U.S. patent number 3,578,092 [Application Number 04/526,740] was granted by the patent office on 1971-05-11 for drilling tools.
This patent grant is currently assigned to Farbwerke Hoechst Aktiengesellschaft vormals Meister Lucius & Bruning. Invention is credited to Herbert Becker, Hans Gotte, Gunther Haverkamp, Hans-Jurgen Tesch, Alexander Wacker.
United States Patent |
3,578,092 |
Tesch , et al. |
May 11, 1971 |
DRILLING TOOLS
Abstract
A drilling tool has been provided which has a gastight cavity
therein, the entrance of which cavity is preferably positioned away
from a wear surface of the tool and which cavity contains krypton
.sup.85 as a wear indicating means either for a bearing wear
surface or for an abrasive drilling wear surface. The indicating
means are activated when, because of wear, the cavity is punctured
and krypton .sup.85 escapes or is expelled by means of auxiliary
agents. The method of marking the tools as well as the tools thus
marked are within the scope of the invention. Further, the
improvement in the method of drilling deep bore holes with a tool
possessing these indicating means is similarly within the scope of
the disclosed invention.
Inventors: |
Tesch; Hans-Jurgen (Hannover,
DT), Haverkamp; Gunther (Hamburg, DT),
Becker; Herbert (Frankfurt, Main, DT), Wacker;
Alexander (Frankfurt, Main, DT), Gotte; Hans
(Kelkheim, Taunus, DT) |
Assignee: |
Farbwerke Hoechst
Aktiengesellschaft vormals Meister Lucius & Bruning
(Frankfurt, Main, DT)
|
Family
ID: |
7100409 |
Appl.
No.: |
04/526,740 |
Filed: |
February 11, 1966 |
Foreign Application Priority Data
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Feb 16, 1965 [DT] |
|
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F45,256 |
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Current U.S.
Class: |
175/39 |
Current CPC
Class: |
E21B
12/02 (20130101); B23Q 17/0957 (20130101) |
Current International
Class: |
B23Q
17/09 (20060101); E21B 12/02 (20060101); E21B
12/00 (20060101); E21b 013/00 () |
Field of
Search: |
;175/39,42 ;166/4 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
"Oil & Gas Journal", Publication of August 29, 1955 Pages
77--79 relied on. opy in 166/4.
|
Primary Examiner: Byers, Jr.; Nile C.
Claims
We claim:
1. A drilling tool containing in a closed cavity therein
krypton.sup.85 or a compound thereof, as a gaseous nonionogenic the
cavity being so positioned in the tool that the krypton.sup.85 or
the compound thereof is liberated when the tool has been subjected
to the highest permissible amount of wear.
2. A tool as claimed in claim 1, wherein the krypton.sup.85 is
present in the form of an inclusion compound.
3. A tool as claimed in claim 1, wherein the krypton.sup.85 is
present in the form of a hydroquinone clathrate.
4. A process for marking a drilling tool to indicate when the
highest permissible amount of wear has taken place, the improvement
of which comprises inserting in a cavity in the tool krypton.sup.85
or a compound thereof as a gaseous nonionogenic indicator.
5. A process as claimed in claim 11, wherein the krypton.sup.85 is
present in the form of an inclusion compound.
6. A process as claimed in claim 11, wherein the krypton.sup.85 is
present in the form of a hydroquinone clathrate.
7. In a process for marking tools and instruments for drilling deep
wells with the aid of a circulating drilling fluid using
radioactive tracer substances which serve to indicate the
occurrence of the highest permissible amount of wear and which are
embedded in bore holes in the tools or instruments in such a manner
that upon the occurrence of the highest permissible amount of wear,
these tracer substances occur in the circulating fluid and with it
are carried to the earth's surface, the improvement which comprises
using krypton.sup.85 as a gaseous nonionogenic radioactive tracer
substance in conjunction with a propellant expelling the same from
the tool into the fluid.
8. A process as claimed in claim 7, wherein the krypton.sup.85 is
present in the form of an inclusion compound.
9. A process as claimed in claim 7, wherein the krypton.sup.85 is
present in the form of a hydroquinone clathrate.
10. In a process for drilling deep bore holes by means of a
drilling tool containing indicating means said drilling being aided
by a fluid, the improvement which comprises:
a. placing in the tool in a gastight cavity krypton .sup.85 and an
agent to expel from the tool krypton.sup.85 if needed, said cavity
being placed at a distance away from a wear surface with a filling
opening away from said wear surface for filling said cavity in the
tool, said distance corresponding to the permissible amount of wear
of said surface,
b. indicating a permissible amount of wear of the drilling tool by
puncturing said compartment by abrasive wear of said tool, and
c. recording a wear indicating occurrence of said krypton.sup.85
aided by the drilling fluid acting as a carrier for krypton.sup.85.
Description
The present invention relates to the marking of tools and
instruments used for deep drilling with radioactive tracer
substances which serve to indicate the occurrence of the critical
wear.
