U.S. patent number 3,578,943 [Application Number 04/853,471] was granted by the patent office on 1971-05-18 for protective coating for plasma apparatus.
This patent grant is currently assigned to La Soudure Electrique Autogene, Procedes Arcos. Invention is credited to Henry P.J.F.M.C. Schoumaker.
United States Patent |
3,578,943 |
Schoumaker |
May 18, 1971 |
PROTECTIVE COATING FOR PLASMA APPARATUS
Abstract
A plasma nozzle and process for treating plasma nozzles used in
operations with reactive gases in which a face of the nozzle,
preferably the front face, is provided with means to protect
against corrosion from reactive gases, the means consisting of a
coating of a metallic element or alloy within the group consisting
of gold, platinum, palladium, rhodium, iridium, osmium and or
ruthenium.
Inventors: |
Schoumaker; Henry P.J.F.M.C.
(Jette, BE) |
Assignee: |
La Soudure Electrique Autogene,
Procedes Arcos (Brussels, BE)
|
Family
ID: |
3841193 |
Appl.
No.: |
04/853,471 |
Filed: |
August 27, 1969 |
Foreign Application Priority Data
Current U.S.
Class: |
219/121.47;
219/121.5; 219/75 |
Current CPC
Class: |
H05H
1/44 (20130101) |
Current International
Class: |
H05H
1/26 (20060101); H05H 1/44 (20060101); B23k
009/00 () |
Field of
Search: |
;219/75,76,121,121 (P)/
;117/93.1 ;239/81 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Truhe; J. V.
Assistant Examiner: Albritton; C. L.
Claims
I claim:
1. A high temperature heating apparatus comprising a first and
second electrically conducting electrode, the second electrode
including a nozzle, the second electrode being provided with a face
adjoining the nozzle exposed to corrosion, means for projecting a
gas through the nozzle in the second electrode, means for applying
a direct current electric arc between the first and the second
electrodes to create a plasma issuing through the nozzle of the
second electrode, and means for superimposing an alternating
current which flows through the plasma, characterized in a coating
on said face of the second electrode composed of a material
selected from a class consisting of metallic elements and alloys of
said elements in which there is as a principal component an element
present whose electrochemical oxidation potential with respect to
hydrogen is lower than -0.80 volt.
2. A heating apparatus of claim 1, in which said coating is of the
class which consists of elements and alloys containing an element
which is gold, platinum, palladium, osmium, iridium, rhodium, and
ruthenium.
Having thus described my invention what I claim as new and desire
to secure by Letters Patent is:
3. A heating apparatus of claim 1, in which said coating consists
of an alloy of 90-- 95 percent platinum and 5-- 10 percent iridium
by weight.
Description
Extensive use is being made of plasma torches in which a gas stream
is projected through an orifice in a nozzle, a direct current
establishes an arc to form a plasma, and an alternating current is
superimposed on the plasma to further heat it.
Examples of apparatus for creating a plasma of this character are
shown in J. A. F. Sunnen U.S. Pat. Nos. 3,205,338 granted Sept. 7,
1965, and 3,248,513 granted Apr. 26, 1966, both for Equipment for
Forming High Temperature Plasma. The intention is to relate the
present invention to any of such plasma torches and to the
protection of the faces of the nozzles used therein, especially the
exposed faces surrounding the orifice through which the plasma
issues and encountered by any reactive gas employed with the
plasma, called the front faces.
When gases which are reactive at high temperature are used in
plasma-producing apparatus which superimposes an alternating
current on a plasma created by a plasma-sustaining direct current,
and circulating between two or more electrodes (nozzles), the front
faces of nozzle or nozzles, which are in contact with any high
temperature reactive gases employed with the plasma may become
deeply corroded. For example, where the reactive gases are
oxidizing, the front face of the nozzle which is likely to be made
of a metal such as copper, becomes oxidized, and the oxidized areas
from impact points for the superimposed alternating current arc,
creating instability of the superimposed alternating applied
voltage after several hours of operation, and localized extensive
corrosion of the nozzle.
One of the major purposes of the present invention is to overcome
the instability of the alternating current voltage and to almost
eliminate such instability.
In accordance with the present invention nozzles used in
plasma-producing apparatus operating with reactive gases as above
described are provided with protective coatings on the front faces
against the attack of the reactive gases.
The protective means used consists of metallic elements which have
an electrochemical potential lower than -0.80 volt, or of alloys
thereof, and which are applied by a suitable means to the faces of
the nozzles, for example by plating. Within the limit referred to,
the affinity of these elements for reactive gases is extremely
weak.
In the drawings I illustrate one only of the numerous embodiments
in which the invention may appear, selecting the form shown from
the standpoints of convenience in illustration, satisfactory
operation, and clear demonstration of the principles involved.
FIG. 1 is a diagrammatic axial section of plasma torches according
to the invention.
FIG. 2 is an enlargement of a portion of FIG. 1.
FIG. 3 is a section on the line 3-3 of FIG. 2.
FIG. 4 is a section on the line 4-4 of FIG. 2.
In order to illustrate a system of torches to which the present
invention is applicable, I show a torch system from Sunnen and
Schoumaker U.S. Pat. application Ser. No. 788,209, filed Dec. 31,
1968, for Heating a Reactive Fluid to High Temperatures.
