacco foils comprising the steps
of mixing a slurry of tobacco dust with a water-soluble binder to a
moldable slurry, forming a tobacco foil or film drying said tobacco
foil or film, the improvement which consists of using as said
water-soluble binder, a water-soluble methylcellulose containing
from 0.05 to 0.25 carboxymethyl groups per anhydro glucose unit and
from 1.4 to 2.1 methoxy groups per anhydro glucose unit in said
methylcellulose.
2. The process of claim 1 wherein said water-soluble
methylcellulose contains from 0.1 to 0.2 carboxymethyl groups per
anhydro glucose unit and from 1.6 to 1.8 methoxy groups per anhydro
glucose unit.
3. The process of claim 1 wherein from 10 to 30 parts by weight of
said water soluble methylcellulose containing 0.05 to 0.25
carboxymethly groups per anhydro glucose unit are employed for 100
parts by weight of tobacco dust.
4. The process of claim 1 wherein said water-soluble
methylcellulose has a viscosity in a 2 percent aqueous solution at
20.degree. C. of between 100 and 40,000 cp.
5. The process of claim 1 wherein said moldable slurry has a
Brookfield viscosity at 20.degree. C. of between 10,000 to 50,000
cp.
6. The process of claim 1 wherein said formed tobacco foil or film
is dried at temperatures between 80.degree. C. and 115 C.
7. The process of claim 1 wherein said water-soluble binder
contains a divalent aldehyde for improving the wet strength of the
tobacco foil or film.
8. The process of claim 1 wherein said moldable slurry contains
fillers and plasticizing components.
9. The tobacco foil produced by the process of claim 1.
Description
THE PRIOR ART
It is known to prepare tobacco foils or films, which serve as
binders for cigars, small cigars or cigarillos, whereby tobacco
dust is made into a paste with aqueous solutions of a high
molecular weight film-forming substance to give a plastic mass and
this mass is then shaped into a film and dried. Cellulose ethers
such as methylcellulose or carboxymethylcellulose (German Pat. No.
872,176 and Swiss Pat. No. 228,204) have been found to be suitable
as the film-forming substances.
The known processes have some disadvantages however. For example,
water-soluble methylcellulose has the disadvantage of flocculating
at elevated temperatures. For this reason the machines for
producing tobacco foils cannot be run at elevated temperatures and
the performance of these relatively expensive machines is thereby
limited. If carboxymethylcellulose is used, higher temperatures may
be used and, therefore, an improved machine performance is obtained
but other disadvantages occur. The foils so made easily adhere to
the carrier belt and the finished foils possess poor burning
properties and also have had taste properties.
OBJECTS OF THE INVENTION
An object of the present invention is the development of a process
for the production of tobacco foils from tobacco dust which
overcomes the disadvantages of the prior art utilizing, as a
binder, a water-soluble methylcellulose having carboxymethyl
groups.
Another object of the invention is the development of a process of
producing tobacco foils comprising the steps of mixing a slurry of
tobacco dust with a water-soluble binder to form a moldable slurry,
forming a tobacco foil or film and drying said tobacco foil or
film, the improvement which consists of using as said water-soluble
binder, a water-soluble methylcellulose containing from 0.05 to
0.25 carboxymethyl groups per anhydro glucose unit in said
methylcellulose.
These and other objects of the invention will become more apparent
as the description thereof proceed.
DESCRIPTION OF THE INVENTION
The above objects have been achieved and the drawbacks of the prior
art have been overcome by the instant inventive process for the
production of tobacco foils or films which comprises adding tobacco
dust, or a paste or slurry thereof with water, to an aqueous
solution of a water-soluble methylcellulose which contains 0.05 to
0.25 especially 0.1 to 0.2 carboxymethyl groups, per anhydro
glucose unit in the molecule so as to form a plastic mass which is
subsequently formed into a film or foil and dried.
Suitable water-soluble cellulose derivatives for the purpose of the
invention are produced starting from methylcellulose which contains
1.4 to 2.1, especially 1.6 to 1.8, methoxy groups per anhydro
glucose unit in the cellulose molecule. The viscosity of a 2
percent aqueous solution of the suitable known and commercial types
of methylcellulose may vary within the wide limits and lies between
100 and 40,000 cp. at 20.degree. C. Preferred starting types of
methylcellulose are those which possess a viscosity which lies
between 500 and 3,000 cp.
The introduction of the carboxymethyl groups is simple. Thus the
methylcellulose can be kneaded with concentrated caustic soda
liquor and monochloroacetic acid neutralized wholly or partly with
caustic soda liquor or soda, and heated in known way for some time
at temperatures from 50.degree. to 80.degree. C. Further, the
reaction can also be carried out using solvents such as ethanol,
isopropanol, butanol or acetone. The quantity of monochloroacetic
acid used depends upon the desired degree of substitution. The
reaction proceeds almost quantitatively. Obviously bromoacetic acid
can also be used instead of monochloroacetic acid.