When using the drilling instruments which are generally applied for
geological and industrial deep drilling, for example, roller bits,
diamond bits, drilling turbines, reamers and smoothing instruments,
it is necessary to know with a high degree of certainty when a
predetermined, namely the highest permissible, amount of wear has
occurred upon the tools and instruments, which are exposed to a
high stress. In roller bits, for example, an excessive wear on the
roller bearings which are exposed to a very high degree of abrasion
causes the rolls to be out of a true alignment and this may result
in the destruction of the cutter head of the drill bit. Extensive
and expensive locating and catching operations are then necessary
as a result. When the reamers and smoothing instruments have
undergone excessive wear the well bores obtained are badly sized
and this requires a time-consuming additional treatment.
Up to now it has to be judged by experience and feeling whether or
not the highest tolerable service life of such tools and
instruments has been reached. When the tools or instruments are
brought to the surface for visual inspection it turns out in most
cases that they could have been used for a much longer period or
that they should have been replaced already a long time ago because
a dangerous amount of wear has occurred. The removal of the tools
or instruments requires much time and expenditure, especially when
the well is very deep.
It has previously been proposed to indicate to the driller that his
bit has worn away the highest admissible amount by providing the
instruments for drilling deep wells with recesses into which a
radioactive tracer substance is embedded, the recesses being closed
in such a manner that the tracer substance is released as soon as
the highest tolerable amount of wear has occurred whereupon the
radioactive tracer substance becomes suspended or dissolved in the
circulating drilling fluid and is brought in it to the earth's
surface where it is detected by a measuring and indicating
instrument. It has also been proposed to embed in the recesses
provided for this purpose in addition to the tracer substance, a
propellent which when coming into contact with the drilling fluid
decomposes with the evolution of gas and expels the tracer
substance from the recess. It has further been proposed to mark the
propellent itself by a radioactive substance for example, to use as
the propellent sodium amide containing nitrogen.sup.13 or tritium,
an alanate or boranate containing tritium, carbon dioxide
containing carbon.sup.14 or a carbide containing carbon.sup.14. It
has also been proposed to use water-soluble radioactive tracer
substances, for example, a chloride containing chlorine.sup.36 or a
radioactive cation such as potassium.sup.42 , sodium.sup.24 or
cesium.sup.134.
The hitherto known processes have not been used for practical
drilling. Soluble tracer substances cannot be used because they
contaminate the drilling fluid and this has to be avoided at all
costs. Ionogenic tracer substances are not reliable as indicators
in the processes concerned since they may be retained in the well
bore by ion exchange or other interferring effects. Besides, many
of the tracer substances which have been proposed for marking
purposes emit gamma particles which must be prevented from
penetrating into the well bore for they would very much complicate
the measurement of natural radioactivity which has to be carried
out during the drilling operation.
The substances emitting beta particles which have hitherto been
proposed are either not suitable for the marking of drilling
instruments for one of the aforesaid reasons as is for example, the
case with the ionogenic chlorine.sup.36, or they are difficulty
accessible substances such as, for example, carbon.sup.14, which
are too expensive for use in practice or they are substances having
too short a hair life, as is the case with nitrogen.sup.13, or they
are substances emitting very soft beta particles, for example,
tritium, which can only be detected by means of sensitive measuring
instruments which are expensive and not able to withstand the hard
usage at drilling sites.
The present invention provides a process for indicating the
occurrence of the critical amount of wear upon instruments and
tools by means of a radioactive tracer substance in which the
radioactive tracer substance is krypton.sup.85. The tracer
substance is advantageously used in the form of an inclusion
compound. It is particularly advantageous to use krypton.sup.85 in
the form of its clathrate with hydroquinone.
The tracer substance is introduced in known manner into the bore
holes with which the instrument is provided and which are cut open
and release the tracer substance as soon as the critical amount of
wear has occurred.
In cases in which the well bores are deeper than about 300 meters
the proper pressure of the gas released from the inclusion compound
is in general too small as compared with the pressure of the
supernatant liquid column so that the gas cannot leave the bore
hole in which it is embedded. Even in cases in which the gas is
embedded as such in the bore hole the pressure cannot be increased
to any desired degree since the increase of the pressure is limited
by increasing tightening difficulties.
In such a case it is preferred to introduce into the tracer bore
hole not only the tracer substance but also a propellent which when
coming into contact with the drilling fluid decomposes with the
evolution of gas. For this purpose there may be used, for example,
mixtures of water-soluble acids and carbonates. There may also be
used alkali metals, for example, sodium or potassium. It is
particularly advantageous to use hydrides, in particular lithium
hydride or calcium hydride, since these compounds enable a
particularly high yield of gas to be obtained in comparison with
the volume of solid substances introduced.
Embodiments of the invention will now be described by way of
example only with reference to the accompanying drawing in
which
FIG. 1 is a sectional view of a smoothing instrument which has been
marked in accordance with the invention,
FIG. 2 illustrates a roller bit marked in accordance with the
invention.