There are three plasma torches 20, 21 and 22, whose projections in
plan view are set at 120.degree. to one another in FIG. 1, and
oriented in fact along the generatrices of an inverted cone having
its apex directed downward and located at the zone of convergence
of plasma jets 23, 24 and 25 which respectively emerge from these
three torches. For the sake of simplicity, the torches are shown as
if they all lie in one plane. Each of said torches comprises a
central solid electrode 26, 27 or 28, and a coaxial hollow
electrode 30, 31 or 32. The torches 20, 21 and 22 are fed
respectively from sources of direct current 33, 34 and 35 to
sustain a direct current arc between the solid electrode and the
hollow electrode of each torch. Means to inject a gas such as an
inert gas, for example argon or nitrogen is suggested by arrows 36
(FIG. 1) through the interior of the hollow electrode from a
suitable gas conduit at the back of the hollow electrode so as to
create the plasmas 23, 24 or 25.
The hollow electrodes 30, 31 and 32 are each connected to one
distinct phase of a source of three-phase alternating current 37
whose neutral point 38 is at the same potential as the center
junction 40 of the zone of convergence of the plasma jets. The
apparatus shown in FIG. 1 also includes a vertical tube 41 located
above the zone of convergence of the plasma jets through which a
material 39 is introduced to enter the plasma jets and to cause or
undergo any suitable reaction or action. A reactive gas suggested
by arrow 53 reacts chemically with the material 39 and first comes
into contact with the plasma near the front faces of the nozzles 30
to pick up the superimposed alternating current, which they later
discharge to the neutral point or center junction 40. Due to the
rotating magnetic field created, the plasma jets and the reactive
gas are subjected to swirling action.
It will be evident that the reactive gas by being brought into
contact with the front faces of the nozzles of the plasma torches,
creates a hazard from the standpoint of corrosion which will impair
the stability of the alternating voltage.
In FIGS. 2, 3 and 4 the construction of the individual torches is
shown more in detail. Each of the torches has an anodic nozzle 42
suitably made of copper and having a cooling medium such as water
circulating through passages 43. The nozzle is provided with a
center orifice 44 through which the plasma 23 issues. The solid
electrode 26 is axially in line with this orifice and is
conveniently mounted in an opening 45 of a plate 46 suitably
secured to a tubular housing 47 which is mounted on the back of the
nozzle 30 and insulated from it by an electrically insulating ring
48. The means for introducing the inert gas to create the plasma is
then a chamber 36 which receives supply of inert gas from a conduit
50 controlled by a valve 51. The front faces of the nozzle 30 (and
all other nozzles) are coated with a protecting layer 52.
Protective metals used in the layer 52 may be gold, platinum,
palladium, rhodium, ruthenium, iridium or osmium or alloys of these
metals such as gold-platinum, platinum-palladium,
platinum-ruthenium, palladium-iridium, platinum-osmium, etc. As
shown in the table, these elements have an electrochemical
oxidation potential of -0.80 volt or lower. ##SPC1## These
elements, however, possess unequal resistances to attack by
chemical agents and they have varying melting points, differing
electrical conductivities and differing physico-chemical
characteristics as set forth in the table which shows their
constants. The table shows the constants also for silver and copper
as a means of comparison. The elements have been listed in order of
resistance to corrosion by acids, and in order of melting points
within each category of acid corrodability.
It should be noted that gold and copper are very close in melting
point and also have comparable resistivity.
Tests performed on three copper nozzles used according to FIG. 1,
electrolytically plated with gold to a thickness of approximately
0.02 mm. on the front faces of the nozzles in contact with oxygen
at a temperature of 1500.degree.--1800.degree. C. have shown a
distinct improvement as measured by better stability of the
superimposed alternating current arc voltage in a practical example
of eliminating corrosion. Thicker and thinner layers may be used if
desired.
It should be noted that electrical contact of the nozzle with the
plasma is preferably made by the copper surfaces so that the
electrical resistance is not increased by the coating.
Since platinum is much more refractory than copper and also has
much higher resistivity, a copper nozzle has been plated with
platinum and much better results obtained in stability of the
superimposed alternating current are by avoiding corrosion of the
nozzle.
Where, however, heating is accomplished under corroding conditions
which are very extreme, the above composition can be further
improved.
As will be seen from the table, platinum, ruthenium, rhodium and
iridium are classified in respect to increasing melting point, but
rhodium, ruthenium and iridium have the highest resistance to
chemical corroding agents. The alloys of platinum, ruthenium,
rhodium and iridium among themselves are particularly interesting
for protecting the nozzle in accordance with the present invention
against virulent chemical agents such as oxygen at elevated
temperatures, since the corrosion resistances of the alloys are
much greater than those of the individual elements. For example,
the platinum-iridium alloy in which platinum makes up 90 to 95
percent of the alloy of weight and iridium composes the balance of
5-- 10 percent is resistant to chemical agents which will corrode
platinum alone and is highly recommended for the protective layer
52.
The protective layer can be applied to the surface of the nozzle
which will be in contact with the reactive fluid by electroplating,
by explosion plating or by plasma spraying. Plasma spraying is
described in Belgian Pat. No. 623,218 and in U.S. Pat. application
of J. A. F. Sunnen, Ser. No. 742,051, filed July 2, 1968, for
Method and Installation for Forming a Plasma Jet at High
Temperature, and U.S. Pat. application of J. A. F. Sunnen and H. R.
P. J. Schoumaker, Ser. No. 788,209, filed Dec. 31, 1968, for
Heating a Reactive Fluid to High Temperature.
In view of my invention and disclosure, variations and
modifications to meet individual whim or particular need will
doubtless become evident to others skilled in the art, to obtain
all or part of the benefits of my invention without copying the
apparatus and process shown, and I therefore claim all such insofar
as they fall within the reasonable spirit and scope of my
claims.
* * * * *