In one embodiment according to the invention, the water-soluble
film-forming methylcellulose is firstly dissolved in water. In this
solution or in the gel, the tobacco dust, or suitably a tobacco
dust made into a paste or slurry with water, is incorporated
therein. The ratio of tobacco dust to film-forming methylcellulose
should be such that 10 to 30 parts by weight of film-forming
methylcellulose are used to 100 parts by weight of tobacco dust (on
a dry basis).
In the aqueous mixture of the ratio of solids to water should be
such that an easily shapable mass is present which, for example, by
calendering, molding, casting, rolling or applying to a suitable
smooth surface by means of a doctor knife, can be worked into a
smooth foil or film. Easily workable masses should have a viscosity
of say 10,000 to 50,000 cp., according to Brookfield, at 20.degree.
C. The foils which can be produced according to the invention are
then dried at temperatures between 80.degree. and 115.degree. C.
The air which may be used for the drying is itself heated to a
substantially higher temperature, say to 150.degree. to 220.degree.
C. In the drying, it is preferable that the water is not removed in
its entirety. A residual moisture of 5 percent to 35 percent is
retained.
Further assistants may also be used during the operation of the
process of the invention, such as agents for improving the wet
strength. It is known that natural tanning materials may be used
for this purpose, such as tannins or tannic acids of different
origin or catechutannic acids, catechols, quercitannic acids or
chestnut tannic acids, ellagic acid or similar compounds. For the
improvement of the wet strength, however, divalent aldehydes, such
as glyoxal, are preferably used.
Further, plasticizing substances or fillers are suitably added
during the production of the tobacco foils. Suitable plasticizers
are, for example, sugar syrup or polyhydric alcohols, such as
ethyleneglycol, glycerine, sorbitol, diethyleneglycol. Suitable
fillers are kaolin, bentonite, diatomaceous earths or finely
divided silicic acid. If desired, tobacco fibers, cellulose fibers
or glass fibers in small amounts may also be added.
The tobacco foils obtainable by the process according to the
invention are marked by an improved tear resistance, which is also
manifested in the increase of the breaking load and the tenacity.
The improvement amounts to about 50 percent compared to the values
which are obtained when utilizing a methylcellulose which has not
treated as above in the process.
It could not have been expected that, by the introduction of the
small amount of carboxymethyl groups, not only the flocculation
point would be raised to over 100.degree. C., but also that a
substantial improvement of the mechanical properties would occur.
This improvement of the tear resistance also enables the machines
for the production of the tobacco foils to be operated
substantially more rapidly without tearing of the foils taking
place.
The following specific embodiments are illustrative of the
invention without, however, being deemed limitative.
EXAMPLE
Commercial methylcellulose (1.7 methoxy groups per anhydro glucose
unit; viscosity of the 2 percent aqueous solution 1,300 cp. at
20.degree. C. according to Hoppler) was moistened with 0.2 mol of
50 percent caustic soda liquor (referred to anhydro glucose unit)
and an amount of neutralized monochloroacetic acid such that 0.175
of monochloroacetic acid was present to one anhydro glucose unit.
The mixture was stored for 20 hours at 60.degree. C.
Twelve grams of the melhylcellulose containing about 0.175
carboxymethyl groups per anhydro glucose unit, prepared as
described above, were dispersed in 350 cc. of water together with
1.75 g. of magnesium oxide, 1.50 g. of potassium nitrate and 2.5 g.
of an aqueous 40 percent glyoxal solution. The binder solution so
prepared was allowed to stand at room temperature for 16 hours.
Seventy five and five tens grams of tobacco dust were dispersed in
150 cc. of water and the dispersion was thoroughly mixed with the
above-prepared binder solution. The pH value was adjusted by 5 by
addition of phosphoric acid. The finished pulp or slurry had a
viscosity of 25,000 to 30,000 cp. according to Brookfield (20
r.p.m. at 20.degree. C.).
The tobacco pulp was applied to stainless polished steel sheet with
a doctor knife of specified width of gap (0.6 mm.) and dried at
100.degree. C.
The dried foil has a moisture content of 13.65 percent and a weight
of 94.25 g./m..sup.2. The tear resistance was 0.412 kp./mm..sup.2,
the breaking load was 0.757 kp. and the tenacity amounted to 626 m.
(German Industrial Standard 53 112).
COMPARATIVE EXPERIMENT
The procedure was as described above, but a methylcellulose was
used which had not been treated with monochloroacetic acid.
In this case a foil was obtained with a moisture content of 13.6
percent and a weight of 90.64 g./m..sup.2. The tear resistance
amounted to 0.248 2, 2, the breaking load was kp./mm..sup. kp., and
the tenacity was 309 m.
The preceding specific embodiment is illustrative of the practice
of the invention. It is to be understood, however, that other
expedients known to those skilled in the art may be employed
without departing from the spirit of the invention.
* * * * *