Referring to FIGS. 1 and 2 the tracer bore hole 1 contains the
tracer substance 2 and, if desired or required, the propellent 3.
The hole is closed by an appropriate closure 5, for example, a
riveted screw or a shrinking closure, so as to be impermeable to
gas. Numerals 4 designate the surfaces of the marked tool which are
exposed to abrasion. The thickness of the material between the bore
hole 1 and the surface 4 is so designed as to correspond to the
highest tolerable amount of wear. As soon as such an amount of
material has been abraded from the surface 4 that the bore hole 1
is cut open the drilling fluid penetrates into the bore hole 1 and
the tracer substance 2 leaves the hole, is carried to the earth's
surface by the drilling fluid and can there be determined by means
of a known counter which by way of known devices can actuate an
indicator, a warning signal or a stopping device.
When the external pressure is high, as is always the case when the
drilling is carried out in a great depth, the discharge of the
tracer substance 2 is supported by the propellent 3 which upon
reacting with the drilling fluid that has entered develops a gas
which expels the tracer substance 2 out of the bore hole 1.
In instruments and tools in which much material is available where
the bore hole for the marking can be made, for example, in
smoothing instruments, the tracer substance may be embedded in the
bore hole in a relatively large, closed capsule which may also
contain the propellent. In such a case the marking need not be
carried out by the manufacturer. It is sufficient to provide the
part to be marked with the bore hole and to introduce the capsule
immediately before use.
The following example serves to illustrate the invention but it is
not intended to limit it thereto.
EXAMPLE
The process according to the invention was tested in practice on a
drilling site in a series of experiments. The results of a typical
test will now be described.
Data of the Drilling
Core boring with a diamond bit;
depth: between 2345.3 and 2363.3 meters
tubing of the well to a depth of 2250 meters
diameter of the well bore in the depth according to the experiment:
216 mm;
geological formation: transition from Zechstein to carboniferous
formation (layers of sandstone and argillaceous slate);
circulating fluid: fluid of clay and brine; total quantity 80 cubic
meters;
speed of circulation of the fluid: 82 minutes per circulation;
throughput of fluid: approximately 1 cubic meter/min. drilling load
at the bottom of the well: 5 to 7 tons;
number of revolutions of the drill poles: 120 revolutions per
minute;
arrangement of the drill poles from bottom to top: diamond head,
core barrel, smoothing instrument, 12 heavy bars, the rest being
normal drill bars.
Test Proceeding
Into appropriate pocket holes disposed in the three ribs of the
smoothing instrument brass capsules were introduced in such a
manner that their points were 1 millimeter below the surface of the
ribs. The upper parts of the capsules were embedded in screws which
had been hollowed by boring, the capsules being thus secured in the
pocket holes. The parts of the screws projecting over the surface
of the ribs were filed off so that the said surface was smooth. The
brass capsules had walls 1 millimeter thick and a total length of
30 millimeters. In their front part which had a length of 20
millimeters they had a diameter of 5.6 millimeters and in their
back part which was designed as a lock they had a diameter of 9
millimeters. In their front parts, which were next to the surface
of the ribs, the capsules contained a mixture of about 100
millicuries of krypton.sup.85 in the form of hydroquinone clathrate
(= 40 milligrams) and 150 milligrams of LiH which latter when
reacting completely with water sufficed to produce at 100.degree.
C. pressure of 1100 atmospheres in the capsule which had a volume
of 0.5 cubic centimeter. At its end the capsule was closed with a
conical lead plug which had been pressed into it by means of a
threaded pin. The place into which the screw was introduced had
been filled with a cold-setting plastic so that no gas could escape
through the threads after the screw had been introduced.
After the smoothing ribs had undergone an abrasion of 1.5 to 2
millimeters during the drilling operation the point of the capsule
was opened, drilling fluid entered the capsule, dissolved the
clathrate and by reacting with the propellent produced hydrogen
which expelled the krypton.sup.85 from the capsule, so that it
entered the ascending fluid. The krypton.sup.85 distributed in the
fluid, one-third of the total quantity of krypton being contained
in the first, uppermost cubic meter of fluid and the rest being
contained in diminishing concentration in the remaining 9 of the 10
cubic meters. Immediately behind the fluid funnel a large area
counter tube was arranged which had a surface of 260 sq.
centimeters and was mounted on a float. The measuring arrangement
comprising counter tube, cathode follower, cable and ratemeter had
a blind counting rate of 600 impulses per minute.
Result
After the first capsule had been perforated by abrasion in the
earth's formation 3.4.times. 10.sup.4 impulses per minute were
first indicated. After the first circulation (82 minutes) only
4.times. 10.sup.3 impulses per minute were indicated had further
dropped to 1.2.times. 10.sup.3, no considerable increase of the
degree of mixing with the fluid taking place. The experiment shows
that 10 millicuries of krypton.sup.85 which corresponds to five
times the blind counting rate are sufficient to produce an alarm.
Also, after another three or four circulations the activity drops
to 1 percent of the value first indicated, so that further
indications will not be disturbed.
* * * * *